{"title":"Recent advances in early warning methods and prediction of thermal runaway events in Li-ion batteries","authors":"Santosh Kumar , Hyeong-Jin Kim","doi":"10.1016/j.jiec.2024.10.057","DOIUrl":"10.1016/j.jiec.2024.10.057","url":null,"abstract":"<div><div>Li-ion batteries find extensive utilization in electric vehicles due to their prolonged operational lifespan and impressive energy density. Nevertheless, the peril of electric vehicle accidents arising from the thermal runaway of lithium-ion batteries, leading to spontaneous combustion, poses a substantial threat to both the safety of passengers and their belongings. This review paper elucidates the intrinsic mechanisms governing the occurrence of thermal runaway in lithium-ion batteries, drawing insights from a multitude of previous studies. Within the context of this review paper, a meticulous examination is undertaken of diverse approaches based on electrochemistry, battery big data and artificial intelligence for predicting and proactively identifying instances of lithium-ion thermal runaway. This analysis encompasses an evaluation of the strengths and weaknesses associated with each approach, along with a discussion of the imminent challenges and potential future directions for the advancement of intelligent methods for predicting lithium-ion battery thermal runaway.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 63-74"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancing the visible-light-catalytic activity of MIL-125(Ti)- based nanocomposites by adjusting the structure of the surface ligand: Mechanism and performance","authors":"Xiaoli Song, Junlong Wang, Shangkui Yu, Junliang Liu, Shuwei Zhang","doi":"10.1016/j.jiec.2024.10.061","DOIUrl":"10.1016/j.jiec.2024.10.061","url":null,"abstract":"<div><div>To further understand the structure impact of surface ligands on the performance of MIL-125(Ti), two molecules (TBPETC and TPETA) with different structures were designed to surface-modify MIL-125(Ti). The characterizations of powder X-ray diffractometry, Fourier transform infrared spectra, scanning electron microscope, transmission electron microscopy and energy-dispersive X-ray spectroscopy indicate the successful preparation of two novel nanocomposites, TBPETC@MIL-125(Ti) and TPETA@MIL-125(Ti). The photoelectrochemical properties of the materials were characterized by UV–visible spectroscopy, UV–visible diffuse reflectance spectra, photoluminescence spectroscopy and electrochemical impedance spectroscopy, respectively, which indicate both nanocomposites have lower bandgap energy and higher electronegativity than MIL-125(Ti). Under visible light irradiation, the removal percentage of tetracycline hydrochloride (TC) by TBPETC@MIL-125(Ti) and TPETA@MIL-125(Ti) were 91 % and 76 %. The active species capture experiments and HPLC-MS analysis indicated that <sup><img></sup>O<sup>2–</sup> and h<sup>+</sup> were the predominate active substances and TC can be degraded into small molecules. In addition, the two nanocomposites showed good performance in practical applications, reusability and stability. All the results demonstrate that the effect of conjugate structures of the surface ligand on the properties of the nanocomposites is larger than that of functional groups, and TBPETC@MIL-125(Ti) is an effective material for degradation of TC under visible light in real environment.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 647-658"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Deep remediation of oil spill based on the photocatalytic degradation of solar light-driven floating C-doped TiO2/Sepiolite composites","authors":"Wenyan Xu, Minghui Yang, Minghe Du, Yuting Gao, Chunjie Yan, Feng Zhou","doi":"10.1016/j.jiec.2024.10.054","DOIUrl":"10.1016/j.jiec.2024.10.054","url":null,"abstract":"<div><div>This study developed a novel C-doped floating-type TiO<sub>2</sub>/sepiolite composite. C-TiO<sub>2</sub>/Sep composites were synthesized using various carbon sources (glucose, acetic acid, acetylacetone) through a simple hydrothermal method, with a Ti to C molar ratio of 5 and a Ti to sepiolite ratio of 40 mmol/g. The floatable composites were obtained via hydrophobic modification using a stearic acid to product ratio of 0.7 mmol/g. The resulting composites were characterized using XRD, SEM, PL, XPS, and UV–vis. The results indicate that the chemical and morphological properties of the composites are significantly affected by the carbon source. Compared to undoped samples, the C-doped samples exhibit improved anatase phase stability and reduced grain sizes. The incorporation of C is predominantly exhibited as C-O-Ti-O, and the surfaces of the samples are modified with carbon photosensitizers. PL spectra and photocatalytic activity tests under visible light reveal that the CTHS-GLU (Hydrophobic Sepiolite with Carbon-Doped TiO<sub>2</sub> Using Glucose as the Carbon Precursor) sample achieved an 80.78 % oil removal rate, demonstrating the best efficiency in oil spill remediation, which is attributed to C-doping’s reduced band gap, high adsorption capacity, uniform TiO<sub>2</sub> distribution, and enhanced surface hydrophobicity.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 610-619"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ji Eon Chae , Jiseon Choi , Dongkeun Lee , Sunyoup Lee , Seonyeob Kim
{"title":"Development of anion exchange membrane-based electrochemical CO2 separation cells for direct air capture","authors":"Ji Eon Chae , Jiseon Choi , Dongkeun Lee , Sunyoup Lee , Seonyeob Kim","doi":"10.1016/j.jiec.2024.10.049","DOIUrl":"10.1016/j.jiec.2024.10.049","url":null,"abstract":"<div><div>The use of direct air capture (DAC) technology, which directly captures and removes carbon dioxide (CO<sub>2</sub>) from the atmosphere is vital for carbon neutrality. This study investigates the applicability of an electrochemical cell for separating CO<sub>2</sub> using an anion-exchange membrane (AEM) in DAC applications. Anions such as OH<sup>−</sup>, CO<sub>3</sub><sup>2−</sup>, and HCO<sub>3</sub><sup>−</sup> are conducted through the AEM, and the cell mechanism is determined by the main ion-type transferred. The composition of the gas generated at the anode was analyzed to understand the operating mechanism. Moreover, the operating conditions of the electrochemical cell were optimized to maximize the CO<sub>2</sub>-capture ratio. To lower the ohmic resistance of the electrochemical cell containing a dry anode, the cathode was used under excessively humid conditions along with an adequately hydrated AEM. Furthermore, the impact of serpentine and metal-foam flow fields on the cell performance was confirmed by observing the behavior of surplus water droplets on both types of systems. The fabricated device demonstrated a CO<sub>2</sub> capture ratio of 95.7 % with air containing 400 ppm of CO<sub>2</sub>, confirming its viability in DAC technology. This study offers guidance for future studies regarding the development of high-performance carbon-capture systems with a widespread applicability.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 543-550"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qing Ye , Wenhao Du , Fei Yang , Xuan Shen , Suhang Cheng , Xinke Ling , Gongming Qian
{"title":"Synergistic effect of Au nanoparticles on hydroxyapatite support for photocatalytic degradation of organic pollutants in wastewater","authors":"Qing Ye , Wenhao Du , Fei Yang , Xuan Shen , Suhang Cheng , Xinke Ling , Gongming Qian","doi":"10.1016/j.jiec.2024.10.060","DOIUrl":"10.1016/j.jiec.2024.10.060","url":null,"abstract":"<div><div>The efficient degradation of organic pollutants in wastewater is an important challenge and process a significant threat to ecosystems. The gold nanoparticles (AuNPs) performed well photocatalytic activity but suffered from the obvious agglomeration of nanoparticles and restriction in application. In this study, hydroxyapatite supports was synthesized for loading gold nanoparticles to enhance the dispersed distribution. The synergistic effect of AuNPs and HAP on photocatalysis degradation process were systematic study. The AuNPs were prepared by liquid phase reduction method and then supported on the HAP prepared by chemical precipitation method to form AuNPs/HAP composites photocatalyst. The prepared HAP support showed sufficient AuNPs supporting sites, with a high specific surface area of 17.25 m<sup>2</sup>/g and a lower porous size of 16.96 nm. The degradation experimental results showed that the AuNPs/HAP had high photocatalytic activity and superior recyclability. When the particle size of AuNPs was lower to 4.82 nm and the mass ratio of AuNPs was 0.5 wt%, the degradation rate of organic pollutants reached 89.9 % under irradiation for 60 min. The excellent characteristics of HAP as support and the fully dispersion of AuNPs with smaller particles size refrained from the particle agglomeration and enhanced the photocatalytic activity of composite photocatalyst.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 637-646"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaofei Gong , Pengfei Zhou , Chenxu Cui , Ao Tang , Miao Ben , Chaoqun Shang , Lei zheng
{"title":"Scalable production and performance optimization of Na3V2(PO4)3 cathode materials for sodium-ion batteries","authors":"Xiaofei Gong , Pengfei Zhou , Chenxu Cui , Ao Tang , Miao Ben , Chaoqun Shang , Lei zheng","doi":"10.1016/j.jiec.2024.10.058","DOIUrl":"10.1016/j.jiec.2024.10.058","url":null,"abstract":"<div><div>The Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> (NVP) cathode materials have garnered significant attention for grid energy storage due to their high theoretical capacity, rate performance, and cyclic stability. However, challenges persist, including inadequate electronic and ionic conductivity. This study addresses these issues through a novel solution-spray drying process using soluble precursors to achieve homogeneous mixing at the atomic level. This method not only promotes the formation of pure-phase NVP but also reduces carbon content effectively. Optimized heat treatment further enhances specific capacity, achieving 114 mAh/g at 0.1C with a coulombic efficiency of 99 %. These results highlight a scalable approach to improve the commercial viability of sodium-ion batteries by enabling efficient production of high-performance NVP cathode composites.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 630-636"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergistic lubrication mechanism and dispersion behavior of dodecanethiol-modified graphene oxide nanolubricant","authors":"Yu Xia , Xinshao Cheng , Ying Wang , Yijia Xie , Zhuoli Ding , Xiaodong Hu , Xuefeng Xu , Ruochong Zhang","doi":"10.1016/j.jiec.2024.10.043","DOIUrl":"10.1016/j.jiec.2024.10.043","url":null,"abstract":"<div><div>To enhance both the load-bearing capacity and dispersion stability of graphene oxide (GO), this study proposes a novel nanolubricant design approach. A dual-function additive acting as both a surface modifier and an extreme pressure agent, dodecanethiol (DDT), was introduced into the GO nanolubricant. As a pioneering dispersion method, sodium dodecyl sulfate-oleic acid (SDS-OA) gelators were incorporated to drag DDT-modified GO (GO/DDT) through the Van der Waals force between alkyl chains, which enables GO/DDT nanolubricant maintain stable dispersion in white oil (WO) for over one year. Additionally, the well-dispersed GO/DDT nanolubricant exhibit superior anti-friction, anti-wear and extreme pressure property under minimum quantity lubrication conditions. Compared with WO, the coefficient of friction (COF) and wear scar diameter (WSD) under 0.06 wt% GO/DDT nanolubricant lubrication were reduced by 31.9% and 28.8%. These are attributed to the fact that the modifier DDT not only participates in the molecular attraction with the gelators to inhibit the sedimentation of GO nanosheets, but also synergizes with GO to form both physical protective films and chemical reaction films on the friction surface.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 477-490"},"PeriodicalIF":5.9,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Peroxymonosulfate enhanced electrokinetic remediation of PAHs-contaminated soil: Effects of periodic electric field","authors":"Mingzhu Zhou , Ruihan Chen , Qiao Huang , Long Cang","doi":"10.1016/j.jiec.2024.10.050","DOIUrl":"10.1016/j.jiec.2024.10.050","url":null,"abstract":"<div><div>Power consumption is a key factor that affects the cost of electrokinetic (EK) remediation technology. However, the impact of a periodic electric field on organic pollutant removal and energy saving when using EK enhanced chemical oxidation technology has been unclear. In this study, one experiment with a continuous current and five experiments with periodic electric fields of different periodic frequencies (1:1, 2:1, and 3:1) and power-off times (0.5, 8, and 24 h) combined with peroxymonosulfate (PMS) were performed to remove polycyclic aromatic hydrocarbons (PAHs) from soil. The results showed that the average current decreased along with an increase in the periodic frequencies (from 1:1 to 3:1). However, under the same periodic frequency (2:1) with different power-off times (0.5, 8, and 24 h), the currents were relatively close. Compared to the continuous current treatment, different periodic frequencies and power-off times all improved the PAHs removal rates, particularly those PAHs with high ring numbers. Among them, the treatment with the 2:1 periodic frequency and 1 day power-off time achieved the highest removal efficiency (36.1 % of total PAHs) and successfully enhanced PAHs removal in the anode area. Except for the treatment with the 1:1 periodic frequency and 1 day power-off time, the unit energy consumptions of the other periodic electric field treatments were lower than that of the continuous current treatment. This study demonstrates that a periodic electric field could reduce unit energy consumption and improve the PAHs removal efficiency, and the periodic frequency was a crucial factor. This study provides a new technical option for PMS-enhanced EK remediation of organic polluted soil and promotes the application and development of EK remediation technology.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 551-560"},"PeriodicalIF":5.9,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiyang Liu , Graham Dawson , Konstantinos Papadikis , Pow-Seng Yap
{"title":"Magnetically separable quaternary g-C3N4/Fe3O4/AgBr/rGO nanocomposite for enhanced photocatalytic degradation of ofloxacin in water under visible light irradiation","authors":"Xiyang Liu , Graham Dawson , Konstantinos Papadikis , Pow-Seng Yap","doi":"10.1016/j.jiec.2024.10.051","DOIUrl":"10.1016/j.jiec.2024.10.051","url":null,"abstract":"<div><div>Novel photocatalytic-magnetic hybrid quaternary nanocomposite (g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/AgBr/rGO) was successfully synthesized for the first time via ultrasonication-assisted wet chemistry technique. The nanocomposite was characterized using various advanced characterization techniques and its visible light photocatalytic performance was analyzed by using ofloxacin (OFL) as target pollutant. The photocatalytic degradation efficiency was 100 % under conditions (pH 6.65, 0.1 g/L nanocomposite and 10 mg/L OFL) in 5 h. The pseudo-first-order kinetic constant of g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/AgBr/rGO was as high as 1.1832 h<sup>−1</sup>. Evaluation of different catalysts, catalyst dosage, initial concentrations of OFL and initial solution pH have been studied. Based on the scavenging tests, benzoquinone (BQ) significantly decreased the removal efficiency of OFL to 41.4 %, indicating that <sup><img></sup>O<sub>2</sub><sup>−</sup> served as the dominant radical involved in the reaction. More importantly, after undergoing five cycles, the g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/AgBr/rGO nanocomposite demonstrated robust stability and was effectively separated from the solution through magnetic means. The remarkable performance of g-C<sub>3</sub>N<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/AgBr/rGO is linked to substantial utilization of visible light and facilitation of Z-scheme heterojunctions, thereby facilitating charge separation. The quaternary nanocomposite can be expected to have tremendous potential for the degradation of emerging organic pollutants. Thus, it is favorable for practical application in water and wastewater treatment.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 561-576"},"PeriodicalIF":5.9,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gitae Kim , Harshavardhan Mohan , Ga Hyeon Ha , Hye Rin Lee , Taeho Shin
{"title":"Photocharging-activated photocatalysis for hydrogen production in CdS@CdxPb1−xS core-shell nanoparticles","authors":"Gitae Kim , Harshavardhan Mohan , Ga Hyeon Ha , Hye Rin Lee , Taeho Shin","doi":"10.1016/j.jiec.2024.10.048","DOIUrl":"10.1016/j.jiec.2024.10.048","url":null,"abstract":"<div><div>The CdS@Cd<sub>x</sub>Pb<sub>1−x</sub>S core–shell photocatalyst was synthesized through cation exchange and demonstrated significant photocatalytic hydrogen production. Initially, the catalyst was inactive due to the formation of an unfavourable Type I heterojunction. However, under continued illumination, electron accumulation in the Cd<sub>x</sub>Pb<sub>1−x</sub>S shell led to electron repulsion, triggering a structural transition from a film-like morphology to quantum dots (QDs). This transition resulted in the formation of a Type II heterojunction between the CdS and PbS components, boosting hydrogen production by 400% compared to CdS nanoparticles. The reversible structural transformation and stable performance over multiple cycles highlight the potential of CdS@Cd<sub>x</sub>Pb<sub>1−x</sub>S nanoparticles as a highly efficient photocatalyst for hydrogen evolution.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"145 ","pages":"Pages 534-542"},"PeriodicalIF":5.9,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}