IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102135

Shuo Wang , Chenjie Lou , Xinbin Wu , Jing Lin , Ajay Gautam , Shenghao Li , Jielei Huang , Zhu Cheng , Shengnan Zhang , Xin Zhang , Florian Strauss , Torsten Brezesinski , Guoqiang Luo , Mingxue Tang , Yang Shen , Yuanhua Lin , Ce-Wen Nan

{"title":"Large-scale manufacturing sulfide superionic conductor for advancing all-solid-state batteries","authors":"Shuo Wang , Chenjie Lou , Xinbin Wu , Jing Lin , Ajay Gautam , Shenghao Li , Jielei Huang , Zhu Cheng , Shengnan Zhang , Xin Zhang , Florian Strauss , Torsten Brezesinski , Guoqiang Luo , Mingxue Tang , Yang Shen , Yuanhua Lin , Ce-Wen Nan","doi":"10.1016/j.matt.2025.102135","DOIUrl":"10.1016/j.matt.2025.102135","url":null,"abstract":"<div><div>Lithium argyrodites with high ionic conductivities are favorable solid electrolytes (SEs) for all-solid-state batteries (ASSBs). However, their low preparation efficiency and poor cycling performance hinder their large-scale applications. In this work, we demonstrate successful large-scale production (over 1 kg per batch for the first time) of Li5.5PS4.5Cl0.75Br0.75 (LPSCB) by fast dry mixing followed by annealing, which presents high room temperature ionic conductivities of 13 mS cm−1 for cold-pressed and 25 mS cm−1 for sintered pellets. Combining neutron powder diffraction and 6Li → 7Li tracer-exchange nuclear magnetic resonance (NMR) spectroscopy measurements, we show that intercage jumps frequently occur through the 48h-16e-48h pathway in LPSCB, promoting the overall lithium conduction. The assembled ASSBs using LPSCB and a LiNi0.83Co0.11Mn0.06O2 electrode can be cycled for over 2,500 cycles at a 0.5 C rate and 1,800 cycles at a 2 C rate without any capacity degradation. Our results will accelerate the commercialization of sulfide SE for ASSBs.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102135"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144933928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Self-intercalated 6R-TaS2 with reduced symmetry for room temperature nonlinear Hall effect 室温非线性霍尔效应中对称性降低的自插层6R-TaS2

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102153

Shengqiang Wu , Wanghao Tian , Runlai Li , Ziyi Han , Xuan Zhou , Song Huang , Ping Li , Peng Song , Xiaoxu Zhao

{"title":"Self-intercalated 6R-TaS2 with reduced symmetry for room temperature nonlinear Hall effect","authors":"Shengqiang Wu , Wanghao Tian , Runlai Li , Ziyi Han , Xuan Zhou , Song Huang , Ping Li , Peng Song , Xiaoxu Zhao","doi":"10.1016/j.matt.2025.102153","DOIUrl":"10.1016/j.matt.2025.102153","url":null,"abstract":"<div><div>The coexistence of multiple phases in two-dimensional (2D) materials enables exotic functionalities via inter-phase proximity and charge effects, but the controlled growth mechanism for heterophase 2D superlattices remains elusive. Herein, we successfully grew a highly crystalline self-intercalated 2D 6R-phase TaS2 (ic-2D 6R-TaS2) crystal by chemical vapor transport. A robust in-plane nonlinear Hall effect (NLHE) was observed in low symmetrical ic-2D 6R-TaS2 material (C1v), i.e., 2–3 orders of magnitude higher than WTe2 and MoTe2. Density functional theory (DFT) calculations revealed a strong Berry curvature dipole in the ic-2D 6R-TaS2 crystal, triggered by band crossings near the Fermi level and universally present in a library of ic-2D transition metal dichalcogenide (TMDC) heterophase superlattices, e.g., Nb1+xS2, Ta1+xSe2, etc. Our findings thus provide the atomic insights for the intercalated stabilized growth mechanism of heterophase superlattices and propose a class of ic-2D heterophase TMDC superlattices as potential candidates for NLHE nanodevices.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102153"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143980078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The phase transition in copper pyrophosphate, Cu2P2O7: Insights and implications for the interpretation of negative thermal expansion 焦磷酸铜，Cu2P2O7的相变：对负热膨胀解释的见解和意义

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102149

Martin T. Dove , Naike Shi

引用次数: 0

Functional supramolecular hosts as platforms for the detection and removal of per- and polyfluoroalkyl substances 功能超分子宿主作为检测和去除全氟烷基和多氟烷基物质的平台

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102246

Yanlei He , Yongping Chai , Zhaoyang Jiao , Hongbing Li , Zhangjie Gu , Jinya Tian , Wenjie Wang , Xiaodong Chi

{"title":"Functional supramolecular hosts as platforms for the detection and removal of per- and polyfluoroalkyl substances","authors":"Yanlei He , Yongping Chai , Zhaoyang Jiao , Hongbing Li , Zhangjie Gu , Jinya Tian , Wenjie Wang , Xiaodong Chi","doi":"10.1016/j.matt.2025.102246","DOIUrl":"10.1016/j.matt.2025.102246","url":null,"abstract":"<div><div>Per- and polyfluoroalkyl substances (PFASs) are persistent, toxic, and bioaccumulative chemicals requiring effective removal and detection methods. Conventional adsorbents like activated carbon and ion-exchange resins suffer from low selectivity, limited capacity, and slow kinetics, while detection methods like high-performance liquid chromatography-mass spectrometry are costly and equipment-intensive. Functional supramolecular host (FSH) materials offer a promising alternative with advantages such as host-guest molecular recognition, adaptability, and tunable structures. This review explores the application of FSHs in PFAS remediation, focusing on adsorbent structural types, adsorption kinetics, isotherms, and mechanisms, as well as regeneration strategies. It also delves into the principles of FSH-based PFAS detection systems, including their design and mechanisms. By addressing key challenges, this review provides insights for developing next-generation materials for cost-effective, efficient PFAS removal and detection in water and environmental samples.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102246"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144930732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Machine learning in X-ray diffraction for materials discovery and characterization x射线衍射中用于材料发现和表征的机器学习

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102272

Connor Davel , Nazanin Bassiri-Gharb , Juan-Pablo Correa-Baena

引用次数: 0

Large propagation-direction-dependent circularly polarized emission and scattering anisotropies of a chiral organic-inorganic semiconductor 手性有机-无机半导体的大传播方向相关圆偏振发射和散射各向异性

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102147

Alan J. Phillips , Liang Yan , Yi Xie , Matthew P. Hautzinger , Rebecca A. Scheidt , Heshan Hewa Walpitage , David B. Mitzi , Valy Vardeny , Wei You , Peter C. Sercel , Jeffrey L. Blackburn

{"title":"Large propagation-direction-dependent circularly polarized emission and scattering anisotropies of a chiral organic-inorganic semiconductor","authors":"Alan J. Phillips , Liang Yan , Yi Xie , Matthew P. Hautzinger , Rebecca A. Scheidt , Heshan Hewa Walpitage , David B. Mitzi , Valy Vardeny , Wei You , Peter C. Sercel , Jeffrey L. Blackburn","doi":"10.1016/j.matt.2025.102147","DOIUrl":"10.1016/j.matt.2025.102147","url":null,"abstract":"<div><div>Chiral materials are important tools for transducing circularly polarized light within many emerging opto-electronic and spin-based technologies. Here, we demonstrate that thin films of a bismuth iodide-based 0D chiral hybrid organic-inorganic semiconductor (HOIS) exhibit large anisotropy values in circularly polarized light emission (CPLE) that approach 50%, with mirror-image responses from front- and back-side measurements. A comprehensive analysis of light-wave propagation, absorption, emission, and scattering is constructed on the basis of a symmetry-derived exciton fine structure model, which accurately describes the direction and polarization dependence of the observed excitonic circular dichroism and CPLE, including contributions from both photoluminescence and resonant Raman scattering. Our analysis indicates that molecular chirality drives preferential film alignment with respect to the out-of-plane lattice vector direction, producing the observed anisotropies. This first demonstration in an HOIS system provides a unique route for enhancing polarization-dependent emission, and circularly polarized light transduction more broadly, in self-assembled HOIS.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102147"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Discovering high-strength alloys via physics-transfer learning 通过物理迁移学习发现高强度合金

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102377

Yingjie Zhao , Hongbo Zhou , Zian Zhang , Zhenxing Bo , Baoan Sun , Minqiang Jiang , Zhiping Xu

{"title":"Discovering high-strength alloys via physics-transfer learning","authors":"Yingjie Zhao , Hongbo Zhou , Zian Zhang , Zhenxing Bo , Baoan Sun , Minqiang Jiang , Zhiping Xu","doi":"10.1016/j.matt.2025.102377","DOIUrl":"10.1016/j.matt.2025.102377","url":null,"abstract":"<div><div>Predicting the strength of materials requires knowledge over multiple scales, striking a balance between accuracy and efficiency. Peierls stress measures material strength by evaluating dislocation resistance to plastic flow, reliant on elastic lattice responses and the crystal slip energy landscape. Computational challenges due to the non-local and non-equilibrium nature of dislocations prohibit Peierls stress evaluation from state-of-the-art material databases. We propose a physics-transfer learning framework that leverages neural networks trained on force-field simulations to understand crystal plasticity physics, predicting Peierls stress from material parameters derived via first-principles calculations, which are otherwise computationally intractable for direct dislocation modeling. This physics-transfer approach successfully screens strengths of metallic alloys from a limited number of single-point calculations with chemical accuracy. Guided by the prediction, we fabricate high-strength binary alloys previously unexplored via high-throughput ion-beam deposition. The framework solves problems facing the accuracy-performance dilemma by harnessing multi-scale physics in materials sciences.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102377"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144824961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

2D RP perovskites as dynamic rulers for supramolecular interactions 二维RP钙钛矿作为超分子相互作用的动态标尺

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102385

Jonghee Yang , Mahshid Ahmadi

引用次数: 0

Mushrooms to brushes: Tackling the PEG dilemma in mRNA lipid nanoparticles with complex polymers 蘑菇到刷子：用复杂聚合物解决mRNA脂质纳米颗粒中的PEG困境

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102386

Kidus E. Biru , Benjamin M. Fiedler , Pratik Gurnani

引用次数: 0

Direct observation of plastic deformation in diamond under extreme loading 极限载荷下金刚石塑性变形的直接观察