Progress in Solid State Chemistry最新文献

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Synthesis, properties, and applications of functionally gradient cemented carbides 功能梯度硬质合金的合成、特性和应用
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-06-01 DOI: 10.1016/j.progsolidstchem.2024.100454
Kunlong Cai , Jialin Sun , Haibin Wang , Rui Bao , Zhixing Guo , Weibin Zhang , Le Zhao , Xiao Li , Ruijun Cao , Xialun Yun , Jun Zhao
{"title":"Synthesis, properties, and applications of functionally gradient cemented carbides","authors":"Kunlong Cai ,&nbsp;Jialin Sun ,&nbsp;Haibin Wang ,&nbsp;Rui Bao ,&nbsp;Zhixing Guo ,&nbsp;Weibin Zhang ,&nbsp;Le Zhao ,&nbsp;Xiao Li ,&nbsp;Ruijun Cao ,&nbsp;Xialun Yun ,&nbsp;Jun Zhao","doi":"10.1016/j.progsolidstchem.2024.100454","DOIUrl":"10.1016/j.progsolidstchem.2024.100454","url":null,"abstract":"<div><p>Cemented carbides have enjoyed widespread applications as a function of their outstanding properties during the past 100 years. Despite the advantages, however, recently there have been concerns about the challenges associated with traditional cemented carbides, i.e. the conflict of properties (hardness and toughness, strength and wear resistance) as well as the instability of reliability in service, necessitating the development of functional gradient cemented carbides (FGCCs). Although recent decades, investigations have seen explosive growth in FGCCs, there is still a lack of comprehensive review on FGCCs. Herein, the current study applies towards summarize the progress of FGCCs during the past 60 years, emphasizing the demand in FGCCs with tailored properties and customized requirements for specific applications. We initially introduce basic cognition of FGCCs, subsequently, comprehensively elucidate the gradient formation mechanisms of carburization, decarburization, nitridation, denitrification, infiltration process, and construction methods (solid-phase sintering, graphene doping and additive manufacturing etc.), then summary processing techniques and mechanical properties of FGCCs. In addition, the impart of additive on further improving the properties of FGCCs is discussed. Afterward, the possible applications of FGCCs at different areas are proposed. At the end of this paper, a summary of concluding remarks and potential developed direction of state-of-the-art FGCCs is provided.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"74 ","pages":"Article 100454"},"PeriodicalIF":12.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140402707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morphological design of LaTiO2N particles by topotactic growth mechanisms for photocatalytic applications 通过拓扑生长机制设计用于光催化应用的 LaTiO2N 粒子形态
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2024.100442
Valérie Werner, Gregor A. Zickler, Simone Pokrant
{"title":"Morphological design of LaTiO2N particles by topotactic growth mechanisms for photocatalytic applications","authors":"Valérie Werner,&nbsp;Gregor A. Zickler,&nbsp;Simone Pokrant","doi":"10.1016/j.progsolidstchem.2024.100442","DOIUrl":"10.1016/j.progsolidstchem.2024.100442","url":null,"abstract":"<div><p>Solar water-splitting using particle photocatalysts is a promising approach to sustainably produce hydrogen. LaTiO<sub>2</sub>N is an auspicious visible light absorbing photocatalyst regarding the oxygen evolution reaction. In this work, the topotactic growth mechanism of LaTiO<sub>2</sub>N particles is investigated by varying the precursor material and the synthesis conditions during thermal ammonolysis. Their influence is discussed in regard to structure, composition, morphology, optical, and functional properties. Using the conventional, layered perovskite oxide, La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>, as precursor resulted in brick-shaped porous LaTiO<sub>2</sub>N particles with a high degree of crystallinity and a high surface area. When adding flux, the increased mobility during thermal ammonolysis leads to larger morphology changes resulting in non-porous, perforated particles with skeletal features. In a novel, alternative approach, LaTiO<sub>2</sub>N is prepared via the topotactic conversion of a double-layered Sillén-Aurivillius type oxyhalide material, La<sub>2·1</sub>Bi<sub>2·9</sub>Ti<sub>2</sub>O<sub>11</sub>Cl. The facile formation of LaTiO<sub>2</sub>N results in a perforated porous structure exhibiting skeletal features whilst maintaining a high surface area due to the presence of pores. By alternating the morphology of the material in this matter the oxygen evolution under one sun illumination is improved by around 10% or 30% depending on whether thermal ammonolysis of La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> is performed with or without flux, respectively.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100442"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139813095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large-sized and highly-uniform superconducting RE123 single crystals by top-seeded solution-growth: A platform for physical research 通过顶播溶液生长技术获得大尺寸和高度均匀的超导 RE123 单晶:物理研究平台
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2024.100438
Yanhan Zhu , Xin Yao
{"title":"Large-sized and highly-uniform superconducting RE123 single crystals by top-seeded solution-growth: A platform for physical research","authors":"Yanhan Zhu ,&nbsp;Xin Yao","doi":"10.1016/j.progsolidstchem.2024.100438","DOIUrl":"10.1016/j.progsolidstchem.2024.100438","url":null,"abstract":"<div><p><span>The last two decades have seen a growing trend towards sizable single crystals of REBa</span><sub>2</sub>Cu<sub>3</sub>O<sub>7−δ</sub><span><span> (RE123, RE = rare earth elements) with fine quality, which have been attracting considerable interest in the study of </span>superconductivity. As an advanced and classic method, top-seeded solution-growth (TSSG) is the only technique to date for producing RE123 single crystals with dimensions of 2 cm, e.g., a Y123 single crystal of 19.8 × 19.5 mm</span><sup>2</sup> in <em>a-b</em><span><span> plane and 16.5 mm in height. Recently, novel approaches were developed such as crystal-pulling combined with continual cooling for rapid growth to attain a large-sized RE123 crystal, and the utilization of dopant-added crucibles for continuous growth to produce highly-uniform doped-Y123 crystals. Consequently, researchers from several tens of physical laboratories worldwide have been benefiting from TSSG-produced RE123 single crystals and generating excellent collaborative work. This paper provides an overview of the progress and achievements on the growth of superior RE123 single crystals by TSSG for fundamental studies and practical applications, focusing on three aspects including crystal enlargement, RE123 stoichiometry control and cation doping. The mechanism of crystal growth and the correlation between phase formation and superconducting properties are comprehensively elucidated on the basis of distinctive features of </span>phase diagrams of RE–Ba–Cu–O systems.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100438"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139501475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel synthetic approaches and morphological design of perovskite-type oxynitrides in powder and ceramic form 粉末和陶瓷形式的包晶型氧化物的新型合成方法和形态设计
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2024.100440
Yuji Masubuchi
{"title":"Novel synthetic approaches and morphological design of perovskite-type oxynitrides in powder and ceramic form","authors":"Yuji Masubuchi","doi":"10.1016/j.progsolidstchem.2024.100440","DOIUrl":"10.1016/j.progsolidstchem.2024.100440","url":null,"abstract":"<div><p><span><span>Perovskite-type oxynitrides are a new class of inorganic materials that have potential applications as </span>photocatalysts, inorganic pigments and </span>dielectrics. Design of the morphology in conjunction with new synthesis methods is essential for their practical use. In this review, we present the formation of fine particles via a low temperature and ammonia-free synthesis method, the morphology of the oxynitride perovskites obtained using metal carbodiimide, and the toughness of the sintered ceramics in relation to their microstructure.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100440"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139454910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bilayered graded phase homojunction FA0.15MA0.85PbI3-based organic-inorganic hybrid perovskite solar cells crossing 22 % efficiency 基于 FA0.15MA0.85PbI3 的双层分级同相结有机-无机混合型过氧化物太阳能电池的效率突破 22
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2023.100437
Jyoti V. Patil , Sawanta S. Mali , Sachin R. Rondiya , Nelson Y. Dzade , Chang Kook Hong
{"title":"Bilayered graded phase homojunction FA0.15MA0.85PbI3-based organic-inorganic hybrid perovskite solar cells crossing 22 % efficiency","authors":"Jyoti V. Patil ,&nbsp;Sawanta S. Mali ,&nbsp;Sachin R. Rondiya ,&nbsp;Nelson Y. Dzade ,&nbsp;Chang Kook Hong","doi":"10.1016/j.progsolidstchem.2023.100437","DOIUrl":"10.1016/j.progsolidstchem.2023.100437","url":null,"abstract":"<div><p><span>Making highly efficient and stable perovskite solar cells (PSCs) are often based on the processing techniques, band gap of the material and effective interface charge separation. The efficiency of PSCs can be enhanced through several methods including the utilization of a solar-friendly absorber, interface passivation and the implementation of multi-junction spectrally matched absorbers or bilayered phase homojunction (BPHJ) consisting of identical absorbers. Here, we demonstrated BPHJ concept by stacking identical compositions of highly efficient and stable FA</span><sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub><span> perovskite<span> absorbers adopting solution process (SP) and thermal evaporation (TEV) techniques. We successfully achieved FA</span></span><sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub> (SP)/FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub>-(TEV) based BPHJ normal n-i-p devices, which significantly crossing 22.</p><p>% PCE. These improvement stems from effective deposition method for achieving high-quality FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub>-based BPHJ enabling smooth charge transfer at the interfaces. The resulting BPHJ-based champion device achieve a 22.13 % PCE and retain &gt;95 % its original efficiency over 1000 hours.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100437"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139013764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Confining oxygen anion to stabilize layered oxide Li1.2Ni0.2Mn0.6O2 via Zr-Al dual doping 通过掺杂 Zr-Al 来限制氧阴离子以稳定层状氧化物 Li1.2Ni0.2Mn0.6O2
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2024.100441
Caiqi Ma , Xin Zhang , Xiaoyan Xie , Xu Zhao , Shilong Fu , Chaochao Fu , Guangshe Li , Jijing Xu , Liping Li
{"title":"Confining oxygen anion to stabilize layered oxide Li1.2Ni0.2Mn0.6O2 via Zr-Al dual doping","authors":"Caiqi Ma ,&nbsp;Xin Zhang ,&nbsp;Xiaoyan Xie ,&nbsp;Xu Zhao ,&nbsp;Shilong Fu ,&nbsp;Chaochao Fu ,&nbsp;Guangshe Li ,&nbsp;Jijing Xu ,&nbsp;Liping Li","doi":"10.1016/j.progsolidstchem.2024.100441","DOIUrl":"10.1016/j.progsolidstchem.2024.100441","url":null,"abstract":"<div><p><span>Lithium-rich manganese-based transition metal oxide Li</span><sub>1.2</sub>Ni<sub>0.2</sub>Mn<sub>0.6</sub>O<sub>2</sub><span> (LNMO) can achieve high energy density due to the interaction of anionic redox kinetics in Li</span><sub>2</sub>MnO<sub>3</sub><span><span><span>. However, the irreversible release of oxygen and migration of Mn ions during deep de-lithiation disrupts the layer structure of LNMO, leading to a decrease in voltage and capacity. Herein, we confine oxygen anion through Zr and Al co-doping. Combined analysis of structure refinement, XPS and </span>XAS, the co-doped strategy effectively prohibits cation disordering of Li/Ni, inhibits the Jahn-Teller effect and reduces the transition metal (TM) and oxygen hybridization. As a result, the Zr and Al co-doping LNMO sample (ZA-LNMO) possesses a capacity retention of 92% after 100 cycles and 86% after 200 long-term cycles, much higher than the value of the undoped sample (79% for 100 cycles and 58% for 200 cycles). Even at the harsh conditions such as ultra-high current rate (10 C) or high temperature (60 °C), ZA-LNMO also maintains 70% retention after 200 cycles. Our findings provide an insight into the synergistic effect of cation co-doping and help to design layered </span>oxides for future applications.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100441"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139677297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterizations of structural, optical, and dielectric properties of oxynitride perovskites ACa0.2M0.8O2.6N0.4 (A= Sr, Ba; M = Nb, Ta) 氧化氮化物包晶 ACa0.2M0.8O2.6N0.4(A= Sr、Ba;M= Nb、Ta)的结构、光学和介电特性表征
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2024-03-01 DOI: 10.1016/j.progsolidstchem.2024.100439
Jae Won Seol , Jong-Sook Lee , Maxim Avdeev , Young-Il Kim
{"title":"Characterizations of structural, optical, and dielectric properties of oxynitride perovskites ACa0.2M0.8O2.6N0.4 (A= Sr, Ba; M = Nb, Ta)","authors":"Jae Won Seol ,&nbsp;Jong-Sook Lee ,&nbsp;Maxim Avdeev ,&nbsp;Young-Il Kim","doi":"10.1016/j.progsolidstchem.2024.100439","DOIUrl":"10.1016/j.progsolidstchem.2024.100439","url":null,"abstract":"<div><p><span>Perovskite-type oxynitrides ACa</span><sub>0.2</sub>M<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> (A = Sr, Ba; M = Nb, Ta) were synthesized <em>via</em> the ammonolytic reaction between A<sub>5</sub>M<sub>4</sub>O<sub>15</sub> and CaCl<sub>2</sub>, where the Ca<sup>2+</sup> insertion and O<sup>2−</sup>/N<sup>3−</sup> substitution occurred cooperatively. In terms of the average structure, SrCa<sub>0.2</sub>Nb<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> and SrCa<sub>0.2</sub>Ta<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> belong to the orthorhombic <em>Pnma</em> space group, and BaCa<sub>0.2</sub>Nb<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> and BaCa<sub>0.2</sub>Ta<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub>, the primitive cubic <em>Pm</em> <span><math><mrow><mover><mn>3</mn><mo>‾</mo></mover></mrow></math></span> <em>m</em> group. The comparison between the experimental lattice volume and the summed ionic volume suggested that ACa<sub>0.2</sub>M<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> have higher degrees of ionicity than AM'<sub>0.2</sub>M<sub>0.8</sub>O<sub>3−<em>x</em></sub>N<sub><em>x</em></sub> (M′ = Li, Mg, Mn), but are more covalent than ANa<sub>0.2</sub>M<sub>0.8</sub>O<sub>2.8</sub>N<sub>0.2</sub>. Despite the significant mismatches of size and charge between Ca<sup>2+</sup> and Nb<sup>5+</sup> (or Ta<sup>5+</sup>), no cation ordering was detected on the octahedral site. On the other hand, the O/N distribution appeared to depend on the bonding geometry around the anion sites in a way N favors the straighter bonding connectivity of M−N−M. The band gap energies of ACa<sub>0.2</sub>M<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub> were estimated to be 1.9–2.25 eV depending on A and M. The band gaps and color properties of AMO<sub>2</sub>N and AM'<sub>0.2</sub>M<sub>0.8</sub>O<sub>3−<em>x</em></sub>N<sub><em>x</em></sub><span><span> (A = Sr, Ba; M = Nb, Ta; M′ = Li, Na, Mg, Ca, Mn) are compared. Thermogravimetry and </span>differential scanning calorimetry<span> were conducted in the air to assess the oxynitride stability. The electrical behaviors were studied by the equivalent circuit analysis of the impedance spectrum using compacted polycrystalline specimens, where BaCa</span></span><sub>0.2</sub>Ta<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub><span> was found to possess a bulk dielectric constant of 4550 along with an electrical conductivity of ≈10</span><sup>−6</sup> S/cm at 27 °C. It remains, however, necessary to assess the extrinsic effects arising from the non-ideal sintering to interpret thoroughly the electrical property of BaCa<sub>0.2</sub>Ta<sub>0.8</sub>O<sub>2.6</sub>N<sub>0.4</sub>.</p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"73 ","pages":"Article 100439"},"PeriodicalIF":12.0,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139456118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bilayered graded phase homojunction FA0.15MA0.85PbI3-based organic-inorganic hybrid perovskite solar cells crossing 22 % efficiency 基于 FA0.15MA0.85PbI3 的双层分级同相结有机-无机混合型过氧化物太阳能电池的效率突破 22
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2023-12-21 DOI: 10.1016/j.progsolidstchem.2023.100437
Jyoti V. Patil, Sawanta S. Mali, Sachin R. Rondiya, Nelson Y. Dzade, Chang Kook Hong
{"title":"Bilayered graded phase homojunction FA0.15MA0.85PbI3-based organic-inorganic hybrid perovskite solar cells crossing 22 % efficiency","authors":"Jyoti V. Patil, Sawanta S. Mali, Sachin R. Rondiya, Nelson Y. Dzade, Chang Kook Hong","doi":"10.1016/j.progsolidstchem.2023.100437","DOIUrl":"https://doi.org/10.1016/j.progsolidstchem.2023.100437","url":null,"abstract":"<p>Making highly efficient and stable perovskite solar cells (PSCs) are often based on the processing techniques, band gap of the material and effective interface charge separation. The efficiency of PSCs can be enhanced through several methods including the utilization of a solar-friendly absorber, interface passivation and the implementation of multi-junction spectrally matched absorbers or bilayered phase homojunction (BPHJ) consisting of identical absorbers. Here, we demonstrated BPHJ concept by stacking identical compositions of highly efficient and stable FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub> perovskite absorbers adopting solution process (SP) and thermal evaporation (TEV) techniques. We successfully achieved FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub> (SP)/FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub>-(TEV) based BPHJ normal n-i-p devices, which significantly crossing 22.</p><p>% PCE. These improvement stems from effective deposition method for achieving high-quality FA<sub>0.15</sub>MA<sub>0.85</sub>PbI<sub>3</sub>-based BPHJ enabling smooth charge transfer at the interfaces. The resulting BPHJ-based device achieve a 22.13 % PCE and retain &gt;95 % its original efficiency over 1000 h.</p>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"19 1","pages":""},"PeriodicalIF":12.0,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139027372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ferroelectric ceramics for pyrocatalytic applications 热催化用铁电陶瓷
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2023-12-01 DOI: 10.1016/j.progsolidstchem.2023.100428
Gurpreet Singh , Moolchand Sharma , Jagmohan Datt Sharma , Sanjeev Kumar , Rahul Vaish
{"title":"Ferroelectric ceramics for pyrocatalytic applications","authors":"Gurpreet Singh ,&nbsp;Moolchand Sharma ,&nbsp;Jagmohan Datt Sharma ,&nbsp;Sanjeev Kumar ,&nbsp;Rahul Vaish","doi":"10.1016/j.progsolidstchem.2023.100428","DOIUrl":"10.1016/j.progsolidstchem.2023.100428","url":null,"abstract":"<div><p><span>Ferroelectric ceramics, which exhibit the phenomenon of reversible spontaneous polarization, have been utilized in multiple conventional applications including sensors, actuators, nano-generators, micro-electromechanical systems (MEMS), memory storage systems, </span>energy harvesting<span><span> devices, etc. Recently, ferroelectric ceramics have been employed for catalysis-induced applications. One of such catalysis process is known as ‘pyrocatalysis’, which makes use of </span>pyroelectric materials to execute catalysis reactions using temperature fluctuation-derived waste thermal energy/heat. This new and evolving pyrocatalysis process has shown promising potential in new and exciting applications including water-cleaning, water-splitting, bacterial disinfection, tooth whitening, carbon-dioxide reduction, tumor therapy, etc. In principle, ferroelectric ceramics are always pyroelectric in nature, which enables them to be utilized for pyrocatalytic applications. High pyrocatalytic performances of ferroelectric ceramics have been reported by various reports in multiple applications. This review starts with the basic introduction to ferroelectric ceramics, pyroelectric effect, and pyrocatalysis process. Further, it provides the review of recent studies utilizing ferroelectric ceramics for pyrocatalytic applications. The strategies to improve pyrocatalytic performance of ferroelectric ceramics are discussed in detail. At last, this review provides insights to new future directions for researchers working on ferroelectric pyrocatalysts.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"72 ","pages":"Article 100428"},"PeriodicalIF":12.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134934309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D MXenes for supercapacitors: Current status, opportunities and challenges 超级电容器的3D MXenes:现状、机遇和挑战
IF 12 2区 化学
Progress in Solid State Chemistry Pub Date : 2023-12-01 DOI: 10.1016/j.progsolidstchem.2023.100425
Sonali Verma , Bhavya Padha , Sheng-Joue Young , Yen-Lin Chu , Rajesh Bhardwaj , Rajneesh Kumar Mishra , Sandeep Arya
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