Journal of Industrial and Engineering Chemistry最新文献

Mitochondria-targeted NIR molecular probe for detecting viscosity of gland damage and SO2 in actual samples 线粒体靶向近红外分子探针，用于检测腺体损伤的粘度和实际样品中的二氧化硫

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-29 DOI: 10.1016/j.jiec.2024.09.046

Peng Lei , Ruifang Wang , Chuan Dong , Shaomin Shuang , Minglu Li

{"title":"Mitochondria-targeted NIR molecular probe for detecting viscosity of gland damage and SO2 in actual samples","authors":"Peng Lei , Ruifang Wang , Chuan Dong , Shaomin Shuang , Minglu Li","doi":"10.1016/j.jiec.2024.09.046","DOIUrl":"10.1016/j.jiec.2024.09.046","url":null,"abstract":"<div><div>Glandular damage can be caused by various factors, including disease, trauma, or other abnormalities within the organism. The viscosity of the gland is one of the important indicators to measure the degree of damage. Sulfur dioxide (SO<sub>2</sub>) is widely used as an important food additive due to its preservative and bleaching properties, but its overuse has serious negative impacts on the environment, so it is urgent to develop a simple detection method. Herein, we designed and synthesized a mitochondria-targeted near-infrared (NIR) fluorescence probe (BDC) for the detection of viscosity and SO<sub>2</sub>. BDC consisted of a donor-π-acceptor (D-π-A) structure and extended double bonds bridging rotor, which enabled sensitive response to viscosity and intense fluorescence emission. The TICT (twisted intramolecular charge transfer) of BDC was inhibited with an increase in viscosity, accompanied by a significant enhancement of red fluorescence signal with emission wavelength beyond 800 nm. Notably, BDC was able to noninvasively and sensitively monitor the viscosity changes in the glands of non-obese diabetic (NOD) mice model. BDC was utilized for monitoring SO<sub>2</sub> in food and environmental samples through Michael addition reactions, providing a straightforward tool for SO<sub>2</sub> detection in food safety and environmental monitoring.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"140 ","pages":"Pages 658-664"},"PeriodicalIF":5.9,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142560753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced Z-scheme H-g-C3N4/Bi2S3 nanocomposites: Boosting photocatalytic degradation of antibiotics under visible light exposure 先进的 Z 型 H-g-C3N4/Bi2S3 纳米复合材料：在可见光照射下促进抗生素的光催化降解

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-26 DOI: 10.1016/j.jiec.2024.09.045

Govinda Raj Muniyandi , Jeyapaul Ubagaram , Abinaya Srinivasan , Daisy Rani James , Nalandhiran Pugazhenthiran , Chandramohan Govindasamy , John Alphin Joseph , Aruljothy John Bosco , Shanmugam Mahalingam , Junghwan Kim

{"title":"Advanced Z-scheme H-g-C3N4/Bi2S3 nanocomposites: Boosting photocatalytic degradation of antibiotics under visible light exposure","authors":"Govinda Raj Muniyandi , Jeyapaul Ubagaram , Abinaya Srinivasan , Daisy Rani James , Nalandhiran Pugazhenthiran , Chandramohan Govindasamy , John Alphin Joseph , Aruljothy John Bosco , Shanmugam Mahalingam , Junghwan Kim","doi":"10.1016/j.jiec.2024.09.045","DOIUrl":"10.1016/j.jiec.2024.09.045","url":null,"abstract":"<div><div>Abnormal concentrations of antibiotics found in aquatic environments have raised serious environmental concerns. For the efficient degradation of antibiotics, it is necessary to develop photocatalysts that react to visible light. In this work, calcination and hydrothermal methods were used to synthesize bare H-g-C<sub>3</sub>N<sub>4</sub> and Bi<sub>2</sub>S<sub>3</sub>, respectively. Various analytic methods, such as XRD, XPS, FT-IR, HR-SEM, and HR-TEM, were utilized to verify the accomplished synthesis of the materials produced. The results of ultraviolet–visible diffuse reflectance spectroscopy (UV–DRS) showed that the synthesized nanocomposites exhibited a lower band gap than the bare materials and thus greater visible-light absorption. The degradation efficacy of the bare materials and hydrothermally synthesized nanocomposites over ciprofloxacin were investigated. A high degradation efficiency of 92 % was demonstrated for ciprofloxacin using the H-g-C<sub>3</sub>N<sub>4</sub>/Bi<sub>2</sub>S<sub>3</sub> (5 %) nanocomposite. This remarkable efficiency underscores the potential of this nanocomposite in removing antibiotic pollutants from wastewater. In addition, the electron transfer dynamics amid the two materials (H-g-C<sub>3</sub>N<sub>4</sub> and Bi<sub>2</sub>S<sub>3</sub>) within the heterojunction was elucidated. The findings provide valuable insights into the mechanisms underlying the enhanced photocatalytic activity of nanocomposites, paving the way for further optimization and development of advanced photocatalytic systems for environmental remediation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"140 ","pages":"Pages 647-657"},"PeriodicalIF":5.9,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142560752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sodium-doped LiFe0.5Mn0.5PO4 using sodium gluconate as both reducing agent and a doping source in Lithium-ion batteries 锂离子电池中使用葡萄糖酸钠作为还原剂和掺杂源的钠掺杂 LiFe0.5Mn0.5PO4

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-12 DOI: 10.1016/j.jiec.2024.09.019

Eunjeong Cho, Sooin Jeong, Donguk Kim, Wonchang Choi

{"title":"Sodium-doped LiFe0.5Mn0.5PO4 using sodium gluconate as both reducing agent and a doping source in Lithium-ion batteries","authors":"Eunjeong Cho, Sooin Jeong, Donguk Kim, Wonchang Choi","doi":"10.1016/j.jiec.2024.09.019","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.09.019","url":null,"abstract":"LiFeMnPO (LFMP) cathode materials faces developmental challenges because Fe and Mn ions are prone to oxidation during the synthesis process and exhibit low electronic and ionic conductivities. We propose employing a multifunctional sodium gluconate that simultaneously acts as a reducing agent and dopant. XPS analysis shows an increased ratio of Fe and Mn ions within LFMP following the introduction of the reducing agent. Rietveld refinement indicates an expanded b-axis lattice space at an appropriate amount of Na-doped LFMP/C, which results in enhancement the Li diffusivity. SEM and TEM-EDS mapping confirm the morphology and elemental distribution of the LFMP materials. Electrochemical properties show the introduction of sodium gluconate enhanced the electrochemical properties of LFMP materials. This result demonstrates that the reducing agent prevents oxidation of transition metals during synthesis and Na doping significantly increases the Li diffusion coefficient. The LiNaFeMnPO/C sample, when combined with a reducing agent, exhibits an outstanding rate performance of 122.6 mAh/g at 1C, 113.4 mAh/g at 5C, and 85.1 mAh/g at 20C. The enhancements in both electronic and ionic conductivities of LFMP cathodes are mainly ascribed to the incorporation of a reducing agent and Na doping.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"17 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Construction on ionic organic polymers by multi-components reactions: Experimental and kinetics modeling of efficient CO2-fixation and high iodine vapor adsorption 通过多组分反应构建离子有机聚合物：高效二氧化碳固定和高碘蒸气吸附的实验和动力学建模

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-10 DOI: 10.1016/j.jiec.2024.09.015

Xuanbo Liu, Ningning Li, Yuhang Zhang, Zheng Zhu, Xionglei Wang, Yafei Sang, Tao Chang, Jiajia Yang, Shenjun Qin, Yongjing Hao

引用次数: 0

Efficient removal of Pb(II) and Cd(II) from water by polyethyleneimine-amidated sepiolite-sodium alginate composite microspheres: Characterization and mechanistic analysis 聚乙烯亚胺酰胺化海泡石-海藻酸钠复合微球高效去除水中的铅(II)和镉(II)：特性和机理分析

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-10 DOI: 10.1016/j.jiec.2024.09.010

Bowen Wang, Hang Yin, Miao Zhang, Fenge Zhang

{"title":"Efficient removal of Pb(II) and Cd(II) from water by polyethyleneimine-amidated sepiolite-sodium alginate composite microspheres: Characterization and mechanistic analysis","authors":"Bowen Wang, Hang Yin, Miao Zhang, Fenge Zhang","doi":"10.1016/j.jiec.2024.09.010","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.09.010","url":null,"abstract":"In order to improve the physicochemical properties of heavy metal adsorbents, researchers developed a novel composite microsphere material (SEI) by incorporating Sepiolite (Sep) and cross-linked polyethyleneimine (PEI) with sodium alginate (SA) as a carrier. The stability of the SEI under normal use conditions was high by thermogravimetric analysis, and COOH, OH, and NH functional groups were detected by FTIR, which were confirmed to be involved in adsorption. It was found that the adsorption rate of SEI on Pb(II) and Cd(II) obeyed a pseudo-second-order kinetic model, while the adsorption pattern was closely related to the Langmuir equation. Notably, the maximum adsorption capacity of SEI for Pb(II) and Cd(II) was 1099.93 mg/g and 112.89 mg/g, respectively, at 30 °C. In addition, thermodynamic analyses showed that the adsorption process was spontaneous, with entropy increase along with heat absorption. After six adsorption and desorption cycles, the removal of Pb(II) and Cd(II) by SEI remained above 90 %. These findings suggest that SEI is a promising and environmentally friendly material for the removal of Pb(II) and Cd(II).","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"111 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Modeling, parameter estimation and optimization of fluidized bed-based alternative ironmaking process for CO2 emission reduction 流化床炼铁替代工艺的建模、参数估计和优化，以减少二氧化碳排放

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-10 DOI: 10.1016/j.jiec.2024.09.008

Jae Hwan Choi, Shikyung Yoon, Sunyoung Kim, Myung Kyun Shin, Jong Min Lee

{"title":"Modeling, parameter estimation and optimization of fluidized bed-based alternative ironmaking process for CO2 emission reduction","authors":"Jae Hwan Choi, Shikyung Yoon, Sunyoung Kim, Myung Kyun Shin, Jong Min Lee","doi":"10.1016/j.jiec.2024.09.008","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.09.008","url":null,"abstract":"This study presents the development of a comprehensive process model for simulating and optimizing the FINEX process consists of the multi-stage fluidized beds, the melter-gasifier unit, and a gas recycling system. The model is developed using Pyomo, a Python-based open-source software package that provides extensive capabilities for formulating, solving, and analyzing optimization models. It incorporates heat and mass balance equations and captures a wide range of chemical reactions, including the reduction of iron ore by hydrogen and carbon monoxide, the calcination of carbonate materials, the water–gas shift reaction, and coal gasification and combustion. Unknown parameters in the model, such as heat loss in each reactor, the extent of the calcination reaction, and the outlet gas temperature from the melter-gasifier, were estimated to calibrate the model. These parameters were estimated by solving an optimization problem that minimizes the gap between the model and real plant data. The optimized model was employed to investigate various scenarios for minimizing CO emissions in the FINEX process. This included assessing the impact of HBI charging rates, iron ore quality, and the integration of a CCUS unit. For each scenario, an optimization problem was formulated to minimize production costs across a range of CO tax levels. The optimal solutions revealed the relationships between process economics and CO emissions for each variable.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"117 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Flash calcination of magnesite in a one-throughput transport bed: reaction characterization and industrial justification 在单程传输床中闪速煅烧菱镁矿：反应特征和工业理由

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-10 DOI: 10.1016/j.jiec.2024.09.012

Ping An, Zhenglong Sun, Xiaofeng Song, Cong Sun, Bowei Yan, Zhennan Han, Dingrong Bai, Guangwen Xu

引用次数: 0

Modifying PVDF/Ppy’s mechanical and luminescent properties by incorporating ZnS nanoparticles for visible light photocatalytic water remediation: Experimental and theoretical approach 通过加入 ZnS 纳米粒子改变 PVDF/Ppy 的机械和发光特性，用于可见光光催化水处理：实验和理论方法

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-06 DOI: 10.1016/j.jiec.2024.09.005

Fawzy G. El Desouky, A.M. Ismail, R.A. Nasr

{"title":"Modifying PVDF/Ppy’s mechanical and luminescent properties by incorporating ZnS nanoparticles for visible light photocatalytic water remediation: Experimental and theoretical approach","authors":"Fawzy G. El Desouky, A.M. Ismail, R.A. Nasr","doi":"10.1016/j.jiec.2024.09.005","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.09.005","url":null,"abstract":"The current research explores nanocomposites PVDF/Ppy/ZnS (PV/PY/ZS) manufactured using co-precipitation and casting processes to improve dynamic mechanical testing, luminescence, and visible light photocatalytic wastewater.ZS is precisely integrated and evenly distributed in the PV/PY matrix, according to XRD, FESEM, and FTIR measurements. The addition of ZS nanoparticles to the PV/PY matrix significantly enhances the change in the storage modulus of the nanocomposites, which ranges from 1.42 to 13.58 GPa at a temperature of 25 °C. PV/PY-0.03ZS has uniform electronic microscopic structures, as demonstrated by a corresponding peak at the same frequency. The addition of ZS species drastically lowered the photoluminescence (PL) spectra of PV/PY-0.03ZS, indicating that ZS modulation inhibited electron-hole pair production.The PV/PY-0.03ZS composite removed brilliant cressyl blue (BCB) 97 % at a rate constant of 0.012 min. In visible light, the scavenger experiment showed that electrons were essential for BCB dye photodegradation over PV, PY, and 0.03 ZS. Reusing the same conditions had no effect on removal efficiency. A factorial design comprising sixteen experiments was used to investigate the effects of variables. This fits in with the sustainability axis, which suggests that the developed immobilized photocatalyst might be used in industrial-scale water treatment units instead of slurry reactors.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"75 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Absorption of dichloromethane using NHD-EG-10 %: Molecular simulation and experimental investigation 使用 NHD-EG-10 % 吸收二氯甲烷：分子模拟和实验研究

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-05 DOI: 10.1016/j.jiec.2024.08.055

Kefan Chao, Li Wang, Zekai Jin, Muhua Chen, Xinbao Zhu, Gang Zhang, Bo Fu

{"title":"Absorption of dichloromethane using NHD-EG-10 %: Molecular simulation and experimental investigation","authors":"Kefan Chao, Li Wang, Zekai Jin, Muhua Chen, Xinbao Zhu, Gang Zhang, Bo Fu","doi":"10.1016/j.jiec.2024.08.055","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.08.055","url":null,"abstract":"The screening of absorbents is crucial to treat dichloromethane (DCM) exhaust gas by using the absorption method. In this work, binding energy calculation based on quantum computational chemistry are used to calculate the absorptive capacity of different absorbents for DCM. The absorption capacity experiment was used to verify the correspondence between the binding energy calculation results and the absorption capacity of the absorbent (R0.872). After intermolecular force analysis and further screening, we choose polyethylene glycol dimethyl ether (NHD) as the main solvent to obtain a better DCM absorbent. The new compound absorbent can be obtained after adjusting the compounding ratio of ethylene glycol (EG) and N-Methyl-2-pyrrolidone (NMP) to NHD. When the compound ratio of NHD and EG is 10:1, the system removal efficiency can reach 93.1 %. It has important application value for the recycling of DCM waste gas in the chemical and medical industries. The theoretical and experimental research in this work is of great significance for the future use of quantum computational chemistry methods to screen high-efficiency absorbents, explore absorption mechanisms and process development.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"45 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142211175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green synthesis of iron oxide nanoparticles from Iris kashmiriana (Mazar-Graveyard) Plant Extract its characterization of biological activities and photocatalytic activity 从 Iris kashmiriana（Mazar-Graveyard）植物提取物中绿色合成氧化铁纳米颗粒及其生物活性和光催化活性表征

IF 6.1 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2024-09-05 DOI: 10.1016/j.jiec.2024.09.004

Asima Imtiyaz, Ajay Singh, Abhishek Bhardwaj

{"title":"Green synthesis of iron oxide nanoparticles from Iris kashmiriana (Mazar-Graveyard) Plant Extract its characterization of biological activities and photocatalytic activity","authors":"Asima Imtiyaz, Ajay Singh, Abhishek Bhardwaj","doi":"10.1016/j.jiec.2024.09.004","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.09.004","url":null,"abstract":"A significant area of interest for researchers has been the creation of trustworthy experimental techniques for producing metallic nanoparticles with specified structures and dimensions. Due to the unique features that make them usable in various scientific and technological disciplines, metallic nanoparticles made by green synthesis have attracted enormous interest over the past ten years. In this study, the plant extract of was used to create iron oxide nanoparticles utilizing a relatively affordable and straightforward conventional heating process. Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray, and X-ray diffraction were used to analyze the iron nanoparticles. Particles with diameters of 20–40 nm were created. The synthesized Iron oxide nanoparticles exhibit significant antibacterial effects against four pathogens by exhibiting a zone of inhibition for Vancomycin. The antioxidant activity DPPH of the iron oxide nanoparticles showed 83.29 %, 84.96 %, 86.71 %, 88.62 %, and 88.65 % at a different concentration, demonstrating that the scavenging percentage increases with increasing the iron oxide nanoparticles concentrations. After an investigation, Iron oxide nanoparticles were capable of photo-catalytically degrading Congo red. It was observed that at the maximum exposure length of 60 min, approximately 95 % of the dye was destroyed. This study’s findings open up new possibilities for creating, modifying, and using plant extract in nanoparticle design, development, and application.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"266 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142211198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0