{"title":"Determining of the material parameters of ZnxCdyHg1-x-yTe by magnetophonon spectroscopy","authors":"J. Cebulski, J. Polit, E. Sheregii","doi":"10.1117/12.435839","DOIUrl":"https://doi.org/10.1117/12.435839","url":null,"abstract":"The phonon and electron subsystems were studied in quaternary solid solutions of ZnxCdyHg1-x-yTe by means of Raman scattering and Magnetophonon Resonance. The Raman spectra of several compositions confirm the three-mode behavior of phonon spectra. The cluster mode has also been observed. Four kinds of LO-phonons participate in the electron-phonon interaction. Four types of one-phonon Magnetophonon Resonances and two types of Magnetophonon Resonances on the difference of phonon frequencies have been observed.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115443983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dynamics of diffusion-controlled recombination of ions in ionic solutions: limits of validity of the Debye-Smoluchowski equation","authors":"K. Wolf, W. Bartczak","doi":"10.1117/12.435814","DOIUrl":"https://doi.org/10.1117/12.435814","url":null,"abstract":"The diffusion and recombination process in an ensemble of isolated single pairs of opposite charges is usually described by the Debye-Smoluchowski equation. The present work is an overview of a series of computer simulations of diffusion and recombination of ions in solution performed with the aim to determine the limits of validity of the Debye-Smoluchowski equation.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":" 10","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"120830514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Possibilities and limitations of multioxide crystals growth","authors":"M. Berkowski, J. Fink-Finowicki, R. Aleksiyko","doi":"10.1117/12.435832","DOIUrl":"https://doi.org/10.1117/12.435832","url":null,"abstract":"The main methods of crystal growth from the melt the Czochralski and floating zone will be discussed and compared. Advantages, disadvantages and limitations of both methods as well as ways of solving some of the problems existing during growth of different types of multioxides crystals will be discussed. The chemical composition of crystals grown by the Czochralski method very often differs from the stoichiometric composition. Such deviations were found and well documented in a few groups of materials for example in garnets. Since the deviation is not known for most of the crystal, a simple way to determine the optimum starting composition of the melt will be presented. In order to determine the composition of the melt one should take into account evaporation of a volatile component that dissociates at high temperatures during crystal growth. Some problems related to the dopant distribution along the crystal growth direction in correlation with segregation coefficient for both methods will be discussed. To grow solid solution single crystal by the Czochralski method with a desired concentration of the admixture one has to know segregation coefficients of the components. A few examples of the dopant solubility limit in different crystal matrices will be presented.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127502046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of material behavior in DAC: system Si-O (SiOx) and compound Fe78Mn20Si2","authors":"B. Efros, N. Shishkova, A. Misiuk","doi":"10.1117/12.435808","DOIUrl":"https://doi.org/10.1117/12.435808","url":null,"abstract":"For the last ten years or so, the gasketed diamond anvil cell (DAC) has become the standard tool for the generation of high pressures. Compared with the classical hydraulic piston-cylinder devices, a DAC is three to four orders of magnitude less massive, and will generate static pressures one to two orders of magnitude higher than previous devices. In this paper, we attempt to give an understanding of the gasket behavior which will be helpful to the worker requiring routine and reliable use of a DAC in the submegabar pressure range.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"45 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122937908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Kłos, A. Pajączkowska, C. Pawlaczyk, E. Markiewicz
{"title":"Growth and dielectric properties of Ca4GdO(BO3)3 single crystals","authors":"A. Kłos, A. Pajączkowska, C. Pawlaczyk, E. Markiewicz","doi":"10.1117/12.435861","DOIUrl":"https://doi.org/10.1117/12.435861","url":null,"abstract":"Single crystals of Ca4GdO(BO3)3 have ben grown from a melt by the Czochralski puling method making use seed orientation. Defects, like dislocation were investigated. Chemical methods were developed on various planes of crystals, in order to reveal the nature and the distribution of these defects. Dielectric measurements in frequency range 20Hz-13MHz in three main crystallographic directions were carried out. The values of elastic and piezoelectric coefficients were calculated for the first mode of piezoelectric vibration in each direction.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"188 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117283407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Molecular simulations of concentrated aqueous solutions: ionic equilibrium structures in solutions","authors":"W. Bartczak, Michal Zapalowski, K. Wolf","doi":"10.1117/12.435813","DOIUrl":"https://doi.org/10.1117/12.435813","url":null,"abstract":"The computer simulation methods have been applied to study the structure of aqueous solutions of simple ionic salts in the region of very high concentrations. The calculations of ionic structures in solutions were performed for NaOH, NaCl, LiCl and MgCl2 solutions. The concentrations ranged from 0.2M to saturated solutions, in some case as much as 19M.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"4412 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128705259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dynamics and thermodynamics of quantum crystals near the instability point in the self-consistent phonon theory","authors":"C. Malinowska-Adamska, P. Słoma, J. Tomaszewski","doi":"10.1117/12.435818","DOIUrl":"https://doi.org/10.1117/12.435818","url":null,"abstract":"Formally one can distinguish between the thermodynamic stability conditions and the dynamical ones. These last consists are easily formulated in the self-consistent phonon theory (SCPT) base don the thermodynamic double-time Green's function method. According to it the dynamic instability temperature Ts for a simple Bravais lattice defines the temperature at which the bound crystalline state of atoms vanishes that really means that the phonon frequencies become complex at sufficiently high temperatures T<EQTs. Using the reduced second order approximation of the SCPT the dynamics of crystal lattice and the thermodynamical properties of the quantum crystal in the vicinity of the instability point are investigated. The results of calculations of the pressure dependence of the instability temperature, melting criterion, internal and free energy, free Gibbs energy gas well as selected dynamic properties obtained with the help of the generalized form of the Buckingham, the Lennard-Jones and the Morse self-consistent potentials are given and compared with experimental data of solid hcp 4He and fcc 20Ne. Comparison of the theoretical and experimental results allows us to state that the limiting temperature of the dynamical stability obtained for the above-mentioned models pair potentials always appear to be the upper estimations of the real melting temperature.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"85 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123505525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Scope of ZnO growth","authors":"R. Triboulet","doi":"10.1117/12.435799","DOIUrl":"https://doi.org/10.1117/12.435799","url":null,"abstract":"The main ZnO physical properties are reviewed and some of them compared to those of GaN. As a result of these attractive properties, the various applications it could be thought of for ZnO are summarized. A critical review is then proposed of the different techniques used for the growth of bulk ZnO crystals and of ZnO epitaxial films. The result are discussed from the assessment of their structural and electrical properties. The key issue of p-type doping is finally discussed in the light of the most recent results.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130131190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Bajor, S. Kaczmarek, I. Pracka, M. Świrkowicz, T. Wrońska
{"title":"Investigation of thermal annealing by gamma irradiation at room temperature in LiNbO3 crystals","authors":"A. Bajor, S. Kaczmarek, I. Pracka, M. Świrkowicz, T. Wrońska","doi":"10.1117/12.435826","DOIUrl":"https://doi.org/10.1117/12.435826","url":null,"abstract":"An interesting phenomenon of thermal annealing in gamma irradiated undoped, and photorefractive Cu- and Fe-doped, Z- oriented LiNbO3 crystal has been observed. Prior and after each gamma irradiation the crystals were thermally annealed in the air at 800 degrees C for a couple of hours. Optical homogeneity was investigated on the entire area of LiNbO3 wafers by measuring distributions of birefringence, the principal azimuth, transmission, and parameters associated with birefringence dispersion, and also by measurements of additional absorption in a few wafers' points. It has been rather unexpectedly observed that the classical thermal annealing can lead to a decease in optical homogeneity in the majority of cases. It is attributed to generation of an internal electric field by the pyroelectric effect, and to the electrooptic effect involved thereafter. On the other hand, the secondary electrons generated by gamma irradiation are believed to increase the optical homogeneity by increasing the crystal's conductivity and dissipating this field. A uniform temperature heating across the wafer generated by this irradiation is also a helpful factor in this gamma- annealing. It has been found that this effect at room temperature by this irradiation is also a helpful factor in this gamma-annealing. It has been found that this effect at room temperature is small for gamma irradiation of 105 Gy, while increasing the doses to 106 Gy and 107 Gy can profile in a considerable reduction of the optical inhomogeneity. A certain influence of Cu-doping on this effect has also been observed.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133946619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. V. Emtsev, V. Emtsev, G. Oganesyan, A. Misiuk, C. A. Londos
{"title":"Peculiarities of the thermal donor formation in Czochralski-grown silicon under high hydrostatic pressure","authors":"V. V. Emtsev, V. Emtsev, G. Oganesyan, A. Misiuk, C. A. Londos","doi":"10.1117/12.435804","DOIUrl":"https://doi.org/10.1117/12.435804","url":null,"abstract":"Oxygen agglomeration processes leading to the formation of thermal donors in Czochralski grown silicon subjected to heat treatment at T equals 450 degrees C at atmospheric pressure and a high hydrostatic pressure of P equals 1 are studied. The samples investigated were doped with isoelectronic impurities of carbon and germanium. Both impurities are known to suppress the formation processes of thermal donors under normal conditions of heat treatment. It has been shown that the stress applied during heat treatment to Cz-Si with high concentrations of these impurities results in an enhanced formation of thermal donors. This effect is thought to be associated with increasing oxygen diffusivity under stress.","PeriodicalId":365405,"journal":{"name":"International Conference on Solid State Crystals","volume":"197 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2001-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132797170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}