Materials Science and Engineering: R: Reports最新文献

{"title":"Recent advances in the transfer of functional oxide thin films: A review","authors":"Sanghun Kim ,&nbsp;Yeomin Yoon ,&nbsp;Dong Hun Kim","doi":"10.1016/j.mser.2026.101186","DOIUrl":"10.1016/j.mser.2026.101186","url":null,"abstract":"<div><div>Thin films used in advanced flexible devices must not only exhibit mechanical flexibility but also maintain stability against moisture and high temperatures while retaining their functional properties. This review focuses on the recent progress in replacing conventional organic-based flexible devices with high-performance inorganic thin-film devices fabricated via high-temperature deposition. As most flexible substrates cannot withstand the high temperatures required for the direct deposition of epitaxial or highly crystallized films, alternative strategies, such as the use of chemically etchable sacrificial layers or physically separable two-dimensional materials, have been developed to enable high-quality thin-film transfer onto flexible substrates. In this review, we systematically summarize the types of sacrificial and two-dimensional layers applied in transfer methods that have been explored to date, including both chemical and physical approaches. This review also highlights the functional properties of the transferred inorganic thin films, including their stability, ferromagnetism, ferroelectricity, multiferroicity, and optical and electrical characteristics, and discusses their potential for novel device applications. Finally, we address the current limitations of sacrificial and two-dimensional layer selection and transfer methodologies, and provide perspectives on future research directions to guide the development of high performance next-generation flexible electronics.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101186"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146073677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fully transparent flexible 2D molybdenum disulfide transistors","authors":"Yang Li ,&nbsp;Lejuan Cai ,&nbsp;Nan Cui ,&nbsp;Xiaoru Li ,&nbsp;Tinghe Yun ,&nbsp;Bohan Wei ,&nbsp;Youchen Chen ,&nbsp;Hua Yu ,&nbsp;Zhenhe Zhao ,&nbsp;Yun Li ,&nbsp;Nianqing Fu ,&nbsp;Lede Xian ,&nbsp;Qingqing Ke ,&nbsp;Wenlong Wang ,&nbsp;Shusheng Pan ,&nbsp;Guangyu Zhang ,&nbsp;Shenghuang Lin","doi":"10.1016/j.mser.2026.101198","DOIUrl":"10.1016/j.mser.2026.101198","url":null,"abstract":"<div><div>Transparent flexible field-effect transistors (FETs) are increasingly desired for cutting-edge electronics, but the performance of flexible two-dimensional (2D) FETs still lags behind traditional rigid 2D devices. This study addresses this issue by introducing lithographically defined poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) electrodes to fabricate high-performance 2D transistors via a transfer method. Both flexible MoS₂ FET and its rigid counterpart demonstrated impressive electron mobility values of 154 ± 20.4 cm² V⁻¹ s⁻¹ and 155 ± 15.9 cm² V⁻¹ s⁻¹ , respectively. The PEDOT:PSS/MoS₂ interface interaction was meticulously characterized and computationally analyzed to elucidate the operational mechanisms. A fully transparent flexible 2D transistor with 71 % transmittance over the visible spectrum and robust FET performance under mechanical bending was also demonstrated. This work highlights the significant potential of integrating organic polymer electrodes with advanced 2D materials for novel high-performance device applications<strong>.</strong></div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101198"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Stepwise donor aggregation and acceptor fibrillization achieve 20% efficiency in bilayer organic solar cells by reducing trap states and balancing charge mobility","authors":"Lixing Tan ,&nbsp;Zhenmin Zhao ,&nbsp;Jingrong Zhang ,&nbsp;Hongxiang Li ,&nbsp;Min Zhang ,&nbsp;Jingjing Zhao ,&nbsp;Yuan Liu ,&nbsp;Liang Bai ,&nbsp;Tao Jia ,&nbsp;Zhipeng Kan","doi":"10.1016/j.mser.2026.101205","DOIUrl":"10.1016/j.mser.2026.101205","url":null,"abstract":"<div><div>Extensive traps in organic solar cells cause severe charge recombination, limiting the performance. However, traps are inherent in bulk heterojunctions, obstructing the efficiency and stability. Herein, we propose a bilayer structure that allows for the independent fine-tuning of donor and acceptor molecular packings to alleviate the recombination. We selected polymer donor PTO2, having a broad absorption range and structural similarity to PM6, and 3,4-ethylenedioxythiophene, with excellent electrical conductivity, to enhance the properties of PM6. The combination modulated the aggregation of PM6, improving the layer crystallinity and hole mobility. Additionally, incorporating an acceptor o-BTP-eC9, offering complementary absorption and shallower highest occupied molecular orbital levels, optimized the fiber structure of L8-BO, producing narrower yet longer fibrils and facilitating electron transport. Bilayer devices achieved a power conversion efficiency of 20.18% (certified 19.78%), with an enhanced fill factor. Our findings highlight the potential of molecular-level morphology engineering to advance the performance of bilayer organic solar cells.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101205"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147384611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Suppressed hydrogen evolution reactions via modulating hydrogen bonds in aqueous battery electrolytes by additives","authors":"Leilei Li ,&nbsp;Yinghua Chen ,&nbsp;Wei Shao ,&nbsp;Qinggang He ,&nbsp;Wandi Wahyudi ,&nbsp;Pushpendra Kumar ,&nbsp;Qian Li ,&nbsp;Junli Zhang","doi":"10.1016/j.mser.2026.101199","DOIUrl":"10.1016/j.mser.2026.101199","url":null,"abstract":"<div><div>The alkaline aqueous batteries (AABs) face a bottleneck posed by the high hydrogen evolution reaction (HER) potentials (∼ −1.0 V <em>vs.</em> Hg/HgO) of alkaline electrolytes. This issue hinders the utilization of exceptional anode materials with redox potentials lower than −1.0 V, limiting the output voltage and energy density. Herein, we introduce urea as an additive to mitigate this challenge by lowering the HER potential of NaOH electrolyte through the formation of hydrogen bond interactions, which reduce the activity of H₂O molecules. Remarkably, the HER potential of 6 m (mol kg⁻¹) NaOH in H₂O-Urea electrolyte is effectively lowered to −1.21 V, which enables a π-conjugated pyrazine-based anode (diquinoxalino[2,3-a:2’,3’-c]phenazine, DQPZ) with a redox potential of −1.1 V to achieve an enhanced capacity of 254 mAh g⁻¹ with a Coulombic efficiency of 99.5% in DQPZ || activated carbon batteries, compared to that in 6 m NaOH in H₂O electrolyte (i.e., 151 mAh g⁻¹, 95.1%). We present a sodium ion solvation structure and interfacial model to elucidate the underlying variation in solvation and dynamic interfacial reactions that contribute to lowering the HER potential. This work helps to design alkaline electrolytes at the molecular level, setting the foundation for practical applications of AABs.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101199"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147384639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomass-based thermal insulation materials: Design strategies, multifunctional integration, and prospects","authors":"Zhijun Zhang ,&nbsp;Chi Hu ,&nbsp;Xuanyu Chen ,&nbsp;Haohe Huang ,&nbsp;Fuguang Ban ,&nbsp;Xuhao Zhu ,&nbsp;Chongxing Huang","doi":"10.1016/j.mser.2026.101188","DOIUrl":"10.1016/j.mser.2026.101188","url":null,"abstract":"<div><div>Thermal insulation materials are indispensable for energy conservation, thermal management, and protection under diverse service conditions. In the context of carbon neutrality and sustainable development, biomass-based materials have emerged as attractive alternatives to petroleum-derived counterparts owing to their renewability, hierarchical porosity, and structural tunability. Nevertheless, their practical applications are hindered by inherent limitations such as thermal instability, moisture sensitivity, and insufficient multifunctionality. This review systematically summarizes recent advances in biomass-based thermal insulation materials, with a focus on raw material selection, structural design strategies, and performance optimization. Particular attention is given to emerging approaches that enable multifunctional integration—ranging from elasticity and thermal management to electromagnetic shielding and infrared stealth—through multiscale structural engineering and interfacial synergy. Finally, the opportunities and challenges associated with balancing thermal insulation, mechanical robustness, and multifunctional performance are highlighted, and future prospects are proposed for guiding the sustainable development of next-generation biomass-based thermal insulation materials.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101188"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145974404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A 4D-printed NiTi alloy with encoded microstructures evades the cooling capacity–energy efficiency trade-off in elastocaloric refrigeration","authors":"Jianbin Zhan ,&nbsp;Yang Li ,&nbsp;Zixu Guo ,&nbsp;Ruijing Ma ,&nbsp;Shengqian Wang ,&nbsp;Xinsheng Yang ,&nbsp;Asker Jarlöv ,&nbsp;Huajun Cao ,&nbsp;Feng Lin ,&nbsp;Yilun Xu ,&nbsp;Kun Li ,&nbsp;Yong-Wei Zhang ,&nbsp;Kun Zhou","doi":"10.1016/j.mser.2026.101191","DOIUrl":"10.1016/j.mser.2026.101191","url":null,"abstract":"<div><div>In elastocaloric (eC) refrigeration, conventionally fabricated NiTi alloys require complex deformation processing such as forging and rolling to achieve desired properties, compromising the intricate geometries for industrial applications. To overcome this limitation, we develop a four-dimensional-printed NiTi alloy with encoded (4D-ped) microstructures, fabricated in a near-net-shape manner. Benefiting from the multi-scale microstructures including tailored grain size and fraction of Ni₄Ti₃ nanoparticles, this alloy evades the trade-off between cooling capacity and energy efficiency. The novel architecture enables a stage-wise phase transformation (PT) mechanism, leading to a quasi-linear mechanical response. This unique architecture triggers a novel eC mechanism other than conventional AM NiTi: the superior properties arise not only from the reduced transformation energy barrier enabled by R-phase nanodomain formation due to fine Ni₄Ti₃ nanoparticles in coarse grains, but also from the enhanced yield strength induced by dense Ni₄Ti₃ precipitation in fine-grained domains, which promotes a stable stress-induced PT and enables effective latent heat absorption. As a result, the 4D-ped NiTi achieves a temperature drop of ∼15 K and a material coefficient of performance of 36.5, delivering superior eC performance compared with existing AM alloys. These findings advance the fabrication of high-performance eC structures with intricate geometries through 4D printing.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101191"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nanodot conductive atomic force microscopy","authors":"Osamah Alharbi ,&nbsp;Yue Yuan ,&nbsp;Wenwen Zheng ,&nbsp;Yue Ping ,&nbsp;Sebastian Pazos ,&nbsp;Husam Alshareef ,&nbsp;Kaichen Zhu ,&nbsp;Mario Lanza","doi":"10.1016/j.mser.2026.101187","DOIUrl":"10.1016/j.mser.2026.101187","url":null,"abstract":"<div><div>Gate-all-around (GAA) transistors and memristors are two key electronic components for the semiconductor industry, as they can enable high-performance computation and memory. State-of-the-art devices contain a 700–100,000 nm² insulating thin film exposed to electrical fields, and understanding its progressive degradation and breakdown is essential to build reliable devices. Investigations in this direction must fabricate test structures and/or devices of similar sizes, otherwise the conclusions extracted are not applicable. Many research groups use electron beam lithography, but this technique introduces polymer residues and leads to low fabrication yields due to the complex lift-off process. Some groups use conductive Atomic Force Microscopy (CAFM), which employs an ultra-sharp conductive tip to analyse the properties of a material at small areas ranging from 1 to 600 nm². However, the currents registered by CAFM strongly depend on three parameters that are difficult to control: the radius of the probe tips, the spring constant of the cantilever, and the relative humidity of the environment. Therefore, a major problem of CAFM is reproducibility. Moreover, the minimum current densities that standard CAFM can detect range from 0.16 to 100 A/cm², but that is insufficient to study gate dielectrics for low power applications (that requires analysing values below 0.01 A/cm²). Here we present nanodot CAFM, a measuring protocol that consists of placing the probe tip of a CAFM on metallic nanodots patterned on the surface of the material under test. These structures cover areas between 700 and 10,000 nm², and they can be easily deposited on any arbitrary sample using a standard evaporator and a cheap aluminium anodic oxide template as shadow mask. Our experiments demonstrate that this setup is insensitive to relative humidity changes from 55 % to 4 %, deflection setpoint changes from −0.5 to 1 V, spring constant changes from 0.8 to 18 N/m, and tip radius changes from 2 to 200 nm, leading to a very high reproducibility. Moreover, this setup allows analysing current densities below 10⁻² A/cm², which extends its range of use. Our approach can help the community to make industry-relevant studies with a high throughput without having to undergo expensive, slow, and low-yield nanofabrication processes (such as electron beam lithography or multi project wafer tape outs).</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101187"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chlorophyll–amino acid bionic cascade strategy for efficient and stable wide-bandgap perovskite solar cells","authors":"Xuelian Liu ,&nbsp;Xianzhao Wang ,&nbsp;Qingyuan Zhao ,&nbsp;Ziyan Liu ,&nbsp;Kun Hao ,&nbsp;Yuting Song ,&nbsp;Naoyuki Shibayama ,&nbsp;Hai Xu ,&nbsp;Aijun Li ,&nbsp;Shin-ichi Sasaki ,&nbsp;Hitoshi Tamiaki ,&nbsp;Tsutomu Miyasaka ,&nbsp;Yisong Zheng ,&nbsp;Xiao-Feng Wang","doi":"10.1016/j.mser.2026.101196","DOIUrl":"10.1016/j.mser.2026.101196","url":null,"abstract":"<div><div>Nickel methyl 13¹-deoxo-pyropheophorbide-<em>a</em> monomer (<strong>NiM</strong>), derived from natural chlorophyll-<em>a</em> (Chl-<em>a</em>), shows significant promise as a hole transporting layer (HTL) material in perovskite solar cells (PSCs). However, the <strong>NiP</strong> films formed by electrochemical polymerization of <strong>NiM</strong> exhibited low carrier mobility, along with substantial energy level mismatch and defects at the <strong>NiP</strong>/perovskite interface, which limited their application in wide-bandgap (WBG) PSCs. Here, inspired by natural Chl–peptide synergies, the Chl–amino acid bionic cascade strategy was first developed. Using aspartic acid and tryptophan to cascade with <strong>NiP</strong>, the energy levels of the HTL were optimized and the carrier mobility was enhanced. Furthermore, the carboxy group effectively passivates the positively charged Pb²⁺ defects and reduces carrier recombination, while the amino group formed hydrogen bonds to halide ions and inhibited photoluminescent halide segregation, which enhanced the performance and stability of the device. A high power conversion efficiency of 22.36 % was achieved in 1.68 eV WBG PSCs modified with tryptophan, which represents the first application of a Chl-based HTL in WBG PSCs. Furthermore, the unencapsulated devices exhibited an efficiency retention of 90.33 % after 1200 h of exposure to air (40 %–50 % relative humidity) and 90.25 % after 1000 h under an argon atmosphere at 85°C.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101196"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructural engineering of zinc anodes: Expediting the fabrication and industrial-scale deployment of high-performance batteries","authors":"Qionglei Hu ,&nbsp;Yanan Liu ,&nbsp;Ye Ding ,&nbsp;Xiangqian Shi ,&nbsp;Chen Chen ,&nbsp;Shichao Guo ,&nbsp;Jie Xu ,&nbsp;Lishuang Fan ,&nbsp;Lijun Yang","doi":"10.1016/j.mser.2025.101175","DOIUrl":"10.1016/j.mser.2025.101175","url":null,"abstract":"<div><div>Zinc-based energy storage devices are considered promising candidates for next-generation high power density and sustainable electrochemical energy storage systems, owing to their intrinsic safety, environmental compatibility, and cost advantages. However, the practical application of zinc anodes remains hindered by challenges such as uncontrolled dendrite growth and interfacial side reactions, which significantly impede their commercialization. Conventional processing techniques, constrained by limited precision and flexibility, struggle to achieve precise control over the micro/nano-structure of zinc anodes as well as large-area, uniform fabrication. Following the research paradigm of structural regulation, performance optimization, scalable manufacturing, this review systematically summarizes recent advances in cross-scale precision machining technologies such as ultrafast laser processing for constructing micro/nano-structured zinc anodes, with a focus on the mechanisms behind the enhanced electrochemical performance and the potential for industrial application. Finally, addressing current research bottlenecks, we outline key future research directions and development pathways, including bio-inspired structural design, scalable fabrication processes, and multi-scenario applicability.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101175"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145923546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-voltage and wide-temperature lithium metal batteries with high-safety enabled by non-flammable electrolytes","authors":"Honghong Liang ,&nbsp;Hongliang Xie ,&nbsp;Hao Yu ,&nbsp;Zexu Wang ,&nbsp;Wandi Wahyudi ,&nbsp;Pushpendra Kumar ,&nbsp;Qian Li ,&nbsp;Zheng Ma ,&nbsp;Jun Ming","doi":"10.1016/j.mser.2026.101177","DOIUrl":"10.1016/j.mser.2026.101177","url":null,"abstract":"<div><div>Lithium metal batteries (LMBs) are promising energy-storage technologies for current unmanned aerial vehicles, but their safety issues (e.g., catching fire and explosion), particularly when operated in extreme conditions, can destroy high-value-added equipment directly. Herein, we develop a novel fluorinated ester electrolyte by incorporating fluoroethylene carbonate (FEC) and bis(2,2,2-trifluoroethyl) carbonate (TFEC) into methyl acetate (MA)-based electrolyte, in which the dual salts of lithium hexafluorophosphate (LiPF₆) and lithium tetrafluoroborate (LiBF₄) are deliberately introduced. The newly designed electrolyte not only has non-flammable features but also enables LMBs to achieve stable cycling performance across a wide temperature range and superior rate capabilities up to 5.0 C at high voltage beyond 4.3 V (vs. Li/Li⁺) when using a LiNi_0.6Co_0.2Mn_0.2O₂ (NCM622) cathode. Moreover, the constructed 50 μm@Li||NCM622 full-cell retains 81.76 % of its capacity beyond 180 cycles at the low temperature of −20°C. The unique role of intermolecular interactions is identified between the solvent molecules, which are capable of tuning the electrolyte solvation structure, in turn significantly improving the compatibility with the lithium metal anode, accelerating the Li⁺ desolvation kinetics, and enhancing the antioxidation capability of the electrolyte. This work provides crucial insights into designing electrolytes to address the critical challenges of LMBs’ extreme operations.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"169 ","pages":"Article 101177"},"PeriodicalIF":31.6,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145898092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}