Journal of Colloid and Interface Science最新文献

{"title":"Constructing lignin-derived hierarchical porous carbon/manganese dioxide composites with robust interfacial bonding for boosting supercapacitive performances","authors":"Xianlong Wang ,&nbsp;Fangbao Fu ,&nbsp;Wenli Zhang ,&nbsp;Jiale Wen ,&nbsp;Xueqing Qiu","doi":"10.1016/j.jcis.2025.138466","DOIUrl":"10.1016/j.jcis.2025.138466","url":null,"abstract":"<div><div>Carbon/transition metal oxide composites hold significant promise for energy storage applications; however, achieving precise control over the carbon structure to enhance the electrochemical activity of metal oxides remains a challenge. In this work, we utilized low-cost enzymatic lignin as a carbon source and harnessed the synergistic effects of magnesium oxide templates and potassium acetate activator to synthesize a lignin-derived hierarchical porous carbon (HPLC) characterized by a high specific surface area of 1704 ± 36 m²/g, well-ordered nanosheet structures, and hierarchical porosity. The comparative analysis demonstrated that HPLC exhibited superior pore anchoring and enhanced interfacial Mn-O-C bonding interactions with manganese dioxide compared to mesoporous carbon synthesized via magnesium oxide templating and microporous carbon derived from potassium acetate activation. This unique architecture significantly boosted the charge storage capacity of manganese dioxide. The composite showed remarkable electrochemical performance, achieving a specific capacitance of up to 567 F/g at a current density of 0.5 A/g, while also demonstrating excellent rate capability. An asymmetric capacitor constructed with the composite electrode delivered a high energy density of 47.22 Wh/kg and maintained a capacity retention of 85.2 % after 12,000 cycles at 2.0 A/g, illustrating its outstanding cycling stability. Analysis of the energy storage mechanism revealed that the capacity of this material was predominantly attributed to redox reactions involving manganese species induced by potassium ion insertion and extraction, as well as the double-layer capacitance arising from the adsorption and desorption of potassium ions. This work elucidates the crucial influence of carbon structure on the loading of metal oxides, providing a novel strategy for tuning carbon carrier structures aimed at developing high-performance carbon/metal composites.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138466"},"PeriodicalIF":9.4,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Activating inert copper hydroxide by coordination effect of stoichiometric nitrate for efficient hydrogen evolution reaction","authors":"Min Li ,&nbsp;Sheng-Xia Yang ,&nbsp;Yu-Feng Liu ,&nbsp;Ya-Nan Zhou ,&nbsp;Hai-Jun Liu ,&nbsp;Xin-Yu Zhang ,&nbsp;Bin Dong ,&nbsp;Qun-Wei Tang","doi":"10.1016/j.jcis.2025.138444","DOIUrl":"10.1016/j.jcis.2025.138444","url":null,"abstract":"<div><div>The hydrogen evolution reaction (HER) process of metal hydroxides is significantly limited by weak hydrogen adsorption and requires a large overpotential. This study presents coordination engineering strategy to activate inert copper hydroxide through the introduction of stoichiometric nitrate ligands (CuHN). Nitrate and Cu are coordinated in an atomic ratio of 1 to 2, leading to expanded lattice space compared to conventional Cu hydroxide. This modification facilitated the successful doping of numerous Co atoms to synthesize the Co-CuHN sample, which works synergistically with nitrate to enhance HER activity. Experimental and theoretical analyses demonstrate that nitrate and Co provide electrons to Cu, thereby modulating the d-band center and surface adsorption capability. Compared to Cu(OH)₂, Co-CuHN exhibits a reduced water dissociation energy barrier of 0.54 eV, supplying abundant protons for hydrogen generation. Notably, the Gibbs free energy of hydrogen adsorption is optimized to approach zero. Consequently, Co-CuHN demonstrates a small Tafel slope of 40.0 mV dec⁻¹ and requires a low overpotential of 18 mV (10 mA cm⁻²), which is 99 mV lower than control Cu(OH)₂. This work is expected to provide a deeper understanding of anion coordination regulation of copper hydroxide.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138444"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144663079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Constructing SnO2/SnSe2 heterostructures anchored on reduced graphene oxide for advanced Lithium-ion batteries","authors":"Ao Shen ,&nbsp;Zhichen Shi ,&nbsp;Wenyuan Zhang ,&nbsp;Yi Zhai ,&nbsp;Yongbao Feng ,&nbsp;Wenbin Gong ,&nbsp;Peng Xu ,&nbsp;Qiulong Li","doi":"10.1016/j.jcis.2025.138460","DOIUrl":"10.1016/j.jcis.2025.138460","url":null,"abstract":"<div><div>Tin-based compounds have an ultrahigh theoretical capacity and low oxidation-reduction potential, making them as a very important type of anode matrix for lithium-ion batteries (LIBs). Nevertheless, the enormous volume dilatation causes structural collapse, limiting its cyclic stability. Herein, a nanoscale SnO₂/SnSe₂@rGO has been designed, in which the interface of SnO₂/SnSe₂ heterostructure generates a built-in electric field, improving charge transfer efficiency. And rGO, as a 3D interconnection network coating SnO₂/SnSe₂ nanoparticles, improves conductivity and serves as a buffer medium for volume expansion. DFT calculations confirm that the formation of built-in electric field enhances the adsorption energy of Li⁺ and reduces the migration energy barrier. As expected, the initial capacity of the SnO₂/SnSe₂@rGO electrode can reach 1405.9 mAh g⁻¹ at 2.0 A g⁻¹. The reversible capacity is 1459.1 mAh g⁻¹ at 0.1 A g⁻¹ after 50 cycles, with 78.1 % capacity retention. Finally, a SnO₂/SnSe₂@rGO//LiFePO₄ (LFP) full battery was assembled, which exhibits a high capacity of 213.1 mAh g⁻¹ at 0.1 A g⁻¹ and energy density of 492.8 Wh kg⁻¹ at 270 W kg⁻¹. The design of this nanoscale heterostructure provides a feasible strategy for developing LIBs anodes with enhanced capacity and extended lifespan.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138460"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144665847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiple redox Centers and defect engineering in Fe/Mo dual-doped Na3V2(PO4)3 cathodes for high-performance sodium-ion batteries","authors":"Min Xie ,&nbsp;Xiaoying Li ,&nbsp;Yufan Chen ,&nbsp;Xiangyue Liao ,&nbsp;Qiaoji Zheng ,&nbsp;Heng Zhang ,&nbsp;Kwok-Ho Lam ,&nbsp;Dunmin Lin","doi":"10.1016/j.jcis.2025.138461","DOIUrl":"10.1016/j.jcis.2025.138461","url":null,"abstract":"<div><div>Sodium superionic conductor (NASICON)-type phosphates cathodes have attracted considerable attention due to their high operational voltage and robust three-dimensional (3D) framework; however, the poor intrinsic electronic conductivity and low energy density hinder their broader application. Herein, a novel NASICON-type Na₃V_1.44Fe_0.5Mo_0.06(PO₄)₃ cathode was designed through Fe/Mo dual-doping at the V sites of Na₃V₂(PO₄)₃ and synthesized via a conventional high-temperature solid-state method. The introduction of Fe³⁺ activates the V⁴⁺/V⁵⁺ redox couple at a high voltage plateau (∼ 4.0 V), while also generates additional Fe²⁺/Fe³⁺ and V⁴⁺/V⁵⁺ redox pairs. Meanwhile, the doing of Mo⁶⁺ creates cation vacancies, effectively modulating the electronic structure of vanadium and promoting ionic transport kinetics. Benefiting from this dual-doping strategy, the Na₃V_1.44Fe_0.5Mo_0.06(PO₄)₃ cathode delivers a high capacity of 123.4 mAh g⁻¹ at 0.2C and an impressive energy density of 406 Wh kg⁻¹ within 2.2–4.2 V. Moreover, it exhibits outstanding cycling stability, presenting a capacity retention of 92 % after 2500 cycles at 30C. This work highlights a viable strategy for advancing high-performance NASICON-type cathodes through complex metal ion doping.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138461"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Marine anemone inspired cerium oxide doped nickel catalysts for enhanced seawater electrolysis efficiency","authors":"Qi Luo ,&nbsp;Xiaoyu Hao ,&nbsp;Kewei Tang ,&nbsp;Jinglun Guo ,&nbsp;Jingyu Kang ,&nbsp;Weihong Qi ,&nbsp;Xuqing Liu","doi":"10.1016/j.jcis.2025.138430","DOIUrl":"10.1016/j.jcis.2025.138430","url":null,"abstract":"<div><div>Seawater electrolysis offers a promising strategy for sustainable hydrogen production, yet inherent chloride ions (Cl⁻) in seawater induce electrode corrosion, posing a major challenge to this process. Herein, we developed a novel biomimetic catalyst by doping Cerium Oxide (CeO₂) into a nickel-based system and depositing it on carbon cloth (CeO₂/Ni/CC) inspired by the tentacle architecture of marine anemones. This design endows the catalyst with abundant active sites and high specific surface area, thereby significantly enhancing its seawater electrolysis performance. Notably, the incorporation of CeO₂ effectively inhibit the adsorption of Cl⁻ and prevent the corrosion of the electrode. The optimized CeO₂/Ni/CC-2 catalyst exhibits outstanding OER activity and chloride corrosion resistance in both 1.0 M KOH and 0.6 M NaCl +1.0 M KOH electrolytes, achieving overpotentials of 214 mV and 220 mV at 10 mA cm⁻², respectively. Tafel slope analysis and Nyquist impedance measurements further confirm that CeO₂ doping substantially improves reaction kinetics and charge transfer efficiency. Moreover, computational investigations employing density functional theory formalism (DFT) uncover that CeO₂ incorporation induces a blue shift in the d-band center of Ni, which optimizes the adsorption energies of oxygenated intermediates and enhances the adsorption capacity for chloride ions. This study not only introduces a new strategy for designing robust catalysts for seawater electrolysis but also lays a theoretical foundation for advancing clean energy technologies.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138430"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144657162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An ultra-dilute Mg(TFSI)2 based electrolyte enabling reversible Mg metal anode","authors":"Caiyun Wang ,&nbsp;Xingxing Wu ,&nbsp;Yufan Xia ,&nbsp;Xuan Zhang ,&nbsp;Hongge Pan ,&nbsp;Mi Yan ,&nbsp;Yong Li ,&nbsp;Yinzhu Jiang","doi":"10.1016/j.jcis.2025.138459","DOIUrl":"10.1016/j.jcis.2025.138459","url":null,"abstract":"<div><div>Mg metal anodes experience significant passivation of harmful side reactions in conventional electrolyte consisting of magnesium bis(trifluoromethane sulfonyl)imide (Mg(TFSI)₂) in 1,2-dimethoxyethane (DME), which critically impedes the advancement of high-performance rechargeable magnesium batteries. Herein, an innovative electrolyte system comprising an ultra-dilute 0.02 M Mg(TFSI)₂ in DME with 4-chlorobutyl methyl ether (CME) as co-solvent is strategically devised. This unique formulation effectively suppresses the formation of TFSI⁻-derived passivation byproducts while simultaneously facilitating the establishment of protective Cl-rich interphase, thereby achieving exceptional reversibility in Mg plating/stripping processes. Remarkably, Mg electrodes demonstrate stable cycling performance with a minimal overpotential of 70 mV at 0.1 mA cm⁻² in the optimized 0.02 M Mg(TFSI)₂-DME/CME electrolyte. More impressively, the system maintains reversible electrochemical operation for 400 h even at 2 mA cm⁻². This work presents a novel electrolyte formulation for overcoming the limitations of Mg metal anode in conventional Mg(TFSI)₂ based electrolytes, offering new perspectives for the development of next-generation rechargeable magnesium batteries.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138459"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144663081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrathin formvar film protective layer via simple dipping strategy for ultra-stable zinc-metal anodes","authors":"Lihong Dong ,&nbsp;Chunhui Zhao ,&nbsp;Linlin Li","doi":"10.1016/j.jcis.2025.138457","DOIUrl":"10.1016/j.jcis.2025.138457","url":null,"abstract":"<div><div>Aqueous Zn ion batteries (ZIBs) have become a strong competitor in the field of large-scale energy storage. However, surface side reactions, such as Zn corrosion, hydrogen evolution reaction, and dendrite growth, lead to low reversibility of Zn anode. This study introduces a time-saving and simple solution-dipping method to address above issues by spreading ultrathin Poly (vinyl formal) (PVF) protective layer on the surface of Zn anode (denoted as PVF@Zn). Owing to its abundant oxygen-containing functional groups, PVF molecule exhibits not only highly adhesive force with Zn metal surface but also higher zincophilicity with Zn²⁺ ions. The former effectively prevents direct contact between electrolyte and Zn anode as well as guides a three-dimensional (3D) diffusion mode of Zn²⁺ plating, the latter reduces the Zn nucleation energy barrier as well as enhances the uniformity of Zn deposition. Meanwhile, the hydrophilic and ion conductivity characters endow the PVF film with abundant nucleation sites and homogenous electric field distribution, further guaranteeing an even Zn deposition. Moreover, the outstanding mechanical strength and elasticity of the PVF film can withstand the volume variation during Zn plating/stripping, which is conducive to inhibit the growth of dendrites. Consequently, symmetrical cells assembled by the PVF@Zn electrodes deliver dendrite-free plating/stripping and an ultra-long stable cycle of 4900 h at 0.5 mA cm⁻², 1.0 mAh cm⁻². Even though the current density is as high as 10 mA cm⁻², the PVF@Zn electrode still possesses a cycling life of 4000 h and the corresponding cumulative plating capacity is up to 20,000 mAh cm⁻². When paired with a MnO₂ cathode, the PVF@Zn anode retains 72.5 % capacity over 1000 cycles at 1 A g⁻¹, which is much better than that of bare Zn (18.4 %). This work provides a promising method for rapidly fabricating ultrathin Zn anode protective layer to inhibit dendrites and side reactions in aqueous Zn ion battery.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138457"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144662975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Upcycling of photovoltaic silicon waste into Si/Cu@GLC anodes for lithium-ion batteries","authors":"Yunfei Bao ,&nbsp;Liping Zhao ,&nbsp;Fengshuo Xi ,&nbsp;Shaoyuan Li ,&nbsp;Xiuhua Chen ,&nbsp;Jijun Lu ,&nbsp;Zhongqiu Tong ,&nbsp;Kuixian Wei ,&nbsp;Bin Luo ,&nbsp;Wenhui Ma","doi":"10.1016/j.jcis.2025.138467","DOIUrl":"10.1016/j.jcis.2025.138467","url":null,"abstract":"<div><div>Silicon anodes are promising candidates for next-generation lithium-ion batteries owing to their high theoretical capacity. However, the practical application of silicon anodes is limited by severe volume expansion and poor cycling stability. This study presents a sustainable and cost-effective strategy for synthesizing high-performance graphene-like carbon (GLC)-coated silicon/nano‑copper (Si/Cu@GLC) composites using photovoltaic silicon cutting waste (SCW) as the starting material. The synthesis combines copper-assisted chemical etching with the catalytic pyrolysis of humic acid, yielding a composite with enhanced electrochemical performance. Economic and environmental assessments reveal that the SCW-derived Si/Cu@GLC exhibits lower production costs and CO₂ emissions than conventional silicon anode fabrication processes. The Si/Cu@GLC composite exhibits a high initial discharge capacity of 2333.98 mAh g ⁻¹, along with excellent cycling stability and superior rate capability. The GLC coating and nanoporous structure synergistically mitigate volume expansion, resulting in a low expansion rate of only 157 % after 100 cycles. Upon integration into a full cell with an LFP (Lithium Iron Phosphate) cathode, Si/Cu@GLC exhibits excellent cycling stability, retaining 86.7 % of its capacity after 200 cycles at 0.5C. This study provides a sustainable and scalable approach for upcycling photovoltaic silicon waste into high-performance silicon–carbon anodes. The findings highlight the potential of an eco-friendly circular production model that combines economic viability with superior battery performance.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138467"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of composite Zn metal anode based on phosphorus-doped carbon nanotubes for aqueous Zn-ion batteries","authors":"Keqing Yang ,&nbsp;Jingbin Han ,&nbsp;Jiahui Zhou ,&nbsp;Kang Yan ,&nbsp;Meng Wang ,&nbsp;Man Xie ,&nbsp;Yibiao Guan ,&nbsp;Yuefeng Su ,&nbsp;Feng Wu ,&nbsp;Lai Chen","doi":"10.1016/j.jcis.2025.138462","DOIUrl":"10.1016/j.jcis.2025.138462","url":null,"abstract":"<div><div>Aqueous Zn-ion batteries exhibit tremendous potential for large-scale energy storage applications due to the dual advantages of abundant Zn metal reserves and high theoretical capacity. However, practical applications are hindered by issues such as dendrite growth, electrode corrosion and hydrogen evolution. In this study, a composite anode composed of pre-deposited Zn on phosphorus-doped carbon nanotubes (P-CNT) is reported. On the one hand, the carbon nanotubes (CNTs) serve to reduce local current density during Zn deposition, enhancing corrosion resistance. On the other hand, the formation of a Zn₃P₂ interfacial layer facilitates more uniform Zn deposition, effectively suppresses dendrite growth, and mitigates the hydrogen evolution reaction (HER) to a certain extent. The composite anode exhibits a high coulombic efficiency of 98.9 % after 300 cycles. Furthermore, the full cell assembled with a LiMn₂O₄ (LMO) cathode demonstrates stable cycling performance over 900 cycles. This work presents a novel and robust design for a Zn metal anode in advanced aqueous Zn-ion batteries.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138462"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144665849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the prospects of hydrogen bond networks and multiple chemical bonds in biomass-derived Ni-doped hydrochar for high-performance integrated silicon anodes","authors":"Qiushi Wang ,&nbsp;Jin Feng ,&nbsp;Hao Yang ,&nbsp;Ping Li ,&nbsp;Tao Meng ,&nbsp;Yifu Zhang ,&nbsp;Yexiang Tong","doi":"10.1016/j.jcis.2025.138451","DOIUrl":"10.1016/j.jcis.2025.138451","url":null,"abstract":"<div><div>Considering the large-scale production of lithium-ion battery anode materials, the advantages of silicon-based anodes would be overshadowed if both performance and cost were not properly optimized. However, current preparation methods for silicon‑carbon anodes face challenges such as low efficiency and high energy consumption, limiting the sustainable commercialization. This work proposes a novel, cost-effective method for fabricating silicon‑carbon anodes by utilizing a hydrogen bond network in combination with multiple chemical bonds. Through a one-step hydrothermal method, silicon nanoparticles, nickel foam, and a Ni-doped hydrochar-based amorphous carbon network are assembled into the integrated NF-Si@GC electrode. The calculation demonstrates that multiple chemical bonds between each component in composite structure introduces a built-in electric field across the three materials, which generates a driving force for electron transfer on the surface of Si. As expected, the NF-Si@GC electrode exhibits a high reversible charge capacity of 1454 mAh g⁻¹ at 0.1 A g⁻¹, maintains 970 mAh g⁻¹ at a high areal loading of 1.41 mg cm⁻², and achieves one of the lowest preparation costs for common silicon anodes reported to date. The study of this reaction mechanism provides inspiration for the large-scale production of other battery materials and the scalable manufacturing of high-performance electrodes.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"700 ","pages":"Article 138451"},"PeriodicalIF":9.4,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144656617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}