Removal of Turbidity from Raw water by Novel Coagulant Based on PVC Pipe Waste and Sodium Alginate

Hawraa Ali Atwan, H. Abdulsahib
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Abstract

In the current study, waste polyvinyl chloride pipes were used as a primary material in the reactions, which are widely used for water supply and drainage systems where the waste pipes were prepared by cleaning them from suspended materials and grinding them into small particles, then reacting natural polymers from a plant; Alginic acid. We have obtained modified polymer (PVC/Alginate)  or AL-PVC which have been grinded to obtain a powder. Four methods were used to characterize the properties of natural and prepared polymers: Fourier infrared spectroscopy (FTIR), scanning electron microscopy (SEM) X-ray diffraction (XRD), and thermogravimetry (TGA-TG). The effectiveness of AL-PVC polymer as a coagulant flocculant in the treatment of surface water has been studied. Tests were carried out in the laboratory on two kinds of water (50 NTU and 100 NTU). The first one is the synthesis of water mixed with high and low concentrations of bentonite, simulating thus turbid water. The second one is raw water from the treatment station of the Shatt Al-Arab River. The performance of the coagulation-flocculation process has been assessed by measuring the supernatant turbidity for different pH, doses, and flocculation times of the AL-PVC polymer. The obtained results show that AL-PVC polymer effectiveness was strongly dependent on pH and the doses of AL-PVC polymer, the initial turbidity, and the water quality. The physical and chemical methods used in the present study of water treatments are mainly due to their simplicity, ease of use, low cost as well as excellent removal efficiency.
聚氯乙烯管材与海藻酸钠混凝剂对原水浊度的去除研究
在目前的研究中,废弃的聚氯乙烯管道被用作反应的主要材料,广泛用于供水和排水系统,其中废管道是通过将其从悬浮物中清洗并将其磨成小颗粒,然后与植物中的天然聚合物反应来制备的;海藻酸。我们已经得到了改性聚合物(PVC/海藻酸盐)或AL-PVC,它们已经被磨成粉末。采用傅里叶红外光谱(FTIR)、扫描电子显微镜(SEM)、x射线衍射(XRD)和热重法(TGA-TG)四种方法对天然聚合物和制备聚合物的性能进行表征。研究了AL-PVC聚合物作为混凝剂处理地表水的效果。在实验室对两种水(50 NTU和100 NTU)进行了测试。第一种是混合高、低浓度膨润土的合成水,模拟浑浊水。第二个是阿拉伯河处理厂的原水。通过测定AL-PVC聚合物在不同pH、剂量和絮凝次数下的上清浊度,评价了混凝-絮凝工艺的性能。结果表明,AL-PVC聚合物的效果与pH值、投加量、初始浊度和水质密切相关。目前在水处理研究中采用的物理和化学方法主要是由于其简单、易用、成本低和去除效果好。
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