Journal of Industrial and Engineering Chemistry最新文献

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Highly sensitive SnO2/Co3O4 nanocomposite materials for H2S gas sensor application 用于H2S气体传感器的高灵敏度SnO2/Co3O4纳米复合材料
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-10 DOI: 10.1016/j.jiec.2025.08.020
Amensisa Negasa Begi , Shahid Hussain , Min Liu , Jesse Nii Okai Amu-Darko , Dyana Aziz Bayz , Mohammed Mujahid Alam , Mohamed Hussien , Rajesh Kumar Manavalan , Guanjun Qiao , Guiwu Liu
{"title":"Highly sensitive SnO2/Co3O4 nanocomposite materials for H2S gas sensor application","authors":"Amensisa Negasa Begi ,&nbsp;Shahid Hussain ,&nbsp;Min Liu ,&nbsp;Jesse Nii Okai Amu-Darko ,&nbsp;Dyana Aziz Bayz ,&nbsp;Mohammed Mujahid Alam ,&nbsp;Mohamed Hussien ,&nbsp;Rajesh Kumar Manavalan ,&nbsp;Guanjun Qiao ,&nbsp;Guiwu Liu","doi":"10.1016/j.jiec.2025.08.020","DOIUrl":"10.1016/j.jiec.2025.08.020","url":null,"abstract":"<div><div>The development of practical and adaptable hydrogen sulfide (H<sub>2</sub>S) detection equipment for air quality monitoring remains challenging. Owing to their remarkable electronic band alignment and excellent features, p-n heterojunction-based sensing technology has attracted significant interest in H<sub>2</sub>S gas sensors. In this study, n-type tin oxide/p-type cobalt oxide (n-SnO<sub>2</sub>/p-Co<sub>3</sub>O<sub>4</sub>) heterojunctions were fabricated using a metal precursor solution, followed by a straightforward hydrothermal method using pure Co<sub>3</sub>O<sub>4</sub> and molar ratios of SnO<sub>2</sub>/Co<sub>3</sub>O<sub>4</sub> = 0.18, SnO<sub>2</sub>/Co<sub>3</sub>O<sub>4</sub> = 0.35, and SnO<sub>2</sub>/Co<sub>3</sub>O<sub>4</sub> = 0.55. The synthesized samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HR-TEM), Brunauer–Emmett–Teller (BET) analysis, and X-ray photoelectron spectroscopy (XPS) to evaluate their structural, morphological, and chemical properties, and surface areas. The nanocomposite sensor with a SnO<sub>2</sub>/Co<sub>3</sub>O<sub>4</sub> molar ratio of 0.35 demonstrated a response of 791.0–100 ppm of H<sub>2</sub>S at a working temperature of 250 °C, with fast response and recovery times of 60 and 94 s, respectively. The SnO<sub>2</sub>/Co<sub>3</sub>O<sub>4</sub> nanocomposite enhanced the gas sensor sensitivity for detecting H<sub>2</sub>S to a level as low as 1 ppm. The p-n junction, particle size, grain boundaries, active sites, and large surface area make it suitable for gas sensing.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 723-734"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exfoliated LDH nanosheets for membrane-based wastewater treatment: surface engineering and performance 用于膜基废水处理的去角质LDH纳米片:表面工程和性能
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-07-28 DOI: 10.1016/j.jiec.2025.07.057
Muhammad ’Adli Nor Azman , Pei Sean Goh , Yi Lin , Ahmad Fauzi Ismail , Khairulnadzmi Jamaluddin , Norafiqah Ismail , Nur Diyana Suzaimi , Adam Haziq Mohamad Fahmi
{"title":"Exfoliated LDH nanosheets for membrane-based wastewater treatment: surface engineering and performance","authors":"Muhammad ’Adli Nor Azman ,&nbsp;Pei Sean Goh ,&nbsp;Yi Lin ,&nbsp;Ahmad Fauzi Ismail ,&nbsp;Khairulnadzmi Jamaluddin ,&nbsp;Norafiqah Ismail ,&nbsp;Nur Diyana Suzaimi ,&nbsp;Adam Haziq Mohamad Fahmi","doi":"10.1016/j.jiec.2025.07.057","DOIUrl":"10.1016/j.jiec.2025.07.057","url":null,"abstract":"<div><div>Exfoliated layered double hydroxide (LDH) nanosheets are increasingly recognized as surface-active nanomaterials capable of enhancing membrane-based wastewater treatment. Owing to their large surface area, tunable surface charge, and strong interfacial affinity, LDH-integrated membranes exhibit improved ion permeability, selectivity, and greater resistance to fouling. This review examines nanoscale exfoliation and the characteristics of LDH surfaces on membrane interactions and performance are examined in thin-film nanocomposites (TFNs), mixed matrix membranes (MMMs) and supported LDH membranes. Exfoliation techniques—chemical, mechanical, thermal and electrochemical—are compared concerning their effects on nanosheet morphology, dispersion stability, and surface charge. Particular attention is given to radiation-assisted exfoliation, which offers a scalable, environmentally benign route for producing well-dispersed LDH suspensions. Furthermore, interfacial strategies such as polymeric coatings and layer-by-layer (LbL) assembly are discussed for their role in minimizing nanosheet aggregation and improving compatibility with polymers. The review also addresses current challenges, including nanosheet stability and the seamless integration into membrane fabrication processes. Emerging pathways that connect laboratory-scale findings with industrial implementation are discussed. From a materials engineering and sustainability perspective, exfoliated LDH nanosheets are presented as promising nanomaterials for developing next-generation membranes targeted at efficient water purification and environmental protection.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 89-109"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review on two-dimensional nanomaterials-mixed matrix membranes for sustainable CO2 separation: from molecular engineering design to efficient modification strategies 二维纳米材料-混合基质膜可持续CO2分离研究综述:从分子工程设计到高效改性策略
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-07-26 DOI: 10.1016/j.jiec.2025.07.054
Mohammad Salehi Maleh , Alireza Bahrami , Mohammad Sajad Sepehri Sadeghian , Hoda Asadimanesh , Mohtada Sadrzadeh
{"title":"A comprehensive review on two-dimensional nanomaterials-mixed matrix membranes for sustainable CO2 separation: from molecular engineering design to efficient modification strategies","authors":"Mohammad Salehi Maleh ,&nbsp;Alireza Bahrami ,&nbsp;Mohammad Sajad Sepehri Sadeghian ,&nbsp;Hoda Asadimanesh ,&nbsp;Mohtada Sadrzadeh","doi":"10.1016/j.jiec.2025.07.054","DOIUrl":"10.1016/j.jiec.2025.07.054","url":null,"abstract":"<div><div>Two-dimensional nanomaterials (2DNMs) are promising for mixed matrix membranes (MMMs) in gas separation but face challenges such as aggregation, interfacial defects, plasticization, and aging. The present review examines key obstacles and strategies to enhance 2DNM-polymer interactions, aiming for durable, high-efficiency membranes. To address such challenges, multifaceted strategies aimed at enhancing the interfacial interaction between 2DNMs and the polymer matrix are examined. Optimizing intrinsic 2DNM properties, pore size, interlayer spacing, and lateral-to-thickness ratio, can improve gas selectivity. Controlling the number of layers, enhancing solubility, and leveraging facilitated transport properties are also crucial. Surface functionalization, such as grafting ionic liquids or macromolecules, enhances compatibility while blending chain molecules fine-tunes membrane performance. Synergistic combinations of 2DNMs with other nanomaterials, including 0D, 1D, and 3D structures, significantly improve gas transport and mechanical strength. Additionally, orientation enhancement techniques, such as applying magnetic or electric fields during fabrication, align 2DNMs within the matrix to optimize gas separation pathways. The insights gained from the study of 2DNMs extend beyond CO<sub>2</sub> separation and are applicable to other gas mixtures. Such principles play a crucial role in shaping the next generation of MMMs, with broad implications for industrial and environmental applications.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 110-146"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic effects of olive oil pomace extract and mineral-medicinal waters in microparticle production for pathogen inhibition 橄榄油渣提取物和矿药水在微颗粒生产中的协同抑菌作用
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-13 DOI: 10.1016/j.jiec.2025.08.022
N. Flórez-Fernández , I. Costa-Trigo , T. Ferreira-Anta , H. Domínguez , J.M Domínguez , A. Paz
{"title":"Synergistic effects of olive oil pomace extract and mineral-medicinal waters in microparticle production for pathogen inhibition","authors":"N. Flórez-Fernández ,&nbsp;I. Costa-Trigo ,&nbsp;T. Ferreira-Anta ,&nbsp;H. Domínguez ,&nbsp;J.M Domínguez ,&nbsp;A. Paz","doi":"10.1016/j.jiec.2025.08.022","DOIUrl":"10.1016/j.jiec.2025.08.022","url":null,"abstract":"<div><div>In recent years, the development of therapeutic agents or bioactive compounds from natural products has increased due to concerns about antimicrobial-resistant bacteria. This study investigates the antimicrobial properties of olive pomace extract (OP-extract) obtained through hydrodistillation and explores its incorporation into microparticles by spray-drying technology to enhance the stability of the OP-extract. Additionally, four mineral-medicinal waters (MMW) from province of Ourense (<em>O Baniño de Arcos</em>, Fonte de <em>O Tinteiro</em>, <em>As Burgas</em> and Parque de <em>O Carballiño</em>) and Milli-Q water (as a control) were studied as ingredients to explore the use of OP-extract microparticles as a natural dermatologic product. HS GC/MS analysis of OP-extracts revealed a volatile profile with over 20 compounds, mainly aldehydes. The antimicrobial activity of the OP-extract was tested against three pathogens, showing significant inhibition at a concentration of 20 %. Several carriers were evaluated to produce the OP-extract microparticles (10 %, w/w), identifying mannitol (1 %, w/w) as a suitable carrier. The incorporation of microparticles into MMW resulted in a consistent production yield of 30 %. For the three tested pathogens, inhibition was enhanced when microparticles were produced with <em>Baniño</em> MMW for two of them, with values around 81 % for <em>C. albicans</em>, 70 % for <em>S. aureus</em>, while for <em>S. epidermis</em> the value obtained was 65 %.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 746-754"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A detailed and A minimal skeletal mechanism for the combustion of the lithium-ion battery vent gas 详细和最小骨架机制的燃烧的锂离子电池排气
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-21 DOI: 10.1016/j.jiec.2025.08.037
Jiarui Liang, Xin Liu, Xianzhong Hu
{"title":"A detailed and A minimal skeletal mechanism for the combustion of the lithium-ion battery vent gas","authors":"Jiarui Liang,&nbsp;Xin Liu,&nbsp;Xianzhong Hu","doi":"10.1016/j.jiec.2025.08.037","DOIUrl":"10.1016/j.jiec.2025.08.037","url":null,"abstract":"<div><div>Study on the combustion characteristics of lithium-ion battery vent gases are vital to prevent and mitigate lithium-ion battery thermal runaway incidents. A skeletal mechanism is developed for the combustion of lithium-ion battery vent gases, in order to increase accuracy and reduce computational time of Computational Fluid Dynamics simulation. Initially, a detailed chemical kinetic model covering C<sub>0</sub>-C<sub>2</sub> small-molecule gases, hydrofluorocarbons, and four typical electrolytes in lithium-ion battery discharge gases was developed. The accuracy of the detailed chemical reaction mechanism is validated by the experimental data of laminar flame velocities and ignition delay time of lithium-ion battery vent gases. Subsequently, the detailed mechanism (226 species, 1656 reactions) was reduced to a minimal skeletal mechanism (66 species, 507 reactions). The minimal skeletal mechanism is validated by the ignition delay time, laminar burning velocity, key species concentrations and extinction limits of three typical lithium-ion battery vent gases in varied conditions. The findings show that the simplified skeletal mechanism effectively reproduces the outcomes of the detailed mechanism.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 755-767"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Isotherm and kinetic study of Malachite green and Congo red removal using Spirulina platensis/CMC/ZnO as a green reusable bioadsorbent 螺旋藻/CMC/ZnO作为绿色可重复使用生物吸附剂去除孔雀石绿和刚果红的等温线及动力学研究
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-07 DOI: 10.1016/j.jiec.2025.08.013
Peyman Abazari , Seyed Ali Hosseini Tafreshi , Saeed Masoum
{"title":"Isotherm and kinetic study of Malachite green and Congo red removal using Spirulina platensis/CMC/ZnO as a green reusable bioadsorbent","authors":"Peyman Abazari ,&nbsp;Seyed Ali Hosseini Tafreshi ,&nbsp;Saeed Masoum","doi":"10.1016/j.jiec.2025.08.013","DOIUrl":"10.1016/j.jiec.2025.08.013","url":null,"abstract":"<div><div>A novel reusable bioadsorbent, <em>Spirulina platensis</em>/CMC/ZnO, was synthesized using <em>Spirulina platensis</em> algae, carboxymethyl cellulose (CMC), and zinc oxide nanoparticles via a co-precipitation method. The material was thoroughly characterized by FT-IR, EDS, elemental mapping, XRD, TGA, and FE-SEM techniques. This bioadsorbent was employed to remove Malachite Green (MG) and Congo Red (CR) dyes from binary mixtures, showing significantly enhanced efficiency compared to individual components. Optimization using Box–Behnken Design (BBD) involved 27 experiments, achieving maximum removal efficiencies of 99.4 % for MG and 99.8 % for CR, with optimal conditions requiring 0.009 g of adsorbent and a 40-minute contact time. Isotherm studies indicated that both dyes followed the Langmuir model in single-dye systems, and the extended Langmuir model was applicable to binary systems. Maximum adsorption capacities in single solutions were 104 mg/g for MG and 80 mg/g for CR, slightly decreasing to 102 mg/g and 72 mg/g in binary systems. Kinetic analysis revealed that the adsorption process followed a pseudo-second-order model. The bioadsorbent demonstrated high reproducibility (%RSD &lt; 3.5 %), good reusability for at least six cycles, and strong thermal and salt stability, making it a promising candidate for dye removal in harsh environmental conditions.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 649-662"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strategy for capacity boosting in aluminum-ion batteries: controlling the interlayer spacing 铝离子电池容量提升策略:控制层间距
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-05 DOI: 10.1016/j.jiec.2025.08.002
Bumjin Kim , Kangjick Kim , Changho Yeon , Chan-Woo Lee , Jeonghun Baek , Sanghui Kang , Seungho Lee , SeungCheol Yang , Won Bin Im , Jungjoon Yoo
{"title":"Strategy for capacity boosting in aluminum-ion batteries: controlling the interlayer spacing","authors":"Bumjin Kim ,&nbsp;Kangjick Kim ,&nbsp;Changho Yeon ,&nbsp;Chan-Woo Lee ,&nbsp;Jeonghun Baek ,&nbsp;Sanghui Kang ,&nbsp;Seungho Lee ,&nbsp;SeungCheol Yang ,&nbsp;Won Bin Im ,&nbsp;Jungjoon Yoo","doi":"10.1016/j.jiec.2025.08.002","DOIUrl":"10.1016/j.jiec.2025.08.002","url":null,"abstract":"<div><div>Al-ion batteries (AIBs) have attracted increasing attention due to their three-electron reactions, abundant raw materials, and inherent safety. They employ cathodes such as graphite-based compounds and metal dichalcogenides, among which molybdenum disulfide (MoS<sub>2</sub>) stands out with its unique layered structure, enhancing AIB capacity. Notably, its 6.2 Å interlayer spacing enables rapid ion diffusion, insertion, and extraction. However, few studies have explored the relationship between areal capacity and interlayer spacing in layered MoS<sub>2</sub> for AIBs. Herein, interlayer-controlled MoS<sub>2</sub> was synthesized via amine intercalation to enhance ion transport. The resulting n-butylamine-intercalated MoS<sub>2</sub> exhibited a larger interlayer spacing of 10.1 Å and achieved ∼ 15-fold higher areal capacity than bulk MoS<sub>2</sub>. Moreover, it maintained 75 % of its initial capacity after 6000 cycles at 1.12 mA cm<sup>−2</sup>, demonstrating excellent long-term stability. These findings contribute to high-performance AIB development using transition-metal sulfide cathodes.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 551-559"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Redox synergy of Cr3+/Co3+ in Cr-Co binary oxide: lattice oxygen dynamics for CO2-mediated oxidative dehydrogenation of propane Cr3+/Co3+在Cr-Co二元氧化物中的氧化还原协同作用:co2介导丙烷氧化脱氢的晶格氧动力学
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-07-25 DOI: 10.1016/j.jiec.2025.07.053
Hannington Nevin Otieno , Samuel Daniel , Liaqat Aqsa , Zhen-Yu Tian
{"title":"Redox synergy of Cr3+/Co3+ in Cr-Co binary oxide: lattice oxygen dynamics for CO2-mediated oxidative dehydrogenation of propane","authors":"Hannington Nevin Otieno ,&nbsp;Samuel Daniel ,&nbsp;Liaqat Aqsa ,&nbsp;Zhen-Yu Tian","doi":"10.1016/j.jiec.2025.07.053","DOIUrl":"10.1016/j.jiec.2025.07.053","url":null,"abstract":"<div><div>The oxidative dehydrogenation of propane with CO<sub>2</sub> is an attractive approach for efficient propene production while concurrently facilitating the reduction of CO<sub>2</sub>. However, a limited understanding of the nature of active sites and structure–activity relationships continues to pose challenges for the rational design of high-performance catalysts in this sustainable process. This study elucidates the interplay between Cr and Co metal oxides in CrCo binary oxide catalysts by varying the Cr/Co weight ratio. Cr<sub>4</sub>Co<sub>1</sub> catalyst, which contains a high Cr concentration, demonstrated the highest activity, achieving 31 ± 1 % propane conversion and 66 ± 1 % propene selectivity. This is due to the high abundance of lattice oxygen, Cr<sup>3+</sup>/Cr<sup>6+</sup>, and Co<sup>3+</sup> species. The higher O<sub>Lat</sub>/O<sub>Ads</sub> ratio in the Cr<sub>4</sub>Co<sub>1</sub> catalyst facilitates hydrogen abstraction from the propane’s C–H bond, resulting in propene formation and oxygen vacancies on the surface of the catalyst. Simultaneously, the Cr<sup>3+</sup>/Cr<sup>6+</sup> species promote C–H bond cleavage while suppressing C–C bond cleavage. In contrast, the Co<sup>3+</sup> species enhances the dissociation of the C=O bond in CO<sub>2</sub>. The resulting O* radicals effectively replenish the oxygen vacancies, completing the redox cycle. The interplay among these species contributes to the promising catalytic performance of CO<sub>2</sub>-ODHP. These insights provide essential guidelines for the development of high-performance CrCo-based catalysts for CO<sub>2</sub>-ODHP.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 420-433"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MOFs for (bio)chemical sensor devices 用于(生物)化学传感器器件的mof
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-07-28 DOI: 10.1016/j.jiec.2025.07.052
Maira Aslam , Muhammad Zain Ali , Muhammad Umair Akram , Ayesha Akram , Laiba Laiba , Sonia Naz , Francis Verpoort
{"title":"MOFs for (bio)chemical sensor devices","authors":"Maira Aslam ,&nbsp;Muhammad Zain Ali ,&nbsp;Muhammad Umair Akram ,&nbsp;Ayesha Akram ,&nbsp;Laiba Laiba ,&nbsp;Sonia Naz ,&nbsp;Francis Verpoort","doi":"10.1016/j.jiec.2025.07.052","DOIUrl":"10.1016/j.jiec.2025.07.052","url":null,"abstract":"<div><div>The potential applications of a family of porous substances called metal–organic frameworks (MOFs) in chemical sensing have sparked a great deal of attention. The creation and synthesis of MOFs using a range of techniques, such as traditional procedures, microwave synthesis, electrochemical synthesis, mechanocompaction, and sonochemical synthesis, are examined in this thorough overview. The paper addresses contemporary issues in the field of chemical sensing while highlighting the principles of the subject and exploring the definition, significance, and necessary specifications of chemical sensor devices. The discussion then turns to MOFs as cutting-edge chemical sensing materials, explaining their special qualities, advantages, and future prospects in relation to other materials. The investigation encompasses electrical, electrochemical, electromechanical, and optical sensing techniques, as well as intrinsic and extrinsic MOF-based optical fiber sensors, and uses of MOF films and devices in chemical sensing. The topic of integrating MOFs into analytical devices is covered, with a focus on optimizing the integration of optical and electrical devices. Solid-state sensing applications using MOF-based sensors are used as examples. The study also describes developments in MOF-based wearables and smartphone sensors.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 52-88"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of PEDOT: PSS-based resistive gas sensors PEDOT: pss型电阻式气体传感器的研究进展
IF 5.9 3区 工程技术
Journal of Industrial and Engineering Chemistry Pub Date : 2026-03-25 Epub Date: 2025-08-07 DOI: 10.1016/j.jiec.2025.08.014
M. Hjiri , G. Neri
{"title":"A review of PEDOT: PSS-based resistive gas sensors","authors":"M. Hjiri ,&nbsp;G. Neri","doi":"10.1016/j.jiec.2025.08.014","DOIUrl":"10.1016/j.jiec.2025.08.014","url":null,"abstract":"<div><div>Conducting polymers (CPs) with high transparency, good environmental stability, and high conductivity, are effective materials for gas sensing applications. There are various types of CPs and among them poly (3,4-ethylenedioxythiophene): poly (styrenesulfonic acid) abbreviated as (PEDOT: PSS) stands one of the most widely used CPs for practical applications. Thanks to its low price, high conductivity, ease of synthesis, high environmental stability, biocompatibility, and excellent mechanical flexibility, PEDOT: PSS is one of the most important CPs for gas sensing applications. In this review, we have discussed various gas sensing features of PEDOT: PSS sensors. Ability to work at low and room temperature is one of the main advantage of PEDOT: PSS gas sensors for detection of gases. To further enhance their gas sensing characteristics, they are doped, decorated, and composited with other materials and we have explained the sensing properties and gas sensing mechanism in detail. We believe that this article can deliver new concepts and idea for the researchers who work in field of gas sensors.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 240-247"},"PeriodicalIF":5.9,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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