Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.最新文献

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Investigation of cation environments in polycrystalline and single crystal PMN-PT using electron spectroscopy 用电子能谱法研究多晶和单晶PMN-PT中的阳离子环境
S. McBride, A. Bell
{"title":"Investigation of cation environments in polycrystalline and single crystal PMN-PT using electron spectroscopy","authors":"S. McBride, A. Bell","doi":"10.1109/ISAF.2002.1195965","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195965","url":null,"abstract":"The present study has been focused on ABO/sub 3/ type perovskite relaxor based ferroelectric single crystals and polycrystalline forms of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbTiO/sub 3/. Electron spectroscopy techniques including X-ray Photoelectron Spectroscopy (XPS) and Electron Energy Loss Spectroscopy (EELS) in the TEM have been used to investigate chemical environments and oxidation states of the A and B site occupants. Shifts in electron binding energies over the reported values for the cations in their native oxides have been measured using XPS and the oxidation state confirmed using EELS. In conclusion, the reported shifts are attributed to electronic polarisation, the greatest shift being exhibited by Pb/sup 2+/.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129829589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Leakage current properties of Ba/sub 0.7/Sr/sub 0.3/TiO/sub 3/ thin films depending on the film thickness Ba/sub 0.7/Sr/sub 0.3/TiO/sub 3/薄膜的漏电流特性随薄膜厚度的变化
C. Kugeler, R. Liedtke, R. Waser
{"title":"Leakage current properties of Ba/sub 0.7/Sr/sub 0.3/TiO/sub 3/ thin films depending on the film thickness","authors":"C. Kugeler, R. Liedtke, R. Waser","doi":"10.1109/ISAF.2002.1195908","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195908","url":null,"abstract":"High permittivity materials such as Ba/sub 0.7/Sr/sub 0.3/TiO/sub 3/ (BST) have attracted much attention as thin film materials for capacitors in further DRAM generations. Of particular interest are not only the dielectric constant but also the leakage current. Therefore the leakage current properties of BST were investigated as a function of the film thickness and the temperature. BST thin films were prepared by using chemical solution deposition (CSD) on platinum bottom electrodes in a thickness range from 26 nm up to 310 nm. To obtain a capacitor structure Pt top electrodes were sputtered on top of the BST. A result of this work is that the leakage current properties of thin films improve with decreasing thickness (at a constant electric field). For an estimation of the barrier height the leakage current properties were measured at different temperatures in a range from room temperature up to 600 K. From these measurements the barrier height can be estimated.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131243333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of multilayer ring transformer 多层环形变压器的研制
Nga-yan Wong, H. Chan, C. Choy
{"title":"Fabrication of multilayer ring transformer","authors":"Nga-yan Wong, H. Chan, C. Choy","doi":"10.1109/ISAF.2002.1195928","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195928","url":null,"abstract":"Residual porosity is one of the most common defects found in multilayer ceramic structures. The pores are created in the binder burnout process when solvents and binders are released from the ceramic green body. Without a well-controlled compaction technique, defects between sheets in the stacked body often exist, leading to delamination problems. Also, it is difficult to fabricate a ring-shaped multilayer structure without cracks, especially near the center hole. Due to the difference in thermal expansion coefficients of the mould and the ceramic green body, large internal stress is often induced in the ceramic green body during hot pressing and cracks are initiated during sintering. In this work, the fabrication process of a lead zirconate titanate (PZT) ring-shaped multilayer to be used as a transformer is described. By a specially designed mould and adjustment of the hot pressing conditions, the internal stress induced during hot pressing has been reduced effectively. In particular, the hot pressing process is divided into two steps in order to reduce the clamping of the inner shaft by the ceramic green body. Therefore, the inner shaft can be released easily and the delamination problem can be improved. Also the binder burnout process has been designed carefully by studying the TGA profile. Scanning electron microscopy is used to study the cross-sectional area of the transformer. It is found that the resulting multilayer transformer did not have cracks, pores and delamination. The performance of the transformer will be measured and reported in later work.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130869213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Fabrication of MFIS diodes using BLT (Bi,La)/sub 4/Ti/sub 3/O/sub 12/ and LaAlO/sub 3/ buffer layers 利用BLT (Bi,La)/亚4/Ti/亚3/O/亚12/和LaAlO/亚3/缓冲层制备MFIS二极管
B. Park, H. Ishiwara
{"title":"Fabrication of MFIS diodes using BLT (Bi,La)/sub 4/Ti/sub 3/O/sub 12/ and LaAlO/sub 3/ buffer layers","authors":"B. Park, H. Ishiwara","doi":"10.1109/ISAF.2002.1195895","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195895","url":null,"abstract":"We fabricated MFIS (metal-ferroelectric-insulator-semiconductor) diodes with Bi/sub 3.35/La/sub 0.75/Ti/sub 3/O/sub 12/ (BLT) films and lanthanum aluminate (LaAlO/sub 3/) buffer layers formed on Si(100) substrates. LaAlO/sub 3/ films were prepared by an MBE (molecular beam epitaxy) method. After the film deposition, they were subjected to ex site N/sub 2/ annealing in a rapid thermal annealing (RTA) furnace at 800/spl deg/C for 1 min. BLT films (150 nm) were deposited on these LaAlO/sub 3//Si structures using a sol-gel technique. The memory window of this BLT film annealed in O/sub 2/ ambient at 750/spl deg/C for 10 min was about 2.7 V. It was found that the leakage current density was on the order of 10/sup -6/ A/cm/sup 2/ at an electric field of 500 kV/cm. It was also found from the retention measurement that the capacitance values biased at a voltage in the hysteresis loop did not change for more than 3 hours.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"32 6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123230021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A model for switching in ferroelectric thin films by nucleation-growth of domains with three-dimensional polarization 三维极化区成核生长的铁电薄膜开关模型
D. Ricinschi, Y. Ishibashi, M. Iwata, L. Mitoseriu, M. Okuyama
{"title":"A model for switching in ferroelectric thin films by nucleation-growth of domains with three-dimensional polarization","authors":"D. Ricinschi, Y. Ishibashi, M. Iwata, L. Mitoseriu, M. Okuyama","doi":"10.1109/ISAF.2002.1195875","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195875","url":null,"abstract":"In this paper we studied the switching kinetics using a discrete Landau-type three-dimensional polarization thermodynamic potential, with the elastic constraints of a film attached to a substrate. We have shown that 180/sup 0/ domain reversal and polarization vector rotations are possible switching mechanisms, depending on field strength and elastic stresses. The role of in-plane polarization components to switching has been investigated and shown to support experimental findings.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"104 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115686661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Piezoelectric functionally gradient material for bending devices based on Ba(Ti,Sn)O/sub 3/ ceramics 基于Ba(Ti,Sn)O/sub 3/陶瓷的弯曲器件压电功能梯度材料
R. Steinhausen, A. Kouvatov, H. Beige, H. Langhammer, H. Abicht
{"title":"Piezoelectric functionally gradient material for bending devices based on Ba(Ti,Sn)O/sub 3/ ceramics","authors":"R. Steinhausen, A. Kouvatov, H. Beige, H. Langhammer, H. Abicht","doi":"10.1109/ISAF.2002.1195943","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195943","url":null,"abstract":"Functionally gradient materials (FGM) with one dimensional gradient of the piezoelectric activity can be used for bending actuators. For this, monolithic ceramics consisting of N layers with different chemical properties are prepared. The gradient of the chemical properties has to be transformed into a gradient of the piezoelectric properties by a poling process. In this work the poling and bending behavior of such FGM devices was investigated and described by analytical approximations. Monolithic samples with 2, 3 or 4 layers of BaTi/sub 1-x/Sn/sub x/O/sub 3/ (BTS) ceramics with different amount of tin (0.075 /spl les/ x /spl les/ 0.15) were prepared. The poling behavior was characterized by measurements of the dielectric virgin loops P(E). The bending deflection of poled devices depends on the amount of tin in the layers and slightly increases with increasing number of layers. Additionally, conventional glued bending devices with the same number of layers and a corresponding chemical composition were investigated. The experimental data were compared with the results of analytical approximations. Here, measured properties of single BTS ceramics with the appropriate amount of tin were used for the calculation of hysteresis loops and bending deflection of the layered systems. A good correspondence between the model structures and the theory was found. However, slight differences for the monolithic ceramics were obtained. We suppose that this is due to the existence of interface layers with indefinite material properties between neighboring layers.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":" 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"113951593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Direct growth of orthorhombic potassium niobate (KNbO/sub 3/) crystal from an aqueous solution 在水溶液中直接生长正交铌酸钾(KNbO/ sub3 /)晶体
R. Komatsu, K. Adachi, K. Ikeda
{"title":"Direct growth of orthorhombic potassium niobate (KNbO/sub 3/) crystal from an aqueous solution","authors":"R. Komatsu, K. Adachi, K. Ikeda","doi":"10.1109/ISAF.2002.1195957","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195957","url":null,"abstract":"Ferroelectric orthorhombic potassium niobate (KNbO/sub 3/) crystal is successfully grown from an aqueous solution dissolving K/sub 2/NbO/sub 3/F as a nutrient. Although the size of each crystal is about 30 /spl mu/m or less, properties of the formed KNbO/sub 3/ crystals have been examined. The possibility of this method in the future to grow KNbO/sub 3/ crystals or thin films has also been investigated in order to apply KNbO/sub 3/ to SAW and BAW devices.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130333560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystalline properties of ferroelectric-relaxor PMN-PT thin films by pulsed laser deposition 脉冲激光沉积铁电弛豫PMN-PT薄膜的结晶特性
S.K. Singh, P. Bhattacharya, P. Thomas, S. Palmer
{"title":"Crystalline properties of ferroelectric-relaxor PMN-PT thin films by pulsed laser deposition","authors":"S.K. Singh, P. Bhattacharya, P. Thomas, S. Palmer","doi":"10.1109/ISAF.2002.1195888","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195888","url":null,"abstract":"The dielectric and crystalline properties of ferroelectric thin films of 0.9[Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/]-0.1PbTiO/sub 3/ (.9PMN-.1PT) have been investigated. Ceramic targets of 0.9PMN-0.1PT with and without excess PbO were used for thin film deposition and were grown on substrates of SrTiO/sub 3/ LaAlO/sub 3/, MgO, and Pt/TiO/sub 2//SiO/sub 2//Si using pulsed laser ablation deposition. It was shown that the phase purity of the films was dependent on the film thickness. Furthermore we have shown that as the thickness of the films increases from 100nm to 600nm there is a progressive decline in the local strain and hence an improvement in the local crystallinity of the films. The dielectric constant for our films (3900 at 10KHz) is higher than previous reports on 0.9PMN-0.1PT films. We have also shown that there is considerable benefit in changing lower electrodes. The XRD shows that the films are highly c-axis orientated as grown on YBa/sub 2/Cu/sub 3/O/sub 7/ (001) or SrRuO/sub 3/ (001) and (111) orientated on Pt(111) lower electrodes. The sizes of the grains depend upon the nucleation density and the rate of growth onto the lower electrode used. Slower growth rates lead to excess of lead in the film at the grain boundaries while accelerated growth rates lead to higher porosity's. It was shown that annealing for 1 hour at 600/spl deg/C reduces porosity and improves surface quality.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"202 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123541765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies of proton irradiated 0.9PMN-0.1PT/P(VDF-TrFE) 0-3 composites 质子辐照0.9PMN-0.1PT/P(VDF-TrFE) 0-3复合材料的研究
K. H. Lam, H. Chan, C. Choy, E. Luo, I. Wilson
{"title":"Studies of proton irradiated 0.9PMN-0.1PT/P(VDF-TrFE) 0-3 composites","authors":"K. H. Lam, H. Chan, C. Choy, E. Luo, I. Wilson","doi":"10.1109/ISAF.2002.1195863","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195863","url":null,"abstract":"Polyvinylidene fluoride-trifluoroethylene [P(VDF-TrFE) 70/30 mol%] copolymer can be transformed from a ferroelectric to a relaxor material after proton irradiation. The phase transition peak broadens and shifts towards lower temperature as the measurement frequency decreases. In the present study, 0-3 composites are fabricated by incorporating 0-9Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-0.1PbTiO/sub 3/ ceramic powder into a P(VDF-TrFE) 70/30 mol% copolymer matrix. 0.9PMN-0.1PT ceramic is a relaxor ferroelectric with high dielectric permittivity. It was found that the relative permittivity of PMN-PT/P(VDF-TrFE) 0-3 composite increases with increasing ceramic volume fraction. Composites with 0.3 and 0.4 volume fraction of 0.9PMN-0.1PT were subjected to proton irradiation. With a 80 Mrad (4.76 /spl times/ 10/sup 13/ ions/cm/sup 2/) proton dosage, the relative permittivity of the 0.4 volume fraction 0-3 composites can go up to 130 near room temperature (at 1 kHz).","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124577405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Piezoelectric transformer for 30 W output AC-DC converters 用于输出功率为30w的交直流变换器的压电变压器
M. Yamamoto, Y. Sasaki, T. Inoue, A. Ochi, S. Hamamura
{"title":"Piezoelectric transformer for 30 W output AC-DC converters","authors":"M. Yamamoto, Y. Sasaki, T. Inoue, A. Ochi, S. Hamamura","doi":"10.1109/ISAF.2002.1195940","DOIUrl":"https://doi.org/10.1109/ISAF.2002.1195940","url":null,"abstract":"A piezoelectric transformer using AC-DC converters is described that has a multilayered construction in the thickness direction and operates in contour-extensional vibration mode. The output impedance is designed to be low - approximately several tens of ohms. Testing of a fabricated transformer 14 mm long, 14 mm, wide, and 5.8 mm showed that it had a 0.4 gain, 26 W output power, and 96.3% efficiency at 135 kHz when the temperature increase was 30/spl deg/C. A fabricated AC-DC converter with this transformer had good line and load regulation and a maximum efficiency of 90.2%.","PeriodicalId":415725,"journal":{"name":"Proceedings of the 13th IEEE International Symposium on Applications of Ferroelectrics, 2002. ISAF 2002.","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126551991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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