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Advancements in organic materials-based nanozymes for broader applications 推进基于有机材料的纳米酶的广泛应用
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-30 DOI: 10.1016/j.trechm.2024.06.007
{"title":"Advancements in organic materials-based nanozymes for broader applications","authors":"","doi":"10.1016/j.trechm.2024.06.007","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.007","url":null,"abstract":"<p>Nanozymes and their constituent substances have primarily relied on inorganic materials. However, researchers now use organic compounds as base materials to create new nanozymes. This review article comprehensively addresses the advent of organic-material-based nanozymes (organic nanozymes) and their broader applications beyond the traditional biomedical and chemical disciplines. It explores the ability of organic nanozymes to address key obstacles of inorganic nanozymes, demonstrating examples and highlighting advancements. The potential impacts and the enhanced capability of organic nanozymes for broader and sustainable applications are succinctly highlighted, and how organic nanozymes will be actively utilized across various domains is envisioned.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"34 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141873089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enantioselective electrochemical and photochemical synthesis of atropisomers 对映选择性电化学和光化学合成阿托品异构体
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-23 DOI: 10.1016/j.trechm.2024.06.013
{"title":"Enantioselective electrochemical and photochemical synthesis of atropisomers","authors":"","doi":"10.1016/j.trechm.2024.06.013","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.013","url":null,"abstract":"<p>The enantioselective synthesis of atropisomers through organic electrochemistry or photochemistry is a valuable and environmentally sustainable alternative to conventional organic synthesis, which has applications in oxidation, reduction, and redox-neutral transformations. These enantioselective reactions have demonstrated considerable potential for rapidly constructing chiral compounds with molecular diversity and complexity. During the past few years, the enantioselective construction of atropisomers via electrochemical and photochemical reactions has reached an impressive level of sophistication and efficiency and has emerged as a powerful tool in synthesis. Our review aims to highlight the enantioselective synthesis of atropisomers through electrochemical and photochemical methods, utilizing transition-metal catalysis and organocatalysis, alongside pinpointing the limitations of existing techniques and potential future development directions.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"54 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141780361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in molybdenum catalyzed asymmetric organic transformations 钼催化不对称有机转化的最新进展
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-23 DOI: 10.1016/j.trechm.2024.06.010
{"title":"Recent advances in molybdenum catalyzed asymmetric organic transformations","authors":"","doi":"10.1016/j.trechm.2024.06.010","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.010","url":null,"abstract":"<p>Transition metal-catalyzed asymmetric organic transformations are powerful tools for the syntheses of chiral building blocks, bioactive molecules, and natural products. Compared with noble transition metals, the development of chiral catalytic systems based on non-noble transition metals is appealing due to their lower cost and ready availability. Among those, the molybdenum complexes are ideal candidates as chiral metal catalysts for catalytic asymmetric organic transformations because of their ready availability and versatile reactivity. The past decades have witnessed advances in the development of chiral Mo-complexes and their application in catalytic asymmetric organic transformations. This review article summarizes the development of several types of chiral Mo-complexes and highlights recent advances in Mo-catalyzed asymmetric organic transformations.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"47 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141780360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Chemistry Women Mentorship Network: women helping women climb higher in chemistry 化学女性导师网络：女性帮助女性在化学领域更上一层楼
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-20 DOI: 10.1016/j.trechm.2024.06.012
{"title":"The Chemistry Women Mentorship Network: women helping women climb higher in chemistry","authors":"","doi":"10.1016/j.trechm.2024.06.012","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.012","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"49 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential for light-induced separation of critical rare-earth elements 光诱导分离临界稀土元素的潜力
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-20 DOI: 10.1016/j.trechm.2024.06.006
{"title":"Potential for light-induced separation of critical rare-earth elements","authors":"","doi":"10.1016/j.trechm.2024.06.006","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.006","url":null,"abstract":"<p>Current methods for separations of critical rare earth elements (REEs) require multi-step, waste-generating procedures that lack the ability to selectively separate similarly sized ions, despite such an onerous process. REEs possess unique optoelectronic properties that are often exploited for photomagnetic or photoluminescent applications but could be harnessed to drive element selective separations. Recent work exploring photochemical reactions of REE complexes points to promise for investigating alternative separations using photoactive molecules and macromolecular frameworks, highlighting a possible pathway towards realizing practical REE separations to increase the sustainability and longevity of mining and recycling these elements.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"46 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Meet our emerging leaders in chemistry – part II 认识我们的化学新领袖--第二部分
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-19 DOI: 10.1016/j.trechm.2024.06.011
{"title":"Meet our emerging leaders in chemistry – part II","authors":"","doi":"10.1016/j.trechm.2024.06.011","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.011","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"162 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Subscription and Copyright Information 订阅和版权信息
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-10 DOI: 10.1016/s2589-5974(24)00123-0
{"title":"Subscription and Copyright Information","authors":"","doi":"10.1016/s2589-5974(24)00123-0","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00123-0","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"34 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141584988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advisory Board and Contents 咨询委员会和内容
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-10 DOI: 10.1016/s2589-5974(24)00120-5
{"title":"Advisory Board and Contents","authors":"","doi":"10.1016/s2589-5974(24)00120-5","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00120-5","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"34 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141584985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontiers of NHC catalysis: radical and site-selective reactions NHC 催化前沿：自由基和位点选择性反应
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-09 DOI: 10.1016/j.trechm.2024.06.005
Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi
{"title":"Frontiers of NHC catalysis: radical and site-selective reactions","authors":"Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi","doi":"10.1016/j.trechm.2024.06.005","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.005","url":null,"abstract":"<p>Previous work focused on (N-heterocyclic carbene) NHC catalysis has mainly centered on forming new chemical bonds and controlling stereoselectivity through electron-pair transfer processes. While these topics remain interesting and impactful, we envisioned that NHC catalysis can offer unique opportunities in radical chemistry and site-selective reactions of sophisticated molecules bearing multiple functional groups with similar reactivities.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"40 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141568379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical conjugation innovations for protein nanoparticles 蛋白质纳米颗粒的化学共轭创新
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-04 DOI: 10.1016/j.trechm.2024.06.004
Mark G. Legendre, Virginia H. Pistilli, Gozde S. Demirer
{"title":"Chemical conjugation innovations for protein nanoparticles","authors":"Mark G. Legendre, Virginia H. Pistilli, Gozde S. Demirer","doi":"10.1016/j.trechm.2024.06.004","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.004","url":null,"abstract":"<p>Protein nanoparticles (PNPs) present versatile platforms for cargo delivery due to their modularity, biocompatibility, and self-assembled structures. PNPs have benefited greatly from developments in bioorthogonal covalent attachment chemistries, which enable efficient post-translational cargo loading. In this paper, we review recent advancements in bioorthogonal strategies for cargo loading onto PNPs, including methods for chemical functionalization of natural scaffolds and the use of established click chemistries. We also discuss how protein engineering strategies, including genetically encoded ligation systems and non-canonical amino acid incorporation, have conferred even greater specificity and control to cargo loading and delivery. We conclude the review with applications and future directions of PNPs in crop and soil sciences, with insights on their translation to industry and agriculture.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"30 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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