{"title":"Recent advances in molybdenum catalyzed asymmetric organic transformations","authors":"","doi":"10.1016/j.trechm.2024.06.010","DOIUrl":null,"url":null,"abstract":"<p>Transition metal-catalyzed asymmetric organic transformations are powerful tools for the syntheses of chiral building blocks, bioactive molecules, and natural products. Compared with noble transition metals, the development of chiral catalytic systems based on non-noble transition metals is appealing due to their lower cost and ready availability. Among those, the molybdenum complexes are ideal candidates as chiral metal catalysts for catalytic asymmetric organic transformations because of their ready availability and versatile reactivity. The past decades have witnessed advances in the development of chiral Mo-complexes and their application in catalytic asymmetric organic transformations. This review article summarizes the development of several types of chiral Mo-complexes and highlights recent advances in Mo-catalyzed asymmetric organic transformations.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"47 1","pages":""},"PeriodicalIF":14.0000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Trends in Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.trechm.2024.06.010","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Transition metal-catalyzed asymmetric organic transformations are powerful tools for the syntheses of chiral building blocks, bioactive molecules, and natural products. Compared with noble transition metals, the development of chiral catalytic systems based on non-noble transition metals is appealing due to their lower cost and ready availability. Among those, the molybdenum complexes are ideal candidates as chiral metal catalysts for catalytic asymmetric organic transformations because of their ready availability and versatile reactivity. The past decades have witnessed advances in the development of chiral Mo-complexes and their application in catalytic asymmetric organic transformations. This review article summarizes the development of several types of chiral Mo-complexes and highlights recent advances in Mo-catalyzed asymmetric organic transformations.
期刊介绍：
Trends in Chemistry serves as a new global platform for discussing significant and transformative concepts across all areas of chemistry. It recognizes that breakthroughs in chemistry hold the key to addressing major global challenges. The journal offers readable, multidisciplinary articles, including reviews, opinions, and short pieces, designed to keep both students and leading scientists updated on pressing issues in the field.
Covering analytical, inorganic, organic, physical, and theoretical chemistry, the journal highlights major themes such as biochemistry, catalysis, environmental chemistry, materials, medicine, polymers, and supramolecular chemistry. It also welcomes articles on chemical education, health and safety, policy and public relations, and ethics and law.
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