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Birdlike multisensory integrated oxide transistors for motion perception 用于运动感知的鸟状多感官集成氧化物晶体管
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-18 DOI: 10.1016/j.nanoen.2025.111045
Muhammad Zahid , Jiaying Gong , Muhammad Irfan Sadiq , Jingwen Wang , Fawad Aslam , Chenxing Jin , Wanrong Liu , Yunchao Xu , Junliang Yang , Jia Sun
{"title":"Birdlike multisensory integrated oxide transistors for motion perception","authors":"Muhammad Zahid ,&nbsp;Jiaying Gong ,&nbsp;Muhammad Irfan Sadiq ,&nbsp;Jingwen Wang ,&nbsp;Fawad Aslam ,&nbsp;Chenxing Jin ,&nbsp;Wanrong Liu ,&nbsp;Yunchao Xu ,&nbsp;Junliang Yang ,&nbsp;Jia Sun","doi":"10.1016/j.nanoen.2025.111045","DOIUrl":"10.1016/j.nanoen.2025.111045","url":null,"abstract":"<div><div>Multisensory inputs have been observed to augment behavioral and neural responses in avian species, underscoring the importance of converging perceptual enhancement, cognitive function, and motion perception into a unified system. To address the need for neuromorphic devices that replicate this process, we present a bio-inspired neuromorphic system that integrates cognitive-vestibular sensory motion perception. The system leverages a multi-input device fabricated from an ion-gel-gated In<sub>2</sub>O<sub>3</sub> transistor, which exhibits adaptive plasticity, stable modulation, and spatiotemporal integration. The system embodies efficacious multisensory integration by processing dual-modal motion signals as spike trains, assigning salience weights via mean-firing rates and postsynaptic currents. Validation experiments demonstrate the system's ability to recognize human activities and classify aircraft flight motion modes, aligning with biologically plausible principles of multisensory integration. This neuromorphic system has far-reaching implications for developing advanced sensory artificial devices, smart electronics, and interactive intelligent electronics.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111045"},"PeriodicalIF":16.8,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143846804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-interface modification of perovskite solar cells with lithium acetate and hydroxyl functionalized alkynyl derivative 醋酸锂和羟基功能化炔基衍生物双界面改性钙钛矿太阳能电池
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-18 DOI: 10.1016/j.nanoen.2025.111027
Yu Yuan , Jing Chen , Yili Wang , Jiandong He , Guosheng Niu , Kaiyi Yang , Jizheng Wang , Yongjun Li
{"title":"Dual-interface modification of perovskite solar cells with lithium acetate and hydroxyl functionalized alkynyl derivative","authors":"Yu Yuan ,&nbsp;Jing Chen ,&nbsp;Yili Wang ,&nbsp;Jiandong He ,&nbsp;Guosheng Niu ,&nbsp;Kaiyi Yang ,&nbsp;Jizheng Wang ,&nbsp;Yongjun Li","doi":"10.1016/j.nanoen.2025.111027","DOIUrl":"10.1016/j.nanoen.2025.111027","url":null,"abstract":"<div><div>Simultaneous regulation of film morphology and defects at the interface is essential to achieving stable and efficient perovskite solar cells (PSCs). In this study, we synthesized a novel alkynyl passivator DOTB, featured acetylenic π-systems that can engage in π-electron coordination with undercoordinated Pb<sup>2 +</sup> and hydroxyl groups that can provide hydrogen bonding with I<sup>-</sup> anions, thereby modifying perovskite/hole transport layer (HTL) interface. Additionally, we integrated lithium acetate (LiAc) into the electron transport layer (ETL)/perovskite interface. Here LiAc simultaneously functions as a crystallization modulator and defect passivator through Li⁺ diffusion and acetate-mediated interaction. This dual-interface modification strategy accomplishes simultaneous bulk phase passivation and dual interfacial passivation in PSCs. It reduces defect density, enhances crystallization, enhances carrier transport, and reduces non-radiative recombination. As a result, the dual-interface modified PSCs achieve a maximum PCE of 25.48 %. Moreover, the unencapsulated devices demonstrate notably improved stability, preserving above 90 % of their initial performance under ambient air conditions for 1200 hours, and exceeding 80 % following 1000-hours thermal stability assessment conducted at 85 ℃.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111027"},"PeriodicalIF":16.8,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143846794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-temperature synthesis of amorphous LiF/Li₃BO₃ interfaces with F, B co-doped subsurface for long-cycling and high-rate Ni-rich cathodes 低温合成长循环高倍率富镍阴极用F、B共掺杂LiF/Li₃BO₃非晶界面
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-18 DOI: 10.1016/j.nanoen.2025.111009
Guangchang Yang , Borui Liu , Feiyan Lai , Ke Xue , Xiaohui Zhang , Hongqiang Wang , Ming Xie , Changhong Wang
{"title":"Low-temperature synthesis of amorphous LiF/Li₃BO₃ interfaces with F, B co-doped subsurface for long-cycling and high-rate Ni-rich cathodes","authors":"Guangchang Yang ,&nbsp;Borui Liu ,&nbsp;Feiyan Lai ,&nbsp;Ke Xue ,&nbsp;Xiaohui Zhang ,&nbsp;Hongqiang Wang ,&nbsp;Ming Xie ,&nbsp;Changhong Wang","doi":"10.1016/j.nanoen.2025.111009","DOIUrl":"10.1016/j.nanoen.2025.111009","url":null,"abstract":"<div><div>Ni-rich layered oxide cathode materials, such as LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub> (NCM), are promising candidates for high-performance lithium-ion batteries (LIBs) due to their high energy density and cost-effectiveness. However, structural degradation and interfacial instability hinder their cycling stability. In this study, we introduce a low-temperature modification strategy to construct an amorphous LiF/Li<sub>3</sub>BO<sub>3</sub> interface with an F, B co-doped subsurface on NCM cathodes. This dual modification enhances bulk structural stability and accelerates interfacial ion transport kinetics. As a result, the LiF/Li<sub>3</sub>BO<sub>3</sub>-modified NCM cathode achieves a high specific capacity of 205.4 mAh·g⁻¹ within a voltage window of 2.8–4.5 V at 1 C. Remarkably, it maintains 70.6 % capacity retention after 500 cycles, a substantial improvement over the unmodified NCM, which retains only 34.2 %. Moreover, the modified cathode exhibits excellent rate capability, delivering high capacities of 185.5 mAh·g⁻¹ at 5 C and 172.8 mAh·g⁻¹ at 10 C. This work offers a novel low-temperature approach to tailor both the bulk and surface microstructures of Ni-rich cathodes, paving the way for high-energy-density and long-life lithium-ion batteries.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111009"},"PeriodicalIF":16.8,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143849758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance underwater energy harvesting using flexible piezoelectric nanogenerator based on electrospun polyvinylidene fluoride-LiNbO3 fibers 基于静电纺聚偏氟乙烯- linbo3纤维的柔性压电纳米发电机的高性能水下能量收集
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-18 DOI: 10.1016/j.nanoen.2025.111042
Athira Mankuni , Soney Varghese
{"title":"High-performance underwater energy harvesting using flexible piezoelectric nanogenerator based on electrospun polyvinylidene fluoride-LiNbO3 fibers","authors":"Athira Mankuni ,&nbsp;Soney Varghese","doi":"10.1016/j.nanoen.2025.111042","DOIUrl":"10.1016/j.nanoen.2025.111042","url":null,"abstract":"<div><div>A piezoelectric nanogenerator based on PVDF/lithium niobate (NB) for water-energy harvesting is described in this paper. PVDF nanofibers with varying concentrations of NB (0, 0.5, 1, 1.5, and 2 wt%) were synthesised by electrospinning using DMF and acetone as solvents. NB microparticles were found to augment the β-phase concentration in PVDF. Optimizing the NB concentration is vital for superior piezoelectric properties, with 1.5 wt% NB in PVDF yielding the highest β-phase content and enhanced performance. The uniform dispersion of NB throughout the PVDF matrix enhances the formation of PVDF's β phase while decreasing the occurrence of the less desirable α phase structure. A PENG was fabricated with PVDF containing 1.5 wt% NB and tested under finger tapping, producing an output of 7 V. Underwater energy harvesting tests, conducted across water flow speeds of 0–2 m/s, revealed a maximum peak-to-peak voltage of 92.5 V and a short-circuit current of 48 µA at 2 m/s. The device produced 1.24 mW of power and a power density of 0.41 W/m² when connected to 10 kΩ load. This performance allowed for the illumination of 50 blue LEDs and facilitated the charging of a 10 µF capacitor to 17 V in just 20 seconds. The nanogenerator exhibited excellent anti-biofouling properties, resisting biofilm formation by Staphylococcus aureus and Pseudomonas aeruginosa, ensuring long-term efficiency under underwater conditions. These findings highlight the potential of the device to harvest water energy effectively, offering a sustainable alternative to conventional batteries and enabling the powering of submersible wireless sensor networks.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111042"},"PeriodicalIF":16.8,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143847036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An efficient charge extraction strategy for high-performance piezoelectric nanogenerators via a 3D nanostructured conductive network 基于三维纳米结构导电网络的高性能压电纳米发电机的高效电荷提取策略
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111037
Jing Yan, Lingling Wang, Yuebin Qin, Weimin Kang, Guang Yang
{"title":"An efficient charge extraction strategy for high-performance piezoelectric nanogenerators via a 3D nanostructured conductive network","authors":"Jing Yan,&nbsp;Lingling Wang,&nbsp;Yuebin Qin,&nbsp;Weimin Kang,&nbsp;Guang Yang","doi":"10.1016/j.nanoen.2025.111037","DOIUrl":"10.1016/j.nanoen.2025.111037","url":null,"abstract":"<div><div>Flexible piezoelectric nanogenerators (PENGs) have emerged as a promising technology for energy harvesting and wearable sensing applications. However, their output power is often low due to high inherent impedance and inefficient charge transfer. Herein, an efficient charge extraction strategy is proposed for developing high-performance PENGs by integrating a three-dimensional (3D) nanostructured conductive network within piezoelectric nanofibers. This 3D conductive network, composed of aligned antimony tin oxide (ATO) nanofibers and in situ grown carbon nanotube (CNT) bridges, facilitates internal instantaneous charge transfer and significantly improves the output performance of PENGs. Consequently, the fabricated barium titanate (BaTiO<sub>3</sub>) nanofiber-based PENG with the 3D conductive network exhibits a voltage of 64.4 V and a current of 29.4 μA, corresponding to 8.8-fold and 12.7-fold improvements, respectively, compared to a PENG with neat BaTiO<sub>3</sub> nanofibers. Additionally, this versatile charge extraction strategy can be applicable to other piezoelectric materials, such as PbZr<sub>0.52</sub>Ti<sub>0.48</sub>O<sub>3</sub> and (Ba<sub>0.85</sub>Ca<sub>0.15</sub>)(Ti<sub>0.9</sub>Zr<sub>0.1</sub>)O<sub>3</sub> nanofibers, achieving remarkable energy output. The application of the developed PENG has been demonstrated in a wearable emergency communication system, highlighting its ability to achieve high-resolution in signal transmission. This work offers an effective and broadly applicable charge extraction strategy for boosting the output of PENGs, greatly expanding their applications across various domains.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111037"},"PeriodicalIF":16.8,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143841770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hafnium oxide-based nonvolatile ferroelectric memcapacitor array for high energy-efficiency neuromorphic computing 用于高能效神经形态计算的氧化铪非易失性铁电memcapacitor阵列
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111011
Xuepei Wang , Sheng Ye , Boyao Cui , Yu-Chun Li , Ye Wei , Yu Xiao , Jinhao Liu , Zi-Ying Huang , Yishan Wu , Yichen Wen , Ziming Wang , Maokun Wu , Pengpeng Ren , Hui Fang , Hong-Liang Lu , Runsheng Wang , Zhigang Ji , Ru Huang
{"title":"Hafnium oxide-based nonvolatile ferroelectric memcapacitor array for high energy-efficiency neuromorphic computing","authors":"Xuepei Wang ,&nbsp;Sheng Ye ,&nbsp;Boyao Cui ,&nbsp;Yu-Chun Li ,&nbsp;Ye Wei ,&nbsp;Yu Xiao ,&nbsp;Jinhao Liu ,&nbsp;Zi-Ying Huang ,&nbsp;Yishan Wu ,&nbsp;Yichen Wen ,&nbsp;Ziming Wang ,&nbsp;Maokun Wu ,&nbsp;Pengpeng Ren ,&nbsp;Hui Fang ,&nbsp;Hong-Liang Lu ,&nbsp;Runsheng Wang ,&nbsp;Zhigang Ji ,&nbsp;Ru Huang","doi":"10.1016/j.nanoen.2025.111011","DOIUrl":"10.1016/j.nanoen.2025.111011","url":null,"abstract":"<div><div>Recent advancements in neuromorphic computing hardware have led to significant progress in image classification, speech recognition, and fuzzy computing, outperforming traditional von Neumann computing paradigm. However, the widely-investigated memristor-based neuromorphic computing hardware still suffers high writing/reading currents and serious variability issue as well as sneak path challenges, leading to high power consumption and peripheral circuit design complication. Memcapacitor-based neuromorphic computing is expected to alleviate these problems, while the limited memory windows and endurance hindered the practical applications. Here, we present a hafnium oxide-based ferroelectric memcapacitor developed through work function engineering. The memcapacitor demonstrates an overall excellent performance in memory windows (∼7.8 fF/μm<sup>2</sup>), endurance (&gt;10<sup>9</sup> cycles), retention (&gt;10 years), dynamic energy consumption (31 fJ/inference), and near-zero standby static power consumption. The fabricated memcapacitor array shows high linearity and device-to-device variations, and can perform complete multiplication-accumulation (MAC) operation. The constructed artificial neural network (ANN) achieves 96.68 % accuracy on the MNIST data set after 200 epochs. Our findings underscore the potential of ferroelectric memcapacitor device as a robust candidate for high energy-efficiency neuromorphic computing applications in intelligent terminals.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111011"},"PeriodicalIF":16.8,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143847038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controllable dual-substitution engineering enable high stability P2-type Mn-rich cathodes under high voltage 可控双取代工程实现高电压下高稳定性p2型富锰阴极
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111040
Yi He , Jinqiang Gao , Haoji Wang , Weishun Jian , Jiangnan Huang , Datong Zhang , Kangyu Zou , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji
{"title":"Controllable dual-substitution engineering enable high stability P2-type Mn-rich cathodes under high voltage","authors":"Yi He ,&nbsp;Jinqiang Gao ,&nbsp;Haoji Wang ,&nbsp;Weishun Jian ,&nbsp;Jiangnan Huang ,&nbsp;Datong Zhang ,&nbsp;Kangyu Zou ,&nbsp;Wentao Deng ,&nbsp;Hongshuai Hou ,&nbsp;Guoqiang Zou ,&nbsp;Xiaobo Ji","doi":"10.1016/j.nanoen.2025.111040","DOIUrl":"10.1016/j.nanoen.2025.111040","url":null,"abstract":"<div><div>P2-type Na<sub>0.67</sub>MnO<sub>2</sub> (NM) cathodes represent a cost-effective and promising material for sodium-ion batteries (SIBs). Suppressing undesirable phase transformations and Jahn-Teller is quite a challenge for the design of high stability Mn-rich cathodes. Herein, we design and optimize the preparation of Ni and Ti dual-substituted P2-type Mn-rich Na<sub>0.67</sub>Ni<sub>x</sub>Mn<sub>0.8</sub>Ti<sub>0.2-x</sub>O<sub>2</sub> (0 ≤x ≤ 0.2), with the goal to enhancing structural stability and facilitating fast Na<sup>+</sup> diffusion under high voltage. The Na<sub>0.67</sub>Ni<sub>0.15</sub>Mn<sub>0.8</sub>Ti<sub>0.05</sub>O<sub>2</sub> (NN<sub>0.15</sub>M<sub>0.8</sub>T<sub>0.05</sub>) exhibits a narrower bandgap, stronger transition metal (TM)-O bonds, and lower Na<sup>+</sup> migration energy barriers compared to P2-Na<sub>0.67</sub>MnO<sub>2</sub> (NM) as demonstrated by DFT results. X-ray absorption spectroscopy (XAS) reveals the charge compensation mechanism of Ni, indicating that the average working voltage is enhanced by Ni. In-situ X-ray diffraction (XRD) show NN<sub>0.15</sub>M<sub>0.8</sub>T<sub>0.05</sub> efficiently suppressing the O-P stacking fault defect transitions observed in the Ni single composition by stabilizing the reversible P2/OP4 structure at high voltage. As a result, NN<sub>0.15</sub>M<sub>0.8</sub>T<sub>0.05</sub> achieves a high energy density of over 460 Wh/kg within the voltage range of 2–4.3 V, along with significantly improved capacity retention and rate capability. Altogether, the findings reveal that the controllable dual-substitution engineering strategy offers a promising and feasible approach for designing cathode materials in sodium-ion batteries (SIBs).</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111040"},"PeriodicalIF":16.8,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143847046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insight into the interplay of the additive and different calcination process for the cobalt-free high voltage spinel LiNi0.5Mn1.5O4 cathode 添加剂与不同煅烧工艺对无钴高压尖晶石LiNi0.5Mn1.5O4阴极的相互作用
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111038
Jinquan Liu , Chaohui Wang , Jian Yu , Qiqiang Huang , Peng Zhang , Zuoguo Xiao , Saiyue Liu , Weijing Yuan , Chenxi Li , Wei Peng , Xufeng Yan , Yu Zhang , Liang Yin , Mingjian Zhang , Lirong Zheng , Jing Zhang , Juping Xu , Wen Yin , Languang Lu , Dongsheng Ren , Xiang Liu
{"title":"Insight into the interplay of the additive and different calcination process for the cobalt-free high voltage spinel LiNi0.5Mn1.5O4 cathode","authors":"Jinquan Liu ,&nbsp;Chaohui Wang ,&nbsp;Jian Yu ,&nbsp;Qiqiang Huang ,&nbsp;Peng Zhang ,&nbsp;Zuoguo Xiao ,&nbsp;Saiyue Liu ,&nbsp;Weijing Yuan ,&nbsp;Chenxi Li ,&nbsp;Wei Peng ,&nbsp;Xufeng Yan ,&nbsp;Yu Zhang ,&nbsp;Liang Yin ,&nbsp;Mingjian Zhang ,&nbsp;Lirong Zheng ,&nbsp;Jing Zhang ,&nbsp;Juping Xu ,&nbsp;Wen Yin ,&nbsp;Languang Lu ,&nbsp;Dongsheng Ren ,&nbsp;Xiang Liu","doi":"10.1016/j.nanoen.2025.111038","DOIUrl":"10.1016/j.nanoen.2025.111038","url":null,"abstract":"<div><div>Solid-state reaction heterogeneity during the calcination process of cathode materials can significantly influence the physicochemical and electrochemical properties of the cathode material, highlighting the importance of carefully controlling the calcination parameters. In this study, by using the high-voltage spinel LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> (LNMO) cathode as an example, the effect of NH<sub>4</sub>H<sub>2</sub>PO<sub>4</sub> additive with two different synthesis processes was systematically examined. It is demonstrated that the LNMO with NH<sub>4</sub>H<sub>2</sub>PO<sub>4</sub> additive in the 2nd calcination process (LNMO-1S2P) exhibits the most stable full cell cycling performances compared to the LNMO-1P, which has 84 % capacity retention after 300 cycles at 25 ℃ and 80 % after 50 cycles at 45 ℃. With various ex-situ characterizations such as XAFS, solid-state NMR, neutron powder diffraction, and in-situ XRD during charging, it is revealed that the LNMO-1S2P cathode formed a robust cathode electrolyte interface (CEI) by surface P element enrichment, moreover with a smoothed high voltage phase transformation, therefore significantly inhibited the lattice change and reduced the Mn ion dissolution during the cycling. In conclusion, this work reveals the interplay between the additive and the calcination process, offering new insights for the rational synthesis of transition metal oxide cathode materials.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111038"},"PeriodicalIF":16.8,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143841771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-powered optical-triboelectric sensor for remote vibration monitoring 用于远程振动监测的自供电光-摩擦电传感器
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111006
Shanshi Gao , Zhao Sha , Yingge Chen , Guang Li , Shuai He , Shuying Wu , Francois Ladouceur , Shuhua Peng , Chun Hui Wang
{"title":"Self-powered optical-triboelectric sensor for remote vibration monitoring","authors":"Shanshi Gao ,&nbsp;Zhao Sha ,&nbsp;Yingge Chen ,&nbsp;Guang Li ,&nbsp;Shuai He ,&nbsp;Shuying Wu ,&nbsp;Francois Ladouceur ,&nbsp;Shuhua Peng ,&nbsp;Chun Hui Wang","doi":"10.1016/j.nanoen.2025.111006","DOIUrl":"10.1016/j.nanoen.2025.111006","url":null,"abstract":"<div><div>Self-powered vibration sensors, particularly those utilising triboelectric nanogenerators (TENG), hold great promise for real-time monitoring of dynamic loads and structural health without external power sources. However, the electrical wiring required by this system can be vulnerable to electromagnetic interference and signal degradation over long distances due to the cable capacitance increasing proportionally with length. To address this challenge, we introduce a novel optical-triboelectric sensor that eliminates the need for a local power source and enables remote monitoring with minimal signal loss over long distances. This design integrates a TENG-based vibration sensor with an electrical-optical transducer, which contains a thin liquid crystal layer whose transm sandwiched between two electrodes. The alternating voltage generated by the triboelectric nanogenerator modulates the optical transmissivity of a thin liquid crystal layer within the transducer. Operating in reflection mode, the electrical-optical transducer detects changes in the optical transmissivity by measuring the intensity of the light that passes through the liquid crystal layer, reflects off a mirror at the opposite side, and returns through the layer. This reflected light intensity is directly proportional to the TENG’s electrical voltage when the voltage across the liquid crystal layer is within its linear range (-2 V to 2 V). An external capacitor is connected in parallel to the TENG to regulate the voltage to within this range. The self-powered optical-triboelectric sensor can achieve a phase angle variation within 5.2° up to 1.0 kHz, a 3.0 dB bandwidth of around 2.8 kHz, and signal attenuation of 1.05 dB per km, which is significantly lower than the attenuation level of 11.73 dB for 60-meter coaxial electrical cable. Furthermore, the optical-triboelectric sensor system shows a considerably higher signal-to-noise ratio of 18.5 (at a distance of 1000 m) than the value of 3.21 at 60-meter electrical wiring. These results indicate that this self-powered optical-TENG sensor shows significant promise for remote load and structural health monitoring; it eliminates the need for a local power source at the sensor location and is immune to electromagnetic interference.</div></div>","PeriodicalId":394,"journal":{"name":"Nano Energy","volume":"140 ","pages":"Article 111006"},"PeriodicalIF":16.8,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143841772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A multi-indicator pulse monitoring system based on an ultra-sensitive and stable self-powered wearable triboelectric sensor with assistance of personalized deep learning 基于超灵敏稳定自供电可穿戴摩擦电传感器和个性化深度学习的多指标脉搏监测系统
IF 16.8 1区 材料科学
Nano Energy Pub Date : 2025-04-17 DOI: 10.1016/j.nanoen.2025.111039
Zhenyuan Xu, Zihu Wang, Jun Wang, Kangshuai Li, Yukun Liu, Xinyi Ji, Yan Dong, Dongzhi Zhang
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