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Thermosensitive adhesion boosts low-grade heat harvesting of ionic thermoelectric hydrogels 热敏附着力提高低品位的热收集离子热电水凝胶
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-09 DOI: 10.1016/j.nanoen.2026.111707
Jiafu Shen, Yiminghao Wang, Weidong Nie, Yu Dai, Fan Xia, Xiaojin Zhang
{"title":"Thermosensitive adhesion boosts low-grade heat harvesting of ionic thermoelectric hydrogels","authors":"Jiafu Shen,&nbsp;Yiminghao Wang,&nbsp;Weidong Nie,&nbsp;Yu Dai,&nbsp;Fan Xia,&nbsp;Xiaojin Zhang","doi":"10.1016/j.nanoen.2026.111707","DOIUrl":"10.1016/j.nanoen.2026.111707","url":null,"abstract":"<div><div>Low-grade waste heat is an overlooked but abundant source of energy that can be converted to electricity, e.g., using a thermoelectric generator (TEG). The development of high-performance thermoelectric materials, however, remains a challenge because it requires structural manipulation and interfacial matching of material-heat source and material-electrode. Here, we report thermosensitive adhesion-boosted body heat harvesting of calcium ion (Ca<sup>2+</sup>)-crosslinked ald-alginate-gelatin imine-based (CaAG) hydrogels. The CaAG hydrogel-assembled TEG shows a high Seebeck coefficient of 21.3 mV K<sup>−1</sup> with the maximum output power density of 5.2 mW m<sup>−2</sup> K<sup>−2</sup> at 10 K temperature difference (55 % relative humidity), which are much greater than those of most ionic thermoelectric materials. A flexible device comprising 16 TEGs generates a voltage of 2.34 V and an output power of 138 μW. Our work proposes an interfacial adhesion strategy for improving the thermoelectric performance and demonstrates the prospect of low-grade heat harvesting using hydrogels.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111707"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145957399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Breaking the cost-performance trade-off in electrocaloric cooling via high-entropy engineered multilayer ceramics 利用高熵工程多层陶瓷打破电热冷却的成本-性能权衡
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-09 DOI: 10.1016/j.nanoen.2026.111709
Hao Wang , Ziyue Ma , Le Zhang , Qi Zhang , Guangzhi Dong , Zhonglin Wang , Biaolin Peng
{"title":"Breaking the cost-performance trade-off in electrocaloric cooling via high-entropy engineered multilayer ceramics","authors":"Hao Wang ,&nbsp;Ziyue Ma ,&nbsp;Le Zhang ,&nbsp;Qi Zhang ,&nbsp;Guangzhi Dong ,&nbsp;Zhonglin Wang ,&nbsp;Biaolin Peng","doi":"10.1016/j.nanoen.2026.111709","DOIUrl":"10.1016/j.nanoen.2026.111709","url":null,"abstract":"<div><div>Pb(Sc0.5Ta0.5)O<sub>3</sub> (PST) has been regarded as a leading candidate for device-grade solid-state cooling due to the exhibition of strong electrocaloric (EC) response. However, its high sintering temperature impedes the fabrication of low-cost multilayer ceramic capacitor (MLCC) device, which has been viewed as one of most potential cooling protocols. To overcome this limitation, we propose a material-to-device co-optimization strategy for the PST system that integrate high-entropy B-site chemistry with a low-temperature MLCC architecture. An equimolar incorporation of Sc, Ta, In, Nb, and Zr into the PST matrix produced the special B-site high-entropy perovskite Pb(Sc<sub>0.2</sub>Ta<sub>0.2</sub>In<sub>0.2</sub>Nb<sub>0.2</sub>Zr<sub>0.2</sub>)O<sub>3</sub> (PSTINZ). This composition enabled co-firing with Ag/Pd (0.4/0.6) internal electrodes at 950°C, requiring only a brief post-anneal at 650°C for 2.5 h. The reduced firing temperature, shortened annealing duration, and decreased use of noble metals collectively lower the overall manufacturing cost by ∼65 %. More importantly, the fabricated PSTINZ-MLCC exhibits a large adiabatic temperature change <em>ΔT</em><sub><em>ad</em></sub> = 8.02 K and a considerable COP of 6.5 at 40°C under 400 kV·cm⁻¹ (direct method) while maintaining this cost-effectiveness. Direct and indirect measurements are mutually consistent and further indicate an effective operating window of ∼35 K around room temperature. Combining these performance and cost advantages, this quinary high-entropy MLCC provides a compelling platform for next-generation electrocaloric solid-state cooling.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111709"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145920542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The path of the separator: Through production, categorization, in-service performance, and sustainable recycling in LIBs 分离器的路径:通过lib的生产,分类,使用性能和可持续回收
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-14 DOI: 10.1016/j.nanoen.2026.111718
Pengfei Zhang , Jiahao Yuan , Mengxing Zhang , Xiuyun Chuan , Fangfang Liu , Jinan Niu , Peizhong Feng
{"title":"The path of the separator: Through production, categorization, in-service performance, and sustainable recycling in LIBs","authors":"Pengfei Zhang ,&nbsp;Jiahao Yuan ,&nbsp;Mengxing Zhang ,&nbsp;Xiuyun Chuan ,&nbsp;Fangfang Liu ,&nbsp;Jinan Niu ,&nbsp;Peizhong Feng","doi":"10.1016/j.nanoen.2026.111718","DOIUrl":"10.1016/j.nanoen.2026.111718","url":null,"abstract":"<div><div>As a critical internal component of lithium-ion batteries (LIBs), the separator plays a dual role: it physically isolates the positive and negative electrodes while simultaneously facilitating the transport of lithium ions (Li<sup>+</sup>). Its performance determines the battery's cycle life, rate capability, and safety. This review presents a holistic, life-cycle-oriented examination of LIB separators, establishing a closed-loop framework linking “Fabrication-Structure-Failure-Recycling”. We first critically evaluate mainstream and emerging fabrication techniques, elucidating how processing parameters determine key microstructural features such as pore tortuosity, anisotropy, and surface chemistry. Subsequently, we bridge the gap between static structures and dynamic failure mechanisms. By integrating multiscale theoretical simulations, we elucidate how fabrication-induced defects predetermine specific failure pathways-ranging from dendrite penetration and thermal shrinkage to electrolyte degradation. Furthermore, responding to the urgent demand for a circular economy, we provide a comprehensive analysis of sustainable upcycling strategies, contrasting the thermodynamic feasibility and environmental footprint of physical, chemical, and pyrolytic recycling routes. Finally, we outline critical bottlenecks and future opportunities for next-generation separator design, including multifunctional architectures, recyclability, and predictive modeling frameworks tailored for emerging battery chemistries. This review aims to provide a failure-informed and multiscale design paradigm for separators, accelerating the rational development of safer and higher-performance energy storage systems.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111718"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Shape-configurable and motion-designed droplet for high performance liquid-solid triboelectric nanogenerator 用于高性能液-固摩擦电纳米发电机的形状可配置和运动设计液滴
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-14 DOI: 10.1016/j.nanoen.2026.111723
Zhaoyang Yu , Yujie Hu , Ke Li , Xizhou Gu , Xuhui Yi , Renjun Xu , Ruijie Tang , Bin Wu , Chenguo Hu , Zhao Wang , Wenlin Liu , Zhong Lin Wang
{"title":"Shape-configurable and motion-designed droplet for high performance liquid-solid triboelectric nanogenerator","authors":"Zhaoyang Yu ,&nbsp;Yujie Hu ,&nbsp;Ke Li ,&nbsp;Xizhou Gu ,&nbsp;Xuhui Yi ,&nbsp;Renjun Xu ,&nbsp;Ruijie Tang ,&nbsp;Bin Wu ,&nbsp;Chenguo Hu ,&nbsp;Zhao Wang ,&nbsp;Wenlin Liu ,&nbsp;Zhong Lin Wang","doi":"10.1016/j.nanoen.2026.111723","DOIUrl":"10.1016/j.nanoen.2026.111723","url":null,"abstract":"<div><div>Liquid-solid triboelectric nanogenerators (LS-TENGs) possess great potential in distributed energy harvesting. Yet the long-standing unresolved issue of the uncontrolled droplet configuration significantly impedes their output performance. Although droplet manipulation technology may be a solution, existing methods are often limited by insufficient driving force and specialized scenarios, restricting droplet size and moving speed. Herein, we propose a novel shape-configurable and motion-designed droplet manipulation (SMDM) strategy that enables droplets with three-dimensional manipulation and non-contact obstacle crossing abilities, achieving a sliding speed of 2.216 m·s<sup>−1</sup> and a momentum of 705 g·mm·s<sup>−1</sup>. We developed a shape-configurable and motion-designed droplet-based TENG (SMD-TENG) with 100 % electrode utilization over a large surface area, reaching a record-high output charge density of 392 µC·m<sup>−2</sup> (5.3 times the previous maximum). Furthermore, a five-grating SMD-TENG with 98.6 % high stability is constructed, and the first water-polymer triboelectric series for accurate material selection is also established. This work presents a universal droplet manipulation strategy and a new fundamental LS-TENG design, offering significant guidance for high-performance liquid energy harvesting and its applications.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111723"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145962766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An energy-dense polysulfide/ferricyanide redox flow battery enabled by cation engineering 一种能量密集的聚硫/铁氰化物氧化还原液流电池
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-14 DOI: 10.1016/j.nanoen.2026.111722
Mahla Sarfaraz Khabbaz , Diqing Yue , Lily Shukla , Anupma Thakur , Sepideh Biabanialitappeh , Jian Xie , J. David Bazak , Xiaoliang Wei
{"title":"An energy-dense polysulfide/ferricyanide redox flow battery enabled by cation engineering","authors":"Mahla Sarfaraz Khabbaz ,&nbsp;Diqing Yue ,&nbsp;Lily Shukla ,&nbsp;Anupma Thakur ,&nbsp;Sepideh Biabanialitappeh ,&nbsp;Jian Xie ,&nbsp;J. David Bazak ,&nbsp;Xiaoliang Wei","doi":"10.1016/j.nanoen.2026.111722","DOIUrl":"10.1016/j.nanoen.2026.111722","url":null,"abstract":"<div><div>Polysulfide/ferricyanide (S/Fe) redox flow battery is an attractive cost-effective grid energy storage system but is limited by low energy density and irreversible performance fading. Here we demonstrate cation engineering as an effective approach to enhance the energy density. The use of Li<sup>+</sup> cation greatly improves the solubilities of redox anions through strengthening the water solvating interactions. Compared to Nafion membranes, a selected commercial cation exchange membrane exhibits an exceptional ability to mitigate the crossover of redox anions and thus substantially extends the cycle life of S/Fe flow cells. By using the attenuated total reflectance mode to minimize spectral interference, we successfully establish the feasibility of exploiting the Fourier transform infrared technique to determine the state of charge of S/Fe flow cells. The strategies of cation engineering and permselective membrane offers an encouraging opportunity to advance the S/Fe flow battery with boosted charge storage and durability.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111722"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145974584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging coordination polymer photocatalysts for water splitting: From mechanistic insights and design strategies to application roadmap 用于水分解的新型配位聚合物光催化剂:从机理和设计策略到应用路线图
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-23 DOI: 10.1016/j.nanoen.2026.111749
Akanksha Chauhan , Rohit Kumar , Pankaj Raizada , Khoa Dang Dang , Quyet Van Le , Aftab Aslam Parwaz Khan , Pardeep Singh , Van-Huy Nguyen , Anita Sudhaik
{"title":"Emerging coordination polymer photocatalysts for water splitting: From mechanistic insights and design strategies to application roadmap","authors":"Akanksha Chauhan ,&nbsp;Rohit Kumar ,&nbsp;Pankaj Raizada ,&nbsp;Khoa Dang Dang ,&nbsp;Quyet Van Le ,&nbsp;Aftab Aslam Parwaz Khan ,&nbsp;Pardeep Singh ,&nbsp;Van-Huy Nguyen ,&nbsp;Anita Sudhaik","doi":"10.1016/j.nanoen.2026.111749","DOIUrl":"10.1016/j.nanoen.2026.111749","url":null,"abstract":"<div><div>Growing concerns regarding environmental and energy challenges have substantially contributed in the development of efficient and sustainable PWS (photocatalytic water splitting) techniques has been greatly aided by. Beyond enormous photocatalytic materials, CPs (coordination polymers), which are made from metal nodes and organic linkers, have demonstrated extensive potential because of their structural tunability, suitable E<sub>g</sub> (energy bandgap) energies, and ability to enable efficient charge separation. High surface areas, dual active sites, a variety of pore architectures and tunable functionalities are some of the distinctive structural features of CPs that cooperatively enhance light harvesting, enable photoinduced charge carrier separation and transport, and promote efficient interaction between catalytic sites and water molecules. These characteristics play a major role in upgrading the overall functioning of PWS systems. In this review, we first examine the detailed molecular structure of CPs using a computational approach. Following this, the classification of CPs is presented, with a particular emphasis on different metal-centered frameworks, dimensionality, and porosity, along with modification strategies. These metals are of particular interest due to favourable redox properties, variable coordination geometries, and strong light absorption capabilities. Moreover, the role of different ligands and heterojunction in CPs have been explored. The construction of heterostructures based on these metals facilitates efficient charge separation, which is critical for effective photocatalytic applications. Additionally, the mechanism of photocatalytic OWS (overall water splitting) has been discussed, with an emphasis on the fundamental processes of light absorption, photocarriers separation, and surface redox reactions involved in H<sub>2</sub> and O<sub>2</sub> evolution. Besides this, we also provided a brief overview of the role of interfacial defects, active sites, and co-catalysts, as well as the unique advantages of CPs in photocatalysis. In addition, recent applications of CP-based photocatalysts for PWS are highlighted, with particular attention to mechanistic insights and performance. Finally, the review summarised by outlining the key disputes and future research directions for advancing CP-based photocatalysts in OWS applications.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111749"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146033821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-sensor polychromatic visual information processing enabled by all-optical controlled neuromorphic devices 全光控制神经形态装置实现传感器内多色视觉信息处理
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-12 DOI: 10.1016/j.nanoen.2026.111715
Dunan Hu , Ruqi Yang , Honglie Lin , Qiujiang Chen , Lu Chen , Yang Tian , Kequan Xia , Jianguo Lu
{"title":"In-sensor polychromatic visual information processing enabled by all-optical controlled neuromorphic devices","authors":"Dunan Hu ,&nbsp;Ruqi Yang ,&nbsp;Honglie Lin ,&nbsp;Qiujiang Chen ,&nbsp;Lu Chen ,&nbsp;Yang Tian ,&nbsp;Kequan Xia ,&nbsp;Jianguo Lu","doi":"10.1016/j.nanoen.2026.111715","DOIUrl":"10.1016/j.nanoen.2026.111715","url":null,"abstract":"<div><div>Traditional vision systems relying on CMOS image sensors typically demand substantial computational resources and network transmission. Particularly when processing color images, they suffer from issues such as system latency and high power consumption. To address these challenges, biomimetic neuromorphic vision sensors integrating sensing, memory, and computation have garnered widespread attention. Herein, we report for the first time a multispectral all-optical controlled neuromorphic device based on an amorphous ZnO/Nb<sub>2</sub>O<sub>5</sub> heterojunction, an in-sensor computing unit that integrates sensing and artificial synaptic functionalities into a single device. This device shows programmable, optically-induced reversible conductance, simulating excitatory and inhibitory postsynaptic currents at 620 nm and 460 nm, respectively. Importantly, it demonstrates wide-spectrum response (365–660 nm) and multispectral selectivity. The multispectral synaptic weight matrix enables accurate in-sensor multicolor visual recognition and classification tasks, encompassing mixed-color digits, flower images, and traffic lights. This work realizes the integration of sensing, memory, all-optical controlled write/erase, multispectral perception, and computation into one device, offering a promising material strategy for low-power, wide-spectrum, and intelligent neuromorphic visual systems.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111715"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145957395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile-processed n-p-type binary cathode interlayers: Concurrent enhancement of photovoltaic performance and mechanical robustness 易加工的n-p型二元阴极中间层:光伏性能和机械稳健性的同步增强
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-06 DOI: 10.1016/j.nanoen.2026.111702
Weidong Li , Xinying Wang , Heng Liu , Qilun Zhang , Xian’e Li , Tong Liu , Can Liu , Xiaofeng Xu , Liangmin Yu , Xichang Bao , Xianjie Liu , Iain McCulloch , Liming Ding , Xinhui Lu , Mats Fahlman , Chuanfei Wang
{"title":"Facile-processed n-p-type binary cathode interlayers: Concurrent enhancement of photovoltaic performance and mechanical robustness","authors":"Weidong Li ,&nbsp;Xinying Wang ,&nbsp;Heng Liu ,&nbsp;Qilun Zhang ,&nbsp;Xian’e Li ,&nbsp;Tong Liu ,&nbsp;Can Liu ,&nbsp;Xiaofeng Xu ,&nbsp;Liangmin Yu ,&nbsp;Xichang Bao ,&nbsp;Xianjie Liu ,&nbsp;Iain McCulloch ,&nbsp;Liming Ding ,&nbsp;Xinhui Lu ,&nbsp;Mats Fahlman ,&nbsp;Chuanfei Wang","doi":"10.1016/j.nanoen.2026.111702","DOIUrl":"10.1016/j.nanoen.2026.111702","url":null,"abstract":"<div><div>n-Type small molecules such as perylene diimides (PDI) and naphthalene diimides (NDI) derivatives are widely used as cathode interlayers (CILs) in organic solar cells (OSCs) employing narrow-band gap electron acceptors (NBGEAs), owing to their excellent electron transport properties. However, such interfacial materials tend to severely aggregate within the film, leading to poor film morphology and mechanical fragility. Moreover, these CILs often pin the cathode Fermi level at energies lower than the electron transport levels of NBGEAs, leading to suboptimal energy level alignment. In this study, we introduce a binary n-p-type CIL by incorporating the classical p-type cathode interfacial material PFN-Br into the n-type cathode interfacial material PDINO. The resulting binary CIL exhibits a modified PDINO aggregation configuration and a smoother film morphology, while it also effectively lowers the cathode work function through the PFN-Br induced double dipole effect. These combined effects enhance and stabilize the electrical properties of the binary CIL. Model OSCs based on PM6: Y6 utilizing this n-p type CIL show suppressed bimolecular and trap assisted recombination, resulting in improved photovoltaic performance. Additionally, the binary CIL enhances the mechanical durability of flexible devices, highlighting its potential for application in high-performance rigid and flexible OSCs.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111702"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145974557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemically passivated Ni3 + /Ni4+ for super stabilized ultrahigh-nickel cathodes 超稳定超高镍阴极的电化学钝化Ni3 + /Ni4+
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-14 DOI: 10.1016/j.nanoen.2026.111724
Xinyu Zhang , Yuming Liu , Luoming Zhang , Haoji Wang , Xinyu Hu , Ningyun Hong , Jiangnan Huang , Xiaoyu Cao , Limin Zhu , Leiming Lang , Wentao Deng , Guoqiang Zou , Hongshuai Hou , Jinhui Cao , Xiaobo Ji
{"title":"Electrochemically passivated Ni3 + /Ni4+ for super stabilized ultrahigh-nickel cathodes","authors":"Xinyu Zhang ,&nbsp;Yuming Liu ,&nbsp;Luoming Zhang ,&nbsp;Haoji Wang ,&nbsp;Xinyu Hu ,&nbsp;Ningyun Hong ,&nbsp;Jiangnan Huang ,&nbsp;Xiaoyu Cao ,&nbsp;Limin Zhu ,&nbsp;Leiming Lang ,&nbsp;Wentao Deng ,&nbsp;Guoqiang Zou ,&nbsp;Hongshuai Hou ,&nbsp;Jinhui Cao ,&nbsp;Xiaobo Ji","doi":"10.1016/j.nanoen.2026.111724","DOIUrl":"10.1016/j.nanoen.2026.111724","url":null,"abstract":"<div><div>Ultrahigh-nickel layered cathode materials (LiNi<sub>0.9</sub>Co<sub>0.05</sub>Mn<sub>0.05</sub>O<sub>2</sub>) are anticipated to achieve commercialization with promised energy density. However, the durability of the structure is seriously reduced by surface parasitic reactions and anisotropic stress accumulation. To alleviate the problems above, we aim to isolate the highly oxidized Ni<sup>3+</sup>/Ni<sup>4+</sup> and O<sup>-</sup> on the surface from the electrolyte and fixing the position of oxygen through a synergistic oxygen immobilization and surface passivation strategy. Highly activity Ni<sup>3+</sup>/Ni<sup>4+</sup> is effectively passivated as a result of an ionic-conduction LiInO<sub>2</sub> coating layer, leading to mitigation of parasitic decomposition reactions, as proved by <em>ex-situ</em> XAS and TOF-SIMS analysis. Moreover, surficial lattice integrality is significantly improved on account of strongly ionic In-O incorporation, contributing to elevated lattice endurance accompanied with outstanding cycle stability, confirmed by <em>in-situ</em> XRD patterns. Leveraging the effects of elemental doping and surface engineering, the designed 1 % In-NCM cathode exhibits an impressive capacity retention of 93.9 % after 120 cycles at 1 C (1 C = 200 mA g<sup>−1</sup>), far exceeding the 75.9 % retention of pristine NCM (LiNi<sub>0.9</sub>Co<sub>0.05</sub>Mn<sub>0.05</sub>O<sub>2</sub>), demonstrating remarkable long-term cycling stability. These findings provide novel insights for accelerating the application of ultrahigh-nickel layered cathode materials.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"149 ","pages":"Article 111724"},"PeriodicalIF":17.1,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145974577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MEMFNet: Toward a knowledge-guided paradigm for interpretable electrochemical performance prediction MEMFNet:面向可解释电化学性能预测的知识导向范式
IF 17.1 1区 材料科学
Nano Energy Pub Date : 2026-03-01 Epub Date: 2026-01-16 DOI: 10.1016/j.nanoen.2026.111735
Kun Han , Jianxing Yang , Chenglong Wang , Junfeng Li , Zhijing Zhu , Wenjie Mai , Jinliang Li , Guang Yang , Likun Pan
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