Applied Nanoscience最新文献

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Exploring SrTiO3 nanoparticles thereby unveiling the impact of europium (Eu3⁺) doping 探索SrTiO3纳米颗粒,从而揭示铕(Eu3 +)掺杂的影响
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2025-01-11 DOI: 10.1007/s13204-024-03079-2
K. Greeshma, K. M. Nissamudeen, Amrutha K. Adiyodi, V. P. Veena, C. K. Shilpa, S. V. Jasira, S. S. Ancy
{"title":"Exploring SrTiO3 nanoparticles thereby unveiling the impact of europium (Eu3⁺) doping","authors":"K. Greeshma,&nbsp;K. M. Nissamudeen,&nbsp;Amrutha K. Adiyodi,&nbsp;V. P. Veena,&nbsp;C. K. Shilpa,&nbsp;S. V. Jasira,&nbsp;S. S. Ancy","doi":"10.1007/s13204-024-03079-2","DOIUrl":"10.1007/s13204-024-03079-2","url":null,"abstract":"<div><p>SrTiO₃ is an interesting as well as evolving material with various applications in electronics, optics, and energy storage. This work includes synthesis and investigation of the different properties of strontium titanate nanoparticles and their effect on doping with rare-earth europium. Rare-earth functionalized materials are ruling the optoelectronic industry due to their characteristic emission properties. Known for its simplicity and cost-effectiveness, the combustion method is used for the successful synthesis of SrTiO<sub>3</sub> nanoparticles. The structural characteristics of the synthesized samples were accurately analyzed using X-ray diffraction (XRD) and found a particle-size difference from (10–15) nm with different dopant percentages of europium. Scanning electron microscopy (SEM) was performed to detect the morphology of the sample and obtain small moong beans-like agglomeration, and Raman spectroscopy was carried out to find the different bonding formations due to its structure. Photoluminescence (PL) spectroscopy was carried out to investigate the optical properties of both pure and Eu<sup>3</sup>⁺-doped SrTiO₃, revealing significant enhancements in luminescent efficiency due to doping concentration. Furthermore, the shift in the bandgap from (3.4 eV–3.2 eV) resulting from europium doping was examined using a UV–Vis spectrometer, demonstrating a noticeable change in optical absorption properties. The CIE parameter is calculated for an excitation wavelength of 395 nm and studied its emission spectra and rare emission in pink color. This study offers valuable insights into the potential applications of Eu<sup>3</sup>⁺doped SrTiO₃ nanoparticles in various technological fields, particularly optoelectronic devices like displays and advanced materials.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"15 1","pages":""},"PeriodicalIF":3.674,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance SiO2, GO, and SiO2@GO nanomaterials on fabricating new polymer nanocomposites for optical, antibacterial, and anticancer applications 二氧化硅、氧化石墨烯和SiO2@GO纳米材料在光学、抗菌和抗癌领域的应用
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2025-01-11 DOI: 10.1007/s13204-024-03080-9
Sara J. Ahmed, Ehssan Al-Bermany
{"title":"Performance SiO2, GO, and SiO2@GO nanomaterials on fabricating new polymer nanocomposites for optical, antibacterial, and anticancer applications","authors":"Sara J. Ahmed,&nbsp;Ehssan Al-Bermany","doi":"10.1007/s13204-024-03080-9","DOIUrl":"10.1007/s13204-024-03080-9","url":null,"abstract":"<div><p>Hybrid nanomaterials-based polymer nanocomposites have achieved unique properties for multiple applications. This investigation focused on the impact of the synthesis of graphene oxide (GO) or silicon oxide (SiO2) nanomaterials (NM) with the combination of SiO2@GO as hybrid nanomaterials (HNMs). Either SiO<sub>2</sub> or GO and SiO@GO HNMs were utilized to reinforce blended polycaprolactone (PCL) and polyethyleneimine (PEI) to fabricate new PCL–PEI/SiO<sub>2</sub>, PCL–PEI/GO, and PCL–PEI/SiO<sub>2</sub>@GO nanocomposites using a developed acoustic-mixing-sonications procedure. Fourier transform infrared analysis reveals substantial interfacial bonds among blended polymers, SiO<sub>2,</sub> nanoparticles, and GO nanosheets in nanocomposites<sub>.</sub> The X-ray diffraction confirms the semi-crystalline nature of samples. Optical and field emission electron microscopy revealed homogenous and rough surfaces turned to smother with the contribution of nanomaterials. Incorporating NM and HNMs in the matrix presented transition elections at 240 nm, significantly improving compared with the blend polymer. HNMs contributions notably reduced the energy gap of the blended PCL–PEI polymers from 3.4 to 1.92 eV and 2.97 to 0.75 eV for allowed and forbidden transitions, respectively. HNMs showed the best efficacy against Gram-negative <i>P. aeruginosa</i> bacteria up to 30 mm and Gram-positive (<i>E. faecalis)</i> up to 16 mm compared to blended polymers. Using the MTT assay, the toxic effect of (PCL–PEI/SiO<sub>2</sub>@GO) nanocomposites against breast cancer cells was notable, growing with concentration and toxic effect on cancer cells. Combining two nanomaterials presented results instead of one nanomaterial, making nanocomposites excellent candidates for several advanced applications, including optoelectronic devices, disinfectants, and antimicrobial materials.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"15 1","pages":""},"PeriodicalIF":3.674,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties of single-walled carbon nanotube film/Si heterojunctions fabricated in situ 原位制备单壁碳纳米管薄膜/硅异质结的性能
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2025-01-04 DOI: 10.1007/s13204-024-03078-3
L. A. Dronina, N. G. Kovalchuk, I. V. Komissarov, A. L. Danilyuk, V. A. Labunov, E. V. Lutsenko, A. V. Danilchyk, P. I. Gaiduk, Roman Sobolewski, M. Salvato, S. L. Prischepa
{"title":"Properties of single-walled carbon nanotube film/Si heterojunctions fabricated in situ","authors":"L. A. Dronina,&nbsp;N. G. Kovalchuk,&nbsp;I. V. Komissarov,&nbsp;A. L. Danilyuk,&nbsp;V. A. Labunov,&nbsp;E. V. Lutsenko,&nbsp;A. V. Danilchyk,&nbsp;P. I. Gaiduk,&nbsp;Roman Sobolewski,&nbsp;M. Salvato,&nbsp;S. L. Prischepa","doi":"10.1007/s13204-024-03078-3","DOIUrl":"10.1007/s13204-024-03078-3","url":null,"abstract":"<div><p>Single-walled carbon nanotube (SWCNT) film/Si heterojunctions were obtained by depositing SWCNT films directly on a Si substrate by the floating catalyst chemical vapor deposition. The single-walled nature of the nanotubes was proven and confirmed by Raman and infrared spectroscopy, respectively. An additional ethanol post-growth treatment improved the properties of the heterojunctions by increasing densification of SWCNTs and decreasing their sheet resistance. Peaks positions of radial breathing mode obtained from the Raman mapping analysis demonstrated a random chirality (varying between armchair and zigzag) of tube structures and their very narrow diameter distribution, centered at ≈ 1.06 nm. This latter result was also confirmed by infrared spectroscopy. Properties of SWCNT/Si heterojunctions, such as ideality factor, Schottky barrier height, series resistance, SWCNT film work function and density of interface states are presented. To obtain the last two parameters by a self-consistent method, the intermediate nanolayer of silicon oxide between the SWCNT film and Si is considered. Impact of interface states and the native silicon oxide at the SWCNT/Si interface on the properties of heterojunctions is also discussed. Finally, such basic optoelectronic figures of merit as the responsivity, detectivity, and external quantum efficiency in the visible spectral range were determined and found to be comparable to the best reported for other SWCNT-based photodetectors.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"15 1","pages":""},"PeriodicalIF":3.674,"publicationDate":"2025-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142925640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in silver nanoparticles: unraveling biological activities, mechanisms of action, and toxicity 纳米银的研究进展:揭示其生物活性、作用机制和毒性
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-12-24 DOI: 10.1007/s13204-024-03076-5
Hien Thi Thu Do, Ngoc Phuong Uyen Nguyen, Shamsaldeen Ibrahim Saeed, Ngoc Tung Dang, Linh Doan, Thi Thu Hoai Nguyen
{"title":"Advances in silver nanoparticles: unraveling biological activities, mechanisms of action, and toxicity","authors":"Hien Thi Thu Do,&nbsp;Ngoc Phuong Uyen Nguyen,&nbsp;Shamsaldeen Ibrahim Saeed,&nbsp;Ngoc Tung Dang,&nbsp;Linh Doan,&nbsp;Thi Thu Hoai Nguyen","doi":"10.1007/s13204-024-03076-5","DOIUrl":"10.1007/s13204-024-03076-5","url":null,"abstract":"<div><p>Silver nanoparticles (AgNPs) have demonstrated exceptional antimicrobial activity, effectively targeting bacterial, fungal, and viral pathogens. This broad-spectrum antimicrobial efficacy makes AgNPs a valuable co-treatment alongside antibiotics, potentially mitigating the growing issue of antimicrobial resistance. Beyond their antimicrobial properties, AgNPs exhibit significant anticancer activity, employing mechanisms such as apoptosis induction and the inhibition of tumor growth and metastasis to selectively target cancer cells. Furthermore, AgNPs exhibit antioxidant potential of scavenging free radicals and reducing oxidative stress within biological systems. While AgNPs are non-toxic to humans at low concentrations, their toxicity is influenced by many factors besides concentration such as size, shape and surface charge. These multifaceted properties of AgNPs underscore the their potential in medical and therapeutic applications, such as wound dressings, catheters, medical devices, health supplement drink as well as targeted drug delivery. This study provides an overview of the characteristics of AgNPs, their diverse bioactivities, and the evidence supporting their mechanisms for effectively inhibiting bacterial growth, viral replication, cancer proliferation, and metastasis. Additionally, updated information on the toxicity, biosafety, and recent medical applications of AgNPs is discussed.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"15 1","pages":""},"PeriodicalIF":3.674,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative evaluation of antibacterial efficacy of silver nanoparticles synthesized with Cannabis sativa extract at different concentrations 不同浓度大麻提取物合成的银纳米粒子的抗菌效果比较评估
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-11-23 DOI: 10.1007/s13204-024-03073-8
Yehidi Medina Castillo, Lourdes Fabiola Cárdenas Guevara, R. J. Rincón, G. A. Murillo Romero, Johana Niño Abella, Jahaziel Amaya, Daniel LLamosa Perez
{"title":"Comparative evaluation of antibacterial efficacy of silver nanoparticles synthesized with Cannabis sativa extract at different concentrations","authors":"Yehidi Medina Castillo,&nbsp;Lourdes Fabiola Cárdenas Guevara,&nbsp;R. J. Rincón,&nbsp;G. A. Murillo Romero,&nbsp;Johana Niño Abella,&nbsp;Jahaziel Amaya,&nbsp;Daniel LLamosa Perez","doi":"10.1007/s13204-024-03073-8","DOIUrl":"10.1007/s13204-024-03073-8","url":null,"abstract":"<div><p>In recent years, concern about the rise of super-resistant bacteria and the environmental pollution associated with the inappropriate use of antibiotics and the waste generated during their production has grown significantly. In response to this problem, innovative solutions have been proposed, such as the use of silver nanoparticles (AgNP), recognized for their potent antimicrobial properties against a wide range of organisms, including pathogenic bacteria. This study presents an innovative and environmentally friendly approach to the synthesis of silver nanoparticles using sonotrode, where <i>Cannabis sativa</i> extract acts as a reducing agent, replacing sodium borohydride (NaBH<sub>4</sub>), a commonly used but highly polluting and carcinogenic chemical reagent. The research explored the use of different concentrations of <i>C. sativa</i> in the green synthesis of AgNP, evaluating their physicochemical properties and antimicrobial efficacy. To confirm the concentration, chemical composition and structural features of the nanoparticles, techniques such as atomic absorption spectroscopy (AAS), dispersion X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy were employed. Scanning electron microscopy (SEM) analysis revealed details about the morphology and average size of the silver nanoparticles. Finally, the antibacterial efficacy of the nanoparticles was evaluated by the agar dilution method, underlining the potential of this innovative approach in the fight against resistant bacteria and environmental pollution. The results obtained show that the 0.5% Bio-AgNPs samples produced 53% nanoparticles, while the 2% Bio-AgNPs produced 87%. EDX analysis confirmed the presence of silver (Ag), while FTIR spectra indicated the presence of phenols, flavonoids, amino groups, alkanes, and alkenes. Ag–Ag metal bond vibrations were observed in Raman spectroscopy, and SEM analysis revealed the formation of predominantly spherical nanoparticles with sizes less than 50 nm. Furthermore, bacteriological assays demonstrated that 50, 25, and 12.5 ppm concentrations of C-AgNPs and Bio-AgNPs showed significant inhibition, highlighting that 2% <i>C. sativa</i> provided the best antimicrobial property. The observed biocompatibility, successful reduction of silver nitrate, and remarkable antibacterial efficacy of the synthesized nanoparticles underline the great potential of green synthesis strategies in nanoparticle production. These findings suggest that nanoparticles synthesized using this method are not only effective, but also compatible with an environmentally sustainable approach.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 12","pages":"1139 - 1155"},"PeriodicalIF":3.674,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142736919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic and electrochemical characterization of magnetite nanoparticles modified with tetrahydroxyquinone 用四羟基苯醌修饰的磁铁矿纳米颗粒的磁性和电化学特征
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-11-21 DOI: 10.1007/s13204-024-03070-x
A. G. González-Gutiérrez, Raúl R. Quiñonez-López, M. E. Cano, L. H. Quintero, Norberto Casillas
{"title":"Magnetic and electrochemical characterization of magnetite nanoparticles modified with tetrahydroxyquinone","authors":"A. G. González-Gutiérrez,&nbsp;Raúl R. Quiñonez-López,&nbsp;M. E. Cano,&nbsp;L. H. Quintero,&nbsp;Norberto Casillas","doi":"10.1007/s13204-024-03070-x","DOIUrl":"10.1007/s13204-024-03070-x","url":null,"abstract":"<div><p>This study presents a method for synthesizing superparamagnetic nanoparticles through the co-precipitation method, with a coating of tetrahydroxy-1,4-quinone (THQ). The diameter of the magnetite nanoparticles (MNPs) covered with THQ varied depending on the recovery method applied. When collected through magnetic decantation, they exhibited an average diameter of 15 ± 3 nm, while centrifugation of the supernatant further reduced the diameter to 12 ± 3 nm. In contrast, the uncoated MNPs had an average diameter of 17 ± 5 nm. The smaller MNPs coated with THQ displayed very low magnetic hysteresis and demonstrated superparamagnetic behavior, indicated by a blocking temperature of less than 300 K. Characterization of both the coated and uncoated MNPs encompassed structural, morphological, size, and magnetic property analyses using X-ray diffraction (XRD), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM), respectively. Fourier-transform infrared spectroscopy (FT-IR) and UV–Vis spectroscopy were employed to investigate the chemical interaction between THQ and the MNPs. In addition, cyclic voltammetry was used to compare the electrochemical changes of THQ, MNPs, and MNPs coated with THQ.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 12","pages":"1103 - 1113"},"PeriodicalIF":3.674,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142737132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction Note: FeNi nanotubes: perspective tool for targeted delivery 撤稿说明:铁镍纳米管:定向输送的透视工具
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-10-21 DOI: 10.1007/s13204-024-03075-6
Egor Kaniukov, Alena Shumskaya, Dzmitry Yakimchuk, Artem Kozlovskiy, Ilya Korolkov, Milana Ibragimova, Maxim Zdorovets, Kairat Kadyrzhanov, Vyacheslav Rusakov, Maxim Fadeev, Eugenia Lobko, Кristina Saunina, Larisa Nikolaevich
{"title":"Retraction Note: FeNi nanotubes: perspective tool for targeted delivery","authors":"Egor Kaniukov,&nbsp;Alena Shumskaya,&nbsp;Dzmitry Yakimchuk,&nbsp;Artem Kozlovskiy,&nbsp;Ilya Korolkov,&nbsp;Milana Ibragimova,&nbsp;Maxim Zdorovets,&nbsp;Kairat Kadyrzhanov,&nbsp;Vyacheslav Rusakov,&nbsp;Maxim Fadeev,&nbsp;Eugenia Lobko,&nbsp;Кristina Saunina,&nbsp;Larisa Nikolaevich","doi":"10.1007/s13204-024-03075-6","DOIUrl":"10.1007/s13204-024-03075-6","url":null,"abstract":"","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 12","pages":"1171 - 1171"},"PeriodicalIF":3.674,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142737136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, optical, and down-conversion properties of 100% pure vermilion-emitting Y2O3:Sm3+, Gd3+ for latent wLED applications 用于潜在发光二极管应用的 100% 纯朱砂发光 Y2O3:Sm3+, Gd3+ 的结构、光学和下转换特性
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-10-08 DOI: 10.1007/s13204-024-03074-7
V. P. Veena, K. Vini, S. S. Ancy, K. M. Nissamudeen
{"title":"Structural, optical, and down-conversion properties of 100% pure vermilion-emitting Y2O3:Sm3+, Gd3+ for latent wLED applications","authors":"V. P. Veena,&nbsp;K. Vini,&nbsp;S. S. Ancy,&nbsp;K. M. Nissamudeen","doi":"10.1007/s13204-024-03074-7","DOIUrl":"10.1007/s13204-024-03074-7","url":null,"abstract":"<div><p>This study focuses on the facile combustion synthesis of highly luminescent Y<sub>2</sub>O<sub>3</sub>:Sm<sup>3+</sup>, Gd<sup>3+</sup> nanophosphors, bringing down the thermal budget to a minimum of 500 K. When Sm<sup>3+</sup> ions are doped in the Y<sub>2</sub>O<sub>3</sub> cubic crystal system of bandgap 5.6 eV and studied under a down-conversion excitation of 260 nm, the emission spectra offered an intense vermilion color at 608 nm due to the <sup>4</sup>G<sub>5/2</sub> → <sup>6</sup>H<sub>7/2</sub> transition within the Sm<sup>3+</sup> ions. The Y<sub>2</sub>O<sub>3</sub>:2wt%Sm<sup>3+</sup> matrix is co-doped with 3wt%Gd<sup>3+</sup>, highlighting 100% pure vermilion emission 4.21 times higher than doped samples, which is a perfect choice for domestic lightening owing to better eye compatibility. Further, post-annealing is performed to improve the structural parameters and luminescence properties, creating sufficient alterations in the crystal lattice. It is professed that Y<sub>2</sub>O<sub>3</sub>:Sm<sup>3+</sup>, Gd<sup>3+</sup> nanophosphors can be effectively used in optoelectronic devices, owing to their enhanced crystallinity and photoluminescence properties resulting from the Gd<sup>3+</sup> → Sm<sup>3+</sup> energy transfer efficiency of 75.15%.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 12","pages":"1157 - 1170"},"PeriodicalIF":3.674,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142737062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced performance of graphene-based tin oxide hybrid nanostructures for ammonia gas detection 增强石墨烯基氧化锡混合纳米结构在氨气检测中的性能
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-09-28 DOI: 10.1007/s13204-024-03071-w
Abdul Shakoor, Javed Hussain, Sofia Siddique, Muhammad Arshad, Imtiaz Ahmad, Yasir A. Haleem, Areebah Abrar, Saqlain A. Shah
{"title":"Enhanced performance of graphene-based tin oxide hybrid nanostructures for ammonia gas detection","authors":"Abdul Shakoor,&nbsp;Javed Hussain,&nbsp;Sofia Siddique,&nbsp;Muhammad Arshad,&nbsp;Imtiaz Ahmad,&nbsp;Yasir A. Haleem,&nbsp;Areebah Abrar,&nbsp;Saqlain A. Shah","doi":"10.1007/s13204-024-03071-w","DOIUrl":"10.1007/s13204-024-03071-w","url":null,"abstract":"<div><p>Ammonia gas detection has garnered widespread attention in various fields, including food, environmental industries, and medical diagnostics. In this article, we present the synthesis of graphene-based tin oxide (graphene–SnO<sub>2</sub>) hybrid nanostructures using the hydrothermal method. Pristine tin oxide nanostructures and a series of graphene-based tin oxide hybrids containing 5 wt.%, 10 wt. %, 15 wt. %, and 20 wt. % graphene concentrations were fabricated to investigate their response as ammonia gas sensors. The X-ray diffraction and high-resolution transmission electron microscopy analysis revealed the tetragonal rutile crystal structure of both pristine SnO<sub>2</sub> and graphene–SnO<sub>2</sub> hybrid structures. The morphology of the synthesized structures was examined using scanning electron microscopy. Fourier transform infrared spectroscopy was employed to validate the functional groups present in the hybrid structures, while the band gap of the graphene–SnO<sub>2</sub> nanohybrid structures was determined using diffuse reflectance spectroscopy. X-ray photoelectron spectroscopy was utilized to investigate the chemical composition, electronic state, and bonding of the materials. Four probe current–voltage (I–V) measurements were conducted to investigate conductivity and ammonia-sensing behavior. Upon exposure to ammonia gas fumes, the pristine SnO<sub>2</sub> exhibited changes in current and resistance, ranging from 0.063 mA to 3.75 mA and 15.87 kΩ to 266.67 Ω, respectively. Similarly, the ammonia sensing behavior of hybrid structures containing 20 wt. % graphene showed changes in current and resistance, ranging from 5.42 mA to 37.8 mA and 0.18 kΩ to 26.45 Ω, respectively. These findings suggest that graphene–SnO<sub>2</sub> hybrid structures exhibit excellent conductivity when exposed to NH<sub>3</sub> gas, unlike their ammonia-absence counterparts.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 12","pages":"1125 - 1137"},"PeriodicalIF":3.674,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142737100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave-assisted biosynthesis of silver nanoparticles for potential antibacterial activity 微波辅助生物合成具有潜在抗菌活性的银纳米粒子
IF 3.674 4区 工程技术
Applied Nanoscience Pub Date : 2024-09-25 DOI: 10.1007/s13204-024-03072-9
Anuskha Kala, Santoshi Uniyal, Krati Saini, Reena Dhyani, Deepika Joshi, Rashmi Verma, Kamal K. Kar, Pankaj Chamoli
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