新型壳聚糖-单宁酸吸附剂的合成去除废水中的铝(III):表征,动力学,平衡等温线和热力学研究

IF 3.1 4区 工程技术 Q3 CHEMISTRY, PHYSICAL
Hari Mohan Meena, Shrikant Kukreti, P. S. Jassal
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引用次数: 0

摘要

采用不同剂量的新型壳聚糖-单酸(CT1、CT3和CT6)生物吸附剂对工业废水中的铝进行了高效脱除。采用797伏安阳极线性扫描伏安法测定Al3+离子。研究了吸附动力学、吸附等温线以及溶液流速的影响。Freundlich等温线准确表征了吸附结果,吸附剂的最大吸附量为684.93 mg/g。实验结果表明,当溶液浓度达到200 mg/L时,对铝的吸附量最大。结果表明,壳聚糖-单宁酸生物材料主要遵循络合-吸附方式,在pH 6.5时吸附量最大。研究了BET吸附-脱附等温线,并评价了吸附剂的吸附效果。因此,这种新型的、可持续的壳聚糖-单宁酸配合物可能是一种成功的生物吸附剂,用于去除废水中的铝金属离子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of novel Chitosan-Tannic acid adsorbent for removal of Aluminum (III) from wastewater: characterisation, kinetics, equilibrium isotherms and thermodynamic studies

Synthesis of novel Chitosan-Tannic acid adsorbent for removal of Aluminum (III) from wastewater: characterisation, kinetics, equilibrium isotherms and thermodynamic studies

This study efficiently removed aluminum from commercial wastewater by using different doses of the novel chitosan-tannic acid (CT1, CT3, and CT6) bio-materials adsorbent. The Al3+ ions were determined using 797 VA anodic linear sweep voltammetry Computrace. The research examined the adsorption kinetics, adsorption isotherms, and the effect of the solution flow rate. The Freundlich isotherms precisely represented the adsorption results, with a maximum adsorption capacity of adsorbent was 684.93 mg/g. The experimental results showed that the adsorption of aluminum was maximum when solution concentrations were up to 200 mg/L. The findings indicated that the chitosan-tannic acid biomaterials primarily followed a complexation-adsorption method, exhibiting maximum adsorption capacity at pH 6.5. The study investigated the BET adsorption–desorption isotherm and evaluated the adsorption efficacy of adsorbents. Consequently, this novel, sustainable chitosan-tannic acid complex might be a successful bio-adsorbent for removing aluminum metal ions from wastewater solutions.

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来源期刊
Adsorption
Adsorption 工程技术-工程:化工
CiteScore
8.10
自引率
3.00%
发文量
18
审稿时长
2.4 months
期刊介绍: The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news. Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design. Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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