新型杂环配体二硫代氨基甲酸酯金属配合物的制备、表征及生物活性研究

R. Ahmed
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引用次数: 0

摘要

本研究合成了新的配体:2,2′-(喹啉-2,3-二基)二(1-苯基肼卡二硫酸钾)(L)。该配体以N1, n2为原料与CS2和KOH反应,加入CS2基团,再与苯二胺反应得到(L)。该配体用于与(CoII, NiII和CdII)合成配合物。利用FT-IR、UV-Vis、1H、13C-NMR、质谱、元素分析等技术对新配体及其配合物进行了表征,并利用磁矩、原子吸收、氯含量、熔点等技术对金属配合物进行了表征。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation, characterisation and biological activity of some metal complexes derived from new dithiocarbamate of heterocyclic ligand
In this study, synthesised new ligand: potassium 2,2'-(quinoxaline-2,3-diyl)bis(1-phenylhydrazinecarbodithioate) (L). The ligand synthesised by reacting N1,N2-dip-tolyloxalamide as the starting material with CS2 and KOH to add the CS2 group and then with phenylendiammine to achieve (L). The ligand used in the synthesis of complexes with (CoII, NiII and CdII). The new ligand and its complexes characterised by FT-IR, UV-Vis, 1H, 13C-NMR, Mass spectroscopy, and elemental analysis, in addition to the above techniques were using magnetic moment, atomic absorption, chloride content, and melting point to describe the metal complexes.
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