Energetic Materials Frontiers最新文献_第3页

Graphical Abstract 图表摘要

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/S2666-6472(24)00045-9

引用次数: 0

Low-temperature rheological properties and viscosity equation of Al/HTPB suspension system Al/HTPB 悬浮体系的低温流变特性和粘度方程

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.04.001

Ke Wang , Min Xia , Qi-fa Yao , Yi-xuan Xie , Lin Zhong , Yu-zhan Li , Wei Yang , Yun-jun Luo

{"title":"Low-temperature rheological properties and viscosity equation of Al/HTPB suspension system","authors":"Ke Wang , Min Xia , Qi-fa Yao , Yi-xuan Xie , Lin Zhong , Yu-zhan Li , Wei Yang , Yun-jun Luo","doi":"10.1016/j.enmf.2024.04.001","DOIUrl":"10.1016/j.enmf.2024.04.001","url":null,"abstract":"<div>The rheological behavior of propellant slurries is crucial for ensuring the feasibility of the 3D printing process, controlling print quality, regulating performance, and simulating predictions. However, there have been relatively few prior studies on the rheological properties of composite solid propellant slurries at low temperatures, which hinders the application of 3D printing propellant technology under extreme temperature conditions. In addition, the use of 3D printing technology to manufacture propellants at low temperatures is advantageous for improving safety. This paper investigates the rheological properties of monodisperse systems with aluminum powder as a solid filler and end-hydroxy polybutadiene (HTPB) as the dispersed phase at low temperatures (−15∼10 °C). It explores the effects of solid content, temperature, and particle size on their rheological properties. Results show that the viscosity of the system in the range of −15∼10 °C increases exponentially with the decrease in temperature, and the viscosity at −15 °C increases by 616.90 % compared with that at 10 °C when the volume fraction (φ) of Al-1 is 35.8 %; the larger size of the particles the larger the viscosity is when the temperature and φ are the same, which is interpretes in terms of interfacial properties between the systems. The low-temperature correction factor is introduced into the Einstein-Roscoe equation to obtain the modified viscosity-volume fraction equation, and the correction factor is 0.0173, as evidenced by its excellent agreement with the experimental data.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647224000319/pdfft?md5=29dd9c399e37a5547f14e23a6ea0135c&pid=1-s2.0-S2666647224000319-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141025884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cover Story 封面故事

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/S2666-6472(24)00044-7

引用次数: 0

Technologies for room-temperature self-healing polymer materials and their applications in energetic materials 室温自愈合聚合物材料技术及其在高能材料中的应用

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.06.001

Xing-ling Hu , Min Xia , Ming-hao Zhang , Wei Yang , Fan-zhi Yang , Yun-jun Luo

引用次数: 0

Deprotonation-assisted electrochemical synthesis of copper nitrotriazole with excellent ignition performance 去质子化辅助电化学合成具有优异点火性能的硝基三唑铜

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2023.12.003

Jun-hong Chen, Chun-pei Yu, Jian-yong Xu, Chang-kun Song, Wei Shi, Xiao-ting Lei, Bo-nan Gu, Ming-hao Bao, Wen-chao Zhang

{"title":"Deprotonation-assisted electrochemical synthesis of copper nitrotriazole with excellent ignition performance","authors":"Jun-hong Chen, Chun-pei Yu, Jian-yong Xu, Chang-kun Song, Wei Shi, Xiao-ting Lei, Bo-nan Gu, Ming-hao Bao, Wen-chao Zhang","doi":"10.1016/j.enmf.2023.12.003","DOIUrl":"10.1016/j.enmf.2023.12.003","url":null,"abstract":"<div>Electrochemical synthesis serves as a green and efficient method with great application potential. However, it has not been extensively applied in the synthesis of energetic materials. Nitrogen-rich heterocyclic compounds, as a new generation of energetic materials, enjoy advantages such as eco-friendliness, high energy output, and excellent safety performance. This study reports the electrochemical cathodic synthesis of copper nitrotriazole [Cu(NTz)2] using copper chloride and 3-nitro-1,2,4-triazole as a reaction substrate and triethylamine as a deprotonation agent. The obtained Cu(NTz)2 comprises uniform spherical particles of nano lamellae. As the dosage of triethylamine increased from 50 μL to 150 μL, Cu(NTz)2 gradually grew into compact solid spherical particles, significantly increasing the energy output. Notably, the heat release increased from 711 J g−1 to 1301 J g−1, accompanied by a significant positive elevation of ignition performance and peak combustion pressure in the process of confined combustion. This greatly boosted the energetic performance of Cu(NTz)2. Moreover, Cu(NTz)2 demonstrates insensitivity to electrostatic discharge (E50＞225 mJ) and friction (FS＞360 N), suggesting excellent safety performance. Owing to its outstanding energetic and safety performance, Cu(NTz)2 boasts great potential for application as pyrotechnic compositions, including military gas-producing and incendiary agents. Moreover, it has been corroborated that Cu(NTz)2 can be applied as a micro ignitor.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647223000696/pdfft?md5=f8d982b8d340f26441ebf2f5550ed0fd&pid=1-s2.0-S2666647223000696-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138627786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural evolvement of 1-methyl-3,4,5-trinitropyrazole at high pressure 高压下 1-甲基-3,4,5-三硝基吡唑的结构演变

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.03.003

Guang-yu Qi , Ye Cao , Tian-yu Jiang , Hong Zhang , Yi Wang

{"title":"Structural evolvement of 1-methyl-3,4,5-trinitropyrazole at high pressure","authors":"Guang-yu Qi , Ye Cao , Tian-yu Jiang , Hong Zhang , Yi Wang","doi":"10.1016/j.enmf.2024.03.003","DOIUrl":"10.1016/j.enmf.2024.03.003","url":null,"abstract":"<div>Explosives, a type of energetic material (EM), face a high-pressure environment in the detonation process or under shock conditions. Determining their high-pressure behavior is critical to their explosion and safety. 1-Methyl-3,4,5-trinitropyrazole (MTNP), a carrier of melt-cast explosives, exhibits the potential for replacing trinitrotoluene (TNT). However, there is limited knowledge about its structural evolvement at high pressure. Using a diamond anvil cell (DAC), this study investigated the structural variation of MTNP through in situ high-pressure synchrotron angle-dispersive X-ray diffraction (ADXRD) experiments and Raman measurements. As evidenced by the results, MTNP underwent phase transition at 8.7 GPa and amorphization at 15.3 GPa due to high pressure. Through the analysis of first-principles calculations and Raman spectra, this study proposed the mechanisms behind the changes in MTNP at high pressure. Furthermore, this study systematically explored the structural evolvement of MTNP and the evolution of its weak intermolecular interactions at high pressure, gaining further understanding of MTNP's detonation and safety.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647224000253/pdfft?md5=3784701aaf015ded1398ec705e2215c5&pid=1-s2.0-S2666647224000253-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140202262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A new crystal form of Hx2TNBI·2H2O through solvent-induced crystallization 通过溶剂诱导结晶获得 Hx2TNBI-2H2O 的新晶体形态

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.03.004

Bi-bo Li , Xiao-long Li , Yang Liu , Peng-cheng Zhang , Mei-qi Wang , Shang-biao Feng , Shu-hai Zhang

{"title":"A new crystal form of Hx2TNBI·2H2O through solvent-induced crystallization","authors":"Bi-bo Li , Xiao-long Li , Yang Liu , Peng-cheng Zhang , Mei-qi Wang , Shang-biao Feng , Shu-hai Zhang","doi":"10.1016/j.enmf.2024.03.004","DOIUrl":"10.1016/j.enmf.2024.03.004","url":null,"abstract":"<div>Polymorphism is universal in energetic materials (EMs), which is originated from the differences of molecular conformers and stacking mode. The polymorphic transition may lead to the change of crystal structure and properties of EMs. In this work, β-Hx2TNBI·2H2O (β-1) was successfully synthesized through solvent-induced conformational transition of Hx2TNBI·2H2O. From the perspective of quantum chemistry and molecular dynamics, the crystal stacking changes caused by different molecular conformations are discussed in detail, which leads to the properties difference of EMs. The results show that β-1 featured wave-like crystal stacking, making it less sensitive to external mechanical stimuli than α-Hx2TNBI·2H2O (α-1) (α-1: IS > 6 J, FS > 288 N; β-1: IS > 20 J, FS > 360 N). α-1 featured better the aromaticity, which gives it higher thermal stability than β-1 (α-1: Td = 186 °C; β-1: Td = 146 °C). Simultaneously, compared with β-1, α-1 has higher crystal density and detonation performance. This work provides a new and effective way to change the safety of EMs.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647224000265/pdfft?md5=e9d0cf0f55927f978afc087416181c7b&pid=1-s2.0-S2666647224000265-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140590946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancements in methodologies and techniques for the synthesis of energetic materials: A review 高能材料合成方法和技术的进展：综述

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.06.002

Wei Du , Lei Yang , Jing Feng , Wei-hua Zhu , Jin-shan Li , Peng-cheng Zhang , Qing Ma

引用次数: 0

Research progress and prospect of explosive crystallization (2022-present) 爆炸结晶的研究进展和前景（2022 年至今）

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.05.003

Yu-jie Song, Ying Wang, Rong Xu, Qi Zhang

{"title":"Research progress and prospect of explosive crystallization (2022-present)","authors":"Yu-jie Song, Ying Wang, Rong Xu, Qi Zhang","doi":"10.1016/j.enmf.2024.05.003","DOIUrl":"10.1016/j.enmf.2024.05.003","url":null,"abstract":"<div>To meet the requirements of explosives in military and civilian fields, researchers are committed to improving the comprehensive performance of explosives. The performance of explosive crystals can be significantly improved by regulating the structure and morphology of single-compound explosive crystals as well as compounding explosive crystals. According to the related research on explosive crystals at home and abroad from 2022 to now, the development of explosive crystal composites and single-compound explosives' crystal morphology, particle size, and crystal form regulation study were reviewed. The explosive crystal composites encompass both the complex consisting of a single-compound explosive and the complex consisting of two separate types of explosives. Simultaneously, the main problems encountered in the development of explosive crystals were also analyzed, such as the deficiency of systematic and broadly applicable regulation methods and theories. Finally, the future development direction of explosive crystal research was envisioned, with the aim of providing guidance for the production, handling, and application of explosives.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647224000356/pdfft?md5=858338ff26c71734ba9eab6f1bed2aa5&pid=1-s2.0-S2666647224000356-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141509275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bio-inspired design of PTFE/B energetic materials with high reactivity and flexibility 受生物启发设计出具有高反应活性和柔韧性的聚四氟乙烯/乙烯高能材料

IF 3.3

Energetic Materials Frontiers Pub Date : 2024-06-01 DOI: 10.1016/j.enmf.2024.03.006

Jun Wang , Hua-Mo Yin , Yao-feng Mao , Ling-feng Yang , Xiaowei Chen

{"title":"Bio-inspired design of PTFE/B energetic materials with high reactivity and flexibility","authors":"Jun Wang , Hua-Mo Yin , Yao-feng Mao , Ling-feng Yang , Xiaowei Chen","doi":"10.1016/j.enmf.2024.03.006","DOIUrl":"10.1016/j.enmf.2024.03.006","url":null,"abstract":"<div>Although new-type energetic materials have been investigated extensively, there is a challenge on how to integrate energy density and mechanical properties of energetic materials simultaneously. Herein, a versatile approach was proposed to design energetic materials with high energy density, reactivity, and flexibility based on a bio-inspired strategy. By mimicking the “brick-and-mortar” structure within a natural nacre, the energetic film with alternative layers of polytetrafluoroethylene (PTFE) and boron (B) was successfully fabricated. The nacre-mimetic PTFE/B energetic film exhibited excellent reaction heat (4413.9 J⋅g−1) and bright combustion flame, which may originate from the exothermic reaction mechanism between fluorine (F) and B. Even more remarkably, such PTFE/B energetic film revealed prominent mechanical flexibility reported for the first time. These findings indicate that the nacre-mimetic strategy provides an effective route to engineer energetic materials with high energy density, reactivity, and flexibility.</div>","PeriodicalId":34595,"journal":{"name":"Energetic Materials Frontiers","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666647224000289/pdfft?md5=251687e8a3f8fc26236be25545e68ff1&pid=1-s2.0-S2666647224000289-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140404674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0