Materials Science and Engineering: R: Reports最新文献

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Advanced nanomaterials for health monitoring and diagnostics in next-generation wearable sensors 用于下一代可穿戴传感器的健康监测和诊断的先进纳米材料
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-14 DOI: 10.1016/j.mser.2025.101015
Murugesan Chandran , Mekala Veerapandian , Barkavi Dhanasekaran, Saravanan Govindaraju, Kyusik Yun
{"title":"Advanced nanomaterials for health monitoring and diagnostics in next-generation wearable sensors","authors":"Murugesan Chandran ,&nbsp;Mekala Veerapandian ,&nbsp;Barkavi Dhanasekaran,&nbsp;Saravanan Govindaraju,&nbsp;Kyusik Yun","doi":"10.1016/j.mser.2025.101015","DOIUrl":"10.1016/j.mser.2025.101015","url":null,"abstract":"<div><div>The rapid development of advanced nanomaterials attracts considerable attention in wearable sensing technology due to its conductivity, selectivity, sensitivity, accuracy, biocompatibility, and active sites in the way of design, fabrication, extensive materials, and exploring the flexible sensing devices to enhance the accuracy and monitoring the signals. The innovative nano materials required various advanced characterized techniques to develop tactile sensors with fundamental sensing capabilities and create efficient materials with tailored electrical and mechanical properties. Here, we provide insights into various innovative nanomaterials, including metal, carbon, and polymer-based materials, with computational studies for the efficient development of wearable technologies. Specifically, it explains the computational study involving materials selection, advanced synthesis methods, and structural engineering development to fabricate the potential and most accurate wearable sensing devices. The review focused on the fabrication of wearable sensors, including the physio-chemical properties of microneedles involved in the real-time monitoring application. In addition, electrochemical and electromechanical techniques based on wearable sensors were comprehensively discussed for a clear understanding of methods used to develop wearable sensors. Moreover, this review systematically analyzes the various health monitoring wearable sensors that are currently available, and it delivers advantages, efficiency, safety and also helps to understand the drawbacks to resolve in the future. In this regard, we summarize the role and importance of advanced nanomaterials, computational studies, components and physio-mechanical properties, structure and design of wearable sensors, detection techniques, wearables involved in health monitoring, and as well as future perspectives.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101015"},"PeriodicalIF":31.6,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143941768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in ion regulation strategies for enhancing the performance of aqueous Zn-ion batteries 离子调控策略在提高水性锌离子电池性能方面的研究进展
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-09 DOI: 10.1016/j.mser.2025.101012
Fan Zhang , Ting Liao , Qianqin Zhou , Juan Bai , Xuefeng Li , Ziqi Sun
{"title":"Advancements in ion regulation strategies for enhancing the performance of aqueous Zn-ion batteries","authors":"Fan Zhang ,&nbsp;Ting Liao ,&nbsp;Qianqin Zhou ,&nbsp;Juan Bai ,&nbsp;Xuefeng Li ,&nbsp;Ziqi Sun","doi":"10.1016/j.mser.2025.101012","DOIUrl":"10.1016/j.mser.2025.101012","url":null,"abstract":"<div><div>Aqueous Zn-ion batteries (AZIBs) are considered as the emerging energy storage devices due to their high safety and economic value. Their widespread application is, however, hindered by challenges arising from unwanted side-reactions, such as dendrite formation, hydrogen evolution reactions (HER), and corrosion. These issues are closely linked to the Zn<sup>2+</sup> ion solvation sheath, migration, desolvation, and deposition behaviours. Despite significant advances in Zn<sup>2+</sup> ion regulation strategies are used to address these challenges, a deeper understanding of how to design state-of-the-art Zn-ion-batteries through the optimization of the anode, electrolyte, and separator is still needed. This review begins with an overview of the historical development and summarizes the mechanisms behind the challenges faced in AZIBs. It then provides a critical review of recent advances in ion regulation strategies, such as adjusting electrolyte/electrode interface wettability, optimizing crystal orientation, modifying separators, and engineering electrolytes. Finally, the review offers a forward-looking perspective on advancing these energy storage devices for practical industrial use. The insights presented are expected to guide the natural development of other types of active metal-ion batteries.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101012"},"PeriodicalIF":31.6,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143923913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On-chip atomristors 片上atomristors
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-07 DOI: 10.1016/j.mser.2025.101006
Yue Yuan , Sebastian Pazos , Junzhu Li , Bo Tian , Osamah Alharbi , Xixiang Zhang , Deji Akinwande , Mario Lanza
{"title":"On-chip atomristors","authors":"Yue Yuan ,&nbsp;Sebastian Pazos ,&nbsp;Junzhu Li ,&nbsp;Bo Tian ,&nbsp;Osamah Alharbi ,&nbsp;Xixiang Zhang ,&nbsp;Deji Akinwande ,&nbsp;Mario Lanza","doi":"10.1016/j.mser.2025.101006","DOIUrl":"10.1016/j.mser.2025.101006","url":null,"abstract":"<div><div>Resistive random access memories (RRAM) have shown interesting electrical performance and are relatively easy to fabricate, but their use is still restricted to a few applications due to limited reliability. The microelectronics industry has explored the fabrication of RRAM devices, but only a few amorphous metal-oxides have been tested on-chip, which are mainly TaO<sub>X</sub>, HfO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, Cu<sub>X</sub>O, SiO<sub>2</sub>, ZrO<sub>2</sub> and NiO. However, in these materials controlling accurately resistive switching through defect generation/recombination is very challenging because the positions of the atoms and the strengths of their bonds are unknown. Here we explore the use of defect-free monolayer hexagonal boron nitride (hBN) as insulating film in RRAM devices — often referred to as atomristors. In this crystalline material the number of atoms is 36.97 nm<sup>−2</sup>, they are arranged in-plane in a hexagonal lattice with covalent bonding, and the minimum energy to form a defect is 7.43 eV. This lower amount of uncertainties and the absence of local defects allows us to better adjust the electrical stresses to be applied for write, erase and read events, resulting in highly-reproducible non-volatile bipolar resistive switching (on-chip) with high endurance up to millions of cycles in multiple devices. These results represent a very significant advancement compared to previous atomristors patterned on SiO<sub>2</sub> substrates. Unlike in previous atomristors, the switching is not produced by native defects, but it is produced by field-driven defects, which exhibit high potential for device ultra-miniaturization.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101006"},"PeriodicalIF":31.6,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143916329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sterilizable vertical n-type organic electrochemical transistors for skin-conformal ECG monitoring 用于皮肤适形心电监护的可灭菌垂直n型有机电化学晶体管
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-06 DOI: 10.1016/j.mser.2025.101003
Ji Hwan Kim , Inho Lee , Won-June Lee , Dongjoon Shin , Hyeongbeom Lee , Lucas Q. Flagg , Jagrity Chaudhary , Liyan You , Keehoon Kang , Jianguo Mei , Sungjun Park
{"title":"Sterilizable vertical n-type organic electrochemical transistors for skin-conformal ECG monitoring","authors":"Ji Hwan Kim ,&nbsp;Inho Lee ,&nbsp;Won-June Lee ,&nbsp;Dongjoon Shin ,&nbsp;Hyeongbeom Lee ,&nbsp;Lucas Q. Flagg ,&nbsp;Jagrity Chaudhary ,&nbsp;Liyan You ,&nbsp;Keehoon Kang ,&nbsp;Jianguo Mei ,&nbsp;Sungjun Park","doi":"10.1016/j.mser.2025.101003","DOIUrl":"10.1016/j.mser.2025.101003","url":null,"abstract":"<div><div>The development of stable, high-performance epidermal biosignal monitoring devices is critical for advancing wearable healthcare technologies. Here, we present a novel electrochemical transistor-based biosignal sensor utilizing a 4-terminal vertical Corbino configuration and an n-doped poly(benzodifurandione) (n-PBDF) polymer. The 4-terminal device configuration effectively reduces the parasitic resistance, enabling a high transconductance of 374 mS at a low operational voltage, and one of the highest reported <em>μC</em>* values of 1787 F cm<sup>−1</sup> V<sup>−1</sup> s<sup>−1</sup> for <em>n</em>-type OECTs. In addition, this device achieves exceptional operational stability, maintaining consistent performance over extended periods, and demonstrates a superior shelf-life stability under ambient conditions. Furthermore, the sensor exhibits robust sterilization capabilities, withstanding both UV and thermal sterilization processes without performance degradation. Mechanical flexibility, a key requirement for on-skin applications, is ensured by the intrinsic properties of the n-PBDF polymer and the ultra-thin device architecture. The combination of these features makes this device an ideal candidate for monitoring of biosignals such as electrocardiograms, addressing practical challenges in wearable biosensing technologies.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101003"},"PeriodicalIF":31.6,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143906380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistically designed carbon-based hybrid non-contact triboelectric-and-electromagnetic nanogenerator with ultralong charge retention for wearable and ambient electromagnetic-waste energy harvesting and self-powered sensing 协同设计的碳基混合非接触摩擦电-电磁纳米发电机,具有超长电荷保留,用于可穿戴和环境电磁废物能量收集和自供电传感
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-05 DOI: 10.1016/j.mser.2025.100994
Xiao Peng , Wei-Chen Peng , Yi-Ting Chen , Zhi-Xian Yan , Li-Yen Lee , Kai-Yuan Hsiao , Ming-Han Lu , Beibei Shao , Dun-Jie Jhan , Bing-Yan Xie , Jiun-Wei Fong , Tai-Chen Wu , Ming-Yen Lu , Yingying Zhang , Ying-Chih Lai
{"title":"Synergistically designed carbon-based hybrid non-contact triboelectric-and-electromagnetic nanogenerator with ultralong charge retention for wearable and ambient electromagnetic-waste energy harvesting and self-powered sensing","authors":"Xiao Peng ,&nbsp;Wei-Chen Peng ,&nbsp;Yi-Ting Chen ,&nbsp;Zhi-Xian Yan ,&nbsp;Li-Yen Lee ,&nbsp;Kai-Yuan Hsiao ,&nbsp;Ming-Han Lu ,&nbsp;Beibei Shao ,&nbsp;Dun-Jie Jhan ,&nbsp;Bing-Yan Xie ,&nbsp;Jiun-Wei Fong ,&nbsp;Tai-Chen Wu ,&nbsp;Ming-Yen Lu ,&nbsp;Yingying Zhang ,&nbsp;Ying-Chih Lai","doi":"10.1016/j.mser.2025.100994","DOIUrl":"10.1016/j.mser.2025.100994","url":null,"abstract":"<div><div>Deformable triboelectric nanogenerators (TENGs) show great promise for wearables and human–machine interfaces, but limited output and friction losses constrain their practical application. Here, we present a highly efficient untethered carbon-based non-contact hybrid nanogenerator that combines triboelectric and electromagnetic (EM) induction to convert biomechanical and ambient EM-waste energy into available electricity while enabling self-powered non-contact sensing. It uses graphite-like powder to capture and transport tribo-charges, and graphite-like textiles as tribo-charge reservoirs and stretchable conductors for EM induction. Notably, the use of recycled cotton fabric as a starting material underscores a sustainable and eco-friendly approach to material sourcing. The synergistic designs significantly enhance triboelectricity output (288 V, ± 1.23 μA, 4 Hz) and extend tribo-charge retention time beyond 10,000 min, achieving EM-induced electrification ( ± 15 V, ± 2.4 μA, 60 Hz). Even in non-contact condition, outputs remain 186.5 V (triboelectricity) and ± 9 V (EM waste) at a 1-mm distance, effectively enabling the powering of electronic devices. To the best of our knowledge, this is the first reported non-contact stretchable nanogenerator that can simultaneously harvest both energy types. Moreover, the performance and tribo-charge retention time are superior to those of reported carbon (graphene, graphene oxide, C<sub>60</sub>)-functionalized non-contact TENGs. Last, a multiplexing self-powered touchless gesture-sensing system is demonstrated. These advancements hold significant potential for real-world applications, such as energy-efficient wearables for health monitoring, touchless human-machine interfaces in robotics, and sustainable self-powered sensors for environmental monitoring, offering efficient material and structural strategies for hybrid energy harvesting and sensing in next-generation devices.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 100994"},"PeriodicalIF":31.6,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A guided review of machine learning in the design and application for pore nanoarchitectonics of carbon materials 机器学习在碳材料孔纳米结构设计与应用中的导览
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-03 DOI: 10.1016/j.mser.2025.101010
Chuang Wang , Xingxing Cheng , Kai Hong Luo , Krishnaswamy Nandakumar , Zhiqiang Wang , Meng Ni , Xiaotao Bi , Jiansheng Zhang , Chunbo Wang
{"title":"A guided review of machine learning in the design and application for pore nanoarchitectonics of carbon materials","authors":"Chuang Wang ,&nbsp;Xingxing Cheng ,&nbsp;Kai Hong Luo ,&nbsp;Krishnaswamy Nandakumar ,&nbsp;Zhiqiang Wang ,&nbsp;Meng Ni ,&nbsp;Xiaotao Bi ,&nbsp;Jiansheng Zhang ,&nbsp;Chunbo Wang","doi":"10.1016/j.mser.2025.101010","DOIUrl":"10.1016/j.mser.2025.101010","url":null,"abstract":"<div><div>Porous carbon materials have demonstrated significant potential in areas such as carbon capture, gas separation, energy storage, and catalysis, improving energy efficiency and aiding in reducing carbon emissions. With the advancement of global environmental policies, developing efficient and sustainable materials is critical to addressing energy and environmental challenges. However, traditional trial-and-error approaches are often costly and inefficient. Recently, the rapid development of artificial intelligence and machine learning (ML) has introduced data-driven methods to materials science, significantly improving the efficiency of new material development. This review summarizes the application of ML in porous carbon materials, outlining key learning processes and commonly used algorithms, and highlights the latest advancements of ML in porous carbon synthesis and applications, such as carbon capture, energy storage, and supercapacitors. Specifically, it discusses the impact of essential features, such as pore shape, surface area, and pore volume, on different applications, identifies research gaps for non-biomass precursors like coal and tar pitch, and proposes future research directions. This review aims to serve as a resource for ML applications in the field of porous carbon materials, promoting the efficient development and broad application of novel porous materials.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101010"},"PeriodicalIF":31.6,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyanionic cathodes for sodium-ion batteries: Materials, working mechanism, and applications 钠离子电池用聚阴离子阴极:材料、工作机理和应用
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-05-02 DOI: 10.1016/j.mser.2025.101008
Zhen-Yi Gu , Xiao-Tong Wang , Yong-Li Heng , Yan Liu , Shuo-Hang Zheng, Kai-Yang Zhang, Ze-Lin Hao, Xing-Long Wu
{"title":"Polyanionic cathodes for sodium-ion batteries: Materials, working mechanism, and applications","authors":"Zhen-Yi Gu ,&nbsp;Xiao-Tong Wang ,&nbsp;Yong-Li Heng ,&nbsp;Yan Liu ,&nbsp;Shuo-Hang Zheng,&nbsp;Kai-Yang Zhang,&nbsp;Ze-Lin Hao,&nbsp;Xing-Long Wu","doi":"10.1016/j.mser.2025.101008","DOIUrl":"10.1016/j.mser.2025.101008","url":null,"abstract":"<div><div>Amidst the global energy matrix transformation and escalating sustainability imperatives, sodium-ion batteries (SIBs) have attracted significant attention in the energy storage field, driven by their resource sustainability and cost competitiveness. As pivotal determinants of electrochemical performance, cathode materials govern essential metrics including specific energy density, cyclability, and operational safety in SIBs. Among these, polyanionic cathode materials have emerged as a focal research domain, distinguished by their excellent thermal and structural stability. This review systematically categorizes the types of polyanionic cathode materials and analyzes their intrinsic merits and challenges as Na hosts. To address intrinsic constrains in electronic conductivity and energy density, modification strategies encompassing lattice doping, surface coating, and nanoengineering are elucidated. Furthermore, the storage and transport mechanisms of Na<sup>+</sup> in polyanionic compounds are revealed with the support of theoretical calculations, which provide theoretical guidance for material design. In addition, the application-specific evaluation of polyanionic cathode materials is conducted, particularly emphasizing suitability for stationary energy storage and low-speed electric vehicles. We further identify critical technical barriers and the future development directions of polyanionic cathodes for SIBs. Through a comparative study of polyanionic cathode materials, this review aims to provide a viable guide for advancing the development paradigm for cost-effective SIB technology.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101008"},"PeriodicalIF":31.6,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143899009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly elastic, lightweight, and high-performance all-aerogel triboelectric nanogenerator for self-powered intelligent fencing training 高弹性,轻质,高性能的全气凝胶摩擦电纳米发电机,用于自供电智能击剑训练
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-04-30 DOI: 10.1016/j.mser.2025.101004
Muqi Chen , Minglan Ji , Lijun Huang , Ning Wu , Tao Jiang , Chengyu Li , Wanpeng Li , Boyang Yu , Jianjun Luo , Xiaoyi Li , Zhong Lin Wang
{"title":"Highly elastic, lightweight, and high-performance all-aerogel triboelectric nanogenerator for self-powered intelligent fencing training","authors":"Muqi Chen ,&nbsp;Minglan Ji ,&nbsp;Lijun Huang ,&nbsp;Ning Wu ,&nbsp;Tao Jiang ,&nbsp;Chengyu Li ,&nbsp;Wanpeng Li ,&nbsp;Boyang Yu ,&nbsp;Jianjun Luo ,&nbsp;Xiaoyi Li ,&nbsp;Zhong Lin Wang","doi":"10.1016/j.mser.2025.101004","DOIUrl":"10.1016/j.mser.2025.101004","url":null,"abstract":"<div><div>With the rapid advancement of the Internet of Things and big data, the sports industry is undergoing a digital transformation. Here, we report a highly elastic, lightweight, and high-performance all-aerogel triboelectric nanogenerator (AA-TENG) for self-powered sensing in intelligent fencing training. Utilizing simple yet effective freeze-drying strategies for fabricating cellulose/carbon nanotube and poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) aerogels, the resulting AA-TENG demonstrates an ultralow density of 7.92 × 10<sup>−3</sup>g/cm<sup>3</sup>, exceptional elasticity (≥90 % height retention) and thermal insulation performance. Moreover, the electrical output performance is significantly enhanced by 57 %, attributed to the increased β-phase content (88.95 %) in the PVDF-TrFE aerogel. Furthermore, a self-powered wireless fencing strike analysis system using convolutional neural network algorithm is developed to accurately classify three types of fencing strikes, enabling more flexible and precise competition judgment and training analysis. This work provides new insights into the application of self-powered systems in intelligent sports and big data analysis, with the potential to significantly impact the global sports industry.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101004"},"PeriodicalIF":31.6,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microfluidic synthesis of MOFs, COFs, and HOFs: Insights and advances mof, COFs和hof的微流控合成:见解和进展
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-04-29 DOI: 10.1016/j.mser.2025.101005
Sebete S. Mabaleha, Ayesha Sandaruwani, Cancan Peng, Da Zou, Wenhao Ren, Chun-Xia Zhao, Xiaoyong Xu
{"title":"Microfluidic synthesis of MOFs, COFs, and HOFs: Insights and advances","authors":"Sebete S. Mabaleha,&nbsp;Ayesha Sandaruwani,&nbsp;Cancan Peng,&nbsp;Da Zou,&nbsp;Wenhao Ren,&nbsp;Chun-Xia Zhao,&nbsp;Xiaoyong Xu","doi":"10.1016/j.mser.2025.101005","DOIUrl":"10.1016/j.mser.2025.101005","url":null,"abstract":"<div><div>Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), and Hydrogen-bonded Organic Frameworks (HOFs) (collectively MCHOFs) are increasingly recognized for their diverse applications in catalysis, drug delivery, separation, sensing, adsorption etc. However, their large-scale production using conventional methods faces significant challenges such as slow kinetics, insufficient control over reaction conditions, wide particle size distribution, and poor reproducibility. Microfluidic synthesis has emerged as a promising and greener solution, offering precise control over reaction conditions and product properties with high reproducibility, while significantly reducing waste generation and cutting synthesis time to minutes. Consequently, it has established itself as one of the most promising and sustainable approaches for industrial production of MCHOFs. This work provides a comprehensive overview of microfluidic synthesis of MCHOFs, covering key topics such as the fundamentals of microfluidics, materials for microfluidic fabrication, and microfluidic reactor configuration. It further covers chemistry underlying MCHOFs synthesis, conventional synthesis methods and their limitations, advances in MCHOFs synthesis enabled by microfluidics, synthesis variables, and techno-economic-environmental implications of microfluidic synthesis. Lastly, it identifies key gaps in the microfluidic synthesis of these materials, highlighting feasible future research directions to enhance the sustainability of microfluidic synthesis. By addressing these, it significantly contributes towards greener, efficient, and sustainable industrial-scale production of these materials.</div></div>","PeriodicalId":386,"journal":{"name":"Materials Science and Engineering: R: Reports","volume":"165 ","pages":"Article 101005"},"PeriodicalIF":31.6,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143882374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging soft medical robots for clinical translations from diagnosis through therapy to rehabilitation 新兴的软医疗机器人,用于临床翻译,从诊断到治疗到康复
IF 31.6 1区 材料科学
Materials Science and Engineering: R: Reports Pub Date : 2025-04-28 DOI: 10.1016/j.mser.2025.100990
Guanghai Fei , Shuaizhong Zhang , Yue Li , Miao Peng , Zhenyuan Tang , Xinyue Gu , Xiaopeng Li , Kaihuan Zhang , Jinbing Xie , Yicheng Ni , Kun Zhou , Min Tu
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