IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-26 DOI: 10.1016/j.joule.2025.102263

Guanlin Wang (王冠霖) , Yong Cui (崔勇) , Miaoning Ou (欧妙宁) , Yue Yu (于跃) , Yang Xiao (肖扬) , Haoyu Yuan (原昊昱) , Tao Zhang (张涛) , Zhihao Chen (陈志豪) , Ni Yang (杨霓) , Lijiao Ma (马丽姣) , Runnan Yu (于润楠) , Shaoqing Zhang (张少青) , Jianhui Hou (侯剑辉)

{"title":"Alcohol-dispersed conductive polymer for high-performance organic photovoltaic cells","authors":"Guanlin Wang (王冠霖) , Yong Cui (崔勇) , Miaoning Ou (欧妙宁) , Yue Yu (于跃) , Yang Xiao (肖扬) , Haoyu Yuan (原昊昱) , Tao Zhang (张涛) , Zhihao Chen (陈志豪) , Ni Yang (杨霓) , Lijiao Ma (马丽姣) , Runnan Yu (于润楠) , Shaoqing Zhang (张少青) , Jianhui Hou (侯剑辉)","doi":"10.1016/j.joule.2025.102263","DOIUrl":"10.1016/j.joule.2025.102263","url":null,"abstract":"<div><div>In high-efficiency organic photovoltaic cells, PEDOT:PSS is widely employed as a hole transport material. However, its aqueous nature limits compatibility with hydrophobic plastic substrates, scalable processing, and tandem architectures. Here, we report an isopropanol-dispersed PEDOT-OH:PSS formulation designed by tailoring solute-solvent interactions. The resulting conductive polymer delivers doping stability and hole transport performance rivaling that of PEDOT:PSS, along with markedly improved wettability on flexible substrates. The efficiency of flexible modules based on PEDOT-OH:PSS achieves 15%. Moreover, the weak proton dissociation of PSS in isopropanol greatly reduces acidity, minimizing zinc oxide (ZnO) breakdown and enabling a high-quality interconnecting layer in conventional tandem cells. The high optical transparency and electrical conductivity of PEDOT-OH:PSS allow the tandem cells to reach a record efficiency of 21.7%. By addressing key interfacial and processing limitations, this work establishes a scalable and high-performance alternative to aqueous PEDOT:PSS.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102263"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146048639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in non/low-crystalline solid-state electrolytes enabled by halide-based electrolytes 由卤化物基电解质实现的非/低晶固态电解质的进展

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-27 DOI: 10.1016/j.joule.2025.102260

Jie Qu , Han Wu , Xingyu Wang , Simeng Zhang , Junyi Yue , Chong Liu , Jianwen Liang , Xueliang Sun , Xiaona Li

{"title":"Advances in non/low-crystalline solid-state electrolytes enabled by halide-based electrolytes","authors":"Jie Qu , Han Wu , Xingyu Wang , Simeng Zhang , Junyi Yue , Chong Liu , Jianwen Liang , Xueliang Sun , Xiaona Li","doi":"10.1016/j.joule.2025.102260","DOIUrl":"10.1016/j.joule.2025.102260","url":null,"abstract":"<div><div>The debate over whether crystalline solid-state electrolytes (CSSEs) or non-crystalline solid-state electrolytes (NSSEs) offer better performance in all-solid-state batteries (ASSBs) has long been a controversial topic. Although NSSEs are known for their better deformability, most CSSEs, especially sulfide- and oxide-based SSEs, exhibit much higher ionic conductivities than their non-crystalline counterparts. Recently, research on NSSEs has regained interest due to the finding of a series of non/low-crystalline halide SSEs (NCHSSEs) with superionic ionic conduction behavior. This review highlights the recent advances in NCHSSEs concerning their local structures, design principles, and ionic conduction mechanisms, intending to provide a deeper understanding of the local chemistry-property-performance relationships and insight into the future design of NCHSSEs. Furthermore, their synthetic routes, mechanical properties, and applications in ASSBs are summarized. Last, the main challenges and future research directions are outlined to guide in progressing the application of NCHSSEs from laboratory research to the industrial field.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102260"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

What can we learn from US national transmission studies? 我们能从美国国家传播研究中学到什么？

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-02-10 DOI: 10.1016/j.joule.2026.102339

Trieu Mai , Patrick R. Brown , David Palchak , Gregory Brinkman , Adria Brooks , Paul Denholm , Rob Gramlich , Juliet S. Homer , Debra Lew , Jess Kuna , James Okullo , Johannes Pfeifenberger , Amy Rose , Christina Simeone , Jarrad Wright

{"title":"What can we learn from US national transmission studies?","authors":"Trieu Mai , Patrick R. Brown , David Palchak , Gregory Brinkman , Adria Brooks , Paul Denholm , Rob Gramlich , Juliet S. Homer , Debra Lew , Jess Kuna , James Okullo , Johannes Pfeifenberger , Amy Rose , Christina Simeone , Jarrad Wright","doi":"10.1016/j.joule.2026.102339","DOIUrl":"10.1016/j.joule.2026.102339","url":null,"abstract":"<div><div>Multiple US regions have announced new electricity transmission plans, are actively revisiting the future role of transmission, and could benefit from findings from recent national-scale transmission studies. A review of seven national studies shows that significant transmission expansion is cost-optimal for serving new demand, integrating additional resources, and supporting grid reliability. A majority of the reviewed scenarios, which span a range of policy and technology assumptions, include at least a doubling of the transmission system by 2050. The national studies find substantial net system cost savings from transmission expansion and high benefit-cost ratios for transmission investments. The results are derived through multi-value, nationally coordinated, co-optimized, multi-scenario modeling, which is an approach that could yield lower-cost pathways compared to current industry planning practices.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102339"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146153243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Machine learning-driven interface material design for high-performance perovskite solar cells with scalability and band-gap universality 具有可扩展性和带隙通用性的高性能钙钛矿太阳能电池的机器学习驱动界面材料设计

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2025-12-23 DOI: 10.1016/j.joule.2025.102264

Chenyang Zhang , Yuteng Jia , Bingqian Zhang , Qiangqiang Zhao , Ruida Xu , Shuping Pang , Han Wang , Stefaan De Wolf , Kai Wang

{"title":"Machine learning-driven interface material design for high-performance perovskite solar cells with scalability and band-gap universality","authors":"Chenyang Zhang , Yuteng Jia , Bingqian Zhang , Qiangqiang Zhao , Ruida Xu , Shuping Pang , Han Wang , Stefaan De Wolf , Kai Wang","doi":"10.1016/j.joule.2025.102264","DOIUrl":"10.1016/j.joule.2025.102264","url":null,"abstract":"<div><div>Perovskite solar cells’ performance is critically governed by interfacial chemistry. Here, we combine correlation analysis, hierarchical clustering, and least absolute shrinkage and selection operator (LASSO) regression to optimize feature engineering, followed by employing LASSO and elastic net (ENET) regression to develop a screening model. A multifunctional buried interface molecule, (2-(1,3-dioxo-1<em>H</em>-benzo[<em>de</em>]isoquinolin-2(3H)-yl)ethyl)phosphonic acid (BIPA), was successfully screened and synthesized. As expected, BIPA binds strongly with SnO<sub>2</sub> through Sn···O–P coordination, effectively passivating Sn<sup>2+</sup> dangling bonds and oxygen vacancies. The Fermi level was shifted upward, facilitating electron extraction. Besides, BIPA modulated crystallization dynamics and alleviated compressive strain through C=O···Pb interaction, enabling the growth of dense perovskite films. Consequently, the BIPA-modified device achieved an efficiency of 26.3%. Varied band-gap performance improvements (23.2% for 1.67 eV and 18.5% for 1.85 eV) further underscored the universality of this approach. Unencapsulated devices retained 91% and 92% of their initial efficiency after 1,600 h of International Summit on Organic Photovoltaic Stability (ISOS-L-1) protocol and 2,000 h of ISOS-D-2 protocol, respectively.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102264"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145813601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Competitive anion coordination overcomes charge-transfer barriers for lithium–sulfur batteries 竞争阴离子配位克服了锂硫电池的电荷转移障碍

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-23 DOI: 10.1016/j.joule.2025.102259

Xi-Yao Li , Bo-Quan Li , Tian Jin , Shuai Feng , Yu-Chen Gao , Meng Zhao , Xiang Chen , Jia-Qi Huang , Qiang Zhang

{"title":"Competitive anion coordination overcomes charge-transfer barriers for lithium–sulfur batteries","authors":"Xi-Yao Li , Bo-Quan Li , Tian Jin , Shuai Feng , Yu-Chen Gao , Meng Zhao , Xiang Chen , Jia-Qi Huang , Qiang Zhang","doi":"10.1016/j.joule.2025.102259","DOIUrl":"10.1016/j.joule.2025.102259","url":null,"abstract":"<div><div>Beyond ionic conduction and solid-electrolyte interphase formation, the fundamental roles of lithium salt anions in batteries remain unexplored. Herein, an anion-induced competitive solvation mechanism that governs lithium polysulfide (LiPS) behaviors in high-energy-density lithium–sulfur batteries is pioneeringly unveiled. Specifically, anions contend against weakly solvating solvents to occupy the LiPS inner solvation shell. Enhancing anion coordination while diminishing weakly solvating solvent coordination overcomes the rate-determining LiPS charge-transfer barriers. As a proof of concept, bis(fluorosulfonyl)imide anion coordination reduces activation polarization and boosts cycling stability at high current densities. Ah-level pouch cells achieve stable operation at high rates of 0.35 C and deliver a record-setting energy density of 622 Wh kg<sup>−1</sup> (based on total weight) with stable cycling. By elucidating the anion-induced competitive solvation mechanism, our work transcends conventional views of anion roles and establishes a new paradigm for advancing practical Li–S batteries.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102259"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146021979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-voltage sulfur electrochemistry enabled by copper-ion mediation in non-aqueous batteries 在非水电池中通过铜离子介质实现高压硫电化学

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-28 DOI: 10.1016/j.joule.2025.102268

Yu Ding (丁钰) , Chunlong Dai (代春龙) , Fei Wang (王飞) , Zhaohui Li (李兆晖) , Haichuan Zhou (周海川) , Zongbin Luo (罗宗斌) , Maowen Xu (徐茂文) , Linyu Hu (胡琳钰) , Zifeng Lin (林紫锋)

{"title":"High-voltage sulfur electrochemistry enabled by copper-ion mediation in non-aqueous batteries","authors":"Yu Ding (丁钰) , Chunlong Dai (代春龙) , Fei Wang (王飞) , Zhaohui Li (李兆晖) , Haichuan Zhou (周海川) , Zongbin Luo (罗宗斌) , Maowen Xu (徐茂文) , Linyu Hu (胡琳钰) , Zifeng Lin (林紫锋)","doi":"10.1016/j.joule.2025.102268","DOIUrl":"10.1016/j.joule.2025.102268","url":null,"abstract":"<div><div>Conventional lithium-sulfur (Li-S) batteries, which rely on alkali metal ions (Li⁺/Na⁺/K⁺) as charge carriers, suffer from polysulfide dissolution, poor Li<sub>2</sub>S conductivity, and low redox potential (−0.5 V vs. the standard hydrogen electrode [SHE]). Here, we report a copper-ion-mediated sulfur battery chemistry that fundamentally circumvents these limitations by leveraging the intrinsically low solubility of Cu<sub><em>x</em></sub>S in non-aqueous electrolytes. By replacing alkali metal ions with copper ions as the charge carrier in a 1,3-dioxolane/1,2-dimethoxyethane (DOL/DME)-based electrolyte, we achieve an insoluble Cu<sub><em>x</em></sub>S discharge intermediate, which elevates the sulfur redox potential to 0.5 V vs. SHE, more than a 1.2 V increase over conventional Li-S systems, enabling a discharge voltage of 3.3 V in a hybrid Li-S full cell. Simultaneously, the formation of conductive Cu<em>ₓ</em>S species ensures efficient reaction kinetics while eliminating polysulfide shuttling. The copper-ion-mediated sulfur electrochemistry unlocks high energy density and fast kinetics, paving the way for practical sulfur-based batteries.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102268"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146070615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Work of adhesion guided nucleation control for energy-dense potassium metal batteries 高能量金属钾电池黏附引导成核控制的研究

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-27 DOI: 10.1016/j.joule.2025.102266

Yupei Han (韩玉培) , Adam Lovett , Neubi Xavier , Matthew Blunt , Pan He , Ajay Piriya Vijaya Kumar Saroja , Wanjun Ren , Yi Lu , Yudong Luo , Thomas S. Miller , Qiong Cai , Yang Xu (徐杨)

{"title":"Work of adhesion guided nucleation control for energy-dense potassium metal batteries","authors":"Yupei Han (韩玉培) , Adam Lovett , Neubi Xavier , Matthew Blunt , Pan He , Ajay Piriya Vijaya Kumar Saroja , Wanjun Ren , Yi Lu , Yudong Luo , Thomas S. Miller , Qiong Cai , Yang Xu (徐杨)","doi":"10.1016/j.joule.2025.102266","DOIUrl":"10.1016/j.joule.2025.102266","url":null,"abstract":"<div><div>Dendrite suppression remains a key obstacle to practical alkali metal batteries. Conventional substrate engineering emphasizes surface energy to promote uniform nucleation, yet we show that surface energy alone cannot predict or control potassium nucleation, as revealed by comparative studies on gold and copper substrates. Revisiting heterogeneous nucleation theory, we propose the work of adhesion (<em>W</em><sub><em>adh</em></sub>) at the nucleus-substrate interface as the key thermodynamic descriptor governing potassium nucleation. Enhancing effective <em>W</em><sub><em>adh</em></sub> through substrate nanotexturing lowers the nucleation barrier and achieves uniform potassium deposition. This <em>W</em><sub><em>adh</em></sub>-guided strategy effectively suppresses dendrite formation, stabilizes plating/stripping, and markedly improves electrochemical performance. Perylenetetracarboxylic dianhydride (PTCDA, 20 mg cm<sup>−2</sup>)||K full cells with an areal capacity of 2.7 mAh cm<sup>−2</sup> deliver >99.9% Coulombic efficiency and 91.1% capacity retention over 680 cycles (0.013% per-cycle fade) under lean electrolyte (3.58 mL <span><math><mrow><msubsup><mi>g</mi><mtext>PTCDA</mtext><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></mrow></math></span>). Potassium manganese hexacyanoferrate (K<sub>1.97</sub>Mn[Fe(CN)<sub>6</sub>])||K cells also exhibit substantial performance gains, providing a viable route toward dendrite-free alkali metal batteries.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102266"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microenvironment engineering within diffusion layer in electrocatalysis 电催化扩散层微环境工程

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-02-06 DOI: 10.1016/j.joule.2025.102307

Wuyong Zhang , Li Yi , Zhiyi Lu

引用次数: 0

Global land and solar energy relationships for sustainability 可持续发展的全球土地和太阳能关系

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2025-12-31 DOI: 10.1016/j.joule.2025.102236

Xiao Li , Rebecca R. Hernandez , Alona Armstrong , Pan Liu , Sarah M. Jordaan

{"title":"Global land and solar energy relationships for sustainability","authors":"Xiao Li , Rebecca R. Hernandez , Alona Armstrong , Pan Liu , Sarah M. Jordaan","doi":"10.1016/j.joule.2025.102236","DOIUrl":"10.1016/j.joule.2025.102236","url":null,"abstract":"<div><div>Global energy transitions with high growth in solar photovoltaics must consider land consequences and economics to align with sustainability goals. We quantify a capacity-weighted average value of land-use efficiency (LUE) as 57 (37–62, 25<sup>th</sup>–75<sup>th</sup> percentile) W/m<sup>2</sup>, and lifetime land transformation (LT<sub>L</sub>) as 409 (300–537) m<sup>2</sup>/GWh for all large, ground-mounted photovoltaic (G-PV) plants globally. Asia Pacific had a 15% higher LUE (and a 21% lower LT) compared with other regions. High growth in solar is anticipated to impact only 0.1%–0.2% of the global land mass by 2050. Results inform comparisons of levelized costs and capital expenditures of rooftop (land-sparing) vs. large, ground-mounted (land-intensive) PV solar energy buildouts by country and region. Substituting land-intensive with land-sparing PV buildouts is most expensive in the United States ($950–1,030/kW by 2050) and cheapest in Brazil ($−70 – −60/kW, by 2050). Results point to the need to determine economic implications of global land-sparing opportunities and enact policies to support local implementation.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102236"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145895734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A novel approach for direct lithium extraction from alkali metal cations in brine mixtures using thermally switchable solvents 利用热切换溶剂从盐水混合物中的碱金属阳离子中直接提取锂的新方法

IF 35.4 1区材料科学

Joule Pub Date : 2026-02-18 Epub Date: 2026-01-21 DOI: 10.1016/j.joule.2025.102265

Elizabeth Dach , Juliana Marston , Sara Abu-Obaid , Allison Peng , Ngai Yin Yip

{"title":"A novel approach for direct lithium extraction from alkali metal cations in brine mixtures using thermally switchable solvents","authors":"Elizabeth Dach , Juliana Marston , Sara Abu-Obaid , Allison Peng , Ngai Yin Yip","doi":"10.1016/j.joule.2025.102265","DOIUrl":"10.1016/j.joule.2025.102265","url":null,"abstract":"<div><div>This study presents a proof-of-concept for switchable solvent selective extraction (S<sup>3</sup>E) for direct lithium extraction from brines. S<sup>3</sup>E utilizes an amine solvent with thermally switchable hydrophilicity to extract Li<sup>+</sup> and water from the brine, and a modest temperature swing toggles the solvent to its hydrophobic state, releasing a purified lithium product stream and regenerating the solvent. S<sup>3</sup>E demonstrated a consistent preference for lithium across amines with different chemical structures, achieving Li<sup>+</sup>/Na<sup>+</sup> selectivities as high as ≈10. The selectivity for lithium was maintained even when challenged with Li<sup>+</sup> concentrations 1,000× lower than Na<sup>+</sup> or K<sup>+</sup>, whereas Li<sup>+</sup>/Na<sup>+</sup> and Li<sup>+</sup>/K<sup>+</sup> selectivities for a simulated Salton Sea geothermal brine are ≈13 and ≈24, respectively, with magnesium completely removed as Mg(OH)<sub>2</sub> precipitates due to the basicity of the amine solvent. Furthermore, repeated semibatch extraction cycles reusing the solvent demonstrated practical Li<sup>+</sup> recovery yields (40% after four cycles) and solvent regenerability while preserving selectivity.</div></div>","PeriodicalId":343,"journal":{"name":"Joule","volume":"10 2","pages":"Article 102265"},"PeriodicalIF":35.4,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146014742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

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