{"title":"Preparation, Characterization, and Study of Antibacterial some new Pyrazole Derivatives","authors":"Lina A. Yaseen, H. K. Al-Amood","doi":"10.36329/jkcm/2022/v2.i9.13304","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13304","url":null,"abstract":"The papear include synthesis of four of pyrazole derivatives from the reaction of chalcones with substituted hydrazine. FT-IR, Mass, and H1-NMR spectra identified the compounds. The new pyrazoles (Py1-Py4) studies as anti-bacterial against negative and positive gram stain. The prepared compounds gave the high and different abilities to inhibit these bacteria according to the type of the substituted group. The inhibition ratio of pyrazole substituted by the COOH group (Py1) was 28 mm, while pyrazole substituted by OH in the meta position was less able to inhibit. ","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114802123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spectrophotometr ic Study of Aryl Mercaptanes with Various Chain Length Linked to DNA/RNA and Cadmium Oxide (CdO) Nanoparticles Sandwiched Complex","authors":"A. Heidari","doi":"10.36329/jkcm/2022/v2.i9.13316","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13316","url":null,"abstract":"CdO nanoparticles show a strong peak of Plasmon absorption in ultraviolet–visible zone. A strong interaction exists between the surface of CdO nanoparticles and aryl mercaptan compounds. Aryl mercaptan compounds cause to aggregation of CdO nanoparticles linked to DNA/RNA and hence, lead to widening of peak Plasmon of CdO nanoparticles surface at 550 (nm) and emerging a new peak at higher wavelength. In the current project, this optical characteristic of CdO nanoparticles is used to time investigate of interaction between different aryl mercaptanes and CdO nanoparticles. The results were shown that aryl mercaptan compounds with shorter chain length interact faster with CdO nanoparticles. Therefore, a simple and fast method for identification of aryl mercaptanes with various chain length using red shift in surficial Plasmon absorption is presented.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"70 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130815134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation, characterisation and biological activity of some metal complexes derived from new dithiocarbamate of heterocyclic ligand","authors":"R. Ahmed","doi":"10.36329/jkcm/2022/v2.i9.13308","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13308","url":null,"abstract":"In this study, synthesised new ligand: potassium 2,2'-(quinoxaline-2,3-diyl)bis(1-phenylhydrazinecarbodithioate) (L). The ligand synthesised by reacting N1,N2-dip-tolyloxalamide as the starting material with CS2 and KOH to add the CS2 group and then with phenylendiammine to achieve (L). \u0000The ligand used in the synthesis of complexes with (CoII, NiII and CdII). The new ligand and its complexes characterised by FT-IR, UV-Vis, 1H, 13C-NMR, Mass spectroscopy, and elemental analysis, in addition to the above techniques were using magnetic moment, atomic absorption, chloride content, and melting point to describe the metal complexes.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131718019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and Thermal Studies of Some Metal azo Complexes Derived from Hydroxy coumarin","authors":"Tadhamun Sabah Younus, Tariq Ali Fahd","doi":"10.36329/jkcm/2022/v2.i9.11156","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.11156","url":null,"abstract":" In the current study, of two azo dyes made from coumarin and procaine (T1) and coumarin and Sulfa guanidine (T2)were synthesized. The dyes were characterized by IR, CHN, 1H-NMR, 13C-NMR and MS spectroscopic techniques. .\u0000To make azo metal(II) complexes, these novel legands were combined with acetate salts of copper(II) and nickel(II) in a 1:2 molar ratio.The metal to ligand ratio [M:L] in all complexes, according to analytical data, is (1:2).This ligand behaves as a bidentate chelating, according to spectral and analytical data.Thermo gravimetric (TGA) analysis was used to study the thermal behavior of these substances. These chemicals' thermal breakdown is a multi-stage process","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131972867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"BiOCl/SrHA nanoparticle for photocatalytic degradation of a malachite green dye","authors":"M. K. Kzar, Z. N. Kadhim, Ali H.Al-Mowali","doi":"10.36329/jkcm/2022/v2.i9.13319","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13319","url":null,"abstract":"In this research, we discuss the removal of malachite green dye by strontium hydroxyapatite supported BiOCl. A modified hydrolysis model, one can synthesise BiOCl/SrHA. BiOCl/SrHA was characterized using Fourier transform-infrared spectroscopy (FTIR), UV-visible (UV-vis) analysis, X-ray diffraction (XRD), energy diffraction X-ray (EDX), and scanning electron microscopy (SEM). SEM outcome confirmed the dispersion of BiOCl onto strontium hydroxyapatite. The shape of the BiOCl catalytic samples overlapped with each other to form 3D hierarchical flower-like structures. The UV-visible was used as a radiation source during photocatalysis. BiOCl/SrHA had an effect on malachite green dye degradation. The oxidative removal occurred through hydroxyl radical formation. UV-visible (UV-vis) /BiOCl/SrHA showed perfect photocatalytic property for the decay of malachite green (MG) from an aqueous solution. According to kinetics analysis, the dye degradation rates could be in a pseudo-first-order model.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117246275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abbas Kadhim Jiheel AL-hameedawi, Ali A.A. Al-Shawi
{"title":"Clinical Evaluation of Some Biochemical and Hematological Variables and Their Relationship to Serum Ferritin Levels of Major Beta Thalassemia Patients in Maysan Governorate - Iraq.","authors":"Abbas Kadhim Jiheel AL-hameedawi, Ali A.A. Al-Shawi","doi":"10.36329/jkcm/2022/v2.i9.13314","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13314","url":null,"abstract":"Thalassemia is a recessive genetic disease resulting from a disorder and defect in hemoglobin production. The current study was designed to evaluate some hematological and biochemical variables and their relationship to serum ferritin (iron stock ) levels in Thalassemia patients and study them in terms of housing, age and blood types in Maysan Governorate. This study was conducted during the period from December 2020 to the end of October. The results of the current study recorded a highly significant relationship (P<0.000) for all hematological parameters with a decrease in the levels of (HGB) (RBC), (MCV) for patients and an increase in the level of white blood cell count (WBC) and platelet count (PLT) compared to the control. The current study recorded a highly significant relationship (P<0.000) and high levels of all liver enzymes (ALP), (ALT), (AST), (TSB), (TP) compared to the control group. The present study showed a slight decrease in urea levels and an increase in creatine levels compared to the control. The results of linear regression analysis showed a correlation between ferritin and hematological parameters, where the relationship was significant with RBC, HGB, MCV and insignificant with WBC, PLT, while there was a correlation between ferritin levels and liver and kidney enzymes, where the relationship was significant and positive with ALP. (AST) (TSB), and non-significant positive for (ALT), (TP), (Urea), (Creatinine). ","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116415826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis , Characterization and Study the Effect of Benzothiazol-pyrazole Derivatives on the Activity of AST, ALT Enzymes","authors":"A. Mohammed, Hamid H. Mohammed, Zainab N. Mageed","doi":"10.36329/jkcm/2022/v2.i9.13297","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13297","url":null,"abstract":" This work includes synthesis some of 2-(4,5-dihydro-1H-pyrazol-1-yl)-1,3-benzothiazole derivatives which synthesized from 2-hydrazino-1,3-benzothiazole with dicarbonyl compounds. The prepared compounds were characterized by FT-IR, 1HNMR and also studied the physical properties. The effect of the biological activity for these compounds were studied on the activity of AST and ALT enzymes in human serum of myocardial infarction patients. The studies show the compounds (A2 and A5) caused inhibition while the compound (A3 and A4) caused activation for the activity for AST and ALT enzymes.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"184 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128927896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Removal of Turbidity from Raw water by Novel Coagulant Based on PVC Pipe Waste and Sodium Alginate","authors":"Hawraa Ali Atwan, H. Abdulsahib","doi":"10.36329/jkcm/2022/v2.i9.13288","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13288","url":null,"abstract":"In the current study, waste polyvinyl chloride pipes were used as a primary material in the reactions, which are widely used for water supply and drainage systems where the waste pipes were prepared by cleaning them from suspended materials and grinding them into small particles, then reacting natural polymers from a plant; Alginic acid. We have obtained modified polymer (PVC/Alginate) or AL-PVC which have been grinded to obtain a powder. Four methods were used to characterize the properties of natural and prepared polymers: Fourier infrared spectroscopy (FTIR), scanning electron microscopy (SEM) X-ray diffraction (XRD), and thermogravimetry (TGA-TG). The effectiveness of AL-PVC polymer as a coagulant flocculant in the treatment of surface water has been studied. Tests were carried out in the laboratory on two kinds of water (50 NTU and 100 NTU). The first one is the synthesis of water mixed with high and low concentrations of bentonite, simulating thus turbid water. The second one is raw water from the treatment station of the Shatt Al-Arab River. The performance of the coagulation-flocculation process has been assessed by measuring the supernatant turbidity for different pH, doses, and flocculation times of the AL-PVC polymer. The obtained results show that AL-PVC polymer effectiveness was strongly dependent on pH and the doses of AL-PVC polymer, the initial turbidity, and the water quality. The physical and chemical methods used in the present study of water treatments are mainly due to their simplicity, ease of use, low cost as well as excellent removal efficiency.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126618612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Delfaa Slman Gassed, A. A. Abdulwahid, Ali A. A. Al-Riyahee
{"title":"Adsorption of Methylene Blue and Safranine Using Activated Carbon of Cinnamon Plant Surface.","authors":"Delfaa Slman Gassed, A. A. Abdulwahid, Ali A. A. Al-Riyahee","doi":"10.36329/jkcm/2022/v2.i9.13294","DOIUrl":"https://doi.org/10.36329/jkcm/2022/v2.i9.13294","url":null,"abstract":"Cinnamon plant Activated Carbon (C/AC) was prepared by chemical and thermal activation. The adsorption behaviour of (C/AC) in aqueous Methylene blue (MB) and Safranine (S) dyes was investigated and characterized by XRD, TEM and FESEM. The possible mechanism of the adsorption of (MB) and (S) dyes on the (C/AC) surface was studied. The influence of various adsorption control parameters like the initial dye concentration, pH, contact time, and temperature was studied. The data confirmed a high removal of (MB) and (S) at pH=11. The experimental data were fitted to Langmuir and Freundlich isotherms to examine the adsorption mechanism. The adsorption data reveal (MB) with the maximum capacity of (294.11) mg/g and (S) with the capacity of (285.714) mg/g. The kinetic data for different initial dye concentration were computed using pseudo-first order, pseudo-second order, and intraparticle diffusion model. Thermodynamic parameters includes enthalpy (∆H), entropy (∆S), free energy (∆G), and activation energy (Ea) of the adsorption process were calculated and used to interpret the results, and revealed that the adsorption systems were a spontaneous and endothermic process for adsorption of MB and S dyes onto the adsorbent surface. Also, low activation energy values (Ea<40 kJ/mol) were characteristics of the physisorption mechanism and diffusion-controlled process.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"434 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126102560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}