Sri Suhartini , Novita Ainur Rohma , Andhika Putra Agus Pratama , Nimas Mayang Sabrina Sunyoto , Efri Mardawati , Kasbawati , Abdul Mudjib Sulaiman , Afifah Harmayanti , Femiana Gapsari
{"title":"Sustainable corrosion protection: Chitosan/reduced graphene oxide nanocomposite coating derived from palm oil empty fruit bunches on low carbon steel","authors":"Sri Suhartini , Novita Ainur Rohma , Andhika Putra Agus Pratama , Nimas Mayang Sabrina Sunyoto , Efri Mardawati , Kasbawati , Abdul Mudjib Sulaiman , Afifah Harmayanti , Femiana Gapsari","doi":"10.1016/j.cscee.2025.101116","DOIUrl":null,"url":null,"abstract":"<div><div>The growing demand for sustainable corrosion protection materials has prompted eco-friendly innovations. This study developed a chitosan/reduced graphene oxide (rGO) nanocomposite coating derived from empty fruit bunches (EFB) for corrosion protection on low carbon steel (LCS). Using a green oxidation-reduction process with KMnO₄ and ZnCl₂ under optimized conditions (temperature, stirring, pH), the rGO was successfully synthesized. The 90 % chitosan/10 % rGO coating achieved a high inhibition efficiency of 90.65 %, reducing corrosion rates by enhancing charge transfer resistance and creating a robust anti-corrosion barrier. This scalable, sustainable solution offers a cost-effective alternative for industrial corrosion protection.</div></div>","PeriodicalId":34388,"journal":{"name":"Case Studies in Chemical and Environmental Engineering","volume":"11 ","pages":"Article 101116"},"PeriodicalIF":0.0000,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Case Studies in Chemical and Environmental Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666016425000234","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
引用次数: 0
Abstract
The growing demand for sustainable corrosion protection materials has prompted eco-friendly innovations. This study developed a chitosan/reduced graphene oxide (rGO) nanocomposite coating derived from empty fruit bunches (EFB) for corrosion protection on low carbon steel (LCS). Using a green oxidation-reduction process with KMnO₄ and ZnCl₂ under optimized conditions (temperature, stirring, pH), the rGO was successfully synthesized. The 90 % chitosan/10 % rGO coating achieved a high inhibition efficiency of 90.65 %, reducing corrosion rates by enhancing charge transfer resistance and creating a robust anti-corrosion barrier. This scalable, sustainable solution offers a cost-effective alternative for industrial corrosion protection.