Applied Physics A最新文献

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Correction: NiO nanosheet-assembled chemiresistive sensor for NO2 detection 更正:用于二氧化氮检测的氧化镍纳米片组装化学电阻传感器
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-03 DOI: 10.1007/s00339-025-08466-2
Ravishankar R. Ambi, Rahul A. Mali, Aniket B. Pawar, Moshim G. Mulla, Raj K. Pittala
{"title":"Correction: NiO nanosheet-assembled chemiresistive sensor for NO2 detection","authors":"Ravishankar R. Ambi, Rahul A. Mali, Aniket B. Pawar, Moshim G. Mulla, Raj K. Pittala","doi":"10.1007/s00339-025-08466-2","DOIUrl":"10.1007/s00339-025-08466-2","url":null,"abstract":"","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 5","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143761662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Notable peak voltage and sensitivity as well as optical-communication of the inclined Bi2Sr2CuOy thin film with different wavelength lasers 倾斜 Bi2Sr2CuOy 薄膜与不同波长激光器的显著峰值电压、灵敏度和光通信性能
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-03 DOI: 10.1007/s00339-025-08484-0
Xianwu Tang, Yanchao Zhang, Ming Liu, Yuxuan Jiang, Xueyao Lu, Gangyi Zhu, Yongjin Wang, Xuebin Zhu
{"title":"Notable peak voltage and sensitivity as well as optical-communication of the inclined Bi2Sr2CuOy thin film with different wavelength lasers","authors":"Xianwu Tang,&nbsp;Yanchao Zhang,&nbsp;Ming Liu,&nbsp;Yuxuan Jiang,&nbsp;Xueyao Lu,&nbsp;Gangyi Zhu,&nbsp;Yongjin Wang,&nbsp;Xuebin Zhu","doi":"10.1007/s00339-025-08484-0","DOIUrl":"10.1007/s00339-025-08484-0","url":null,"abstract":"<div><p>In this work, the laser-induced thermoelectric voltage (LITV) of the solution-deposited inclined Bi<sub>2</sub>Sr<sub>2</sub>CuO<sub>y</sub> (BSCO) thin films with different wavelength semiconductor lasers was investigated. Microstructure results indicate the BSCO thin film inclined growth along the substrate with the same angle. Obvious LITV keeps a linear increase with the increased power density for each wavelength laser. The peak voltage is over 40 mV at the power density of 40 mW/cm<sup>2</sup>. It is slightly different with the laser wavelength, caused by the difference in optical absorption and light penetration depth. The sensitivity is higher than 0.8 and increases to 1.15 V·cm<sup>2</sup>/W with the laser changes from green to ultraviolet. Furthermore, based on the LITV effect of the BSCO thin film, the carry information can be transmitted and decoded correctly via the optical communications system composed of the light diode laser. All these results demonstrate the potential application and favorable properties of the inclined BSCO thin films in broad-spectrum response of photodetection.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 5","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143761661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controlled co-precipitation synthesis of Gd and Mn doped zinc tungstate: insights into structural, optical, magnetic behavior, and dielectric properties
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-02 DOI: 10.1007/s00339-025-08399-w
Sadegh Azadmehr, Sanaz Alamdari, Majid Jafar Tafreshi, Zaighum Tanveer, Omid Mirzaee, Aliasghar Najafzadehkhoee, Jose J. Velázquez
{"title":"Controlled co-precipitation synthesis of Gd and Mn doped zinc tungstate: insights into structural, optical, magnetic behavior, and dielectric properties","authors":"Sadegh Azadmehr,&nbsp;Sanaz Alamdari,&nbsp;Majid Jafar Tafreshi,&nbsp;Zaighum Tanveer,&nbsp;Omid Mirzaee,&nbsp;Aliasghar Najafzadehkhoee,&nbsp;Jose J. Velázquez","doi":"10.1007/s00339-025-08399-w","DOIUrl":"10.1007/s00339-025-08399-w","url":null,"abstract":"<div><p>Gadolinium and manganese-doped zinc tungstate (ZnWO₄: Gd &amp; ZnWO₄: Mn (1 at%)) nanocrystals were successfully prepared using a simple co-precipitation method. The structural, morphological, and chemical properties of the materials were thoroughly investigated using X-ray diffraction (XRD), scanning/transmission electron microscopy (SEM/TEM), and energy dispersive X-ray (EDX) analysis. The crystallite sizes of the Gd-doped and Mn-doped samples were 46 nm and 59 nm, respectively. XRD analysis confirmed that both samples exhibited a single monoclinic phase crystal structure. The Gd-doping resulted in a more uniform particle size distribution and smoother surface morphology, which could enhance the optical and magnetic properties of the material. In contrast, Mn-doping led to the formation of more agglomerated particles with a rougher texture, potentially affecting the specific surface area and its interaction with external fields. SEM/TEM images also revealed an increase in average particle size with the Mn dopant. Optical properties, as measured by diffuse reflectance spectroscopy (DRS), showed a band gap of 3.79 eV for ZnWO₄: Gd and 3.40 eV for ZnWO₄: Mn. Magnetic measurements indicated enhanced magnetic properties for ZnWO₄: Mn compared to both pure ZnWO₄ and ZnWO₄: Gd. The dielectric properties, including the dielectric constant (εr), dielectric loss (tan δ), and AC conductivity, were studied over a frequency range from 100 Hz to 3 MHz at room temperature. The reduced coercivity observed in the Mn-doped sample suggests improved performance for potential applications in transformers, windings, and magnetic storage devices, where reduced core loss and enhanced efficiency are key requirements.This study not only enhances the understanding of the influence of Gd and Mn doping on ZnWO₄ properties but also opens up new possibilities for the development of multifunctional materials for advanced technological applications.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 5","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on laser processing characteristics of single-crystal diamond with different pulse widths
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-01 DOI: 10.1007/s00339-025-08461-7
Jiancai Zhang, Jiadong Lan, Jiabin Lu, Ziyuan Luo, Qiusheng Yan, Shaolin Xu
{"title":"Study on laser processing characteristics of single-crystal diamond with different pulse widths","authors":"Jiancai Zhang,&nbsp;Jiadong Lan,&nbsp;Jiabin Lu,&nbsp;Ziyuan Luo,&nbsp;Qiusheng Yan,&nbsp;Shaolin Xu","doi":"10.1007/s00339-025-08461-7","DOIUrl":"10.1007/s00339-025-08461-7","url":null,"abstract":"<div><p>Due to challenges and low efficiency in processing single-crystal diamonds, its large-scale application has been limited. However, laser processing emerges as an effective method for diamond machining, where the laser pulse width plays a crucial role in determining processing efficiency and quality. In this study, we utilized lasers with different pulse widths ranging from 300 fs to 3 ps, to perform microgrooving on the surface of a single-crystal diamond. Our research focused on evaluating various aspects, including the ablation threshold, material removal rate (MRR), microgroove dimensions, surface morphology, bottom region roughness, and material removal mechanisms of single-crystal diamonds under different laser pulse widths. The primary objective was to investigate the processing characteristics and the corresponding variations of single-crystal diamonds under these different laser pulse width conditions. The results of our study reveal that ultra-short pulse lasers with varying pulse widths significantly influence the ablation threshold, MRR, microgroove dimensions, surface morphology, and roughness of diamonds through their peak power. Remarkably, reducing the laser pulse width from 3 ps to 300 fs resulted in an impressive 75% decrease in the diamond ablation threshold. Additionally, the microgroove dimensions and <i>MRR</i> demonstrated gradual increments. Particularly, during the high average power stage, the influence of pulse width on groove depth and <i>MRR</i> became more pronounced due to incubation effects and plasma shielding. Another notable finding was the evolution of the surface morphology of diamond microgrooves, transitioning from periodic ripple structures to the appearance of damage, cracks, and even microgroove fragmentation. Moreover, the roughness (Rz) of the microgroove bottom region increased from 40 to 264 nm. While the effect of laser pulse width on the material removal mechanism of diamond was relatively weak, it was observed to induce less subsurface damage (sp<sup>3</sup> + sp<sup>2</sup>). Additionally, in our experimental conditions, we detected the involvement of oxygen in the laser processing of diamonds. However, the main material removal mechanisms were identified to be evaporation or sublimation.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies on morphology, conduction mechanism and dielectric properties of Li2ZrO3 prepared using solid-state reaction
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-01 DOI: 10.1007/s00339-025-08455-5
Imen Ibrahmi, Samia Aydi, Sondes Hajlaoui, Raja Naouari, Iskandar Chaabane, Abderrazek Oueslati
{"title":"Studies on morphology, conduction mechanism and dielectric properties of Li2ZrO3 prepared using solid-state reaction","authors":"Imen Ibrahmi,&nbsp;Samia Aydi,&nbsp;Sondes Hajlaoui,&nbsp;Raja Naouari,&nbsp;Iskandar Chaabane,&nbsp;Abderrazek Oueslati","doi":"10.1007/s00339-025-08455-5","DOIUrl":"10.1007/s00339-025-08455-5","url":null,"abstract":"<div><p>The ceramic materials have recently found a vast variety of applications due to their outstanding structurale and photoluminisenece characteristics. However, despite the promising properties of these materials, there remains a need to explore novel performance for practical applications. For this reason, we focus is on addressing this scientific challenge by synthesizing and characterizing the Li<sub>2</sub>ZrO<sub>3</sub>. In the present work Li<sub>2</sub>ZrO<sub>3</sub> is prepared via solid state process. X-ray diffraction reveals that the compound has a well-defined crystalline structure in the monoclinic phase having a C2/c space group. Scanning electronic microscope indicated a compact microstructure and well grown grains separated by grain boundaries. Furthermore, we also use the complex impedance spectroscopy method to report the electrical and dielectric characteristics of Li<sub>2</sub>ZrO<sub>3</sub> in the 100–10<sup>6</sup> Hz frequency range. Over a temperature range of 353–573 K, the conductivity measurements of the produced ceramic are examined. In addition, the Nyquist plots revealed contributions from both the grains and the grain boundaries suggesting that the material demonstrates a relaxation behaviour characteristic of the non Debye type and provide reasons supporting the semi conducting nature of this sample. In addition, dielectric analysis demonstrated significant frequency-dependent behavior, characterized by various polarization effects and relaxation phenomena. Jonscher’s power law is used to analyze alternating current and conductivity, and it is found that the fluctuation of the exponent “s” adequately describes the conduction mechanism and agrees with CBH models. The findings demonstrate that LZO holds significant potential for various technological applications, including energy storage, micoelectronic devices, highlighting the potential they hold as multifunctional materials.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Buried interface engineering with amphoteric ion for inverted perovskite solar cells
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-01 DOI: 10.1007/s00339-025-08372-7
Liquan Zhang, Zhuo Chen, Jiayu Han, Tingfeng Wang, Chongyang Xu, Sheng Wu, Zhihai Liu
{"title":"Buried interface engineering with amphoteric ion for inverted perovskite solar cells","authors":"Liquan Zhang,&nbsp;Zhuo Chen,&nbsp;Jiayu Han,&nbsp;Tingfeng Wang,&nbsp;Chongyang Xu,&nbsp;Sheng Wu,&nbsp;Zhihai Liu","doi":"10.1007/s00339-025-08372-7","DOIUrl":"10.1007/s00339-025-08372-7","url":null,"abstract":"<div><p>The efficiency of perovskite solar cells (PSCs) primarily depends on the quality of the perovskite films. The buried interface, located at the bottom surface of the perovskite layer, significantly influences the performance of perovskite photovoltaics. This study utilizes cetyltrimethylammonium bromide (CTAB), an amphoteric organic salt, on the surface of poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT: PSS) to modify the bottom interface between the perovskite film and the hole transport layer. The ammonium group and bromine ion in CTAB can passivate vacancy defects at the PEDOT: PSS/perovskite interface, while the long carbon chain enhances the humidity stability of PEDOT: PSS. The application of CTAB significantly improved the photoelectric performance of PSCs, increasing the power conversion efficiency (PCE) from 15.16 to 17.30%, with excellent reproducibility. The unencapsulated device retained over 60% of its initial PCE after 400 h. As an emerging technology, modifying the buried interface of the perovskite film presents new strategies for achieving high-performance and long-lasting PSCs.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The enhancement of the optical, magnetic, and ferroelectric properties of BaTiO3-δ by doping with SrFeO3-δ
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-01 DOI: 10.1007/s00339-025-08398-x
E. K. Abdel-Khalek, A. Abd El-Naser, E. Nabhan, M. S. Gaafar, N. S. Abd El-Aal
{"title":"The enhancement of the optical, magnetic, and ferroelectric properties of BaTiO3-δ by doping with SrFeO3-δ","authors":"E. K. Abdel-Khalek,&nbsp;A. Abd El-Naser,&nbsp;E. Nabhan,&nbsp;M. S. Gaafar,&nbsp;N. S. Abd El-Aal","doi":"10.1007/s00339-025-08398-x","DOIUrl":"10.1007/s00339-025-08398-x","url":null,"abstract":"<div><p>In the present work, (1-x) BaTiO<sub>3-δ</sub> − xSrFeO<sub>3-δ</sub> (where x = 0 and 0.05) perovskite samples were prepared. The structure of these samples was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), high-resolution TEM (HR-TEM), EDS elemental mapping, X-ray photoelectron spectroscopy (XPS) and differential scanning calorimetry (DSC). The optical properties of BaTiO<sub>3-δ</sub> were enhanced with introducing SrFeO<sub>3-δ</sub> (x = 0.05) by the reduction of the direct and indirect band gap energies. The magnetic measurements of these samples confirmed the ferromagnetic ordering and it was enhanced with introducing SrFeO<sub>3-δ</sub> (x = 0.05). The dielectric constant (ε<sub>r</sub>) of BaTiO<sub>3-δ</sub> enhanced with introducing SrFeO<sub>3-δ</sub> (x = 0.05). The polarization-electric field (P-E) hysteresis loops and the bipolar strain-electric field (S-E) loops measurements showed that these samples have ferroelectric and piezoelectric nature, respectively. The sample at x = 0.05 showed good ability to generate ultrasonic waves with nominal frequency of proximately 5 MHz.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00339-025-08398-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive evaluation of thermal, structural, magnetic, and radiation shielding properties of CuAlNi and CuAlNi-X (X = Co, CoFe, CoFeMn, CoFeMnCr) high-temperature shape memory alloys
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-04-01 DOI: 10.1007/s00339-025-08444-8
İskender Özkul, Oktay Karaduman, Telem Şimşek, Tuncay Şimşek, Canan Aksu Canbay, Ömer Güler, Mert Hüseyin Şan, Ghada ALMisned, H. O. Tekin
{"title":"Comprehensive evaluation of thermal, structural, magnetic, and radiation shielding properties of CuAlNi and CuAlNi-X (X = Co, CoFe, CoFeMn, CoFeMnCr) high-temperature shape memory alloys","authors":"İskender Özkul,&nbsp;Oktay Karaduman,&nbsp;Telem Şimşek,&nbsp;Tuncay Şimşek,&nbsp;Canan Aksu Canbay,&nbsp;Ömer Güler,&nbsp;Mert Hüseyin Şan,&nbsp;Ghada ALMisned,&nbsp;H. O. Tekin","doi":"10.1007/s00339-025-08444-8","DOIUrl":"10.1007/s00339-025-08444-8","url":null,"abstract":"<div><p>This study investigates the thermal, structural, magnetic, and radiation shielding properties of CuAlNi-based high-temperature shape memory alloys (HTSMAs) enhanced through sequential alloying with Co, Fe, Mn, and Cr. Five different variants were produced, designated as CRef (reference CuAlNi alloy), CCo (CuAlNiCo), CFe (CuAlNiCoFe), CMn (CuAlNiCoFeMn), and CCr (CuAlNiCoFeMnCr). Differential scanning calorimetry (DSC) confirmed the presence of reversible martensitic transformations in all alloys, with Co and Mn additions significantly enhancing thermal stability. Structural analyses using X-ray diffraction (XRD) and microscopy showed significant grain refinement and phase transitions, while magnetic measurements highlighted the strong ferromagnetic response of CCo (CuAlNiCo) and the increased coercivity of CMn (CuAlNiCoFeMn) due to domain-pinning effects. Moreover, radiation shielding analyses demonstrated the critical influence of density and elemental composition, with CRef exhibiting superior linear attenuation coefficients (LAC), effective atomic number (Zeff), and energy absorption buildup factor (EBF) performance, attributed to its optimized Cu fraction and high density (7.1296 g/cm<sup>3</sup>). In contrast, CMn (CuAlNiCoFeMn) showed the weakest shielding properties due to reduced density and Mn content. Among the samples, CRef emerged as the superior alloy, demonstrating exceptional multifunctionality across all evaluated parameters, while CCr (CuAlNiCoFeMnCr) displayed synergistic properties, combining shape memory behavior with competitive shielding efficiency. It can be concluded that CuAlNi-based HTSMAs hold significant potential as multifunctional materials, particularly for nuclear safety and aerospace engineering applications, where adaptive functionality and radiation protection are critical.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating the thermoelectric power factor of AlPbTe2 thin film grown by thermal evaporation route
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-03-31 DOI: 10.1007/s00339-025-08465-3
M. Yasir Ali, Adnan Ali, Khalid Mehmood, Ahmed H. Ragab, Meznah M. Alanazi, Tagreed Wael Alghamdi, Arslan Ashfaq
{"title":"Investigating the thermoelectric power factor of AlPbTe2 thin film grown by thermal evaporation route","authors":"M. Yasir Ali,&nbsp;Adnan Ali,&nbsp;Khalid Mehmood,&nbsp;Ahmed H. Ragab,&nbsp;Meznah M. Alanazi,&nbsp;Tagreed Wael Alghamdi,&nbsp;Arslan Ashfaq","doi":"10.1007/s00339-025-08465-3","DOIUrl":"10.1007/s00339-025-08465-3","url":null,"abstract":"<div><p>In this study, the thermoelectric properties of AlPbTe<sub>2</sub> thin films are investigated with a focus on the effects of post-annealing on their structural, electrical, and thermoelectric performance. X-ray diffraction (XRD) analysis reveals that the maximum peak intensity is observed after 1 h of post-annealing, with a subsequent decrease in intensity up to 3 h, while additional peaks become more prominent in the 3-hour sample, indicating enhanced polycrystallinity. Scanning electron microscope (SEM) images show grain growth and structural changes with post-annealing time, where small grains coalesce into larger grains, followed by crack formation after 3 h of annealing. Electrical conductivity increases from 320 S/cm in the as-grown sample to 545 S/cm in the 3-hour post-annealed sample, although conductivity decreases with increasing measurement temperature from 300 to 450 K, due to phonon scattering. The charge carrier concentration also increases significantly from 1.05 × 10<sup>20</sup> cm<sup>− 3</sup> to 2.59 × 10<sup>20</sup> cm<sup>− 3</sup> after 3 h of post-annealing, while charge carrier mobility decreases due to carrier-carrier scattering. The Seebeck coefficient is negative, confirming n-type behavior, and increases with temperature across all samples. The 1-hour post-annealed sample shows the highest Seebeck coefficient, peaking at 242 µV/K at 450 K. Finally, the thermoelectric power factor of the 1-hour post-annealed sample reaches a maximum of 24.4 µWcm<sup>− 1</sup>K<sup>− 2</sup> at 400 K, highlighting the improved thermoelectric performance at mid-temperatures.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of PA6-PVA composite fiber membrane based on coaxial spinning method and wettability study
IF 2.5 4区 材料科学
Applied Physics A Pub Date : 2025-03-31 DOI: 10.1007/s00339-025-08471-5
Sun Yingting, Shi Yao, Yin Jinghui, Ma Teng, Zhang Yonghu, Xiong Xiaoqin, Zhang Xiaolei, Liu Jianxin
{"title":"Preparation of PA6-PVA composite fiber membrane based on coaxial spinning method and wettability study","authors":"Sun Yingting,&nbsp;Shi Yao,&nbsp;Yin Jinghui,&nbsp;Ma Teng,&nbsp;Zhang Yonghu,&nbsp;Xiong Xiaoqin,&nbsp;Zhang Xiaolei,&nbsp;Liu Jianxin","doi":"10.1007/s00339-025-08471-5","DOIUrl":"10.1007/s00339-025-08471-5","url":null,"abstract":"<div><p>Membrane separation technology is widely employed for the treatment of oily wastewater. Nevertheless, the wettability characteristics of the membrane present a constraint on the rate at which the oil-water mixture can permeate through it. This research presents an innovative methodology involving the fabrication of a double-layer composite fiber membrane via coaxial electrospinning. The process employs polyvinyl alcohol (PVA) fibers to form the composite fiber shell, while nylon fibers (PA6) serve as the inner core. The results indicate that the composite membrane made from PA6-PVA fiber exhibits advantageous hydrophilic properties and superoleophobic characteristics, as evidenced by a contact angle of 60° for water in air and 150° for oil submerged in water. Furthermore, the stable membrane flux of the PA6-PVA composite fiber membrane was found to be approximately double that of the PA6 fiber membrane. This investigation presents a viable technique for integrating PA6 into oil-water separation applications.</p></div>","PeriodicalId":473,"journal":{"name":"Applied Physics A","volume":"131 4","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143740655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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