Adsorption最新文献_第6页

Efficient calculation of the equilibrium composition in multicomponent batch adsorption with the steric mass action model 用立体质量作用模型高效计算多组分间歇吸附平衡组成

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-30 DOI: 10.1007/s10450-024-00580-6

Norbert Kaiblinger, Rainer Hahn, Giorgio Carta

{"title":"Efficient calculation of the equilibrium composition in multicomponent batch adsorption with the steric mass action model","authors":"Norbert Kaiblinger, Rainer Hahn, Giorgio Carta","doi":"10.1007/s10450-024-00580-6","DOIUrl":"10.1007/s10450-024-00580-6","url":null,"abstract":"<div><p>Streamlined relationships are derived to predict the equilibrium composition in batch adsorption when the isotherm is described by the steric mass action (SMA) model, which is used extensively to represent macromolecule adsorption on ion exchange resins. In the general case with <i>N</i> components, the approach reduces the mathematical problem from a system of 2<i>N</i> equations to a single non-linear algebraic equation whose numerical solution is easily found. A graphical approach is also presented where isotherm lines describing mixture equilibrium values of the adsorbed concentrations of each component are plotted against the equilibrium solution concentration of a common reference species. In this case, the actual equilibrium composition is obtained at the intercept of the reference component equilibrium curve with the straight line representing the material balance for the reference species. Analytical expressions are provided for two and three-component mixtures. The graphical approach provides insight on the effects of the ratio of adsorbent and solution volumes on the equilibrium composition.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10450-024-00580-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142906040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Adsorption-biased characterization of porous solids 多孔固体的吸附偏置特性

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-30 DOI: 10.1007/s10450-024-00565-5

Katsumi Kaneko

{"title":"Adsorption-biased characterization of porous solids","authors":"Katsumi Kaneko","doi":"10.1007/s10450-024-00565-5","DOIUrl":"10.1007/s10450-024-00565-5","url":null,"abstract":"<div><p>This article summarizes opening address in 9th Characterization of Porous Materials (CPM9). The role and historical sketch of main adsorption-based conferences such as Fundamentals of Adsorption (FOA), Characterization of Porous Solids (COPS), Pacific Basin Conference on Adsorption Science and Technology (PBAST), and Characterization of Porous Materials (CPM) are given. The unique role of CPM in adsorption-based characterization of porous materials is introduced in the above conferences. The concerted stimulation between innovated well-defined nanoporous materials and modernized adsorption studies supported by new theoretical and experimental approaches have given rise to quite active research activities mentioned above. The brief research activities of author’s group, which have aimed to bridge experimental and theoretical studies, are described; they have introduced in-situ X-ray diffraction, in-situ small angle X-ray scattering, high resolution adsorption measurement even from ultrahigh vacuum range, wide-temperature range in-situ IR spectroscopy for elucidation of the intermolecular structure of molecules adsorbed in nanopores. Also, future scope of the research on characterization of porous solids is proposed.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10450-024-00565-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142906052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal-loaded porous materials made from gold tailings: preparation and application in pollutants adsorption 金尾矿载金属多孔材料的制备及其在污染物吸附中的应用

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-26 DOI: 10.1007/s10450-024-00554-8

Ning Yang, Yinghua Li, Yuxin Li, Shutong Yang, Sinan Liu, Fei Su, Jie Qian

{"title":"Metal-loaded porous materials made from gold tailings: preparation and application in pollutants adsorption","authors":"Ning Yang, Yinghua Li, Yuxin Li, Shutong Yang, Sinan Liu, Fei Su, Jie Qian","doi":"10.1007/s10450-024-00554-8","DOIUrl":"10.1007/s10450-024-00554-8","url":null,"abstract":"<div><p>In this study, gold tailings were modified as a carrier and loaded with iron oxides. The composites with different Fe<sub>2</sub>O<sub>3</sub> doping were prepared by adjusting the mass ratio of Fe<sub>2</sub>O<sub>3</sub>/modified slag (Fe<sub>2</sub>O<sub>3</sub>/MS) to obtain porous materials with larger specific surface area and more adsorption sites. The adsorption of Levofloxacin hydrochloride (LEV) from aqueous solutions over Fe<sub>2</sub>O<sub>3</sub>/MS samples was investigated. The process of adsorption was studied in terms of a number of variables, such as adsorbent dosage, LEV concentration, solution pH. The results showed that the optimal mass ratio of Fe<sub>2</sub>O<sub>3</sub> to MS was 3:10. The ionic strength and coexisting ions had little influence on the adsorption effect of the composite material, so the material had a strong anti-interference ability. However, the pH of the initial solution and the ion phosphate had a significant effect on the adsorption effect, indicating that electrostatic and coordination interaction were the main adsorption mechanisms. The adsorption process of Fe<sub>2</sub>O<sub>3</sub>/MS to LEV can be better described by quasi secondary rate equation with a faster adsorption rate (K<sub>2</sub> = 4.43 × 10<sup>−3</sup>g/(mg·min)) and the maxmium adsorption capacity (Q<sub>e</sub>= 57.65 mg/g). In a wide temperature range (288–308 K), the adsorption behavior of LEV can be well described by the Langmuir isothermal model. Moreover, the ecyclability and stability of the material was explored. This study provides a new idea for the recycling of gold tailings. While solving the problem of water pollution, it realizes the high value reuse of solid waste resources and achieves the purpose of using waste to curb pollution.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142889611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cadmium removal using Rhassoul/alginate composite beads: isotherms, kinetics, and thermodynamic study 使用藻酸盐/海藻酸盐复合微珠去除镉：等温线，动力学和热力学研究

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-25 DOI: 10.1007/s10450-024-00583-3

Khadija Achchatar, Sabine Valange, Abdelhak Kherbeche, Hervé Gallard, Khalid Draoui

{"title":"Cadmium removal using Rhassoul/alginate composite beads: isotherms, kinetics, and thermodynamic study","authors":"Khadija Achchatar, Sabine Valange, Abdelhak Kherbeche, Hervé Gallard, Khalid Draoui","doi":"10.1007/s10450-024-00583-3","DOIUrl":"10.1007/s10450-024-00583-3","url":null,"abstract":"<div><p>Cadmium is a threat to human health and the environment. Therefore, there is a need for efficient and sustainable adsorbents to remediate cadmium-contaminated water. This study explores the effectiveness of Rhassoul clay/alginate composite beads in adsorbing cadmium from aqueous solutions, a simple, efficient, and cost-effective water treatment method. Various physicochemical factors influencing the adsorption capacity of the Rhassoul/alginate hybrid composite beads were examined, including adsorbent dosage (0.5–4.0 g/L suspension), contact time (30–360 min), pH (2–7), initial Cd<sup>2+</sup> concentration (20–200 mg/L), and temperature (25–40 °C). The results revealed an adsorption capacity of 20 mg/g for non-modified Rhassoul clay, while the Rhassoul/alginate composite beads exhibited a significantly higher maximum adsorption capacity of 105 mg/g. Thermodynamic parameters (∆G°, ∆H°, and ∆S°) indicated the process was spontaneous and endothermic.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><img></picture></div></div></figure></div></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142890527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Graphene Oxide as a Highly Efficient and Reusable Adsorbent for Simultaneous Removal of Parabens: Optimization by Response Surface Methodology, Adsorption Isotherms and Reusability Studies 氧化石墨烯作为同时去除对羟基苯甲酸酯的高效可重复使用吸附剂：响应面法优化、吸附等温线和可重复使用研究

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-19 DOI: 10.1007/s10450-024-00581-5

Elif Öztürk Er

{"title":"Graphene Oxide as a Highly Efficient and Reusable Adsorbent for Simultaneous Removal of Parabens: Optimization by Response Surface Methodology, Adsorption Isotherms and Reusability Studies","authors":"Elif Öztürk Er","doi":"10.1007/s10450-024-00581-5","DOIUrl":"10.1007/s10450-024-00581-5","url":null,"abstract":"<div><p>Paraben contamination in aquatic systems, primarily from personal care products, pharmaceuticals and industrial effluents, is an increasing environmental concern due to their widespread use as preservatives. The removal of parabens through conventional wastewater treatment processes is challenging and requires the development of innovative water treatment methods. In this study, graphene oxide nanoflakes were produced by Improved Hummers’ method and their adsorption characteristics were investigated for simultaneous removal of five parabens. Fourier transform infrared spectroscopy, Raman Spectroscopy, X-Ray Powder Diffraction, Scanning Electron Microscope and Transmission Electron Microscope were used and the nanoflakes were successfully characterized. A chromatographic method was developed for the simultaneous quantification of parabens. Process optimization for overall removal efficiency of parabens was achieved using Response Surface Methodology by a multiple response function. Nonlinear regression was used to fit the equilibrium data and the Freundlich model described the adsorption isotherm data accurately with R<sup>2</sup> values between 0.9807 and 0.9957. Factors such as mass of adsorbent, pH of solution and their interaction have the most significant impact on the adsorption process, while contact time shows low significance on the response. The adsorption behaviors of parabens were closely correlated with their hydrophobicity. Along with hydrophobic interactions, other mechanisms such as π–π stacking, hydrogen bonding and electrostatic forces, likely played significant role in the strong adsorption of parabens onto the GO surface. The reusability experiment showed that graphene oxide nanoflakes had a high potential present as a reusable adsorbent for the removal of parabens.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced rGO/ZnO/Chitosan Nanozyme Photocatalytic Technology for Efficient Degradation of Diazinon Pesticide Contaminated Water 增强型 rGO/ZnO/Chitosan 纳米酶光催化技术用于高效降解受重氮农农药污染的水体

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-16 DOI: 10.1007/s10450-024-00582-4

Fitri Handayani Hamid, Fathur Rizqa Rasyid, Mashuni Mashuni, La Ode Ahmad, M. Jahiding

{"title":"Enhanced rGO/ZnO/Chitosan Nanozyme Photocatalytic Technology for Efficient Degradation of Diazinon Pesticide Contaminated Water","authors":"Fitri Handayani Hamid, Fathur Rizqa Rasyid, Mashuni Mashuni, La Ode Ahmad, M. Jahiding","doi":"10.1007/s10450-024-00582-4","DOIUrl":"10.1007/s10450-024-00582-4","url":null,"abstract":"<div><p>The increasing presence of pesticide contaminants in water bodies poses significant environmental and health challenges. This study introduces a novel enzyme-based photocatalytic technology composed of reduced graphene oxide (rGO), zinc oxide (ZnO), and chitosan (CS) designed to enhance the degradation efficiency of diazinon pesticides in polluted water. The nanozymes were characterized by XRD, SEM-EDX, and FTIR to ensure homogeneous structure and distribution of the materials, and the adsorbed pesticide content was measured using a UV-Vis spectrophotometer. Adsorption studies showed that the diazinon removal efficiency increased with higher pH, longer contact time, and initial concentration, reaching maximum adsorption efficiency at neutral pH. Isotherm analysis showed that diazinon adsorption on rGO/ZnO/CS nanozymes followed the Freundlich model, exhibiting heterogeneous adsorption characteristics with moderate adsorption capacity. These findings highlight the potential of rGO/ZnO/CS nanozymes as effective adsorbents for removing diazinon pesticides from contaminated water, offering promising applications in environmental remediation.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The effect of double-doped (B, N) on graphene’s N2O4 gas adsorption performance: an ab initio study 双掺杂（B、N）对石墨烯 N2O4 气体吸附性能的影响：一项 ab initio 研究

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-16 DOI: 10.1007/s10450-024-00578-0

Fatin Hasnat Shihab, Abu Talha, Mohammad Tanvir Ahmed, Abdullah Al Roman, Md Mehade Hasan, Debashis Roy

{"title":"The effect of double-doped (B, N) on graphene’s N2O4 gas adsorption performance: an ab initio study","authors":"Fatin Hasnat Shihab, Abu Talha, Mohammad Tanvir Ahmed, Abdullah Al Roman, Md Mehade Hasan, Debashis Roy","doi":"10.1007/s10450-024-00578-0","DOIUrl":"10.1007/s10450-024-00578-0","url":null,"abstract":"<div><p>In the modern era, there is a pressing need to develop potential gas adsorbents to reduce the toxic gases produced by modern technology in the environment. In this project, we have investigated 2D graphene and double-doped (B, N) nanosheets for adsorption of N<sub>2</sub>O<sub>4</sub> gas. We used density functional theory calculations to examine how N<sub>2</sub>O<sub>4</sub> gas interacts with pure graphene, doubly boron, nitrogen, and boron-nitrogen-doped graphene sheets. We study the geometrical structure changes, cohesive energy, electronic property, and optical property to assess the stability of the sheets and complex structures, as well as their adsorption ability. Upon analyzing the adsorption energy, we observe an increase in adsorption energies for all the doped nanosheets undergoing N<sub>2</sub>O<sub>4</sub> gas adsorption. The band structure analysis reveals a change in the band gap due to doping and gas adsorption, suggesting an interaction between the gas and the nanosheets. The optical properties analysis primarily reveals the highest values in the X-ray region; however, the analysis of the change in intensity peaks and shifting in the UV region for all structures confirms the interaction between the N<sub>2</sub>O<sub>4</sub> gas and the adsorbent.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Modelling combined diffusion and surface resistances in adsorbent particles: zero length column for spherical and slab geometries 吸附剂颗粒中的综合扩散和表面阻力建模：球形和板状几何形状的零长度柱

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-14 DOI: 10.1007/s10450-024-00557-5

Stefano Brandani, Enzo Mangano

{"title":"Modelling combined diffusion and surface resistances in adsorbent particles: zero length column for spherical and slab geometries","authors":"Stefano Brandani, Enzo Mangano","doi":"10.1007/s10450-024-00557-5","DOIUrl":"10.1007/s10450-024-00557-5","url":null,"abstract":"<div><p>Mass transport in nanoporous materials is a key property that allows to improve the performance of many gas separation processes and design more efficient heterogeneous catalytic reactors. In many instances a combination of surface resistance and internal diffusion are present. The combined model for surface barrier and diffusion in a ZLC system is discussed in detail and the analytical solutions valid for the traditional and the partial loading experiments have been derived for the spherical and slab geometries. The model reduces to the limiting forms of pure diffusion when <span>(frac{k{R}_{p}}{D}>100)</span>, and pure surface barrier when <span>(frac{k{R}_{p}}{D}<1)</span>. This study has shown that most literature studies have analysed ZLC responses incorrectly based on an effective combined dimensionless parameter. Two methods are described to obtain the parameters from the long-time asymptotic behaviour of the response curves. Both approaches have been demonstrated on curves generated from the full model solution and experimental data on an etched sample of Y zeolite. Both the analysis of the model and of the experimental results confirm that to characterize combined surface barriers and diffusion one should perform at least experiments at two different flowrates where the system is kinetically controlled, and crucially a partial loading experiment with a time to the switch which should be at least an order of magnitude smaller than the smallest of the diffusion and surface barrier times.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10450-024-00557-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142821362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stochastic desorption of water molecules adsorbed inside single-wall carbon nanotube through nanowindows 单壁碳纳米管内吸附的水分子通过纳米窗口随机解吸

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-14 DOI: 10.1007/s10450-024-00576-2

Yuma Kawamata, Yuki Nagata, Hayato Otsuka, Ayumi Furuse, Ryusuke Futamura, Koki Urita, Isamu Moriguchi, Taku Iiyama, Katsumi Kaneko

{"title":"Stochastic desorption of water molecules adsorbed inside single-wall carbon nanotube through nanowindows","authors":"Yuma Kawamata, Yuki Nagata, Hayato Otsuka, Ayumi Furuse, Ryusuke Futamura, Koki Urita, Isamu Moriguchi, Taku Iiyama, Katsumi Kaneko","doi":"10.1007/s10450-024-00576-2","DOIUrl":"10.1007/s10450-024-00576-2","url":null,"abstract":"<div><p>Understanding water adsorption/desorption process through nanowindows provides new insights into membrane applications, supercapacitors and elucidation of biological ion separation mechanism. This study evidenced a new stochastic desorption mechanism of water molecules adsorbed inside highly pure single-wall carbon nanotube (SWCNT) through nanowindows, which evidently differs from conventional water desorption mechanism from carbon micropores. This new mechanism was clarified by the comparative analysis of water adsorption/desorption behaviors on endcap-closed SWCNT having nanowindows and endcap-open SWCNT without nanowindows. The water desorption for both open SWCNT samples was deeply associated with unique adsorbed water structures consisting of an ice-like adlayer akin to the graphene wall of SWCNT and core liquid-like water. Nanowindows destabilize the ice-like adlayer, leading to stochastic desorption of water molecules, followed by single-step desorption of adsorbed water through nanowindows of endcap-closed SWCNT having nanowindows. In contrast, water molecules are desorbed from ice-like adlayer and core liquid-like water separately for the endcap-open SWCNT without nanowindows.</p></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10450-024-00576-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142821364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Non-modified cellulose fibers for toxic heavy metal adsorption from water 用于吸附水中有毒重金属的非改性纤维素纤维

IF 3 4区工程技术

Adsorption Pub Date : 2024-12-14 DOI: 10.1007/s10450-024-00559-3

Jhonny Caicho-Caranqui, Gabriela Vivanco, David A. Egas, Cristina Chuya-Sumba, Victor H. Guerrero, Lenín Ramirez-Cando, Carlos Reinoso, Frederico B. De Sousa, Marco Leon, Valeria Ochoa-Herrera, Aracely Zambrano-Romero, Cesar Zambrano, Md M. Bhuyan, Frank Alexis

{"title":"Non-modified cellulose fibers for toxic heavy metal adsorption from water","authors":"Jhonny Caicho-Caranqui, Gabriela Vivanco, David A. Egas, Cristina Chuya-Sumba, Victor H. Guerrero, Lenín Ramirez-Cando, Carlos Reinoso, Frederico B. De Sousa, Marco Leon, Valeria Ochoa-Herrera, Aracely Zambrano-Romero, Cesar Zambrano, Md M. Bhuyan, Frank Alexis","doi":"10.1007/s10450-024-00559-3","DOIUrl":"10.1007/s10450-024-00559-3","url":null,"abstract":"<div><p>Heavy metal pollution poses a considerable environmental threat as toxic substances accumulate in ecosystems, causing prevailing ecological damage and generating risks to human health. We characterized physicochemically unmodified cellulose samples extracted from Ecuadorian biodiversity and used them as potential decontaminants of heavy metal ions in water. The isolated materials underwent characterization using Fourier Transform Infrared Spectroscopy-Attenuated Total Reflectance (FTIR-ATR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and X-ray Photoelectron Spectroscopy (XPS). Initial testing of heavy metal adsorption involved 2.0 mmol/L and 10.0 mmol/L copper (Cu<sup>2+</sup>) solutions as models. The results demonstrated a removal percentage of Cu<sup>2+</sup> ions by non-modified cellulose, reaching up to 88.75 ± 2.49% and 54.96 ± 2.51%, respectively using material F25. Additionally, natural (F25, F27, F28, and OP) and control (C1, C, and Af) celluloses were selected to study the removal of Cu<sup>2+</sup>, Cd<sup>2+</sup>, and Pb<sup>2+</sup> ions from control isolated metal ion solutions ranging from 1 to 100 mg/L. The findings revealed that samples C, OP, and F25 effectively removed Cu<sup>2+</sup>, Cd<sup>2+</sup>, and Pb<sup>2+</sup> ions when they were present isolated in solutions at concentrations as high as 30 mg/L. Furthermore, assays with mixed metal ion solutions exhibited promising removal of heavy metal ions using OP + F25. Overall, the results suggest that non-modified cellulose derived from biomass holds potential as a material for effectively removing toxic heavy metal ions from water.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":458,"journal":{"name":"Adsorption","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142821365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0