革命性的NiCo层状双氢氧化物电极:高性能超级电容器的进展、挑战和未来前景

IF 31.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Syed Shaheen Shah , Md. Abdul Aziz , Takaya Ogawa , Laiq Zada , Mohsin Ali Marwat , Syed Muhammad Abdullah , Abdul Jabbar Khan , Muhammad Usman , Ibrahim Khan , Zafar Said , Munetaka Oyama
{"title":"革命性的NiCo层状双氢氧化物电极:高性能超级电容器的进展、挑战和未来前景","authors":"Syed Shaheen Shah ,&nbsp;Md. Abdul Aziz ,&nbsp;Takaya Ogawa ,&nbsp;Laiq Zada ,&nbsp;Mohsin Ali Marwat ,&nbsp;Syed Muhammad Abdullah ,&nbsp;Abdul Jabbar Khan ,&nbsp;Muhammad Usman ,&nbsp;Ibrahim Khan ,&nbsp;Zafar Said ,&nbsp;Munetaka Oyama","doi":"10.1016/j.mser.2025.101041","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing global energy demand and transition to renewable sources emphasize the critical need for advanced energy storage technologies. Supercapacitors, with their high power density, rapid charge/discharge rates, and long cycle life, have emerged as a promising solution. Among various electrode materials, NiCo layered double hydroxides (NiCoLDHs) are particularly notable due to their tunable composition, large surface area, high electrical conductivity, multiple redox states, and exceptional redox activity. This review comprehensively explores the structural and electrochemical properties of NiCoLDHs, highlighting recent advancements in their development as revolutionary electrode materials for supercapacitors. Strategies for enhancing capacitance, such as doping with metals/non-metals, hybridization with carbon materials (e.g., graphene, carbon nanotubes, biomass-derived carbon), and integration with metal oxides, sulfides, selenides, MXenes, MOFs, and conducting polymers, are systematically discussed. Additionally, synthetic methodologies and their impact on electrochemical performance are explored. Current challenges, including scalable synthesis, structural stability, and enhanced energy and power densities, are addressed. Insights from computational modeling and density functional theory provide guidance for optimizing performance at commercial scales. This work provides an overview of advances in NiCoLDHs for next-generation, cost-effective, and sustainable energy storage devices.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"166 ","pages":"Article 101041"},"PeriodicalIF":31.6000,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Revolutionary NiCo layered double hydroxide electrodes: Advances, challenges, and future prospects for high-performance supercapacitors\",\"authors\":\"Syed Shaheen Shah ,&nbsp;Md. Abdul Aziz ,&nbsp;Takaya Ogawa ,&nbsp;Laiq Zada ,&nbsp;Mohsin Ali Marwat ,&nbsp;Syed Muhammad Abdullah ,&nbsp;Abdul Jabbar Khan ,&nbsp;Muhammad Usman ,&nbsp;Ibrahim Khan ,&nbsp;Zafar Said ,&nbsp;Munetaka Oyama\",\"doi\":\"10.1016/j.mser.2025.101041\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The increasing global energy demand and transition to renewable sources emphasize the critical need for advanced energy storage technologies. Supercapacitors, with their high power density, rapid charge/discharge rates, and long cycle life, have emerged as a promising solution. Among various electrode materials, NiCo layered double hydroxides (NiCoLDHs) are particularly notable due to their tunable composition, large surface area, high electrical conductivity, multiple redox states, and exceptional redox activity. This review comprehensively explores the structural and electrochemical properties of NiCoLDHs, highlighting recent advancements in their development as revolutionary electrode materials for supercapacitors. Strategies for enhancing capacitance, such as doping with metals/non-metals, hybridization with carbon materials (e.g., graphene, carbon nanotubes, biomass-derived carbon), and integration with metal oxides, sulfides, selenides, MXenes, MOFs, and conducting polymers, are systematically discussed. Additionally, synthetic methodologies and their impact on electrochemical performance are explored. Current challenges, including scalable synthesis, structural stability, and enhanced energy and power densities, are addressed. Insights from computational modeling and density functional theory provide guidance for optimizing performance at commercial scales. This work provides an overview of advances in NiCoLDHs for next-generation, cost-effective, and sustainable energy storage devices.</div></div>\",\"PeriodicalId\":386,\"journal\":{\"name\":\"Materials Science and Engineering: R: Reports\",\"volume\":\"166 \",\"pages\":\"Article 101041\"},\"PeriodicalIF\":31.6000,\"publicationDate\":\"2025-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science and Engineering: R: Reports\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927796X25001184\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Engineering: R: Reports","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927796X25001184","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

日益增长的全球能源需求和向可再生能源的过渡强调了对先进储能技术的迫切需求。超级电容器以其高功率密度、快速充放电速率和长循环寿命而成为一种很有前途的解决方案。在各种电极材料中,NiCo层状双氢氧化物(NiCoLDHs)因其可调的成分、大表面积、高导电性、多种氧化还原状态和优异的氧化还原活性而特别引人注目。本文综述了NiCoLDHs的结构和电化学性能,重点介绍了其作为超级电容器的革命性电极材料的最新进展。系统地讨论了增强电容的策略,例如金属/非金属掺杂,与碳材料(例如石墨烯,碳纳米管,生物质衍生碳)的杂化,以及与金属氧化物,硫化物,硒化物,MXenes, mof和导电聚合物的集成。此外,还探讨了合成方法及其对电化学性能的影响。解决了当前的挑战,包括可扩展合成,结构稳定性以及增强的能量和功率密度。从计算建模和密度泛函理论的见解为优化商业规模的性能提供了指导。这项工作概述了下一代,具有成本效益和可持续的能量存储设备的NiCoLDHs的进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Revolutionary NiCo layered double hydroxide electrodes: Advances, challenges, and future prospects for high-performance supercapacitors
The increasing global energy demand and transition to renewable sources emphasize the critical need for advanced energy storage technologies. Supercapacitors, with their high power density, rapid charge/discharge rates, and long cycle life, have emerged as a promising solution. Among various electrode materials, NiCo layered double hydroxides (NiCoLDHs) are particularly notable due to their tunable composition, large surface area, high electrical conductivity, multiple redox states, and exceptional redox activity. This review comprehensively explores the structural and electrochemical properties of NiCoLDHs, highlighting recent advancements in their development as revolutionary electrode materials for supercapacitors. Strategies for enhancing capacitance, such as doping with metals/non-metals, hybridization with carbon materials (e.g., graphene, carbon nanotubes, biomass-derived carbon), and integration with metal oxides, sulfides, selenides, MXenes, MOFs, and conducting polymers, are systematically discussed. Additionally, synthetic methodologies and their impact on electrochemical performance are explored. Current challenges, including scalable synthesis, structural stability, and enhanced energy and power densities, are addressed. Insights from computational modeling and density functional theory provide guidance for optimizing performance at commercial scales. This work provides an overview of advances in NiCoLDHs for next-generation, cost-effective, and sustainable energy storage devices.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Materials Science and Engineering: R: Reports
Materials Science and Engineering: R: Reports 工程技术-材料科学:综合
CiteScore
60.50
自引率
0.30%
发文量
19
审稿时长
34 days
期刊介绍: Materials Science & Engineering R: Reports is a journal that covers a wide range of topics in the field of materials science and engineering. It publishes both experimental and theoretical research papers, providing background information and critical assessments on various topics. The journal aims to publish high-quality and novel research papers and reviews. The subject areas covered by the journal include Materials Science (General), Electronic Materials, Optical Materials, and Magnetic Materials. In addition to regular issues, the journal also publishes special issues on key themes in the field of materials science, including Energy Materials, Materials for Health, Materials Discovery, Innovation for High Value Manufacturing, and Sustainable Materials development.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信