Case Studies in Chemical and Environmental Engineering最新文献

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Sustainable development versus urban sprawl: A Landsat imagery analysis of ecological impact in Savar Upazila, 2011–2022 可持续发展与城市扩张:2011-2022 年萨瓦乌帕兹拉生态影响的陆地卫星图像分析
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-22 DOI: 10.1016/j.cscee.2024.100819
Taslima Akter Sathe, Syed Hafizur Rahman
{"title":"Sustainable development versus urban sprawl: A Landsat imagery analysis of ecological impact in Savar Upazila, 2011–2022","authors":"Taslima Akter Sathe,&nbsp;Syed Hafizur Rahman","doi":"10.1016/j.cscee.2024.100819","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100819","url":null,"abstract":"<div><p>This study investigates the ecological impacts of urban expansion in Savar Upazila, adjacent to Dhaka City, from 2011 to 2022. Utilizing Landsat (Level 2) imagery and the Time-weighted Dynamic Time Warping (TWDTW) classification method, the research assesses urban sprawl with high accuracy (98.87%, 96.01%, and 96.53% for 2011, 2015, and 2022, respectively). Urban expansion was predominantly through extension, with a 9.19% increase in urban areas. The study also calculates Urban Hotspot Zones (UHs) and the Urban Thermal Field Variance Index (UTFVI) from Land Surface Temperature (LST) data, highlighting the growth of urban hotspots. The Partial Least Squares Regression (PLSR) reveals that development type affects the Urban Heat Island effect and extension is the most determining factor for ecological change. A local level analysis reveals that nearly all unions, except Shimulia and Pathalia, experienced a rise in areas with adverse ecological conditions, with Tetulihora, Amin Bazar, Ashulia, and nearby areas facing the most significant ecological deterioration due to urbanization (∼50%). The findings underscore a considerable decline in the region's ecological health due to urban expansion, urging policymakers to integrate stable ecological zones into urban planning for sustainable development.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100819"},"PeriodicalIF":0.0,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002135/pdfft?md5=c77d19c76e9367b7141f9285e361b51c&pid=1-s2.0-S2666016424002135-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141479115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valourization of using efficiency of filtration drying for alcohol distillery stillage 酒精酿造厂蒸馏物过滤干燥使用效率的评估
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-22 DOI: 10.1016/j.cscee.2024.100820
O.S. Ivashchuk, V.M. Atamanyuk, R.A. Chyzhovych
{"title":"Valourization of using efficiency of filtration drying for alcohol distillery stillage","authors":"O.S. Ivashchuk,&nbsp;V.M. Atamanyuk,&nbsp;R.A. Chyzhovych","doi":"10.1016/j.cscee.2024.100820","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100820","url":null,"abstract":"<div><p>The article presents the results of the calculation of specific energy consumption for the filtration drying process of corn alcohol distillery stillage. It was determined that the optimal total energy consumption for the evaporation of 1 kg of moisture during the filtration drying of corn alcohol distillery stillage from the initial moisture content of the material ω<sub>1</sub> = 72.78 % wt. to the final value ω<sub>2</sub> = 14 % wt. is 9468.96 kJ/kg H<sub>2</sub>O or 2.63 kW h/kg H<sub>2</sub>O for the following process parameters: the height of the layer of dried material H = 120 mm, the thermal agent temperature T = 90 °C, the thermal agent velocity v<sub>0</sub> = 1.76 m/sec. Based on the selected optimal parameters of the filtration drying process of corn alcohol distillery stillage at the experimental installation, an evaluation calculation of the efficiency of filtration drying in industrial conditions was made. The total amount of energy required to dry ⁓ 1000 kg of corn alcohol distillery stillage in the filtration drying installation is approximately 1923.91 kW h. The total energy consumption for the removal of 1 kg of moisture during the test material drying at an industrial filtration drying installation is approximately 2.64 kW h/kg H<sub>2</sub>O. To compare the effectiveness of the filtration method of drying for corn alcohol distillery stillage, it was calculated for drying under a similar technical task in a rotary dryer. During the drying of 1000 kg of corn alcohol distillery stillage, a total of approximately 2146.91 kW h of energy is required, and the total energy consumption for removing 1 kg of moisture during the corn alcohol distillery stillage drying in a rotary dryer is approximately 3.13 kW h/kg H<sub>2</sub>O. It was calculated that the use of the filtration drying method makes it possible to reduce the specific energy consumption for removing 1 kg of moisture by 15.65 % with the required amount of thermal agent compared to drying in a rotary dryer. The use of filtration drying in industry would have a higher economic effect, given the higher heat losses in a rotary dryer to the environment and the need for energy-intensive auxiliary equipment for rotary dryers.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100820"},"PeriodicalIF":0.0,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002147/pdfft?md5=f6f2bc4f6c2f81cacf0e9adb72465a84&pid=1-s2.0-S2666016424002147-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A case study on functional polymer modification of cacao husk for enhanced removal of nitrate and phosphate from vinasse waste 关于对可可壳进行功能性聚合物改性以增强从蔗渣废料中去除硝酸盐和磷酸盐的案例研究
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-22 DOI: 10.1016/j.cscee.2024.100814
Nur Aini , Aster Rahayu , Siti Jamilatun , Ilham Mufandi
{"title":"A case study on functional polymer modification of cacao husk for enhanced removal of nitrate and phosphate from vinasse waste","authors":"Nur Aini ,&nbsp;Aster Rahayu ,&nbsp;Siti Jamilatun ,&nbsp;Ilham Mufandi","doi":"10.1016/j.cscee.2024.100814","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100814","url":null,"abstract":"<div><p>Cacao husk (CH) is a waste product from Indonesian cacao cultivation and holds potential as an adsorbent. In this study CH was modified using 2-[(methacryloyloxy)ethyl]trimethylammonium chloride (META) for removing nitrate and phosphate ions. The applicability of various adsorption isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich (D-R), and Temkin) was explored, and the chemical structure changes were characterized. The results demonstrate that CH-T-META effectively adsorbs nitrates and phosphates from vinasse waste. The Langmuir isotherm model described the adsorption process excellently, suggesting monolayer adsorption. Fourier-transform infrared spectroscopy (FTIR) analysis revealed the presence of <em>O</em>–H/N–H and C<img>O bonds after vinasse adsorption, indicating potential interaction mechanisms. Additionally, scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses confirmed structural modifications on the CH-T-META surface. Furthermore, CH-T-META exhibited increased H, C, and N content compared to unmodified CH-T-META. Significantly, CH-T-META achieved a removal efficiency (<em>Re</em>) of approximately 93.4 % for nitrates and 96 % for phosphates. These findings strongly support the effectiveness of META modification in enhancing the adsorption capacity of CH for nitrate and phosphate removal from vinasse waste.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100814"},"PeriodicalIF":0.0,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002081/pdfft?md5=31b77cfd1d7a824f5e56781dc1d1a28f&pid=1-s2.0-S2666016424002081-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reverse logistics toward a circular economy: Consumer behavioral intention toward polyethylene terephthalate (PET) recycling in Indonesia 实现循环经济的逆向物流:印度尼西亚消费者的聚对苯二甲酸乙二酯(PET)回收行为意向
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-22 DOI: 10.1016/j.cscee.2024.100807
Yuniar Farida , Nurhadi Siswanto , Iwan Vanany
{"title":"Reverse logistics toward a circular economy: Consumer behavioral intention toward polyethylene terephthalate (PET) recycling in Indonesia","authors":"Yuniar Farida ,&nbsp;Nurhadi Siswanto ,&nbsp;Iwan Vanany","doi":"10.1016/j.cscee.2024.100807","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100807","url":null,"abstract":"<div><p>Indonesia has the second-highest level of ocean plastic pollution. Polyethylene terephthalate (PET) plastic, used in food and beverage packaging, is the most accessible plastic for recycling. Recycling PET plastic waste can address the issue of waste management and support a circular economy, while protecting the environment. However, consumer participation is crucial for maintaining recycling programs. In this study, we determined the driving forces of customer participation with respect to post-consumption PET waste. The Theory of Planned Behavior (TPB) was used to understand the factors that motivate the consumers’ recycling intentions. We conducted a survey to assess the post-consumption behavior related to PET usage (with 294 respondents), using a questionnaire; to analyze the survey results, we used a structural equation model with partial least squares (SEM-PLS). The attitudes, moral norms, and consequence awareness of the consumers significantly affected their recycling intentions. Perceived behavior and subjective norms did not affect this desire. In Indonesia, consumer behavior after PET consumption primarily involves disposal. This study improves the understanding of consumer behavior and can help businesses and governments to implement strategies that encourage consumers to return used PET goods. In addition, this study enriches the literature on reverse logistics from a consumer perspective.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100807"},"PeriodicalIF":0.0,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002019/pdfft?md5=aed5d1161cd232c15f4c52c330ba3a4a&pid=1-s2.0-S2666016424002019-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141479137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning the electrochemical potential window of Niobium carbide based electrodes for symmetric electrochemical supercapacitors 为对称电化学超级电容器调谐碳化铌基电极的电化学电位窗口
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-21 DOI: 10.1016/j.cscee.2024.100812
SyamSai Ravuri , Amani Al-Othman , Sameer Al-Asheh , Paul Nancarrow , Karnail Singh , Mohammad Al-Sayah
{"title":"Tuning the electrochemical potential window of Niobium carbide based electrodes for symmetric electrochemical supercapacitors","authors":"SyamSai Ravuri ,&nbsp;Amani Al-Othman ,&nbsp;Sameer Al-Asheh ,&nbsp;Paul Nancarrow ,&nbsp;Karnail Singh ,&nbsp;Mohammad Al-Sayah","doi":"10.1016/j.cscee.2024.100812","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100812","url":null,"abstract":"<div><p>The electrochemical potential window for nano-sized Niobium carbide (NbC) based electrodes for supercapacitive energy storage applications was investigated. The nano-size NbC electrodes were fabricated and supported on carbon cloth (<span>CC</span>). The NbC@CC materials were assembled into a symmetric supercapacitor with a 1 M sulfuric acid (H<sub>2</sub>SO<sub>4</sub>) as an electrolyte. The properties of the symmetric supercapacitor were evaluated for their electrochemical behavior, surface properties and morphology. The results showed that the nano-size NbC material was uniformly coated on the surface of CC. The electrochemical performance of the fabricated symmetric supercapacitor was evaluated in the range from -2V to + 2V and showed that the currents were spiked. To further understand the electrochemical behavior, the potentials were systematically reduced to +0.8V and evaluated. The charging-discharging behavior was studied systematically with the aim of avoiding the overestimation of the electrode performance. The specific capacitance was estimated to be around 27 F/g at the reduced potential window. Overall, this work presents a selection of the right potential window for the testing of the NbC based supercapacitor in such a way that avoids the overestimation of the potential window.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100812"},"PeriodicalIF":0.0,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002068/pdfft?md5=cc4e5fffe2d07cffa75f8c69deef5563&pid=1-s2.0-S2666016424002068-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141444353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enrichment of al, fe, ca, mg, and Na in the ash released from the Assiut Thermal Power Plant, Egypt 埃及阿苏特热电厂排放的灰烬中 al、fe、ca、mg 和 Na 的富集情况
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-21 DOI: 10.1016/j.cscee.2024.100815
Mahmoud Bady , Hassanien M. Hassanien , Asim Laeeq Khan
{"title":"Enrichment of al, fe, ca, mg, and Na in the ash released from the Assiut Thermal Power Plant, Egypt","authors":"Mahmoud Bady ,&nbsp;Hassanien M. Hassanien ,&nbsp;Asim Laeeq Khan","doi":"10.1016/j.cscee.2024.100815","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100815","url":null,"abstract":"<div><p>This study provides a comprehensive analysis of the ash content resulting from the combustion of heavy fuel oil (HFO) at the Assiut Thermal Power Plant in Egypt, with a specific focus on the enrichment of trace metals and their environmental implications. We meticulously quantified the concentrations of Na, K, Mg, Fe, Ca, and Al in both HFO and the resultant ash. The calculated pollution indices, such as the Single Element Pollution Index (SEPI), Combined Pollution Index (CPI), and Pollution Load Index (PLI), reveal the severe environmental impact. The SEPI values for metals in ash ranged from 384.62 for Al to 34,000 for K, indicating a high contamination level. The CPI was 12,373.4, signifying a severe metal accumulation, while the PLI was 655.1, reflecting a significant pollution load. These findings underscore the urgent need for immediate and effective pollution control measures and sustainable waste management practices. The results provide a foundation for future research on advanced pollution control technologies and the long-term environmental impacts of trace metal accumulation, contributing to the development of improved environmental management strategies.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100815"},"PeriodicalIF":0.0,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002093/pdfft?md5=e480ab11eee23e2f0bf2e383e1ee9ce5&pid=1-s2.0-S2666016424002093-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141479138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of mesoporous silica nanoparticles (MSNs) and its application on degradation of triclosan 介孔二氧化硅纳米粒子(MSNs)的绿色合成及其在三氯生降解中的应用
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-21 DOI: 10.1016/j.cscee.2024.100818
E Babu Vamsi, C.P. Devatha
{"title":"Green synthesis of mesoporous silica nanoparticles (MSNs) and its application on degradation of triclosan","authors":"E Babu Vamsi,&nbsp;C.P. Devatha","doi":"10.1016/j.cscee.2024.100818","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100818","url":null,"abstract":"<div><p>The widespread use of triclosan (TCS) across the globe poses a substantial threat to both human well-being and the ecosystem. This necessitates the development of eco-friendly adsorption techniques to address triclosan contamination in wastewater. This research aims to develop novel eco-friendly synthesis method using <em>Syzygium jambos</em> (SJ) leaf extract to produce small-sized Mesoporous Silica Nanoparticles (MSNs) by varying surfactant to silica ratio. Different ratios such as 1:50, 1:100, and 1:200 (1 mL of tetraethyl orthosilicate (TEOS) is equivalent to cetyltrimethylammonium bromide (CTAB) in mg) were explored without chemical stabilising agents or alcohol diluents. The synthesized materials were named as MSN1, MSN2, and MSN3. Characterisation studies using Field emission scanning electron microscopy (FE-SEM) showed that MSN3 exhibited smallest size of 30 ± 5nm. The physical, chemical and morphological properties were analysed for the materials using X-Ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDS), Zeta potential (ZP), Brunauer-Emmett-Teller (BET), Thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR). Notably, the developed nanomaterial demonstrated noteworthy stability with a ZP of −33.1 mV and an impressive surface area of 545 m<sup>2</sup>/g. FT-IR peaks of biosorbent were obtained at 460, 800, and 975 1/cm. This confirms the existence of (Si–<em>O</em>–Si) bonds. The XRD results reveals that it possess amorphous nature of silica without any impurities. N<sub>2</sub> adsorption-desorption studies yielded a pore radius of 16.8 Å and volume of pores are 0.890 cc/g indicating its potential as an adsorbent and its utility for material functionalisation. The developed biosorbent exhibited enhanced adsorption properties for removal of triclosan from synthetic wastewater with 76 % removal at 0.5g/L dose of adsorbent.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100818"},"PeriodicalIF":0.0,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002123/pdfft?md5=cd2cb8febc80d74436b594a96be433e7&pid=1-s2.0-S2666016424002123-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance and fouling characteristics of direct contact membrane distillation applied to raw and membrane bioreactor-treated landfill leachate 直接接触膜蒸馏应用于未经处理和经膜生物反应器处理的垃圾填埋场渗滤液的性能和污垢特征
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-19 DOI: 10.1016/j.cscee.2024.100813
Samunya Sanguanpak , Pawinee Milintawisamai , Wilai Chiemchaisri , Chart Chiemchaisri
{"title":"Performance and fouling characteristics of direct contact membrane distillation applied to raw and membrane bioreactor-treated landfill leachate","authors":"Samunya Sanguanpak ,&nbsp;Pawinee Milintawisamai ,&nbsp;Wilai Chiemchaisri ,&nbsp;Chart Chiemchaisri","doi":"10.1016/j.cscee.2024.100813","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100813","url":null,"abstract":"<div><p>Direct contact membrane distillation (DCMD) was applied to the treatment of raw and membrane bioreactor (MBR)-treated municipal landfill leachate. The experiments were conducted using feed side temperatures of 50, 60, and 70<sup>o</sup>C while permeate side temperature was controlled at 10<sup>o</sup>C. The effects of organic matter, solid particles, and salinity presented in raw leachate and MBR permeate on the DCMD flux and pollutant rejection efficiencies were investigated. Moreover, fouling and wetting of the MD membrane were examined. The experimental results revealed that the application of DCMD to MBR permeate yielded higher fluxes than those of raw leachate but its higher flux decline was also observed due to the formation of denser foulant layer on the MD membrane surface. High organic carbon and salt rejection efficiencies (&gt;90 %) were achieved and maintained in DCMD treating MBR permeate. Significant deterioration of organic rejection efficiencies was observed in DCMD treating raw leachate at higher feed temperature (70<sup>o</sup>C) and increasing pollutant concentrations during closed-loop operation. Partial volatilization of volatile fatty acids from the feed side and their penetration through MD was also observed, being more severe at higher feed temperatures. The best condition for the operation of the system was found at 50<sup>o</sup>C using MBR permeate as feed water at which pollutant rejection efficiencies were highest while membrane wetting and fouling were also minimized.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100813"},"PeriodicalIF":0.0,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266601642400207X/pdfft?md5=4bc6b0df8ffae6d10a7521a66ff51506&pid=1-s2.0-S266601642400207X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141433985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Suppression capacity and environmental impact of three extinguishing agents for lithium-ion battery fires 三种锂离子电池灭火剂的灭火能力和环境影响
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-19 DOI: 10.1016/j.cscee.2024.100810
S. Ubaldi , C. Di Bari , M. Quinterno , A. De Rosa , M. Mazzaro , G. Ferrigno , D. Secci , P. Russo
{"title":"Suppression capacity and environmental impact of three extinguishing agents for lithium-ion battery fires","authors":"S. Ubaldi ,&nbsp;C. Di Bari ,&nbsp;M. Quinterno ,&nbsp;A. De Rosa ,&nbsp;M. Mazzaro ,&nbsp;G. Ferrigno ,&nbsp;D. Secci ,&nbsp;P. Russo","doi":"10.1016/j.cscee.2024.100810","DOIUrl":"https://doi.org/10.1016/j.cscee.2024.100810","url":null,"abstract":"<div><p>Fire suppression and rapid cooling methods are required to reduce the risk of battery fires. However, the liquid and solid residues generated during fire extinguishing pose a risk to the environment and human health. With the aim of correlating the extinguishing efficiency and environmental impact of the residues, fire tests were carried out on NMC lithium-ion pouch cells using different agents, namely water mist, F-500 water additive 2 % (v/v) and CO<sub>2</sub>. The combination of cell temperature measurements and videos allowed the efficiency of the extinguishing agents to be assessed. It was found that the efficiency of the water-based agents was higher than that of the gaseous agents (cooling rate of 30.5 ± 4.9 °C/s for water mist, 36.5 ± 6.4 °C/s for F-500 and 20.0 ± 1.4 °C/s for CO<sub>2</sub>). Analysis of solid and liquid residues using gas chromatography and induced coupled plasma showed that the use of F-500 resulted in a higher (one order of magnitude) concentration of VOCs in solid residues compared to the other extinguishing agents. The comparison of these concentrations of VOCs with the limits established for waste (EU Regulation N. 1357/2014) showed that the solid residues did not exceed the concentration limit for classification as hazardous waste. Regarding the concentration of metals, the highest values in the solid and liquid residues are due to Li, Ni and Cu. Based on these values, all solid samples can be classified as carcinogenic and toxic for reproduction. While the concentration of metals in the liquid residues was higher than the limit value that poses a risk to aquatic organisms. The overall results showed the need for site remediation and waste management procedures in the event of a major accident.</p></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"10 ","pages":"Article 100810"},"PeriodicalIF":0.0,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666016424002044/pdfft?md5=e5e1d1689ababadc0ef4ace5b40e32eb&pid=1-s2.0-S2666016424002044-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141478965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of banana peel-derived activated carbon for the removal of heavy metals from industrial wastewater 利用香蕉皮活性炭去除工业废水中的重金属
Case Studies in Chemical and Environmental Engineering Pub Date : 2024-06-19 DOI: 10.1016/j.cscee.2024.100791
Timoth Mkilima , Yerkebulan Zharkenov , Aisulu Abduova , Nursulu Sarypbekova , Nurlan Kudaibergenov , Kuandyk Sakanov , Gyulnara Zhukenova , Zhumabek Omarov , Parida Sultanbekova , Gulmira Kenzhaliyeva
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