作为高热稳定性高能生物杀灭材料的全碘桥接吡咯

IF 3.9 Q2 CHEMISTRY, MULTIDISCIPLINARY

Energetic Materials Frontiers Pub Date : 2025-03-01 DOI:10.1016/j.enmf.2025.03.002

Xin-yuan Zhao , Xun Zhang , Hao-tian Yu , Yan Liu , Si-ping Pang , Chun-lin He

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引用次数: 0

摘要

吡咯是功能材料中重要的多用途骨架之一，全取代吡咯可以实现多次取代。但空间位阻效应使其合成困难。本文采用两步法合成了一系列全碘化桥接吡咯（化合物8 ~ 13）作为含能生物杀灭化合物。它们具有高碘含量（82.98% ~ 88.02%）和高热稳定性（Td: 267 ~ 344℃），与2,3,4,5-四碘- 1h -吡咯（TIPL, Td: 168℃）相比有显著提高。此外，还实现了良好的爆轰压力(P)和爆轰速度(D)，作为潜在的高能杀菌材料具有广阔的应用前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Fully-iodinated bridged pyrroles as high thermostable energetic biocidal materials

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Fully-iodinated bridged pyrroles as high thermostable energetic biocidal materials

Pyrrole is one of the important versatile skeletons for functional materials, fully-substituted pyrroles can achieve multiple substitutions. But, spatial site resistance effects make its synthesis difficult. In this work, a series of fully-iodinated bridged pyrroles (compounds 8–13) as energetic biocidal compounds were synthesized through two-step. They show high iodine content of 82.98 %–88.02 %, and high thermal stability (T_d: 267–344 °C) which is a significantly improved compared to 2,3,4,5-tetraiodo-1H-pyrrole (TIPL, T_d: 168 °C). Furthermore, good detonation pressure (P) and detonation velocity (D) were realized, showing great prospective for applications as potential energetic biocidal materials.

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来源期刊

Energetic Materials Frontiers Materials Science-Materials Science (miscellaneous)

CiteScore

6.90

自引率

0.00%

发文量

审稿时长

12 weeks