IET Nanodielectrics最新文献

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Enhanced electrocaloric effect over a broad temperature range in lead-free Na0.5Bi0.5TiO3-based relaxor ferroelectrics via doping with Bi(Mg0.5Zr0.5)O3 通过掺杂 Bi(Mg0.5Zr0.5)O3,在无铅 Na0.5Bi0.5TiO3 基弛豫铁电体中增强宽温度范围内的电致发光效应
IF 2.7
IET Nanodielectrics Pub Date : 2023-12-06 DOI: 10.1049/nde2.12069
Xiang Niu, Yuleng Jiang, Junying Lai, Wei Liang, Huanwei Liu, Xiaodong Jian, Xiaobo Zhao, Yingbang Yao, Bo Liang, Tao Tao, Sheng-Guo Lu
{"title":"Enhanced electrocaloric effect over a broad temperature range in lead-free Na0.5Bi0.5TiO3-based relaxor ferroelectrics via doping with Bi(Mg0.5Zr0.5)O3","authors":"Xiang Niu,&nbsp;Yuleng Jiang,&nbsp;Junying Lai,&nbsp;Wei Liang,&nbsp;Huanwei Liu,&nbsp;Xiaodong Jian,&nbsp;Xiaobo Zhao,&nbsp;Yingbang Yao,&nbsp;Bo Liang,&nbsp;Tao Tao,&nbsp;Sheng-Guo Lu","doi":"10.1049/nde2.12069","DOIUrl":"10.1049/nde2.12069","url":null,"abstract":"<p>With an increasing demand for environmentally friendly refrigeration, the solid-state refrigeration based on the electrocaloric effect (ECE) has been drawn extensive attention. It is a challenge to maintain a large adiabatic temperature change (∆<i>T</i>) over a broad temperature span. Herein, the authors designed and synthesised (0.74-<i>x</i>) Na<sub>0.5</sub>Bi<sub>0.5</sub>TiO<sub>3</sub>-0.06BaTiO<sub>3</sub>-0.2SrTiO<sub>3</sub>-<i>x</i>Bi(Mg<sub>0.5</sub>Zr<sub>0.5</sub>)O<sub>3</sub> (abbreviated as NBT-<i>x</i>BMZ) (<i>x</i> = 0, 0.02, 0.04, 0.06 and 0.08) lead-free relaxor ferroelectrics. Their microstructures, dielectric properties, ferroelectric properties, ECEs and the structure-property relationships were investigated. Via doping with BMZ, an enhanced relaxor feature and a wider temperature range where multi-phases coexist were achieved. The relaxor ferroelectric characteristics were illustrated using the Vogel-Fulcher relation. The indirectly calculated ECE results showed that the optimal Δ<i>T</i> of 1.11 K was obtained for the <i>x</i> = 0.02 sample at 90°C and 70 kV/cm over a wide <i>T</i><sub>span</sub> of 120°C, providing a potential ECE material. The direct ECE results procured using thermocouple indicated that the maximal ∆<i>T</i> of 2.14 K and ∆<i>T</i>/∆<i>E</i> of 0.31 K m/MV were achieved in the same sample at 70°C and 7 MV/m and the variation trend of ECE results was consistent with the indirect results. Moreover, the multi-phases coexistent strategy can be extended to other materials system to generate a large Δ<i>T</i> over a wide temperature range.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 2","pages":"59-67"},"PeriodicalIF":2.7,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12069","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138595188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress in insulating and thermal conductivity of fluorinated graphene and its polyimide composites 氟化石墨烯及其聚酰亚胺复合材料的绝缘性和导热性研究进展
IF 2.7
IET Nanodielectrics Pub Date : 2023-12-04 DOI: 10.1049/nde2.12068
Xin Wang, Shuyan Liu, Haoyu Han, Xiangyang Liu, Xu Wang
{"title":"Research progress in insulating and thermal conductivity of fluorinated graphene and its polyimide composites","authors":"Xin Wang,&nbsp;Shuyan Liu,&nbsp;Haoyu Han,&nbsp;Xiangyang Liu,&nbsp;Xu Wang","doi":"10.1049/nde2.12068","DOIUrl":"10.1049/nde2.12068","url":null,"abstract":"<p>The demand for innovative thermal management materials with superior thermal conductivity and electrical insulating properties has significantly increased with the development of portable and flexible electronic gadgets. Fluorinated graphene (FG) has recently attracted the attention of the scientific community because of its exceptional thermal conductivity and electrical insulating qualities. This work aims to provide a detailed analysis of the structure-property relationships inherent in FG, including both chemical and physical properties, and to explain the FG manufacturing process. Special attention should be paid to a thorough analysis of the thermodynamic conduction mechanism exhibited by FG, including the effects of corrugation size, fluorine coverage, and fluorine atom distribution on its thermal conductivity. The essay also examines in-depth the most current and cutting-edge developments addressing the utilisation of FG as a functional filler in composite-modified polyimide (PI) materials. Furthermore, it has been noted as a crucial component in answering the needs for possible applications by maximising thermal conductivity and mechanical qualities in FG/PI composites through particular FG structural engineering and increased FG-PI interaction. As a result, these elements serve as the main focus of ongoing research projects, highlighting important directions for development and investigation.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 2","pages":"47-58"},"PeriodicalIF":2.7,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12068","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138604618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Siloxane-containing polyimide films with high heat resistance and low dielectric constant 具有高耐热性和低介电常数的含硅氧烷聚酰亚胺薄膜
IF 2.7
IET Nanodielectrics Pub Date : 2023-11-23 DOI: 10.1049/nde2.12064
Song Mo, Lei Zhai, Yi Liu, Gang Han, Yan Jia, Min-Hui He, Lin Fan
{"title":"Siloxane-containing polyimide films with high heat resistance and low dielectric constant","authors":"Song Mo,&nbsp;Lei Zhai,&nbsp;Yi Liu,&nbsp;Gang Han,&nbsp;Yan Jia,&nbsp;Min-Hui He,&nbsp;Lin Fan","doi":"10.1049/nde2.12064","DOIUrl":"10.1049/nde2.12064","url":null,"abstract":"<p>A series of siloxane-containing polyimide films (PIS) were prepared by copolymerising with rigid aromatic dianhydride, siloxane diamines and six different aromatic diamines. The effects of siloxane structures, fluorine and imide content, rigid or flexible segment on the heat resistance, moisture absorption, dielectric performance, mechanical and bonding properties were systematically studied. The results show that PIS films maintain good heat resistance with <i>T</i><sub><i>g</i></sub> between 292 and 420°C and 5% weight loss temperature higher than 500°C. The moisture absorption and dielectric constant can be significantly reduced due to the presence of siloxanes and fluorinated groups, with the absorption rate as low as 1.2% and dielectric constant of 2.85 at 1 MHz. When measured at 10 GHz, the dielectric constant ranges from 3.10 to 3.50, and dielectric loss varies from 0.0059 to 0.0098. The PIS-6 film has the best comprehensive performance due to the low imide content, introduction of trifluoromethyl and ether bonds. The peeling strength of bonding PIS-6 film with a copper foil can reach 9.2 N/cm. It is proven that siloxane-containing PIS films with high heat resistance, low dielectric and outstanding adhesion are achieved, which can be applied for flexible integrated circuit boards, high-frequency electronics and microelectronics fields.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 1","pages":"33-45"},"PeriodicalIF":2.7,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12064","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139242785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
AI safety of film capacitors 薄膜电容器的 AI 安全性
IF 3.8
IET Nanodielectrics Pub Date : 2023-11-16 DOI: 10.1049/nde2.12071
Yong-Xin Zhang, Fang-Yi Chen, Di-Fan Liu, Jian-Xiao Wang, Qi-Kun Feng, Hai-Yang Jiang, Xin-Jie Wang, Hong-Bo Zhao, Shao-Long Zhong, Faisal Mehmood Shah, Zhi-Min Dang
{"title":"AI safety of film capacitors","authors":"Yong-Xin Zhang,&nbsp;Fang-Yi Chen,&nbsp;Di-Fan Liu,&nbsp;Jian-Xiao Wang,&nbsp;Qi-Kun Feng,&nbsp;Hai-Yang Jiang,&nbsp;Xin-Jie Wang,&nbsp;Hong-Bo Zhao,&nbsp;Shao-Long Zhong,&nbsp;Faisal Mehmood Shah,&nbsp;Zhi-Min Dang","doi":"10.1049/nde2.12071","DOIUrl":"10.1049/nde2.12071","url":null,"abstract":"<p>With a large number of film capacitors being deployed in critical locations in electrical and electronic systems, artificial intelligence (AI) technology is also expected to address the problems encountered in this process. According to our findings, AI applications can cover the entire lifecycle of film capacitors. However, the AI safety hazards in these applications have not received the attention they deserve. To meet this, the authors argue, with specific examples, risks that flawed, erratic, and unethical AI can introduce in the design, operation, and evaluation of film capacitors. Human-AI common impact and more multi-dimensional evaluation for AI are proposed to better cope with unknown, ambiguity, and known risks brought from AI in film capacitors now and in the future.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 3","pages":"131-139"},"PeriodicalIF":3.8,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12071","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139267314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improvement of the flashover threshold of TUK pressboard by using FeO3-based nanofluid of monoesters 使用基于 FeO3 的单酯纳米流体提高 TUK 压板的闪蒸阈值
IF 2.7
IET Nanodielectrics Pub Date : 2023-11-13 DOI: 10.1049/nde2.12070
Jean Lambert Jiosseu, Ghislain Mengata Mengounou, Emeric Tchamdjio Nkouetcha, Adolphe Moukengue Imano
{"title":"Improvement of the flashover threshold of TUK pressboard by using FeO3-based nanofluid of monoesters","authors":"Jean Lambert Jiosseu,&nbsp;Ghislain Mengata Mengounou,&nbsp;Emeric Tchamdjio Nkouetcha,&nbsp;Adolphe Moukengue Imano","doi":"10.1049/nde2.12070","DOIUrl":"10.1049/nde2.12070","url":null,"abstract":"<p>This article deals with the improvement of the dielectric properties of TUK cellulose paper by impregnation. The experiment was carried out using a nanofluid based on vegetable oil esters and iron nanoparticles (FeO<sub>3</sub>). The insulating liquids used are palm kernel oil methyl ester (PKOME) and castor oil methyl ester (COME). The evaluation of the improvement is based on the analysis of the flashover voltage of the creeping discharges produced on the immersed paper. The tests were carried out under a positive lightning impulse voltage and for two electrode configurations. The concentrations of nanoparticles used in the experiment are 0.10 wt.%, 0.15 wt.% and 0.20 wt.%. The experimental results show that the 0.10 wt.% concentration gives the best improvement for the two electrode configurations used. The improvements are 53% for the inclined tip and 56.90% for the vertical tip in the case of COME + FeO<sub>3</sub>. For PKOME + FeO<sub>3</sub>, the results are 59.90% and 64.60%, respectively, for the two configurations.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 2","pages":"78-87"},"PeriodicalIF":2.7,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12070","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136347694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improved dielectric and energy storage properties of three-dimensional BaTiO3/polyvinyl alcohol-boron nitride flexible dielectric composite via template infiltration strategy 通过模板浸润策略改善三维 BaTiO3/ 聚乙烯醇-氮化硼柔性介电复合材料的介电和储能性能
IF 2.7
IET Nanodielectrics Pub Date : 2023-11-01 DOI: 10.1049/nde2.12067
Yongzhi Yang, Jinxiang Chao, Peng Jiang, Runhan Xu, Yuchao Li, Yanhu Zhan, Zhicheng Shi, Chengzhu Liao
{"title":"Improved dielectric and energy storage properties of three-dimensional BaTiO3/polyvinyl alcohol-boron nitride flexible dielectric composite via template infiltration strategy","authors":"Yongzhi Yang,&nbsp;Jinxiang Chao,&nbsp;Peng Jiang,&nbsp;Runhan Xu,&nbsp;Yuchao Li,&nbsp;Yanhu Zhan,&nbsp;Zhicheng Shi,&nbsp;Chengzhu Liao","doi":"10.1049/nde2.12067","DOIUrl":"10.1049/nde2.12067","url":null,"abstract":"<p>Continuous three-dimensional BaTiO<sub>3</sub> (3DBT) ceramic network was prepared by the sol-gel method using cleanroom wipers as the template. Subsequently, flexible 3DBT/polyvinyl alcohol-boron nitride nanosheets (PVA-BNNS) composite dielectric films were facilely fabricated by inversely introducing different BNNS concentrations of PVA-BNNS solution into the 3DBT network. The results demonstrated that PVA solution effectively embedded into the 3DBT framework through an inverse infiltration process, thereby endowing the material with excellent flexibility. The content of 3DBT in the saturated 3DBT/PVA-BNNS composite was ∼27 wt% (6.9 vol%). In addition, the 3DBT/PVA-1.0%BNNS system exhibited an excellent dielectric constant of 17.4 (at 1 kHz), a high breakdown strength of 114.5 kV·mm<sup>−1</sup> and an energy density of 2.51 J·cm<sup>−3</sup> (at 110 kV·mm<sup>−1</sup>), being 1.67, 1.58 and 7.17 times higher than those of traditional fabricated 27 wt% nano-BT/PVA (at 70 kV·mm<sup>−1</sup>) composite, respectively. What's more, the obtained 3DBT/PVA-BNNS dielectric film exhibited superior thermal and mechanical stability, indicating potential applications in harsh environments.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"7 2","pages":"68-77"},"PeriodicalIF":2.7,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12067","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135373078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanism of positive electret inhibition of Staphylococcus aureus biofilms 驻极体阳性抑制金黄色葡萄球菌生物膜的机制
IF 2.7
IET Nanodielectrics Pub Date : 2023-10-31 DOI: 10.1049/nde2.12065
Hongbao Wang, Hejuan Liang, Xin Guo, Jiajie Xu, Jian Jiang, Zhipeng Sun, Yuanyuan Liang
{"title":"Mechanism of positive electret inhibition of Staphylococcus aureus biofilms","authors":"Hongbao Wang,&nbsp;Hejuan Liang,&nbsp;Xin Guo,&nbsp;Jiajie Xu,&nbsp;Jian Jiang,&nbsp;Zhipeng Sun,&nbsp;Yuanyuan Liang","doi":"10.1049/nde2.12065","DOIUrl":"10.1049/nde2.12065","url":null,"abstract":"<p>Bacterial biofilm is an important factor in bacterial drug resistance. Recently, it has been proved that electret films can inhibit the bacterial biofilm, while its mechanism of action on biofilms is under further investigation. In this work, taking <i>Staphylococcus aureus</i> as an example, the inhibition of positive electret on bacterial biofilm was verified and its mechanism was explained. Two factors have been found to explain the inhibition mechanism of electret on bacterial biofilms. One is probably due to its inhibition of the expression of key genes related to bacterial biofilms induced by the electric field of positive electret, and the other is to prevent the aggregation of bacteria rather than the direct bactericidal effect. The conclusions are expected to be extended to other types of bacteria and expand the application of electrostatic materials in the field of biomedicine.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"6 4","pages":"282-289"},"PeriodicalIF":2.7,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12065","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135928032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyetherimide nanocomposites filled with in-situ synthesised bismaleimide-DDE@CCTO hybrid nanofibers enabling improved dielectric and interfacial performance 原位合成bismaleimide-DDE@CCTO杂化纳米纤维填充的聚醚酰亚胺纳米复合材料改善了介电和界面性能
IF 2.7
IET Nanodielectrics Pub Date : 2023-10-30 DOI: 10.1049/nde2.12066
Peiyuan Zuo, Bowen Sun, Donglin Chen, Lianping Yuan, Yi Chen, Jingyu Lin, Qixin Zhuang
{"title":"Polyetherimide nanocomposites filled with in-situ synthesised bismaleimide-DDE@CCTO hybrid nanofibers enabling improved dielectric and interfacial performance","authors":"Peiyuan Zuo,&nbsp;Bowen Sun,&nbsp;Donglin Chen,&nbsp;Lianping Yuan,&nbsp;Yi Chen,&nbsp;Jingyu Lin,&nbsp;Qixin Zhuang","doi":"10.1049/nde2.12066","DOIUrl":"10.1049/nde2.12066","url":null,"abstract":"Most current research of nanocomposite dielectrics for modern electronic devices and electric equipment usually focuses more on dielectric properties while in some extent ignoring the interfacial adhesion characteristics. However, the poor interfacial adhesion frequently results in serious dielectric field distortion, which would in return impair the dielectric performance enhancement. As such, how to simultaneously achieve the excellent dielectric properties and interfacial adhesion performance in organic‐inorganic nanocomposite system is worth in‐depth investigation. To realise this aim, novel hybrid nanofibers are neatly fabricated using in situ copolymerisation reaction of bismaleimide and diamino‐diphenyl ether monomers on the CCTO nanofiller surface via covalent bond connections. The resulting nanocomposites achieve high dielectric constant (9.3) and low dielectric loss (0.0185) at 1 kHz. The BMI‐DDE@CCTO/PEI yields a high discharge energy density (3.09 J/cm3) at moderate electric field (200 MV/m). Noticeably, the nanocomposites enable stable dielectric performance over a wide temperature range from room temperature to 150°C. Moreover, the binding energy for BMI‐DDE and PEI is 1052 kJ/mol according to DFT calculation. As such, the authors speculate this interesting study would inspire the broad researchers devoting to investigating bismaleimide‐coated high‐aspect‐ratio nanofillers and their dielectric materials for collaboratively improved dielectric and interfacial performance.","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"6 4","pages":"246-256"},"PeriodicalIF":2.7,"publicationDate":"2023-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ietresearch.onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12066","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136069130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Guest Editorial: High-performance polyimide dielectric materials 客座编辑:高性能聚酰亚胺介电材料
IF 2.7
IET Nanodielectrics Pub Date : 2023-09-15 DOI: 10.1049/nde2.12063
Jun-Wei Zha, Lei Zhai
{"title":"Guest Editorial: High-performance polyimide dielectric materials","authors":"Jun-Wei Zha,&nbsp;Lei Zhai","doi":"10.1049/nde2.12063","DOIUrl":"https://doi.org/10.1049/nde2.12063","url":null,"abstract":"&lt;p&gt;Polyimides are advanced polymeric materials that are well known for their excellent thermal, mechanical, electrical and chemical resistance properties. As an important kind of high-temperature resistant dielectric material, polyimides have been widely used in various applications such as electronics, microelectronics and electrical fields, due to their high thermal stability, high glass transition temperature (&lt;i&gt;T&lt;/i&gt;&lt;sub&gt;&lt;i&gt;g&lt;/i&gt;&lt;/sub&gt;), outstanding dielectric and electrical insulating performance at the high electric field or at high frequencies. Polyimide dielectric materials have a rich variety of reactive monomers, which endows the molecular structures with strong designability and facilitates the regulation of material properties. Moreover, polyimides can be compounded with various functional fillers to achieve the multifunctional dielectric materials with low or high dielectric properties, low dielectric loss and high breakdown strength. Polyimide dielectric materials also have an ease of processability that make them patternable for many types of integrated devices. With the ongoing advancements in a wide range of novel electronic, microelectronic and new energy applications, polyimide dielectric materials have gained increasing interest from both fundamental and applied research. High-performance polyimide dielectric materials are essential for the development of new electronic or electrical devices where further considerations are required, including higher temperature resistance and energy storage, lower dielectric constant and dielectric loss, improved thermal conduction management as well as better reliability or flexibility in harsh environments. In order to meet the more stringent application requirements mentioned above, there is an urgent need to develop polyimide dielectric materials with higher comprehensive performance, which requires joint development through new theoretical designs, new structures, methods, processes and other means. A wide variety of research is being conducted to prepare kinds of functional polyimide dielectric materials to address applicable challenges and explore possible opportunities in different fields. This current Special Issue is focused on ‘&lt;b&gt;&lt;i&gt;High performance polyimide dielectric materials&lt;/i&gt;&lt;/b&gt;’ and their applications in different topics, emphasising the latest innovations in polyimide or polyimide-based dielectric materials and better understanding of deep relationship between their chemical or composition structures and overall performances.&lt;/p&gt;&lt;p&gt;In this Special Issue, four high-quality papers have undergone peer-reviewed and eventually been accepted for publication. These published papers include five original research papers and one review article in the application field of high-performance polyimide dielectric materials. All the papers can be clustered into three main categories related to dielectric materials, namely preparation, molecular design and measurement or simulation. (","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"6 3","pages":"73-75"},"PeriodicalIF":2.7,"publicationDate":"2023-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12063","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50134673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Significant enhancement of dielectric properties in polyimides with sulfonyl groups in the side chains 侧链带有磺酰基的聚酰亚胺的介电性能显著提高
IF 2.7
IET Nanodielectrics Pub Date : 2023-08-09 DOI: 10.1049/nde2.12062
Jinpeng Luo, Hui Tong, Shimo Cao, Junbiao Liu, Xiaomin Li
{"title":"Significant enhancement of dielectric properties in polyimides with sulfonyl groups in the side chains","authors":"Jinpeng Luo,&nbsp;Hui Tong,&nbsp;Shimo Cao,&nbsp;Junbiao Liu,&nbsp;Xiaomin Li","doi":"10.1049/nde2.12062","DOIUrl":"10.1049/nde2.12062","url":null,"abstract":"<p>Polymer dielectrics with excellent thermal resistance and superior energy storage behaviour are extensively demanded with the increasing development of film capacitors applied in hostile environments. In this study, novel diamine with sulfonyl-containing side chain was designed and synthesised. The corresponding polyimide (PI) dielectrics derived from the sulfonyl-containing diamine were prepared, so were the polyimides possessing the same backbone but without side chains. Consequently, superior thermal resistance of glass transition temperature ranged from 162–208°C was obtained. Moreover, the polyimides presented permittivity of 3.34–5.89 at 1 kHz, Weibull breakdown strength of 377–538 MV/m and discharged energy density of 3.82–5.85 J/cm<sup>3</sup>. In particular, sulfonyl-containing polyimide of SPI-2 with flexible backbone and sulfonyl side chain indicates the highest discharged energy density and charge-discharge efficiency simultaneously. The introduction of the strong polar sulfonyl group in the side chain enhances dielectric and energy storage properties effectively. In addition, it is found that the dipolar moment density (μ/<i>V</i><sub>vdw</sub>) calculated from molecular simulation is closely correlated to permittivity measured from experiments. The combined method of molecular simulation and experiments would offer an effective approach to assist in molecular design of high-performance polymer dielectrics.</p>","PeriodicalId":36855,"journal":{"name":"IET Nanodielectrics","volume":"6 3","pages":"105-115"},"PeriodicalIF":2.7,"publicationDate":"2023-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/nde2.12062","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45734393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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