Journal of Industrial and Engineering Chemistry最新文献

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Recovery of volatile fatty acids from anaerobic fermentation broth of baker’s yeast industry effluent by liquid−liquid extraction 用液液萃取法回收面包酵母工业废水厌氧发酵液中的挥发性脂肪酸
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-07-05 DOI: 10.1016/j.jiec.2024.07.005
Ece Polat, Ayşegül Nalan Genç, Füsun Şeyma Güngör, Mahmut Altınbaş
{"title":"Recovery of volatile fatty acids from anaerobic fermentation broth of baker’s yeast industry effluent by liquid−liquid extraction","authors":"Ece Polat, Ayşegül Nalan Genç, Füsun Şeyma Güngör, Mahmut Altınbaş","doi":"10.1016/j.jiec.2024.07.005","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.07.005","url":null,"abstract":"As metabolic intermediates, volatile fatty acids (VFAs) can be recovered by separation and purification and contribute to the economy. It was necessary, however, to investigate the optimization of liquid–liquid extraction (LLE) in this study because of the technical difficulties encountered during the recovery of VFAs. For this reason, the organic solvents diethyl ether, trioctylamine, and toluene were investigated as LLE solvents to extract VFAs from Baker’s yeast industry effluent, which contains high levels of organic matter. An optimal pH value of 3 was determined by a pH scan performed between pH 2.5 and pH 7.5. Principal component analysis (PCA) was used to determine the effects of organic solvents and pH on extraction efficiency. The extraction efficiency was evaluated using the optimal pH and multi-stage extraction experiments. In a three-stage extraction, diethyl ether recovered 82% of the VFAs, making it a promising organic solvent for extracting VFAs from anaerobic fermentation broth. PCA revealed that an opposite correlation between VFA recovery and pH for each organic solvent. Based on the results of the cost analysis, it was determined that the costs of recovering VFAs were reduced by 90% per kilogram.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"3 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141568903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-induced PMS activation for ofloxacin degradation from pharmaceuticals wastewater: DFT calculation, mechanisms and toxicity evolution 超声波诱导 PMS 激活制药废水中氧氟沙星的降解:DFT 计算、机理和毒性演变
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-07-02 DOI: 10.1016/j.jiec.2024.06.046
Arvind Kumar, Radha Devi Pyarasani, Abdul Gaffar Sheik, Basheswer Prasad, Sheena Kumari, Faizal Bux
{"title":"Ultrasound-induced PMS activation for ofloxacin degradation from pharmaceuticals wastewater: DFT calculation, mechanisms and toxicity evolution","authors":"Arvind Kumar, Radha Devi Pyarasani, Abdul Gaffar Sheik, Basheswer Prasad, Sheena Kumari, Faizal Bux","doi":"10.1016/j.jiec.2024.06.046","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.046","url":null,"abstract":"The degradation of persistent and refractory pollutants particularly antibiotics from drugs and pharmaceuticals wastewater remains challenging due to their high toxicity. Herein, a hybrid system CuFeZnO − layer double oxide (LDO)/PMS/US designed for the degradation of ofloxacin (OFC) and total organic carbon (TOC) from drugs and pharmaceuticals wastewater. Catalyst 0.4CFZ-LDO exhibited a remarkable catalytic activity for OFC (98.76 %, 0.0703 min) and TOC (76.97 %, 0.0259 min) removal, with synergistic index value (OFC, 3.45) and (TOC, 1.69) under the optimum conditions. The quenching experimental study reveals that sulfate radical (SO) was dominant reactive oxygen species (ROS) for OFC and TOC removal. Density functional theory (DFT) demonstrates that strong attacking sites on the OFC structure were C14, C15 and C23 due to high concentration of Fukui index. Based on the as quantitative structure–activity relationship (QSAR) prediction model system 0.4CFZ-LDO/PMS/US potentially reduced the bio-toxicity (acute toxicity, mutagenicity, bioaccumulation factor) after treatment. Furthermore, catalyst 0.4CFZ-LDO demonstrated remarkable stability with minor leaching of metal ions. Critical contribution of Fe/Fe and Cu/Cu surface catalyzed-redox cycle was evaluated with the help of X-ray photoelectron spectroscopy (XPS) analysis. Furthermore, six potential routes of OFC degradation were proposed based on the DFT study, and intermediates were identified by GC–MS analysis. Based on the electrical energy per order (EEO) analysis, economic cost of pharmaceutical wastewater was estimated to be $0.059/L.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"33 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical analysis of production of C2 olefins from methane in Partially Decoupled process 部分解耦工艺中甲烷生产 C2 烯烃的数值分析
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-07-02 DOI: 10.1016/j.jiec.2024.07.002
Maliheh Saravani Ghayour, Seyed Reza Shabanian
{"title":"Numerical analysis of production of C2 olefins from methane in Partially Decoupled process","authors":"Maliheh Saravani Ghayour, Seyed Reza Shabanian","doi":"10.1016/j.jiec.2024.07.002","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.07.002","url":null,"abstract":"Ethylene (CH) and acetylene (CH) are crucial materials in the petrochemical industry, obtained through various processes utilizing natural gas and other hydrocarbon fuels. In this research, the Partially Decoupled Process (PDP) has been investigated through Computational Fluid Dynamics (CFD) simulation to analyze the effects of different parameters on the production of acetylene and ethylene. The evaluated parameters included the mass flow rate ratio, fuel preheating temperature, the addition of ethane and propane to the fuel, the addition of H, CO, and HO to the inlet feed and, reducing the jet inlet diameter. The results showed that an increase in the mass flow rate leads to an increase in the mole fraction of C (CH + CH) in the reactor outlet. Furthermore, the substitution of 30 % methane with a combination of 20 % ethane and 10 % propane has resulted in a 6 % increase in the mole fraction of CH, a 43 % reduction in the mole fraction of CH, and a 5.6 % increase in the mole fraction of H at the outlet of the reactor. It was also observed that by decreasing the diameter of the side tubes from 43.3 mm to 20 mm, methane conversion decreases by 1.14 %, and C yield decreases by 46.8 %.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"12 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of tetracycline photocatalytic degradation under visible light: Unleashing the synergy of Z-scheme Ag3PO4/GCN/FeNi-BTC photocatalyst with carbon quantum dots 增强可见光下的四环素光催化降解:释放 Z 型 Ag3PO4/GCN/FeNi-BTC 光催化剂与碳量子点的协同作用
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-07-02 DOI: 10.1016/j.jiec.2024.07.001
Manh B. Nguyen, Huan V. Doan, Doan Le Hoang Tan, Tran Dai Lam
{"title":"Enhancement of tetracycline photocatalytic degradation under visible light: Unleashing the synergy of Z-scheme Ag3PO4/GCN/FeNi-BTC photocatalyst with carbon quantum dots","authors":"Manh B. Nguyen, Huan V. Doan, Doan Le Hoang Tan, Tran Dai Lam","doi":"10.1016/j.jiec.2024.07.001","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.07.001","url":null,"abstract":"This study presents a novel photocatalytic composite, AgPO/GCN/FeNi-BTC/CQD (AGF-CQD), synthesized via a green microwave-assisted hydrothermal method, integrating carbon quantum dots (CQDs) derived from aquaculture by-products. The AGF-CQD composite demonstrates superior photocatalytic activity, attributed to enhanced visible light absorption, efficient charge transfer, and improved electron-hole separation. Analytical techniques such as photoluminescence (PL), UV–Vis diffuse reflectance spectroscopy (DRS), and transmission electron microscopy (TEM) validate the composite’s structural and optical properties. In tetracycline degradation tests, AGF-CQD outperforms AgPO, GCN, FeNi-BTC, and 20 % AGF samples by 5.5, 3.6, 4.4, and 2.3 times, respectively, achieving a remarkable 98.4 % removal rate after 60 min under visible light. Factors affecting degradation, including dosage, concentration, pH, and water source, are investigated. Furthermore, an operating mechanism based on electrochemical properties and the involvement of radicals is proposed. This research offers a sustainable approach to synthesizing efficient photocatalysts for environmental remediation.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"22 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced the electrochemical performance of Ni-doped α-MnO2 prepared with one-pot process for supercapacitors 提高一锅法制备的掺镍 α-MnO2 在超级电容器中的电化学性能
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-30 DOI: 10.1016/j.jiec.2024.06.041
Bengang Tan, Nali Chen, Lizhi Huang, Xin Gao, Lin Tan, Huixia Feng
{"title":"Enhanced the electrochemical performance of Ni-doped α-MnO2 prepared with one-pot process for supercapacitors","authors":"Bengang Tan, Nali Chen, Lizhi Huang, Xin Gao, Lin Tan, Huixia Feng","doi":"10.1016/j.jiec.2024.06.041","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.041","url":null,"abstract":"Poor capacitive behavior caused by low electronic conductivity and slow reaction kinetics is the main obstacle faced by the MnO electrode materials in current supercapacitors. Herein, the influence of Ni doping on the capacitive behavior of α-MnO synthesized by a low-cost and one-pot chemical coprecipitation method was investigated. During the doping process, the amount of Ni was increased from 0.05 mmol to 0.45 mmol in steps of 0.1 mmol. The structure and chemical composition of Ni-doped MnO (MnO-Ni) were characterized by XRD, FTIR, SEM, EDS, and XPS. Comprehensive studies show that no change in the crystal phase structure of MnO, while the decrease in the nanoparticle size and the increase in electronic conductivity by Ni doping, which improve the capacitive behavior of α-MnO. With specific capacitance values increasing with increasing amounts of Ni up to a certain limit 0.25 mmol, the specific capacitance of 325.8 F/g was given by MnO-Ni electrode at a current density of 0.5 A/g, which was nearly 1.72 times that of MnO electrode of 189.47 F/g. Moreover, the MnO-Ni electrode showed excellent capacitance retention (112%) than the MnO electrode (109.5%) after 3000 cycles.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"41 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Antibacterial properties of reduced graphene oxide fibers fabricated by hydrothermal method 水热法制备的还原氧化石墨烯纤维的抗菌性能
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-28 DOI: 10.1016/j.jiec.2024.06.038
Lili Wang, Wei Mu, Yufeng Liu, Xin Wang, Xianliang Zheng
{"title":"Antibacterial properties of reduced graphene oxide fibers fabricated by hydrothermal method","authors":"Lili Wang, Wei Mu, Yufeng Liu, Xin Wang, Xianliang Zheng","doi":"10.1016/j.jiec.2024.06.038","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.038","url":null,"abstract":"The antibacterial activity of reduced graphene oxide fibers (rGOFs) fabricated by a one-step dimensionally confined hydrothermal technique was investigated on both Gram-positive and Gram-negative models of bacteria in this study. The surface morphology, microstructure, and chemical composition of the as-prepared rGOFs were determined using scanning electron microscopy (SEM), X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. SEM images showed the fiber to have an average diameter of 46.6 ± 0.53 μm, composed of rGO nanosheets with numerous sharp edges. XPS and Raman spectroscopy confirmed the presence of -bonded carbon and structural defects in the samples. Antibacterial properties of rGOFs were tested and analyzed using agar well diffusion, colony counting method, SEM observation, and reactive oxygen species generation. The excellent broad-spectrum antibacterial ability of rGOFs is attributed to the physicochemical properties and unique surface morphological features of the samples, which could facilitate the development of rGOFs-based biomaterial for various biomedical and nano-technological applications such as a promising antibacterial agent or an implant/scaffold for nerve tissue engineering and regeneration.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"6 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In vivo self-assembly of an intact functional cage protein: Intracellular generation of chimeric ferritins without disassembly-involved damage 在体内自组装完整的功能笼蛋白:在细胞内生成嵌合铁蛋白而不会造成分解损伤
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-28 DOI: 10.1016/j.jiec.2024.06.040
Koung Hee Kim, Mi-Ran Ki, Thi Khoa My Nguyen, Ki Ha Min, Seung Pil Pack
{"title":"In vivo self-assembly of an intact functional cage protein: Intracellular generation of chimeric ferritins without disassembly-involved damage","authors":"Koung Hee Kim, Mi-Ran Ki, Thi Khoa My Nguyen, Ki Ha Min, Seung Pil Pack","doi":"10.1016/j.jiec.2024.06.040","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.040","url":null,"abstract":"Ferritin (Fn) is an attractive nano-biomaterial with a hollow structure. Functional chimeric cage-protein Fns (chimera-Fn) can be designed by combining two different monomer subunits. However, unavoidable damage is induced by the severe disassembly conditions required for preparing the Fn monomer. Here, a biocompatible method using a designed dual-expression vector to obtain chimera-Fns without a damage-inducing process is described. Fn monomer and silica-forming peptide (Kpt)-fused Fn monomer are expressed simultaneously and assembled within host-cells to form chimera-Fn of Kpt. Characteristic analysis showed that the chimera-Fns obtained intracellularly were composed of the two monomers in a ratio of 1:1. Morphological and functional analyses determined that the intracellularly-generated chimera-Fns had more intact forms and bioactive functions compared with those produced by chemical-involved disassembly and reassembly. This is the first report about the self-assembly of chimera-Fn with intact function and hold promise in designing functional templates for various nanomaterial preparations.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"69 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the swelling behavior of κ-carrageenan hydrogels: Influence of composition and physiological environment on drug delivery potential 揭示κ-卡拉胶水凝胶的溶胀行为:成分和生理环境对药物输送潜力的影响
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-28 DOI: 10.1016/j.jiec.2024.06.032
Emad Mozaffari, Bahareh Tanhaei, Maryam Khajenoori, Saeedeh Movaghar Khoshkho
{"title":"Unveiling the swelling behavior of κ-carrageenan hydrogels: Influence of composition and physiological environment on drug delivery potential","authors":"Emad Mozaffari, Bahareh Tanhaei, Maryam Khajenoori, Saeedeh Movaghar Khoshkho","doi":"10.1016/j.jiec.2024.06.032","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.032","url":null,"abstract":"This study aims to develop a biodegradable hydrogel wound dressing film based on carrageenan and agar loaded with tetracycline (TC), which exhibits high antibacterial properties and accelerates wound healing. The swelling behavior of κ-carrageenan/agar and tetracycline-loaded hydrogel films was examined, with a focus on the hydrogel’s efficacy in various physiological fluids, as well as the effects of polysaccharide ratio, cross-linker concentration, and surfactant concentration. The results revealed that the polysaccharide ratio significantly influenced the hydrogel swelling capacity of hydrogel, and a 1:1 ratio of agar to κ-carrageenan achieved the highest swelling degree of 1386 %. Addition of KCl, as a cross-linker, increased swelling capacity to 1713 %. Furthermore, surfactant concentration also influenced swelling behavior, and higher concentrations resulted in an increase in hydrophilicity and swelling. Hydrogel swelling performance varied across physiological fluids, with the highest and lowest swellings observed in deionized water (DIW) and simulated wound fluid (SWF), respectively. The swelling process in DIW and phosphate buffered saline (PBS) exhibited second-order kinetics, whereas non-Fickian diffusion mechanisms were observed in SWF. The drug release of the κC/AG/TC hydrogel film was controlled by its swelling capacity and the pH of medium. The hydrogels’ mechanical properties, antibacterial activity, and water vapor permeability were also investigated.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"2015 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption and separation of lead ions in phosphoric acid by co-doped carbon nanotubes with sulfur, oxygen, and manganese 硫、氧和锰共掺杂碳纳米管对磷酸中铅离子的吸附和分离
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-28 DOI: 10.1016/j.jiec.2024.06.029
Gang Cheng, Xin Zhou, Chongyu Du, Guotao Hu, Qian Lin, Hongyan Pan
{"title":"Adsorption and separation of lead ions in phosphoric acid by co-doped carbon nanotubes with sulfur, oxygen, and manganese","authors":"Gang Cheng, Xin Zhou, Chongyu Du, Guotao Hu, Qian Lin, Hongyan Pan","doi":"10.1016/j.jiec.2024.06.029","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.029","url":null,"abstract":"The purpose of this study was to prepare a novel and efficient adsorbent for the removal of trace Pb(II) from phosphoric acid. Manganese oxide/sulfur-oxygen doped carbon nanotube composites (CNTs-S-O-Mn) were prepared from multi-walled carbon nanotubes modified with nitric acid, mercaptoacetic acid, acetic anhydride, concentrated sulfuric acid and potassium permanganate. Characterisation revealed that CNTs-S-O-Mn contained hydroxyl, sulphonate groups, MnO and MnO. At 298 K, 15.362 mg·L initial concentration of lead ions, and 18.4 % phosphoric acid concentration, the adsorption capacity of the composites for lead ions was 38.65 mg·g, which was higher than that of the unmodified CNTs, 8.04 mg·g. The adsorption kinetic data at 298 K conformed to the quasi-second-order kinetic equation, R = 0.997; 298, adsorption isotherms at 308 and 318 K conformed to the Langmuir equation, R = 0.990–––0.991. The adsorption capacity increased with decreasing phosphoric acid concentration. In this system, the adsorption is affected by a certain concentration of lead ions. Adsorption occurs via chemisorption and is exothermic. Sulfonic acid groups and hydroxyl groups on manganese oxides play an important role in the adsorption of Pb (II) through surface complexation with Pb (II). These results indicate that the removal of trace Pb (II) from phosphoric acid by modified carbon nanotubes is feasible, revealing a new use of carbon nanotubes for phosphoric acid purification.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"17 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Basil seed hydrogel incorporated activated carbon as a Capable, Bio-Based, and Cost-Effective interfacial solar steam generator 含有活性炭的罗勒种子水凝胶是一种具有能力、生物基础和成本效益的界面太阳能蒸汽发生器
IF 6.1 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2024-06-28 DOI: 10.1016/j.jiec.2024.06.037
Mahtab Farahpour, Saeid Azizian
{"title":"Basil seed hydrogel incorporated activated carbon as a Capable, Bio-Based, and Cost-Effective interfacial solar steam generator","authors":"Mahtab Farahpour, Saeid Azizian","doi":"10.1016/j.jiec.2024.06.037","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.037","url":null,"abstract":"Utilization of solar energy for desalination and purification of seawater opens up a state-of-the-art way to meet the water needs all around the world specially in coastal cities. Herein, the eco-friendly, low cost and bio-based basil seed (BS) hydrogel is combined with activated carbon (AC) to synthesize activated carbon merged with basil seed hydrogel (AC-BS) composite material. Due to the photothermal property of the AC, the AC-BS composite was used to design an interfacial solar steam generator (ISSG) for water purification. The AC absorbs the sunlight and converts it to the required heat needed for water evaporation and the superhydrophilic BS hydrogel supplies water to the surface causing the high salt rejection ability of the system, in addition, it decreases the required energy for evaporation. The AC-BS is characterized using characterization methods such as EDX and FESEM. The two-dimensional (2D) AC-BS system containing a cotton fiber used to transfer water from the bulk to the surface, a layer of styrofoam as a heat insulator and AC-BS on the surface shows evaporation rate of 1.93 kg mh. The three-dimensional (3D) AC-BS, designed to solve the solar irradiation angle fluctuation problem during a day and seasons, shows an evaporation rate of 2.70 kg mh and an efficiency of about 91 % under 1 sun illumination. The ability of the AC-BS system for saline water desalination and waste water-contaminated dyes as a pollutant treatment is highly acceptable. The AC-BS ISSG can be studied and used on large scales to provide fresh water from saline water.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"10 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141569153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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