M. M. Krupa, Yu. B. Skirta, A. Kravets, S. M. Konoplyuk
{"title":"Retraction Note: Electric transport effects in Sr2FeMoO6 with SrMoO4 tunneling barriers","authors":"M. M. Krupa, Yu. B. Skirta, A. Kravets, S. M. Konoplyuk","doi":"10.1007/s13204-023-02990-4","DOIUrl":"10.1007/s13204-023-02990-4","url":null,"abstract":"","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 3","pages":"603 - 603"},"PeriodicalIF":3.674,"publicationDate":"2023-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142409984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nagarajan Usharani, Swarna V. Kanth, Natarajan Saravanan
{"title":"Biomimetic nanomaterials for pulmonary infections: A prospective view in drug delivery systems","authors":"Nagarajan Usharani, Swarna V. Kanth, Natarajan Saravanan","doi":"10.1007/s13204-023-02981-5","DOIUrl":"10.1007/s13204-023-02981-5","url":null,"abstract":"<div><p>Respiratory infections are quite challenging due to their complexity in ailments and composition of viral genetic material and their rate of proliferation. In particular, the eradication of viral illness is still a concern, irrespective of advancements in prevention and remedial procedures. The nature of the viral particle with the possibility of rapid transmission is prone to attach on the deposited surface for days together. This antigen expulses due to sneezing or coughing resulted in multiphase turbulent flow, contaminates the surroundings and is carried away by simple touch or inhalation and find newer hosts for instance, SARSCoV-2 aerosols remain viable for about an hour leading to infection. The present review focuses on the remedial aspects of respiratory infections through a knowledge-based approach towards nanosystems. The complete understanding of standard antiviral drugs and the remodelling of these drugs through nanosystems still is the need of the hour. The genetic material and epidemiology of viral antigen, help in redefining standard drugs along with nanocarriers to achieve more feasible and hour-based approach. The main goal of this review is to elaborate on the repurposing of existing standard antiviral drugs and ways to accelerate their mode of action to promote a feasible and hour-based approach. The consolidated three-dimensional approaches aimed at sustained, targeted and optimized levels of drug concentration in the circulating system along with bioactive nanocarriers which could effectively pass the cell membrane were reported. The platforms for nanomaterial evolution depend on nature of source, size, structure, and their unique functionalities (Stable, speedy, and long-lasting recovery procedure). However, the research activities and literature on coronavirus have been overwhelming but the information on the sustainability of nanotherapy in SARS-CoV-2 is still in the developmental stage. Hereby, the clinical aspects of SARS-CoV-2 and the eradication strategy developed for antiviral infections through nanotechnology will pave the way ahead for treating upcoming new variants or other pandemics.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 2","pages":"363 - 373"},"PeriodicalIF":3.674,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138495978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu. I. Venhryn, A. S. Serednytski, S. A. Korniy, D. I. Popovych, S. I. Mudry
{"title":"Photoluminescent properties in different gas ambient of ZnO nanopowders doped by Mo and V","authors":"Yu. I. Venhryn, A. S. Serednytski, S. A. Korniy, D. I. Popovych, S. I. Mudry","doi":"10.1007/s13204-023-02961-9","DOIUrl":"10.1007/s13204-023-02961-9","url":null,"abstract":"<div><p>This study investigated the structural, morphological, and photoluminescent properties of ZnO nanopowders doped with Mo and V, which were synthesized using pulsed laser reactive technology. The nanoparticles’ structure, shape, and size were determined using electron microscopy and X-ray diffractometry. The photoluminescence properties of the Mo- and V-doped ZnO nanopowders in different gas environments were studied, revealing that changes in the gas environment led to significant alterations in the intensity and deformation of the photoluminescence spectra. All samples exhibited strong emission bands in the UV range and a broad, non-elemental emission band in the visible region ranging from 410 to 600 nm. Decomposing the photoluminescence spectra into elementary bands revealed peaks at 430 and 520 nm. Chromaticity diagrams of the photoluminescence light emitted by the nanopowders were obtained, and it was found that the color coordinates varied depending on the gas environment, which could be useful in gas sensors.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"13 12","pages":"7631 - 7636"},"PeriodicalIF":3.674,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138517133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of bismuth-doped praseodymium ortho ferrite nanomaterials for LPG sensing","authors":"Keval Bharati, Prabhat Ranjan Tiwari, Rahul Pratap Singh, Ajeet Singh, Bal Chandra Yadav, Manish Pratap Singh, Santosh Kumar","doi":"10.1007/s13204-023-02976-2","DOIUrl":"10.1007/s13204-023-02976-2","url":null,"abstract":"<div><p>Liquefied petroleum gas (LPG) is used as fuel for cooking, heating, and transportation globally. This gas is highly inflammable, poisonous, explosive, and hazardous, and it creates several health issues when inhaled. Thus, its leakage detection is of the utmost importance. There are several sensors used for LPG detection, but they have a high operating temperature; therefore, developing sensors that work at normal temperatures has always been a challenge. This paper describes the synthesis of bismuth (Bi)-doped Praseodymium orthoferrite (PrFeO<sub>3</sub>) nanomaterials by the sol–gel self-combustion technique and their application in LPG detection. The synthesized nanomaterials were characterized using powder X-ray diffraction (PXRD), field emission scanning electron microscope (FESEM), Brunauer–Emmett–Teller (BET), ultraviolet–visible spectroscopy (UV–Vis), and Fourier transform infrared spectroscopy (FTIR). PXRD reveals that the synthesized nanomaterial has an orthorhombic structure with the Pbnm space group, and the crystallite size (D) changes from 30 to 41 nm. FESEM was used for the analysis of surface morphology. BET analysis reveals the mesoporous nature of synthesized nanomaterials with a 16.331 to 37.645 m<sup>2</sup>g<sup>−1</sup> specific surface area. UV–Vis spectroscopy affirms the optical energy band gap lying between 2.27 and 1.95 eV. The FTIR study represents the existence of different functional groups and their lattice vibration. Synthesized nanomaterials were explored as an LPG detector working at room temperature for the first time. Different sensing parameters have been evaluated. The gas sensing studies reveal that the response and recovery times are 15.3 and 22.4 s for 0.5 vol% of LPG, and the sensor shows high selectivity towards LPG. This study reveals that the designed sensor is capable of working at room temperature, and the synthesized nanomaterials are promising for LPG sensing.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 2","pages":"277 - 289"},"PeriodicalIF":3.674,"publicationDate":"2023-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138517134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Prafulla Kumar Behera, Deepak Sahu, Sarat K. Swain, Priyaranjan Mohapatra
{"title":"Capsule-shaped nano silver-embedded reduced graphene oxide nanocomposites for sensing of mercury ions","authors":"Prafulla Kumar Behera, Deepak Sahu, Sarat K. Swain, Priyaranjan Mohapatra","doi":"10.1007/s13204-023-02980-6","DOIUrl":"10.1007/s13204-023-02980-6","url":null,"abstract":"<div><p>Capsule-shaped nano silver-based reduced graphene oxide nanocomposites (RGO–Ag) are prepared using “one pot” synthetic protocol. Herein, we have taken tamarind leaf extract for the reduction of Ag<sup>+</sup> ion which has been used towards the synthesis of RGO–Ag nanocomposites. Different temperature conditions are considered for the optimization of formation of nanoparticles. Scanning electron microscope (SEM) has been used to find out the micrograph of as-synthesized nanocomposites. From SEM image, capsule-shaped nanocomposites can be clearly observed. The as-synthesized nanocomposites display a better response to Hg<sup>2+</sup>(aq) in pH 4.0–10. There is negligible effect of other ions for the recognition of Hg<sup>2+</sup> (aq) ion and, therefore, as-synthesized nanocomposites can be used for the sensitive and selective recognition of mercury (II) ion in aqueous phase. Since tamarind leaf extract has been used as reducing agent and water is used as solvent, it is a green and eco-friendly process. The recognition limit of Hg<sup>2+</sup> ion in water sample is found to be 15 nM.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 2","pages":"353 - 361"},"PeriodicalIF":3.674,"publicationDate":"2023-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138517115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effects of length, diameter, and doping on the thermal transport in carbon nanotubes: a molecular dynamics study","authors":"P. S. Ebin, Jeetu S. Babu","doi":"10.1007/s13204-023-02979-z","DOIUrl":"10.1007/s13204-023-02979-z","url":null,"abstract":"<div><p>In this study, we have investigated numerous influential factors such as length, diameter, impurity introduction, and vacancy defects on the thermal conductivity of carbon nanotubes (CNTs). These investigations were conducted through molecular dynamics simulations using the large-scale atomic/molecular massively parallel simulator (LAMMPS). It is observed that longer CNTs tend to exhibit heightened thermal conductivity, a consequence of the increased support for phonon vibration modes that facilitate efficient thermal transport. Furthermore, CNTs with larger diameters display superior thermal characteristics owing to reduced phonon scattering effects. The introduction of boron doping reduces CNTs thermal conductivity by approximately 3% with the inclusion of 6% boron atoms, whereas nitrogen doping increases it by a similar margin. These doping effects hold great potential for optimizing the performance of MEMS and NEMS devices. This duality in doping offers a versatile means to fine-tune the thermal conductivity of CNTs, enabling effective heat management in micro/nanodevices. By strategically modulating thermal conductivity, we can optimize the heat transfer properties of CNT-based materials and devices. This optimization is of utmost importance in ensuring efficient heat dissipation and averting thermal-induced issues, such as overheating, performance degradation, or failure. Additionally, this paper explores how vacancy defects impact the thermal conductivity of CNTs. By varying the vacancy concentration from 1 to 6%, a decrease in thermal conductivity of approximately 2% to 4% was observed in both SWCNTs and DWCNTs. These results emphasize the pivotal role of defects in perturbing the efficient phonon transport mechanisms in CNTs and suggest the potential for customizing CNTs with specific defect concentrations to enhance their suitability for thermoelectric devices and thermal insulation materials.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 2","pages":"339 - 351"},"PeriodicalIF":3.674,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138517121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ana Laura Curcio, Marcio Peron Franco de Godoy, Ariano De Giovanni Rodrigues
{"title":"Raman spectroscopy as a method for structural characterization of ZnO-based systems at the nanoscale","authors":"Ana Laura Curcio, Marcio Peron Franco de Godoy, Ariano De Giovanni Rodrigues","doi":"10.1007/s13204-023-02978-0","DOIUrl":"10.1007/s13204-023-02978-0","url":null,"abstract":"<div><p>We present a straightforward method for determining the crystalline coherence length (<i>D</i><sub>c</sub>) of ZnO-based systems with long-range order in the scale of tens of nanometers. The proposed equation enables calculating <i>D</i><sub>c</sub> by simply utilizing the intensities of two peaks of a Raman measurement, namely: <i>D</i><sub>c</sub> = <i>A</i> (<i>I</i><sub><i>E</i>1(LO)</sub>/<i>I</i><sub><i>E</i>2</sub><sup>high</sup>) + 66.5, where <i>I</i><sub><i>E</i>1(LO)</sub> and <i>I</i><sub><i>E</i>2</sub><sup>high</sup> are the intensities of E<sub>1</sub>(LO) and E<sub>2</sub><sup>high</sup> Raman peaks, respectively, and the coefficient <i>A</i> depends on the laser wavelength used as excitation. Such methodology can be applied to measurements taken with most of the visible lasers available for Raman experiments. Based on the results of photoluminescence analyses, it can be inferred that the relative intensities of these Raman peaks are influenced by both <i>D</i><sub>c</sub> and the exciting laser wavelength, owing to resonance processes that selectively involve phonons out of the Brillouin Zone center. A significant competitive advantage of this method stands out in the fact that Raman spectra are very sensitive even to slight structural modifications that are below the detection limit of conventional characterization techniques, such as X-ray diffraction, and the versatile and easy way of performing in-situ analyses, in addition to the possibility to take measurements with microscopic spatial resolution without the demand for large X-ray sources or synchrotron environments.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 1","pages":"269 - 275"},"PeriodicalIF":3.674,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138495961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Manisha Thakur, Charanjeet Singh, Kirill D. Martinson, Ivan V. Buryanenko, Valentin G. Semenov, Sanjay R. Mishra, Md Farhan Azim, A. K. Srivastava, Vadim I. Popkov
{"title":"Exploration of structural, Mössbauer, and hysteresis performance metrics of SrCoxZnxFe12−2xO19 hexaferrite for recording applications","authors":"Manisha Thakur, Charanjeet Singh, Kirill D. Martinson, Ivan V. Buryanenko, Valentin G. Semenov, Sanjay R. Mishra, Md Farhan Azim, A. K. Srivastava, Vadim I. Popkov","doi":"10.1007/s13204-023-02975-3","DOIUrl":"10.1007/s13204-023-02975-3","url":null,"abstract":"<div><p>The present study aims to improve the magnetic properties with tunable coercivity of SrM hexaferrite by substituted Co and Zn ions instead of Fe and to elucidate in detail the changes in their structural, morphological, and site occupancy characteristics. Sr<span>({text{Co}}_x {text{Zn}}_x {text{Fe}}_{12 - 2x} {text{O}}_{19})</span> (Co, Zn; <i>x</i> = 0.4, 0.8, 1.2, 1.6 and 2.0) powders were synthesized by the autocombustion sol–gel method. Substitution of Co–Zn ions caused the formation of magnetoplumbite and a secondary phase (CoFe<sub>2</sub>O<sub>4</sub>) in the structure. Increasing the Co–Zn content ratio led to a nonlinear increment in crystallite size ranging from 41.9 to 49.8 nm. SEM micrographs depicted platelet-shaped hexagonal particles that were nano-scale in thickness and micro-scale in diameter. Mössbauer spectra revealed that the substituent tends to occupy both spin-up sites 12k-2a-2b and spin-down sites 4<i>f</i><sub>1</sub> and 4<i>f</i><sub>2</sub> of crystal lattice from <i>x</i> = 0.4 to <i>x</i> = 2.0, which elucidate meagre change observed in magnetization, as per literature. The saturation magnetization (<i>M</i><sub><i>s</i></sub>) and remanent magnetization (<i>M</i><sub><i>r</i></sub>) were higher than the initial values of <i>M</i><sub><i>s</i></sub> = 75.26 emu/g and <i>M</i><sub><i>r</i></sub> = 26.95 emu/g. The highest coercivity and saturation magnetization was observed as, 4159 Oe and 80 emu/g, respectively, for <i>x</i> = 2.0. The squareness ratio (<i>M</i><sub><i>r</i></sub>/<i>M</i><sub><i>s</i></sub>) of <i>x</i> = 1.6 and <i>x</i> = 2.0 samples, was observed to be greater than 0.5, elucidating the existence of single-domain particles. The magnetic parameters <i>M</i><sub><i>s</i></sub> with tunable <i>H</i><sub>c</sub>, <i>M</i><sub><i>r</i></sub>/<i>M</i><sub><i>s</i></sub>, and magnetic susceptibility (d<i>M/</i>d<i>H</i>) results make the synthesized sample considerable for recording applications.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 1","pages":"251 - 267"},"PeriodicalIF":3.674,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135391209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Arun, Debabrata Barik, Prabhakar Sharma, Ali Etem Gürel, Ümit Ağbulut, Bhaskar Jyoti Medhi, Bhaskor Jyoti Bora
{"title":"Experimental and CFD analysis of dimple tube parabolic trough solar water heater with various nanofluids","authors":"M. Arun, Debabrata Barik, Prabhakar Sharma, Ali Etem Gürel, Ümit Ağbulut, Bhaskar Jyoti Medhi, Bhaskor Jyoti Bora","doi":"10.1007/s13204-023-02977-1","DOIUrl":"10.1007/s13204-023-02977-1","url":null,"abstract":"<div><p>A solar collector is a device used to absorb energy from the sun by collecting solar radiation and turning it into electricity or heat. The material type and coating of a solar collector are utilized to enhance solar energy absorption. This research combines experimental and computational methods to examine the performance of a parabolic-type plate solar water heater (PTSWH). The nanoparticles-DI water at a rate of mass flow (MFR) of 0.5–3.0 kg/min in 0.5 kg/min increments were used in a tube-in-tube heat exchanger featuring dimpled inner tubes with a pressure-to-diameter (P/D) ratio of 3. The researchers examined the fluid flow patterns and heat transfer efficiency in a dimple texture tube using nanoparticles of TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, CuO, and SiO<sub>2</sub> with a size range of 10–15 nm and a volume concentration (VC) of 0.1–0.5% in increments of 0.1%. Computational Fluid Dynamics (CFD) was used to explore and verify the impact of nanoparticle concentration on the PTSWH. It was revealed that CuO /DI-H<sub>2</sub>O at a nanoparticles VC of 0.3% and a MFR of 2.5 kg/min yielded the best PTSWH performance. With a nanoparticle concentration of 0.3% and MFR of 2.5 kg/min, the efficiency of PTSWH was increased by approximately 34.3% for TiO<sub>2</sub>, 32.3% for Al<sub>2</sub>O<sub>3</sub>, 38.4% for CuO, and 36.4% for SiO<sub>2</sub>. The results also show that the solar water heater’s thermal efficiency rose steadily with the rise in MFR. At a MFR of 2.5 kg/min, Cu/DI-H<sub>2</sub>O was found to have a higher Nusselt number than TiO<sub>2</sub>/DI-H<sub>2</sub>O, Al<sub>2</sub>O<sub>3</sub>/DI-H<sub>2</sub>O, and SiO<sub>2</sub>/DI-H<sub>2</sub>O, respectively, by 10.5%, 8.2%, and 5%. TiO<sub>2</sub>/DI-H<sub>2</sub>O, Al<sub>2</sub>O<sub>3</sub>/DI-H<sub>2</sub>O, Cu/DI-H<sub>2</sub>O, and SiO<sub>2</sub>/DI-H<sub>2</sub>O nanoparticle-coated dimple texturing tubes all had lower friction coefficients than a plain tube did. Finally, a comparison was made between the experimental and simulated data, and the overall variation of ± 3.1% was found to be within an acceptable range.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 2","pages":"291 - 337"},"PeriodicalIF":3.674,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135589324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y. Slimani, M. A. Almessiere, A. Baykal, A. Demir Korkmaz, I. A. Auwal
{"title":"Impression of partial replacement of Fe3+ by Sn4+ ion on structural and magnetic features of NiCuZn nanospinel ferrites","authors":"Y. Slimani, M. A. Almessiere, A. Baykal, A. Demir Korkmaz, I. A. Auwal","doi":"10.1007/s13204-023-02974-4","DOIUrl":"10.1007/s13204-023-02974-4","url":null,"abstract":"<div><p>In the current study, Ni<sub>0.4</sub>Cu<sub>0.2</sub>Zn<sub>0.4</sub>Fe<sub>2−4x</sub>Sn<sub>3x</sub>O<sub>4</sub> (Sn → NiCuZn) (x ≤ 0.10) nanospinel ferrites (NSFs) have been fabricated by a citrate sol–gel approach, and their structure, morphology, and magnetic features were investigated via XRD, SEM with EDX, HR-TEM, TEM, and VSM, respectively. Their cubic spinel phase was endorsed from their Rietveld refinement. The products’ D<sub>XRD</sub> (crystallite sizes) were estimated within the 36–69 nm range. The 10 and 300 K magnetization measurements show ferromagnetic and superparamagnetic behaviors, respectively. The saturation magnetization (M<sub>s</sub>) decreases at both temperatures with increasing Sn ratio up to <i>x</i> = 0.06 into the lattice of NSFs but thereafter rises with the additional rise of Sn ratio from 0.06 to 0.10. The alterations of M<sub>s</sub> values with Sn substitution have been deliberated via cation redistribution, and changes in the anisotropy constant. H<sub>c</sub> value at 10 K almost initially increased for lower Sn content and then decreased at higher Sn content. The coercivity is in reverse proportionality to the particle/crystallite size and domain wall movement of ferromagnetism.</p></div>","PeriodicalId":471,"journal":{"name":"Applied Nanoscience","volume":"14 1","pages":"241 - 249"},"PeriodicalIF":3.674,"publicationDate":"2023-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136158467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}