用于近红外光源的 Fe3+ 激活型发光材料的研究进展

IF 9.1 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Fangyi Zhao, Zhen Song, Quanlin Liu
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引用次数: 0

摘要

铁激活的近红外(NIR)发光材料因其可调谐的宽带发射和在夜视、生物医学成像、无损食品分析等领域的广泛应用潜力而吸引了越来越多的研究兴趣。深入了解晶体结构与发光性能之间的关系对于开发新型高效近红外功能材料具有重要作用。在这篇综述中,在简要介绍之后,我们首先基于 Tanabe-Sugano 能级图讨论了八面体和四面体晶场中铁的发光机理。接着,总结了掺铁近红外发光材料的研究进展,包括结构、性质和潜在应用,然后介绍了增强近红外稳态发光、持续发光和机械发光性能的策略。然后,我们比较了掺铁近红外材料的发光效率和发光热稳定性。最后,我们提出了铁激活近红外发光材料研究中的几个挑战和展望。本综述的目的不仅在于加深对铁发光机理的理解,还在于介绍当前掺铁材料的研究进展,从而为开发高效的铁激活近红外发光材料提供建设性策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Advances in Fe3+-activated luminescent materials for near-infrared light sources

Fe3+-activated near-infrared (NIR) luminescent materials have attracted growing research interests for their tunable broadband emission and extensive application potentials in the fields of night vision, biomedical imaging, nondestructive food analysis, etc. Deep insight into the relation between crystal structure and luminescence performance plays a significant role in developing novel efficient NIR functional materials. In this review, after a brief introduction, we first discuss the mechanism of Fe3+ luminescence in octahedral and tetrahedral crystal fields based on the Tanabe-Sugano energy level diagram. Next, the research progress of Fe3+-doped NIR luminescent materials, including structure, property and potential application, is summarized, followed by the strategies to enhance NIR steady-state luminescence, persistent luminescence and mechanoluminescence performances. Then we conduct a comparison of luminescence efficiency and luminescence thermal stability of Fe3+-doped NIR materials. At last, we propose several challenges and outlooks in the research of Fe3+-activated NIR luminescent materials. This review is aimed to provide a deeper understanding of not only Fe3+ luminescence mechanism but also the current research progress of Fe3+-doped materials, so as to provide constructive strategy in the exploitation of efficient Fe3+-activated NIR luminescent materials.

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来源期刊
Progress in Solid State Chemistry
Progress in Solid State Chemistry 化学-无机化学与核化学
CiteScore
14.10
自引率
3.30%
发文量
12
期刊介绍: Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.
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