离子溶液中离子的扩散控制复合动力学:Debye-Smoluchowski方程的有效性限制

K. Wolf, W. Bartczak
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引用次数: 2

摘要

孤立的单对相反电荷系综中的扩散和复合过程通常用Debye-Smoluchowski方程来描述。本工作概述了一系列离子在溶液中扩散和重组的计算机模拟,目的是确定Debye-Smoluchowski方程的有效性极限。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Dynamics of diffusion-controlled recombination of ions in ionic solutions: limits of validity of the Debye-Smoluchowski equation
The diffusion and recombination process in an ensemble of isolated single pairs of opposite charges is usually described by the Debye-Smoluchowski equation. The present work is an overview of a series of computer simulations of diffusion and recombination of ions in solution performed with the aim to determine the limits of validity of the Debye-Smoluchowski equation.
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