Journal of Industrial and Engineering Chemistry最新文献_第10页

Corrosion inhibition of mild steel using N1, N2-bis[4-(dimethylamino)benzyl]ethane-1,2-diamine with synergistic interaction of KI KI协同作用下N1， n2 -双[4-（二甲氨基）苄基]乙烷-1,2-二胺对低碳钢的缓蚀作用

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-17 DOI: 10.1016/j.jiec.2025.07.041

Sachin Dua , Nishtha Arora , B.G. Prakashaiah , Varsha Choudhary , Punit Kumar , T. Senthilkumar

{"title":"Corrosion inhibition of mild steel using N1, N2-bis[4-(dimethylamino)benzyl]ethane-1,2-diamine with synergistic interaction of KI","authors":"Sachin Dua , Nishtha Arora , B.G. Prakashaiah , Varsha Choudhary , Punit Kumar , T. Senthilkumar","doi":"10.1016/j.jiec.2025.07.041","DOIUrl":"10.1016/j.jiec.2025.07.041","url":null,"abstract":"<div><div>The anti-corrosion effectiveness of N<sup>1</sup>, N<sup>2</sup>-bis[4-(dimethylamino)benzyl]ethane-1,2-diamine (BDBEH) and its synergy with potassium iodide (KI) in 1 M HCl was evaluated for the first time on C1010 mild steel (MS) using electrochemical and gravimetric analysis. Both studies confirmed that BDBEH offers superior anti-corrosion performance, which improves with higher concentrations. According to gravimetric analysis, the BDBEH exhibited an average corrosion protection efficiency (<em>η</em>) of 93.43 % with 2 mM BDBEH at 303.15 K. At elevated temperature (333.15 K), the anti-corrosion performance of BDBEH reduced to 88.34 % with 2 mM. Adding KI further boosted the anti-corrosion performance of BDBEH; the enhanced <em>η</em> mean value is 98.23 % at 303.15 K and 98.51 % at 333.15 K. The synthesised molecule acted as a mixed corrosion inhibitor supported by potentiodynamic polarisation (PDP) spectra. The thermodynamic and kinetic parameters indicate that the superior anti-corrosion performance of BDBEH is exhibited via a mixed chemisorption-physisorption mechanism. BDBEH adheres to the Langmuir adsorption, forming a single layer. Field Emission Scanning Electron Microscopy (FE-SEM) confirmed inhibitor-induced surface protection. Density Functional Theory (DFT) and Molecular Dynamics (MD) simulations were used to study BDBEH’s interaction with MS. The combined system exhibits superior surface coverage and stronger adsorption, distinguishing it from earlier studies on similar diamine-based inhibitors.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 762-778"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergistic NH3 adsorption on a bimetallic CuCoBTC series via Lewis acid–base interaction and DFT analysis 基于Lewis酸碱相互作用和DFT分析的双金属CuCoBTC系列协同NH3吸附

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-06-27 DOI: 10.1016/j.jiec.2025.06.050

Jia-Yin Lin , Bing-Ze Lin , Yi-Fan Yao , Chih-Ying Wang , Wen-Ta Yang

{"title":"Synergistic NH3 adsorption on a bimetallic CuCoBTC series via Lewis acid–base interaction and DFT analysis","authors":"Jia-Yin Lin , Bing-Ze Lin , Yi-Fan Yao , Chih-Ying Wang , Wen-Ta Yang","doi":"10.1016/j.jiec.2025.06.050","DOIUrl":"10.1016/j.jiec.2025.06.050","url":null,"abstract":"<div><div>Ammonia (NH<sub>3</sub><span>) is a hazardous air pollutant with strong toxicity and corrosiveness, necessitating the development of efficient and reusable adsorbents. In this study, a series of bimetallic metal–organic frameworks (Cu</span><sub>1</sub>Co<sub>x</sub>BTC, x = 0.1, 0.5, 1, 2) were synthesized via partial substitution of Cu<sup>2+</sup> in Cu<sub>1</sub>BTC with Co<sup>2+</sup><span><span> through a solvothermal method. Structural and </span>chemical characterizations<span> confirmed successful Co incorporation, accompanied by changes in morphology, crystallinity, acidity, and porosity. Among the tested materials, Cu</span></span><sub>1</sub>Co<sub>1</sub>BTC exhibited the highest NH<sub>3</sub><span> uptake of 13.45 mg/g at 100 ppm and 25 °C, with over 94 % capacity retained<span> after ten adsorption–desorption cycles, indicating excellent stability and regenerability. Parametric studies<span> demonstrated that lower temperatures, moderate flow rates, and optimized adsorbent dosage favored NH</span></span></span><sub>3</sub> capture. NH<sub>3</sub><span><span>-TPD and XPS<span> analyses revealed coexisting physisorption and </span></span>chemisorption, predominantly through Lewis acid–base interactions. Density functional theory (DFT) calculations further confirmed that NH</span><sub>3</sub> binds preferentially to both Cu<sup>2+</sup> and Co<sup>2+</sup> via nitrogen lone-pair donation, forming M−N coordination bonds. Co<sup>2+</sup> sites showed stronger binding energies and shorter bond distances, highlighting the synergistic role of dual-metal centers. This study integrates experimental and theoretical evidence to elucidate a dual-site adsorption mechanism and provides design principles for MOF-based adsorbents with improved NH<sub>3</sub><span> selectivity, capacity, and recyclability.</span></div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 300-310"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydroxyalkyl oxadiazole-thione surfactants: Preparation, and clean flotation separation of galena from sphalerite 羟基烷基恶二唑硫酮表面活性剂的制备及方铅矿与闪锌矿的清洁浮选分离

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-04 DOI: 10.1016/j.jiec.2025.07.004

Liying Fu, Mahmoud Mohamed Mohamed Ahmed, Sheng Liu, Wei Chen, Guangyi Liu

{"title":"Hydroxyalkyl oxadiazole-thione surfactants: Preparation, and clean flotation separation of galena from sphalerite","authors":"Liying Fu, Mahmoud Mohamed Mohamed Ahmed, Sheng Liu, Wei Chen, Guangyi Liu","doi":"10.1016/j.jiec.2025.07.004","DOIUrl":"10.1016/j.jiec.2025.07.004","url":null,"abstract":"<div><div><span>Reducing the lime consumption in the galena-sphalerite flotation separation is important for CO</span><sub>2</sub> emission control. Here, novel hydroxyalkyl oxadiazole-thione surfactants including 5-(5-hydroxypentyl)-1,3,4-oxadiazole-2-thione (HPODT), 5-(3-hydroxyoctyl)-1,3,4-oxadiazole-2-thione (HOODT) and 5-(3-hydroxydecyl)-1,3,4-oxadiazole-2-thione (HDODT) were synthesized and adopted in the separation. Micro-flotation results exhibited that HOODT presented the superior collecting affinity towards galena and excellent selectivity against sphalerite under the dosage of 1.0 × 10<sup>−5</sup> mol·L<sup>−1</sup> at pH ∼ 8.0. DFT calculation deduced that the exocyclic S atom connected to oxadiazole group was the chemical reactivity center of HOODT anion. The oxadiazole-thione configuration offered the dominant contribution to HOODT’s LUMO, which delocalized the valence electrons of all the atoms in the configuration, and enhanced its electron-accepting ability. XPS and FTIR demonstrated that HOODT chemically adsorbed on the surface of galena, and its exo-S and endo-N atoms combined with surface Pb(Ⅱ) atom(s) to generate Pb<img>S and Pb<img>N bonds. On the other hand, the octyl group of HOODT oriented outward to attach bubbles, while its hydroxyl group might form the intermolecular hydrogen bond, making HOODT molecules more closely arrange on galena surface. As a result, HOODT returned the selective flotation separation of Pb/Zn sulfide minerals under weak alkaline conditions, which would benefit their clean flotation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 386-396"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in OFET-based NO2 detection: Molecular engineering, film morphology control, and device optimization 基于ofet的NO2检测进展：分子工程、膜形态控制和器件优化

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-13 DOI: 10.1016/j.jiec.2025.07.011

Kyuhyeon Ahn , Bong-Gi Kim , Yeongkwon Kang

引用次数: 0

Design of an environmentally friendly new chiral SHNFM–CuCl3 DES as solvent, electrolyte, and catalyst for electro-catalytic asymmetric carboxylation 设计一种环保的新型手性SHNFM-CuCl3 DES作为电催化不对称羧基化的溶剂、电解质和催化剂

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-25 DOI: 10.1016/j.jiec.2025.07.040

Hayder Ghanim Chfat , Mohammad Mahtab Alam , Talib H. Mawat , Rustamkhon Kuryazov , Shatha abd aljabbar Ismael , Hussein Ali Al-Bahrani , Abdullah Yahya Abdullah Alzahrani , Mohammed Muayad T.A , Elyor Berdimurodov , Jasur Tursunqulov , Qais R. Lahhob , Lala Gurbanova

{"title":"Design of an environmentally friendly new chiral SHNFM–CuCl3 DES as solvent, electrolyte, and catalyst for electro-catalytic asymmetric carboxylation","authors":"Hayder Ghanim Chfat , Mohammad Mahtab Alam , Talib H. Mawat , Rustamkhon Kuryazov , Shatha abd aljabbar Ismael , Hussein Ali Al-Bahrani , Abdullah Yahya Abdullah Alzahrani , Mohammed Muayad T.A , Elyor Berdimurodov , Jasur Tursunqulov , Qais R. Lahhob , Lala Gurbanova","doi":"10.1016/j.jiec.2025.07.040","DOIUrl":"10.1016/j.jiec.2025.07.040","url":null,"abstract":"<div><div>The increasing costs and environmental impact of raw materials, reagents, catalysts and solvents in organic syntheses have prompted the need for more sustainable and cost-effective approaches. In this study, we present the design and synthesis of a new multifunctional chiral SHNFM–CuCl<sub>3</sub> DES, which serves as a solvent, electrolyte, and chiral catalyst for electro-catalytic asymmetric carboxylation reactions. This electro-catalyst system was developed using inexpensive and readily available raw materials and is utilized in the presence of graphite rod electrodes. The DES system was thoroughly characterized using FT-IR, TGA, and 1HNMR, 13CNMR to confirm its structural integrity and composition. The electro-organic synthesis of (R)-1-formyl-2-oxo-3-phenylindoline-3-carboxylic acid derivatives <strong>3(a–i)</strong> was optimized under ambient temperature conditions, with a reaction time of 1.5 h and an applied current of 10 mA, resulting in high yields ranging from 89 % to 97 %. The final products were characterized and confirmed by FT-IR spectroscopy, measurement of optical rotation, 1HNMR spectroscopy, and elemental analysis (CHN). This work demonstrates the potential of using multifunctional DES as an efficient, environmentally friendly approach to electrochemical synthesis, reducing chemical consumption, lowering costs, and minimizing environmental impact, in line with the principles of green chemistry.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 748-761"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An efficient nanoplatelets-like CoNi2S4 captor for highly selective adsorption of gold ions from acidic aqueous solutions 一种高效的纳米片状CoNi2S4捕集剂，用于高选择性吸附酸性水溶液中的金离子

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-16 DOI: 10.1016/j.jiec.2025.07.035

George V. Belessiotis , Islam Ibrahim , Rabeea D. Abdel-Rahim , Mahmoud Thabet , Hassanien Gomaa

{"title":"An efficient nanoplatelets-like CoNi2S4 captor for highly selective adsorption of gold ions from acidic aqueous solutions","authors":"George V. Belessiotis , Islam Ibrahim , Rabeea D. Abdel-Rahim , Mahmoud Thabet , Hassanien Gomaa","doi":"10.1016/j.jiec.2025.07.035","DOIUrl":"10.1016/j.jiec.2025.07.035","url":null,"abstract":"<div><div>In this study, an efficient mesoporous nanoplatelet-like CoNi<sub>2</sub>S<sub>4</sub> adsorbent was successfully synthesized for selective trapping of gold (Au(III)) ions from acidic aqueous solutions. A comprehensive characterization of nanoplatelet-like CoNi<sub>2</sub>S<sub>4</sub> was conducted, encompassing its physicochemical properties, including textural and structural characteristics, morphology, and elemental composition. The performance of CoS, NiS, and CoNi<sub>2</sub>S<sub>4</sub> in Au(III) ion adsorption was assessed through a parametric study that considered various influencing factors, including pH, reaction time, captor dose, initial Au(III) concentration, and temperature. Among the materials tested, CoNi<sub>2</sub>S<sub>4</sub> proved to be the most effective adsorbent, exhibiting a maximum adsorption capacity of 247.38 mg/g and demonstrating high selectivity at pH 2 and room temperature. The employed isotherm models and thermodynamic investigations indicated an endothermic, single-layer Au(III)-CoNi<sub>2</sub>S<sub>4</sub> chemisorption interaction with thermodynamic favourability at higher temperatures. Selectivity and recycling findings highlighted the high gold-targeting capability of CoNi<sub>2</sub>S<sub>4</sub> in the presence of competitive ions, along with its preserved reusability for repeated Au(III) ion adsorption. Moreover, the study demonstrates that CoNi<sub>2</sub>S<sub>4</sub> exhibits superior Au(III) ion trapping performance at pH 2, with strong binding affinity, thermodynamic stability, and effective interactions, as confirmed by adsorption energy calculations, non-covalent interaction analysis, and zeta potential analysis.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 724-733"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in Polyphosphazene-Functionalized MXene composites 聚磷腈功能化MXene复合材料的研究进展

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-06-21 DOI: 10.1016/j.jiec.2025.06.039

Omar Dagdag , Ngoc Tuyet Anh Nguyen , Rajesh Haldhar , Hansang Kim

{"title":"Recent advances in Polyphosphazene-Functionalized MXene composites","authors":"Omar Dagdag , Ngoc Tuyet Anh Nguyen , Rajesh Haldhar , Hansang Kim","doi":"10.1016/j.jiec.2025.06.039","DOIUrl":"10.1016/j.jiec.2025.06.039","url":null,"abstract":"<div><div>MXenes—a class of two-dimensional transition-metal carbides and nitrides—have attracted considerable attention because of their high electrical conductivity, mechanical strength, and tunable surface chemistry. Functionalization with polyphosphazenes—a distinctive class of organic–inorganic hybrid polymers—has opened new avenues for enhancing the multifunctionality of MXene-based composites. This review provides a comprehensive overview of the recent advances in the synthesis of MXenes, covering fluorine-based, fluoride-free, and alternative preparation methods, along with a detailed discussion of their structural and chemical characterization. It examines their key physical properties, electrical performance, catalytic activity, mechanical strength, and energy-storage capabilities, along with their environmental stability, toxicity, and degradation mechanisms. This review also discusses various fabrication strategies for incorporating MXenes into polymer matrices, emphasizing polyphosphazene-based systems prepared using techniques such as <em>ex situ</em> blending, melt blending, and in situ polymerization. Additionally, emerging applications of polyphosphazene-functionalized MXene composites in flame retardancy, energy storage, and environmental remediation are explored. Finally, the current challenges, research gaps, and future directions for the development of next-generation MXene-based materials for sustainable and high-performance technological applications are highlighted.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 20-65"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design and synthesis an optical polymer sensor based on MIP-UiO66/Fe3O4 for detection of Cypermethrin insecticide in aqueous media: RSM (CCD) 基于MIP-UiO66/Fe3O4光学聚合物传感器的设计与合成：RSM （CCD）

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-06-19 DOI: 10.1016/j.jiec.2025.06.036

Fatemeh Abdi , Karim Akbari Dilmaghani , Reza Mohammadi , Negin sohrabi

{"title":"Design and synthesis an optical polymer sensor based on MIP-UiO66/Fe3O4 for detection of Cypermethrin insecticide in aqueous media: RSM (CCD)","authors":"Fatemeh Abdi , Karim Akbari Dilmaghani , Reza Mohammadi , Negin sohrabi","doi":"10.1016/j.jiec.2025.06.036","DOIUrl":"10.1016/j.jiec.2025.06.036","url":null,"abstract":"<div><div><span><span>The immoderate use of pesticides worldwide necessitates the development of rapid and reliable detection methods. Cypermethrin is a widely used pesticide in agriculture, but its residues persist in agricultural products, affecting their quality and safety. This study synthesized a new </span>molecularly imprinted polymer<span> (MIP) for the detection of Cypermethrin using Cypermethrin (as the template molecule), ethylene glycol dimethacrylate (as the crosslinker), </span></span>methacrylic acid<span><span><span> (as the monomer), and AIBN (as the initiator). In addition, the synthesis was carried out in the presence of graphene quantum dots<span> (GQDs), and therefore the synthesized polymer had fluorescent properties. These polymers were characterized using various techniques such as FE-SEM, EDX<span>, Mapping, FT-IR and XRD. </span></span></span>Response surface methodology (RSM) was used to optimize the trapping process of Cypermethrin insecticide by the polymer sensor. Based on the experimental results, the imprinting factor (IF) of this polymer was determined to be 2.58. Furthermore, this polymer exhibited excellent Cypermethrin adsorption capacity, achieving a removal percentage of 99.91 % under optimized conditions: a pH 6.4, a Cypermethrin concentration of 10.53 ppm, a polymer dosage of 1.04 g/L, and an initial contact time of 16 min. Cypermethrin detection was performed using </span>fluorescence spectroscopy<span><span> within a concentration range of 0.0001 to 30 ppm, sensitivity of 4.12 a.u/ppm and a detection limit<span> of 0.24 ppm. Furthermore, this polymer sensor exhibited excellent selectivity by IF equal to 2.58, demonstrating minimal interference from other pesticides such as </span></span>diazinon<span>, imidacloprid<span>, and abamectin, despite their structural similarities to Cypermethrin.</span></span></span></span></div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 165-177"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development and industrial-scale production of functional wool/polyester blended fabrics for sportswear: Anti-pilling and hydrophilic modifications 运动服用功能性毛/涤混纺面料的开发和工业规模生产：抗起球和亲水改性

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-06-22 DOI: 10.1016/j.jiec.2025.06.041

Siping Gong , Liujun Pei , Yi Wang , Xiaomin Gu , Kaixuan Zhang , Jiping Wang

{"title":"Development and industrial-scale production of functional wool/polyester blended fabrics for sportswear: Anti-pilling and hydrophilic modifications","authors":"Siping Gong , Liujun Pei , Yi Wang , Xiaomin Gu , Kaixuan Zhang , Jiping Wang","doi":"10.1016/j.jiec.2025.06.041","DOIUrl":"10.1016/j.jiec.2025.06.041","url":null,"abstract":"<div><div><span>Wool/polyester blended fabrics are extensively used in the textile industry due to their ability to combine the natural warmth, moisture absorption<span><span> and breathability of wool fibers with the wear-resistant and wrinkle-resistant properties of </span>polyester fibers<span>. However, the anti-pilling performance of wool/polyester blended fabrics is inferior to that of pure fabrics which significantly limits their application. In this investigation, wool/polyester blended fabrics were treated with five anti-pilling agents using dipping and pad-dry-cure methods. The anti-pilling grade of the fabrics was improved without changing the crystal structure and mechanical properties of the original wool blended fabrics. The anti-pilling, thermal, physio-mechanical, and colour properties of the treated fabrics were also evaluated. The results indicate that the auxiliary agents were successfully crosslinked into the blended fabrics. Treatment with these agents enhanced the fabric’s anti-pilling rating from grade 2 to grade 4, with the effect remaining stable after five washing cycles. Furthermore, the treated fabrics demonstrated improved anti-static and moisture-wicking properties, whereas maintaining their softness. A slight reduction in air permeability was observed, while the colour parameters and </span></span></span>colour fastness<span> of the dyed fabrics did not differ significantly. Therefore, water-based polyurethane agents possess promising potential for anti-pilling and moisture-wicking finishing of wool/polyester blended textiles.</span></div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 203-213"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nucleus targeting-functionalized cell-membrane nanovesicles for intranasal delivery of therapeutic plasmid DNA into the brain for the treatment of glioblastoma 核靶向功能化细胞膜纳米囊泡用于治疗性质粒DNA的鼻内递送到脑内治疗胶质母细胞瘤

IF 5.9 3区工程技术

Journal of Industrial and Engineering Chemistry Pub Date : 2026-02-25 Epub Date: 2025-07-15 DOI: 10.1016/j.jiec.2025.07.034

Jae Young Park , Mincheol Son , Chuanyu Zhuang , Unchang Choi , Kangmin Park , Sung Bin Ahn , Minji Kang , Jihun Oh , Chowon Lee , Joon Sig Choi , Minhyung Lee

{"title":"Nucleus targeting-functionalized cell-membrane nanovesicles for intranasal delivery of therapeutic plasmid DNA into the brain for the treatment of glioblastoma","authors":"Jae Young Park , Mincheol Son , Chuanyu Zhuang , Unchang Choi , Kangmin Park , Sung Bin Ahn , Minji Kang , Jihun Oh , Chowon Lee , Joon Sig Choi , Minhyung Lee","doi":"10.1016/j.jiec.2025.07.034","DOIUrl":"10.1016/j.jiec.2025.07.034","url":null,"abstract":"<div><div>In the gene delivery to the glioblastoma, intranasal delivery has been developed for delivery of drugs into the brain. However, nose-to-brain delivery of plasmid DNA (pDNA) has been unsuccessful, due to the large size of pDNA and low efficiency of nuclear translocation in the cells. In this study, a novel pDNA delivery system with enhanced nuclear translocation function was developed using a cell-membrane (CM)/dexamethasone-conjugated polyethylenimine (PD) hybrid nanovesicle. PD and CM from C6 glioblastoma cells were mixed at a 2:1 wt ratio to produce hybrid-nanovesicle. Addition of negatively charged pDNA to hybrid nanovesicles formed the spherical shaped complexes. Confocal microscopy study showed that the pDNA/PD/CM nanovesicle-complex entered the nuclei of cells efficiently, due to the nuclear translocation effect of the glucocorticoid receptor on binding to dexamethasone. In orthotopic glioblastoma rat models, the pSV-HSVtk/PD/CM nanovesicle-complex had higher delivery efficiency than naked pSV-HSVtk and pSV-HSVtk/PD complex into the brain. As a result, pSV-HSVtk/PD/CM had higher apoptosis and lower Ki67 level than the other groups. Tumor size was effectively reduced by pSV-HSVtk/PD/CM, compared with the other groups. The results suggest that pDNA/PD/CM nanovesicle-complex may be an efficient intranasal delivery carrier of pDNA and may be useful for the treatment of glioblastoma.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"154 ","pages":"Pages 712-723"},"PeriodicalIF":5.9,"publicationDate":"2026-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0