Journal of Industrial and Engineering Chemistry最新文献

{"title":"CO2-adsorption and kinetic studies of zeolites synthesized from halloysite","authors":"D. Ballesteros-Plata,S. Essih,A. Infantes-Molina,F. Franco,E. Vilarrasa-García,E. Rodríguez-Castellón,J.A. Cecilia","doi":"10.1016/j.jiec.2026.09.004","DOIUrl":"https://doi.org/10.1016/j.jiec.2026.09.004","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"11 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148896010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pore-Regulation strategy of AlFum mediated by polyethyleneimine for CO2 capture","authors":"Wenzheng Hou,Duoyong Zhang,Jiarui Ji,Xinnan Cui,Huashan Bao,Chen Zhang,Liwei Wang","doi":"10.1016/j.jiec.2026.08.050","DOIUrl":"https://doi.org/10.1016/j.jiec.2026.08.050","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"1 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148895076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanism-guided functionalization of graphene oxide–based adsorbents for the removal of heavy metal ions from water: A review","authors":"Yibei Fan,Shengchi Feng,Yongrui Zhang,Peng Chee Tan","doi":"10.1016/j.jiec.2026.08.040","DOIUrl":"https://doi.org/10.1016/j.jiec.2026.08.040","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"8 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148895078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recover high-purity FePO4 synchronously during the lithium extraction from mixed spent lithium iron phosphate powder","authors":"Xiaolong Dai, Tiangui Qi, Xiaobin Li, Zhihong Peng, Guihua Liu, Qiusheng Zhou, Yilin Wang, Leiting Shen, Jian Guo","doi":"10.1016/j.jiec.2026.08.010","DOIUrl":"https://doi.org/10.1016/j.jiec.2026.08.010","url":null,"abstract":"Conventional lithium extraction methods from spent lithium iron phosphate (LFP) battery generate substantial quantities of intractable residues enriched with iron and phosphorus. This study proposed a novel two-stage method for the simultaneous recovery of lithium, iron, and phosphorus from mixed spent LFP powder. In the first stage, the powder was reacted with nitric acid solution at 25℃, achieving leaching efficiencies of over 95% for lithium, iron, and phosphorus. The leachate was then regulated and fed into the second stage, a high-temperature (105°C) precipitation process, where iron and phosphorus in the solution are selectively precipitated as FePO<ce:inf loc=\"post\">4</ce:inf>·2H<ce:inf loc=\"post\">2</ce:inf>O. After calcination, the precipitate yielded anhydrous FePO<ce:inf loc=\"post\">4</ce:inf> product. It was proposed to supplement the leachate with fluoride to complex aluminum and reduce its co-precipitation. Copper in the leachate was removed by displacement with iron powder. The aluminum and copper contents in the final FePO<ce:inf loc=\"post\">4</ce:inf> product were reduced to 0.021% and 0.001%, respectively, and the product purity meets the requirements for battery production. The lithium-containing solution after the precipitation process could be recycled as Li<ce:inf loc=\"post\">2</ce:inf>CO<ce:inf loc=\"post\">3</ce:inf> through purification and lithium precipitation. The proposed method improves resource utilization efficiency and reduces the generation of lithium-extracted residues, which will benefit the sustainable development of the LFP battery industry.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"8 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2026-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148717585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coal gangue modified biochar for adsorption and degradation of carbamazepine and ibuprofen from wastewater: Mechanisms and ecological risk assessment","authors":"Tao Jiang, Bing Wang, Xueyang Zhang, Masud Hassan","doi":"10.1016/j.jiec.2026.07.008","DOIUrl":"https://doi.org/10.1016/j.jiec.2026.07.008","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"2020 1","pages":""},"PeriodicalIF":6.1,"publicationDate":"2026-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148460904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Water-stable halide perovskite nanocomposite with dual S-scheme for enhanced photocatalysis","authors":"Walaa Omer ,&nbsp;Hamza El-Hosainy ,&nbsp;Haitham M. El-Bery ,&nbsp;Maged El-Kemary","doi":"10.1016/j.jiec.2025.07.051","DOIUrl":"10.1016/j.jiec.2025.07.051","url":null,"abstract":"<div><div>Lead-free halide perovskites, particularly Cs₂AgBiBr₆, have gained attention as promising photocatalysts due to their excellent light absorption and tunable photo-responsive properties. However, their practical application is hindered by poor stability in aqueous media and reduced efficiency in high-water environments, where Cs₂AgBiBr₆ undergoes self-passivation by forming BiOBr, significantly decreasing its photocatalytic activity when water content exceeds 50 vol%. To overcome these limitations, we in situ coupled Cs₂AgBiBr₆ nanoplatelets (NPLs) with g-C₃N₄, forming a stable Cs₂AgBiBr₆ NPLs@g-C₃N₄@AgBr ternary composite in water (100 vol%). This nanocomposite demonstrated remarkable stability in water through the formation of AgBr rather than BioBr, as confirmed by various spectroscopic and diffraction techniques. The optimized 1:2 wt% ratio of Cs₂AgBiBr₆ to g-C₃N₄ leads to the highest degradation rate of Rhodamine B (RhB) of 0.082 min ^-1 which was 14 times greater than Cs₂AgBiBr₆ NPLs, g-C₃N₄, or AgBr alone, surpassing all previously reported Cs₂AgBiBr₆-based nanocomposites in both efficiency and stability. Furthermore, the scavenging action of RhB led by the heterojunction photocatalyst resulted in the elimination of 98.3 % of RhB under light. The superior photocatalytic activity of the Cs₂AgBiBr₆ NPLs@g-C₃N₄@AgBr ternary composite in aqueous media was confirmed through detailed characterization, which revealed that the formation of a dual S-scheme mechanism significantly enhances interfacial charge separation and transfer, resulting in elevated photocurrent, pronounced photoluminescence quenching, and minimized charge transfer resistance. In addition, this ternary composite exhibited robust environmental stability, preserving its crystallinity and morphology after 6 months of air exposure, while maintaining consistent photocatalytic performance across 4 successive cycles in aqueous conditions. Thus, the present results introduce a novel strategy for stabilizing halide perovskites in high water content, expanding their potential for photocatalytic applications in environmental remediation and sustainable energy solutions.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 407-419"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic integration of nickel oxide and low-valent copper for enhanced electrocatalytic nitrate reduction to ammonia","authors":"Fengjiao Quan ,&nbsp;Pengfei Xu ,&nbsp;Xiufan Liu ,&nbsp;Wenjuan Shen ,&nbsp;Yuhao Li ,&nbsp;Jianfen Li ,&nbsp;Yun He ,&nbsp;Fangyuan Chen","doi":"10.1016/j.jiec.2025.07.049","DOIUrl":"10.1016/j.jiec.2025.07.049","url":null,"abstract":"<div><div>Nitrate (NO₃⁻) pollution in groundwater has emerged as a pressing environmental issue of global concern. The excessive application of chemical fertilizers is widely recognized as the primary contributor to this pollution Nitrate ions pose significant risks to human health and the ecological environment. Electrochemical reduction of NO₃⁻ to NH₃ (NITRR) represents an effective approach for nitrogen recovery and recycling. Among many electrode materials, copper-based catalysts were considered promising due to their low cost and strong NO₃⁻ conversion capability. However, excessively strong adsorption can lead to catalyst deactivation, thereby diminishing catalytic activity. In this study, we developed an electrode material (Cu@NiO/NF) with low-valent copper (Cu^δ+) through the combination of Cu and NiO, and it exhibited excellent catalytic performance in the NITRR process. At − 0.45 V vs. RHE, this catalyst achieved a Faraday efficiency of 95.7 % and an ammonia yield of 0.85 mg h⁻¹ cm⁻². Further experiments and theoretical calculations demonstrate that the presence of NiO in Cu@NiO/NF stabilizes Cu^δ+, thereby enhancing the charge transfer rate and promoting the formation of hydrogen radicals (H•). This work has pioneered a new avenue for the development of efficient and innovative NTIRR materials.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 387-395"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Heterogeneous biochar-based catalytic advanced oxidation of emerging contaminants: Detailed synergy and radical generation mechanism","authors":"Ragavan Chandrasekar,&nbsp;Jyoti Prakash Ray,&nbsp;Pavithra Prakash,&nbsp;Jeevanantham Sathasivam,&nbsp;Jothika Jeyabalan,&nbsp;Selvaraju Narayanasamy","doi":"10.1016/j.jiec.2025.07.045","DOIUrl":"10.1016/j.jiec.2025.07.045","url":null,"abstract":"<div><div>Conventional heterogeneous catalysts utilized for the advanced oxidation of emerging contaminants often suffer from limitations such as agglomeration, surface passivation, wide bandgap, and low surface area, which hinder their practical applicability. Engineered biochar presents a cost-effective alternative, offering tunable physicochemical properties like sp²-hybridized graphitic structure, structural defects, high specific surface area, and surface-bound persistent free radicals that can address the challenges faced by commonly used heterogeneous catalysts. Rational design of biochar-based catalysts requires understanding the physicochemical properties of biochar contributing to synergy between the biochar and conventional metal-based catalysts. Despite the advancements in biochar research, the synergistic role of engineered biochar-based catalysts in catalytic advanced oxidation processes (CAOPs) remains unclear. This review meticulously examines the interfacial synergy of engineered biochar with conventional catalysts used in non-energy-assisted CAOPs and energy-assisted CAOPs. A wide range of oxidant activation systems involving peroxymonosulfate, persulfate, ozone, hydrogen peroxide, peracetic acid, percarbonate, and periodate are discussed along with sonocatalysis and photocatalysis. Additionally, radical formation mechanisms are discussed in detail, highlighting how molecular and interfacial properties of biochar aid in enhanced radical generation, providing insights into the rational design of biochar-based catalysts for efficient emerging contaminant degradation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 27-51"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reconstruction of electric double layer via sodium persulfate additive for enhanced aluminium-air battery","authors":"Lei Guo ,&nbsp;Ankang Su ,&nbsp;Viswanathan S. Saji ,&nbsp;Yan Tan ,&nbsp;Peiyi Zhao ,&nbsp;Amir Mahmoud Makin Adam","doi":"10.1016/j.jiec.2025.08.027","DOIUrl":"10.1016/j.jiec.2025.08.027","url":null,"abstract":"<div><div>The use of aluminium (Al) in Al-air batteries (AABs) is promising owing to its lightweight characteristics, accessibility, affordability, and high safety features. However, AABs’ main challenge lies in effectively suppressing hydrogen evolution on the anode in the alkaline electrolyte. Herein, we have used sodium persulfate (Na₂S₂O₈) as an electrolyte additive to construct a unique water barrier film, regulating the electrical double layer structure at the anode surfac to inhibit hydrogen precipitation effectively. Theoretical and experimental studies provide compelling proof for the role of Na₂S₂O₈ in inhibiting the self-corrosion of Al by establishing a thin shielding layer, efficiently regulating the hydrogen evolution kinetics, and improving battery performance. Compared to the pristine 4 M NaOH electrolyte, anode utilization of the Na₂S₂O₈-added electrolyte increased from 42.5 % to 75.5 %, capacity density improved from 1266.1 to 2247.8 mAh g⁻¹, and energy density rose from 1428.2 to 2567 Wh kg⁻¹. The significant outcome of this work could provide more insights into the development of efficient electrolytes for AABs.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 842-851"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancing O2/N2 separation with thin film coatings on hollow fiber membranes: A review","authors":"Oğuz Orhun Teber ,&nbsp;Anil Kuban ,&nbsp;Vahid Vatanpour ,&nbsp;Ismail Koyuncu","doi":"10.1016/j.jiec.2025.07.064","DOIUrl":"10.1016/j.jiec.2025.07.064","url":null,"abstract":"<div><div>There is an ever-increasing need for separation technologies to efficiently use oxygen and nitrogen from air, driven by advancements in industrial applications such as petrochemistry, electronics, agriculture and aviation. Membrane-based air separation is one of the fastest growing technologies due to its unique advantages in terms of compactness, cost and energy effectiveness. However, this technology, which is mature with existing polymeric hollow fiber membrane materials, has obstacles to the industrial scale application of new generation high permeance polymers. Existing gas separation membranes need to be further improved in terms of permeability and selectivity to expand the market share and compete with traditional separation technologies. This article provides a comprehensive overview of air separation regarding the elimination of existing obstacles. Then, thin film coating strategies and materials followed in the fabrication and structural development of hollow fiber membranes for air separation are discussed. Polymeric properties affecting oxygen and nitrogen in air separation are investigated. Finally, the role of composite materials in oxygen transport in thin film coatings and elimination of existing obstacles and future research directions are evaluated. Consequently, this review aims to serve as a compilation for advancing membrane technology towards more sustainable and efficient air separation solutions.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 164-180"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}