Journal of Industrial and Engineering Chemistry最新文献

{"title":"Bi-doped g-C3N4/Bi2WO6 ternary composites for superior photocatalytic degradation of reactive orange 16 under visible light irradiation","authors":"Priti Rohilla ,&nbsp;Bonamali Pal ,&nbsp;Raj Kumar Das","doi":"10.1016/j.jiec.2024.07.007","DOIUrl":"10.1016/j.jiec.2024.07.007","url":null,"abstract":"<div><div>Because of unrestricted disposal, the concentration of reactive dyes in wastewater is gradually increasing. Owing to their eco-toxicity their removal becomes so crucial. In this regard, Bi(0)-doped g-C₃N₄/Bi₂WO₆ (g-C₃N₄/Bi@Bi₂WO₆) nanocomposites were prepared by wet impregnation followed by calcination. Remarkably, the Bi(0) doping occurs concertedly during the preparation of Bi₂WO₆ without the addition of any extra reducing agent. The efficacy of the photocatalyst for eliminating reactive orange 16 was evaluated under visible light irradiation. XRD, FESEM, HRTEM, DRS, XPS, BET, etc., were employed to characterize these hybrids. The presence of Bi(0) was confirmed by HRTEM and XPS. Increasing the g-C₃N₄ content enhances the specific surface and reduces the charge transfer resistance. Among the various photocatalysts, the 20 wt% g-C₃N₄/Bi@Bi₂WO₆ hybrid owned the highest degradation efficiency of 89 % after 300 min of reaction time. The controlled experiments confirm the participation of holes and superoxide anions during the reactions. The various reaction intermediates were detected by HRMS providing the necessary evidence about the mechanism. The heterostructure possesses excellent reusability and stability. Due to enhanced catalytic activity, high stability, and ease of synthesis, the reported composite can be considered as a promising catalyst for the degradation of pollutants.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"141 ","pages":"Pages 456-467"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141696972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advanced application of polyacrylic acid in laser-induced graphene technology","authors":"Yachuan Qu ,&nbsp;Zhifu Yin ,&nbsp;Shi Chen ,&nbsp;Xue Yang ,&nbsp;Linlin Sun","doi":"10.1016/j.jiec.2025.01.036","DOIUrl":"10.1016/j.jiec.2025.01.036","url":null,"abstract":"<div><div>Laser-induced graphene (LIG) has emerged as a revolutionary material in the graphene field, capitalizing on its remarkable electrical conductivity, excellent mechanical properties and exceptional chemical stability, underpinning its extensive applications in cutting-edge technologies. Polyacrylic acid (PAA), a soluble and film-forming PI precursor, allows for introducing various dopants into LIG, consequently significantly improving the electrical performances of the composite LIG. PAA heralds a paradigm shift in LIG synthesis. However, the existing reviews focused on the mainstream precursor materials like PES, PSU and PEEK. There are very limited reviews to summarize the synthesis, laser induction, and the application of PAA based LIG. Herein, we comprehensively investigate the diverse applications of PAA in LIG preparation and expound on its substantial advantages. PAA not only facilitates the uniform distribution of dopants but also significantly enhances the overall performance of LIG, unveiling unprecedented application potential in key areas such as energy storage, environmental protection and highly efficient sensors. The principal objective of this study is to systematically explore the unique role of PAA in LIG technology and examine its applications in energy storage, environmental protection and sensors, thereby providing novel insights and directions for further research and innovation in this burgeoning area.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 300-314"},"PeriodicalIF":5.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of electrochemical solution activation on kinetics of pyrite flotation: Experimental and theoretical investigations","authors":"Konstantin V. Prokhorov ,&nbsp;Mary A. Chibisova ,&nbsp;Anurag Srivastava","doi":"10.1016/j.jiec.2025.01.038","DOIUrl":"10.1016/j.jiec.2025.01.038","url":null,"abstract":"<div><div>This study modeled the molecular structure of adsorbed water films on the pyrite (100) surface using density functional theory (DFT) to investigate the effects of hydronium ions on the surface bonding interactions. Adding hydronium ions to the water films weakened the Fe–O interaction, increasing the Fe–O bond distance from 2.145 to 3.245 Å and, consequently, reducing hydrogen bonding among water molecules within a 5.5-Å range of the FeS₂ surface. Molecular dynamics simulations further revealed the proton transfer dynamics from the subsurface to upper water layers, aligning with experimental observations of the kinetics of pyrite particle attachment to air bubbles. Electrochemical activation of a sodium bicarbonate solution enhanced the pyrite particle loading on the bubbles by up to 32 % compared to a nonactivated solution. These results suggest that hydronium-mediated surface modifications intensify the flotation process, providing insights into optimizing mineral separation techniques.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 791-796"},"PeriodicalIF":5.9,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A brief review of dynamic membrane bioreactors for wastewater treatment: Research status and development trends","authors":"Elisabet Segredo-Morales,&nbsp;Enrique González,&nbsp;Oliver Díaz","doi":"10.1016/j.jiec.2025.01.032","DOIUrl":"10.1016/j.jiec.2025.01.032","url":null,"abstract":"<div><div>In membrane bioreactors used for wastewater treatment, self-forming dynamic membranes have recently been considered as promising alternatives for high-cost conventional micro/ultrafiltration membranes. Recent research has focused on selecting suitable support material and reactor configuration, as well as on evaluating treatment performance and optimizing operating conditions. This review begins with a bibliometric analysis to describe publication patterns and then provides information on recent developments, mainly from the last five years, on the above aspects. Several factors affecting dynamic membrane formation and stable operation are critically examined, revealing the crucial role of biological conditions (aerobic or anaerobic), support material pore size, hydraulic/solid retention time and filtration conditions (permeate flux and cleaning methods). The technology has demonstrated its ability to produce high-quality effluent with rapid dynamic membrane formation, where the appropriate selection of biological conditions is critical for stable operation. Additionally, sustainable long-term operation can be achieved by optimizing hydrodynamic conditions and implementing physical cleaning strategies. Finally, future research efforts aimed at addressing the current limitations of the technology that would be practical on a larger scale are proposed.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 230-246"},"PeriodicalIF":5.9,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress and recent developments in carbon nanotube (CNT) based composite coatings for tribological and bio-tribological applications","authors":"Anshika Babbar ,&nbsp;Gurpreet Singh ,&nbsp;Vasundhara Singh ,&nbsp;R.S. Walia","doi":"10.1016/j.jiec.2025.01.031","DOIUrl":"10.1016/j.jiec.2025.01.031","url":null,"abstract":"<div><div>Tribological phenomena such as wear and friction cause huge loss of material and resources, mechanical failures, energy consumption, CO₂ emissions, and financial loss. Composite coatings have been trending in overcoming wear and friction between interacting parts and components used in transportation, industrial, and bio-medical sectors owing to their superior mechanical and tribological properties over bare metal, ceramics, and polymer coatings. Immense progress and development have been made during the last decade by reinforcing coatings with CNT to achieve self-lubrication property and higher mechanical properties with the ultimate aim of obtaining superior tribological and bio-tribological characteristics. Thus, this article reviews recent progress and developments made in CNT-based composite coatings for both tribological and bio-tribological applications. The primary idea of this review is to elucidate the role of CNTs in improving tribological and bio-tribological characteristics. The review entails a detailed discussion of the basic fundamentals of CNT, tribological and bio-tribological characteristics of CNT-metals/ceramics/polymers-based composite coatings under different testing conditions. This review shall benefit researchers from multidisciplinary areas working on the wear and friction-related challenges encountered in aeronautical, marine, transportation, defense as well as healthcare sectors. Lastly, this review provides the scope for future advancements in both tribology and bio-tribology areas.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 196-229"},"PeriodicalIF":5.9,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Continuous manufacturing and scale up of metal organic materials (MOM): Current situation, challenges and future direction","authors":"Ahmed M. Metawea,&nbsp;Gavin Walker","doi":"10.1016/j.jiec.2025.01.020","DOIUrl":"10.1016/j.jiec.2025.01.020","url":null,"abstract":"<div><div>In the last 20 years, metal organic materials (MOMs) have developed from academic lab research into market demand through their excellent performances in several fields and industrial trials leading to a market demand. Engineering activities, scale up and bulk production is now required to feed the supply chain channels and speed up the commercialization process. These materials have shown distinguishable characteristics including porosity, adsorption, high surface area, regeneration capacity and structural flexibility which facilitated their integration into several applications such as gas separation and drug delivery. As a result, new business has started with the aim of applying the MOMs physical and chemical properties towards solving real-world problems. In this direction, research efforts have been intensified towards commercialization of the MOMs, However, moving lab scale synthesis into large scale industrial production is always associated with challenges and obstacles. These challenges mainly include production cost, quality control, and absence of common regulations, time consumption and the intense use of toxic solvents. This have resulted into their exclusion from commercial application with preferences with cheaper materials for similar applications such as zeolites and activated carbon. As an example, majority of the MOMs are synthesised up to date using over 90 % of toxic solvents as production requirement which impose environmental and production hazard.</div><div>In this review we will discuss Challenges for MOM scale up using conventional lab synthesis techniques, Continuous manufacturing techniques that are employed aiming towards commercialization. These techniques include spray drying (SD), Continuous flow synthesis (CFR), continuous stirred reactor (CSTR) and twin-screw extrusion (TSE). CSTR showed successfully synthesised UiO-66 and MOF-5 but with requirement of post treatment, CFR was also successful approach but was never tested for kilogram scale production. Spray drying was a successful technique but for reason of quality monitoring post and pre-treatment were required, Twin screw extrusion showed huge potential regarding solventless approach but only for the MOM that can be synthesised mechanocehmically. Finally, multivariate analysis and chemometrics are discussed as potential future directions research towards quality control, monitoring, process optimization and control. Aiming towards continuous synthesis of MOMs and discussing potential solutions for the existing challenges in order synthesis large quantities at affordable cost of the MOMs to meet the market demand.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 150-173"},"PeriodicalIF":5.9,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring the nanoarchitecture of Y2O3 − α-Fe2O3 bimetallic nanocomposite as a potential electrode material for high performance asymmetric supercapacitor application","authors":"Gunasekar Vijay ,&nbsp;Murugan Sethupathi ,&nbsp;Shen-Ming Chen ,&nbsp;Z. Mohamed Riyas","doi":"10.1016/j.jiec.2025.01.035","DOIUrl":"10.1016/j.jiec.2025.01.035","url":null,"abstract":"<div><div>Rapid technological breakthroughs are driving the creation of high-performance electronics, and supercapacitors are a critical component because of their quick charge–discharge characteristics. The goal of research on bimetallic nanocomposites is to improve supercapacitor performance and scalability by increasing energy storage efficiency, charge–discharge rates, and long-term stability. A supercapacitor three-electrode system has been used to study the Y₂O₃-α-Fe₂O₃ composite’s electrochemical performance. The results show that the composite provides a greater capacitance of 1216F/g at 1 A /g. Furthermore, the Trasatti approach demonstrates the charge accumulation mechanism that yields the inner, outer, and overall capacities of 473.91, 225.36, and 699.30F/g respectively, along with the corresponding percentages of diffusion contribution and capacity of 67.77 % and 32.23 %. Furthermore, Y₂O₃-α-Fe₂O₃ asymmetric supercapacitor devices demonstrate a high power density of 800 W/kg, with an exceptional energy density of approximately 28.8 Wh/kg at 1 A/g. A current density of 5 A/g was observed, with a capacitive retention of 92.5 % even after 5,000 continuous charge/discharge cycles. Additionally, the Coulombic efficiency was measured at 95.8 %. These favorable characteristics, along with the produced nanocomposite Y₂O₃-α-Fe₂O₃, suggest that it may serve as a promising electrode material for next-generation supercapacitors.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 767-777"},"PeriodicalIF":5.9,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling cutting-edge progress in coordination chemistry of the metal-organic frameworks (MOFs) and their composites: Fundamentals, synthesis strategies, electrochemical and environmental applications","authors":"Valentine Chikaodili Anadebe ,&nbsp;Abhinay Thakur ,&nbsp;Chandrabhan Verma ,&nbsp;Bhekie B Mamba ,&nbsp;Akram Alfantazi ,&nbsp;Eno E. Ebenso ,&nbsp;Rakesh Chandra Barik","doi":"10.1016/j.jiec.2025.01.033","DOIUrl":"10.1016/j.jiec.2025.01.033","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) refer to materials consisting of metal ions connected to organic ligands and resulting in tightly packed, periodically porous structures. The present review casts light on the role of coordination chemistry in MOF formation and the resultant impact on the electrochemical and environmental performances. That is, the nature of metal–ligand interactions particularly coordination geometry and bonding modes is demonstrated to dictate important attributes like porosity, stability and electronic character of the systems. In energy storage applications, the incorporation of transition metal-based MOFs such as NiVO₃@CoNi-MOF has shown a vast improvement. From these materials, the specific capacitance of 19.20F/cm² and energy density of 1.27 mWh/cm² are obtained with high cycling stability of 96.43 % after 10,000 cycles due to a controlled coordination environment. In environmental applications, the catalytic activity of MOF-based systems is believed to be a result of the ordered distribution of metal nodes and organic linkers. For instance, the V₂O₅@C catalyst showed low over-potential (282 mV) for OER with improved electron transfer due to the well-defined coordination structures of the catalysts. The results highlight the role of coordination chemistry in the control of the stimuli-responsive properties of MOFs and show their high efficiency in numerous processes, including energy storage and pollutant removal. This review demonstrates how improvements in coordination chemistry can enhance MOF performance thus expanding their applications in sustainable technologies.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 247-299"},"PeriodicalIF":5.9,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144106256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Statistical physics and fractal like kinetic modelling for adsorption of acetaminophen on MgO/aminated β-cyclodextrin: Variables optimization using Box-Behnken Design","authors":"Mohd Nasir ,&nbsp;Sara Chishti ,&nbsp;Atif Afroz ,&nbsp;Mohammad Kashif ,&nbsp;Nafisur Rahman ,&nbsp;Mohammad Shahzad Samdani ,&nbsp;Kim Min","doi":"10.1016/j.jiec.2025.01.030","DOIUrl":"10.1016/j.jiec.2025.01.030","url":null,"abstract":"<div><div>Magnesium oxide/aminated β-cyclodextrin (MgO/β-CD-O-C₂H₄-NH₂) was synthesized for the elimination of acetaminophen from water. The material was characterized using various analytical techniques. Box-Behnken design (BBD) combined with response surface methodology (RSM) was employed to optimize key adsorption parameters (contact time = 70 min, adsorbent dose = 15 mg, pH = 6.5, and initial acetaminophen concentration = 125 mg/L) to achieve the maximum removal efficiency (99.28 %). Equilibrium data were analyzed using classical isotherm and statistical physics models. Among the classical isotherm models, Langmuir model (R² = 0.9996–0.9997) fitted best to adsorption data with the maximum saturation capacity of 213.84 mg/g at 298 K. Statistical physics model (M 2: monolayer with two energies) revealed that acetaminophen adsorption occurred on two distinct receptor sites, supported by adsorption energies (E₁ = 28.35–35.36 kJ/mol; E₂ = 11.97–13.03 kJ/mol), indicating physical forces primarily govern the uptake of acetaminophen. The kinetic data were best fitted to the fractal-like pseudo-first-order model (R² = 0.9927–0.9998), revealing energetic heterogeneity. Diffusion-based models (Weber-Morris and Boyd) confirmed the involvement of both intraparticle and film diffusion mechanisms. The material demonstrated excellent reusability, maintaining high acetaminophen removal efficiency over eight adsorption–desorption cycles.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 742-757"},"PeriodicalIF":5.9,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanistic exploration and optimization of amoxicillin adsorption using discarded disposable diapers (D3) activated carbon: A multi-analytical approach","authors":"Darween Rozehan Shah Iskandar Shah ,&nbsp;Nur Faradila Anuar ,&nbsp;Wan Mohd Ashri Wan Daud ,&nbsp;Azil Bahari Alias ,&nbsp;Nasrin Aghamohammadi","doi":"10.1016/j.jiec.2025.01.024","DOIUrl":"10.1016/j.jiec.2025.01.024","url":null,"abstract":"<div><div>This study investigates the potential of activated carbon derived from discarded disposable diapers (D3AC) for cost-effective removal of amoxicillin (AMX) from water. D3AC was prepared using CO₂ activation at 900 °C, yielding a high surface area (1235.32 m²/g) and total pore volume (0.88 cm³/g). Optimal AMX removal (86.52 %) was achieved under conditions of 5 g D3AC dosage, pH 4.0, and 50 min contact time, as determined by the Box-Behnken Design. Adsorption kinetics followed a pseudo-second-order model, while isotherm data aligned with the Langmuir model, indicating a maximum adsorption capacity of 208.17 mg/g at 25 °C. The adsorption mechanism involved electrostatic interactions, π–π stacking, hydrogen bonding, and pore-filling effects, enhancing AMX binding to the D3AC surface. The process was statistically robust, with a highly significant ANOVA p-value (&lt; 0.0001) and R² = 0.9841. This dual-purpose strategy addresses pharmaceutical pollution and waste management, offering a circular, sustainable solution to environmental challenges. By converting diaper waste into efficient adsorbents, D3AC contributes to improved water quality and public health, presenting an innovative approach to tackling global environmental and health issues. This study demonstrates the feasibility of transforming waste into high-performance materials for environmental applications.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"148 ","pages":"Pages 665-678"},"PeriodicalIF":5.9,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}