Intermetallics最新文献

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Influence of the Ti:Al:Cr proportion on the structure and oxidation resistance of ternary intermetallic coatings produced by non-vacuum electron beam cladding
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-15 DOI: 10.1016/j.intermet.2025.108745
D.V. Lazurenko , A.A. Ruktuev , Yu N. Malyutina , G.D. Dovzhenko , L. Song , N.S. Aleksandrova , E.A. Lozhkina , E.V. Domarov , A.V. Ukhina
{"title":"Influence of the Ti:Al:Cr proportion on the structure and oxidation resistance of ternary intermetallic coatings produced by non-vacuum electron beam cladding","authors":"D.V. Lazurenko ,&nbsp;A.A. Ruktuev ,&nbsp;Yu N. Malyutina ,&nbsp;G.D. Dovzhenko ,&nbsp;L. Song ,&nbsp;N.S. Aleksandrova ,&nbsp;E.A. Lozhkina ,&nbsp;E.V. Domarov ,&nbsp;A.V. Ukhina","doi":"10.1016/j.intermet.2025.108745","DOIUrl":"10.1016/j.intermet.2025.108745","url":null,"abstract":"<div><div>Titanium is known to be a material with poor oxidation resistance. When heated, it reacts with atmospheric gases, leading to the formation of the TiO<sub>2</sub> oxide film on its surface. This film does not protect the material against further oxidation. To solve this problem, heat-resistant coatings, including TiAl-based ones, are applied to titanium. This study investigates ternary Ti-Al-Cr surface layers with different concentrations of components. The protective layers were fabricated on titanium substrates by non-vacuum electron beam cladding. This method provides the formation of thick coatings (up to 2 mm in a single pass of the electron beam); however, the structure of the cladding layers can be significantly inhomogeneous. To reveal the influence of microstructural features of the coatings and the uneven elemental distribution on their oxidation behavior, detailed structural studies combined with the CALPHAD method were performed both before and after oxidation testing. It was found that an Al-rich alloy consisting primarily of the γ-phase provided the best protection against oxidation. The introduction of high concentrations of both Al and Cr yielded contradictory results. Although the L1<sub>2</sub>-and C14-phases formed in the coating are predicted to contribute to the development of a protective Al<sub>2</sub>O<sub>3</sub> film, the oxidation resistance of this cladding layer was comparable to that of titanium. This result can be attributed to the inhomogeneity of the coating and the appearance of the B2-phase in local areas of the coating at oxidation temperature and the decomposition of the Cr-depleted C14-phase. Furthermore, the Cr-rich B2-phase provides better oxidation resistance than the α<sub>2</sub>-phase of Al-lean cladding layers.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108745"},"PeriodicalIF":4.3,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143628415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Annealing-induced softening and metamagnetictransition control in MnFePSi microwires
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-14 DOI: 10.1016/j.intermet.2025.108742
Mohamed Salaheldeen , Valentina Zhukova , James Rosero , Daniel Salazar , Arcady Zhukov
{"title":"Annealing-induced softening and metamagnetictransition control in MnFePSi microwires","authors":"Mohamed Salaheldeen ,&nbsp;Valentina Zhukova ,&nbsp;James Rosero ,&nbsp;Daniel Salazar ,&nbsp;Arcady Zhukov","doi":"10.1016/j.intermet.2025.108742","DOIUrl":"10.1016/j.intermet.2025.108742","url":null,"abstract":"<div><div>The effect of high-temperature annealing on the magnetic, morphological, and microstructural properties of MnFePSi glass-coated microwires (GCMWs) and bulk sample is studied. A comparative analysis is conducted to elucidate the direct influence of annealing at 1373 K on their physical characteristics. Notably, significant differences in magneto-structural behavior are observed between as-prepared GCMWs and the bulk alloy. For the bulk sample, annealing promotes homogenization and a decrease in the average grain size from 24 μm to 2 μm, as confirmed by SEM and XRD analyses. In contrast, a broader grain size distribution in MnFePSi GCMWs, ranging from 0.8 μm to 40 nm compared to the as-prepared sample's with relatively uniform size of 36 nm is induced by annealing. Additionally, annealing enhances the Fe<sub>2</sub>P phase content in both samples. The annealing process significantly affects magnetic properties of MnFePSi GCMWs. A notable reduction in coercivity (<em>H</em><sub><em>c</em></sub>) is observed, with a decrease in <em>H</em><sub><em>c</em></sub> from 761 Oe (as-prepared) to <em>H</em><sub><em>c</em></sub> = 46 Oe (annealed), as evaluated from the hysteresis (M − H) loop measured at <em>T</em> = 5 K. The as-prepared MnFePSi-GCMWs exhibit a unique metamagnetic phase transition in M − H loops measured at various temperatures (200 K–5 K). Conversely, the annealed GCMWs display a more uniform metamagnetic transition in M − H loops measured at <em>T</em> = 20 K and 5 K. Furthermore, as-prepared GCMWs exhibit multistep magnetic M − H loops below 100 K, which is absent in the annealed samples. This study underlines the substantial effect of the annealing on MnFePSi-GCMWs, enabling the tailoring of magnetic phenomena, such as metamagnetic phase transition, multistep magnetic behavior, and the control of magnetic response (hardening/softening). These tailored properties can be exploited in a wide range of applications based on glass-coated microwires.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108742"},"PeriodicalIF":4.3,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143621096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and characterization of CoCrFeNi high entropy alloy composites reinforced by B4C ceramic particles
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-14 DOI: 10.1016/j.intermet.2025.108740
Aoxiang Li, Kaiwen Kang, Borui Zhang, Jinshan Zhang, Di Huang, Mingkun Xu, Saike Liu, Yiteng Jiang, Gong Li
{"title":"Development and characterization of CoCrFeNi high entropy alloy composites reinforced by B4C ceramic particles","authors":"Aoxiang Li,&nbsp;Kaiwen Kang,&nbsp;Borui Zhang,&nbsp;Jinshan Zhang,&nbsp;Di Huang,&nbsp;Mingkun Xu,&nbsp;Saike Liu,&nbsp;Yiteng Jiang,&nbsp;Gong Li","doi":"10.1016/j.intermet.2025.108740","DOIUrl":"10.1016/j.intermet.2025.108740","url":null,"abstract":"<div><div>To address the challenge of the low yield strength of single-phase FCC high-entropy alloys (HEAs), developing high-performance HEA composites has emerged as a promising strategy for enhancing the mechanical properties of HEAs. In this study, we propose a novel CoCrFeNi-based HEA composites incorporating a small amount of B<sub>4</sub>C ceramic particles. The influence of varying B<sub>4</sub>C ceramic particle content on the microstructure evolution and mechanical properties of CoCrFeNi(B<sub>4</sub>C)<sub>x</sub> HEAs was systematically investigated. Microstructure analysis reveals that increasing the B<sub>4</sub>C ceramic particles promoted the precipitation of M<sub>7</sub>C<sub>3</sub> carbides at grain boundaries, resulting in a dendritic microstructure. Mechanical testing demonstrated a significant improvement in yield strength and Vickers hardness, attributed to the synergistic strengthening of solution and precipitation strengthening. Furthermore, the microhardness of the M<sub>7</sub>C<sub>3</sub> carbides increased from 12.1 GPa to 15.5 GPa with higher B<sub>4</sub>C ceramic particle content, highlighting the contribution of these carbides to the overall hardness of the composite. This design strategy exploits the synergy between the metal matrix and ceramic reinforcements, improving mechanical performance and offering new possibilities for the development of advanced materials for demanding industrial applications.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108740"},"PeriodicalIF":4.3,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143621095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hot deformation induced microstructural evolution in Fe14Cr ODS alloy manufactured by selective laser melting
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-13 DOI: 10.1016/j.intermet.2025.108736
An Li , Qingchun Chen , Changqing Teng , Jianjun Mao , Xiaoyong Wu , Zhongqiang Fang , Xianggang Kong , Lu Wu , Jun Tang
{"title":"Hot deformation induced microstructural evolution in Fe14Cr ODS alloy manufactured by selective laser melting","authors":"An Li ,&nbsp;Qingchun Chen ,&nbsp;Changqing Teng ,&nbsp;Jianjun Mao ,&nbsp;Xiaoyong Wu ,&nbsp;Zhongqiang Fang ,&nbsp;Xianggang Kong ,&nbsp;Lu Wu ,&nbsp;Jun Tang","doi":"10.1016/j.intermet.2025.108736","DOIUrl":"10.1016/j.intermet.2025.108736","url":null,"abstract":"<div><div>Hot working, as an important post-treatment process in additive manufacturing (AM), can be used to reduce solidification defects, property anisotropy, grain refinement, and improve the applicability of AM technology. In this work, hot deformation tests were conducted on the preformed Fe14Cr oxide dispersion strengthened (ODS) parts, fabricated by selective laser melting (SLM), on the Gleeble-3800 simulator at temperatures ranging from 850 °C to 1150 °C. The microstructure evolution before and after deformation, the effects of deformation temperature on microstructure, and the stability of nanoparticles were analyzed. The results indicate that friction-induced stress distribution during hot compressive deformation leads to microstructural heterogeneity. The increase of deformation temperature promotes dynamic recrystallization (DRX) and reduces the nonuniform deformation. The relative position of oxide nanoparticles with respect to grain boundaries is primarily determined by grain migration and dissolution precipitation during hot deformation. The pinning effect of solute elements on crystal defects can inhibit dynamic recovery during high-temperature plastic deformation, thereby promoting recrystallization.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108736"},"PeriodicalIF":4.3,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanosynthesis formation study and electrical resistivity of short milled Fe50Mn35Sn15 Heusler intermetallic compound
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-13 DOI: 10.1016/j.intermet.2025.108738
Florin Popa , Traian Florin Marinca , Niculina Argentina Sechel , Horea Florin Chicinaș , Dan Ioan Frunză , Ionel Chicinaș
{"title":"Mechanosynthesis formation study and electrical resistivity of short milled Fe50Mn35Sn15 Heusler intermetallic compound","authors":"Florin Popa ,&nbsp;Traian Florin Marinca ,&nbsp;Niculina Argentina Sechel ,&nbsp;Horea Florin Chicinaș ,&nbsp;Dan Ioan Frunză ,&nbsp;Ionel Chicinaș","doi":"10.1016/j.intermet.2025.108738","DOIUrl":"10.1016/j.intermet.2025.108738","url":null,"abstract":"<div><div>Although the Heusler alloys are usually obtained by arc melting, in this study we choose to investigate the formation of the off stoichiometric Fe<sub>50</sub>Mn<sub>35</sub>Sn<sub>15</sub> (at. %) Heusler alloy by mechanical alloying using elemental powders as raw materials. The mechanical alloying was conducted in high-purity argon gas up to 30 h, using a planetary ball mill. The formation by mechanical alloying can be described as complex one, with the formation of the A<sub>2</sub> disordered Heusler phase as the majority phase after 15 h of milling. Milling the alloy up to 30 h, led to Heusler phase decomposition. The phase formation and obtained quantities were analysed using the Rietveld method applied to the recorded X-ray diffraction patterns. Evolution of the mean crystalline size and lattice strain versus milling time were computed. After 30 h of milling, the mean crystallite size of the milled alloy reached a value of 50 nm. The morphology and element distribution were analysed by scanning electron microscopy and energy dispersive X-ray spectroscopy. Particle size distribution showed important changes upon elements reaction, as the elements react, the median particle size (D50) decreases up to 3.5 μm and further increases at 5 μm as the main phase is the A<sub>2</sub> Heusler phase. The electrical resistivity was investigated, and an evolution with phase formation was found, as the electrical resistivity increased up 5.83mΩm at 10 h where an equilibrium between initial elements and Ni2MnSn Heusler phase is found, followed by a sharp decrease up to 2.8 mΩm for 30 h of milling as the Heusler phase is the main phase.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108738"},"PeriodicalIF":4.3,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical properties of novel 3D printing 316L stainless steel honeycomb structure reinforced aluminum matrix composites
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-13 DOI: 10.1016/j.intermet.2025.108743
Chengjian Wang , Cheng Wang , Zhenhua Li , Yuanhuai He , Zhijun Zhang , Yingying Zhang
{"title":"Mechanical properties of novel 3D printing 316L stainless steel honeycomb structure reinforced aluminum matrix composites","authors":"Chengjian Wang ,&nbsp;Cheng Wang ,&nbsp;Zhenhua Li ,&nbsp;Yuanhuai He ,&nbsp;Zhijun Zhang ,&nbsp;Yingying Zhang","doi":"10.1016/j.intermet.2025.108743","DOIUrl":"10.1016/j.intermet.2025.108743","url":null,"abstract":"<div><div>The investigation of engineering materials has consistently focused on developing lightweight structures that can bear loads and absorb energy efficiently. This study involved the creation of a novel aluminum (Al) matrix composite by merging selective laser melting technology with infiltration casting. The mechanical properties of the composite material were manipulated by altering the parameters of the reinforced body cells. The results show that a strong metallurgical bond is formed between the honeycomb structure and the matrix, which greatly improves the overall performance of the composite. The hexagonal tubular intermetallic compounds (IMC) layer and the honeycomb-filled tube strengthen the honeycomb-filled tube/Al matrix composites (HFT/AMC). The new composite material's compressive strength was found to be positively related to the percentage of the IMC layer. The analysis of data from HFT/AMCs made from honeycomb-filled tubes with structurally different parameters demonstrated this relationship. The introduction of honeycomb-filled tube reinforcements and the distribution regulation of IMCs provide new methods and ideas for the design and development of Al matrix composites.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108743"},"PeriodicalIF":4.3,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143621097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser-beam powder bed fusion and post-build annealing of polycrystalline Fe81Ga19 alloys: Microstructure manipulation and magnetostrictive properties
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-13 DOI: 10.1016/j.intermet.2025.108734
Chengde Gao , Xiong Yao , Qi Zeng , Wei Tan , Shuaishuai Zhu , Ping Wu , Cijun Shuai
{"title":"Laser-beam powder bed fusion and post-build annealing of polycrystalline Fe81Ga19 alloys: Microstructure manipulation and magnetostrictive properties","authors":"Chengde Gao ,&nbsp;Xiong Yao ,&nbsp;Qi Zeng ,&nbsp;Wei Tan ,&nbsp;Shuaishuai Zhu ,&nbsp;Ping Wu ,&nbsp;Cijun Shuai","doi":"10.1016/j.intermet.2025.108734","DOIUrl":"10.1016/j.intermet.2025.108734","url":null,"abstract":"<div><div>Magnetostrictive polycrystalline Fe-Ga alloys are gaining increasing attention for boarder practicalities, unfortunately, always facing limitations in magnetostrictive properties hindered by random grain structure and complex phase composition. In this work, an innovative method was established to fabricate massive polycrystalline Fe<sub>81</sub>Ga<sub>19</sub> alloys via laser-beam powder bed fusion (LPBF) followed by post-build annealing treatment, and the magnetostrictive performances of the LPBF-fabricated Fe-Ga alloys annealed at various temperatures (800, 1000, and 1200 °C) were systematically investigated. Microstructural analyses revealed that &lt;001&gt; grain orientation and disordered A2 structure were obtained within the LPBF-fabricated (LPBFed) Fe<sub>81</sub>Ga<sub>19</sub> alloys as a result of the steep temperature gradient and rapid solidification. Furthermore, the post-LPBF annealing treatment promoted the grain growth and release of residual stresses, simultaneously accompanied by intensified oriented texture within the annealed alloys. As a result, the Fe<sub>81</sub>Ga<sub>19</sub> alloy annealed at 1200 °C showed optimal magnetostrictive performances with a magnetostrictive strain of ∼70 ppm and especially a 64 % reduction in saturation field relative to the LPBFed alloy. Moreover, the prepared Fe-Ga alloys also manifested good magnetostrictive dynamic response and desirable soft magnetic properties. In addition, electrochemical tests also indicated accelerated corrosion for the annealed alloys owing to the increased grain sizes. This work may pave a processing base to fabricate structure-tailored polycrystalline magnetostrictive Fe-Ga alloys for diverse applications.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108734"},"PeriodicalIF":4.3,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143609418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design, formability, and strengthening mechanism of CoCrFeNiTix high-entropy alloys fabricated using laser directed energy deposition
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-10 DOI: 10.1016/j.intermet.2025.108725
Bin Zhang, Weidong Mu, Yan Cai
{"title":"Design, formability, and strengthening mechanism of CoCrFeNiTix high-entropy alloys fabricated using laser directed energy deposition","authors":"Bin Zhang,&nbsp;Weidong Mu,&nbsp;Yan Cai","doi":"10.1016/j.intermet.2025.108725","DOIUrl":"10.1016/j.intermet.2025.108725","url":null,"abstract":"<div><div>A method combining theoretical calculations, phase diagram simulations, and experimental validation was used to strengthen the design of the CoCrFeNi high-entropy alloy (HEA). The strengthening effect of the designed alloy was confirmed through hardness simulations and experimental validation. CoCrFeNiTi<sub>x</sub> (x: 0.3–1.0) HEAs were prepared using laser directed energy deposition (LDED) technology, and the influence of Ti elements on the microstructure and strengthening effect of CoCrFeNi HEA was investigated. Through thermodynamic parameter calculations and JMatPro software simulations, it was revealed that CoCrFeNiTi<sub>x</sub> HEAs tend to form second phases, with the FCC phase as the main phase and the presence of BCC, Laves, η, σ, and γ′ phases, significantly enhancing the alloy's strengthening effect. As the Ti content increases, the strengthening effect gradually increases. However, when x &gt; 0.7, the LDED CoCrFeNiTi<sub>x</sub> HEAs tends to crack. The addition of Ti elements promotes the microstructure transition from cellular equiaxed grains to dendritic crystals and increases the microhardness of the HEAs. The average microhardness of CoCrFeNiTi<sub>0.3</sub>, CoCrFeNiTi<sub>0.7</sub>, and CoCrFeNiTi<sub>1.0</sub> HEAs deposition layers are approximately 328 HV, 506 HV, and 660 HV, respectively, with simulated hardness values very close to the experimental results. Through the calculation and analysis of the strengthening mechanism, it was determined that second-phase strengthening is the main strengthening mechanism of CoCrFeNiTi<sub>x</sub> HEAs. To meet the strengthening and remanufacturing needs of EH36 steel, while also considering hardness, wear resistance, corrosion resistance, and formability requirements, the maximum atomic ratio of Ti elements in CoCrFeNiTi<sub>x</sub> HEAs was determined to be x ≤ 0.7. This design approach not only applies to the current work but also provides a new strategy for the subsequent design of HEAs with customized microstructures and properties.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108725"},"PeriodicalIF":4.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Outstanding radiation resistance of reduced-activation VCrMnFe based high-entropy alloy 基于还原活化 VCrMnFe 的高熵合金的出色抗辐射性能
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-08 DOI: 10.1016/j.intermet.2025.108728
Feng Jiao Ye , Te Zhu , Qiao Li Zhang , Hai Liang Ma , Hai Biao Wu , Peng Zhang , Run Sheng Yu , Bao Yi Wang , Da Qing Yuan , Xing Zhong Cao
{"title":"Outstanding radiation resistance of reduced-activation VCrMnFe based high-entropy alloy","authors":"Feng Jiao Ye ,&nbsp;Te Zhu ,&nbsp;Qiao Li Zhang ,&nbsp;Hai Liang Ma ,&nbsp;Hai Biao Wu ,&nbsp;Peng Zhang ,&nbsp;Run Sheng Yu ,&nbsp;Bao Yi Wang ,&nbsp;Da Qing Yuan ,&nbsp;Xing Zhong Cao","doi":"10.1016/j.intermet.2025.108728","DOIUrl":"10.1016/j.intermet.2025.108728","url":null,"abstract":"<div><div>This study examines the irradiation resistance of a novel Ti<sub>8</sub>V<sub>22.5</sub>Cr<sub>22.5</sub>Mn<sub>22.5</sub>Fe<sub>22.5</sub>Si<sub>2</sub> high-entropy alloy (HEA) through techniques such as scanning/transmission electron microscopy, positron annihilation spectroscopy, and grazing incidence X-ray diffraction. The results highlight an unusual lattice contraction upon irradiation, diverging from typical responses of traditional alloys, with no evidence of irradiation-induced precipitation. Under high-dose irradiation (∼188 dpa), the HEA displayed no discernible void swelling, potentially due to abundant precipitate interfaces, high equilibrium vacancy concentration, and the intrinsic properties of HEA. The HEA, exhibiting smaller dislocation loops (∼3.2 nm) and a lower irradiation hardening rate (∼3.3 %) compared to conventional alloys, demonstrates significant promise as a material for future-generation core components.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108728"},"PeriodicalIF":4.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143578247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Non-uniform domain wall propagation in Fe-based magnetic microwires
IF 4.3 2区 材料科学
Intermetallics Pub Date : 2025-03-08 DOI: 10.1016/j.intermet.2025.108726
Valerii Savin , Valeria Kolesnikova , Artem Ignatov , Valentina Zhukova , Valeria Rodionova , Arcady Zhukov
{"title":"Non-uniform domain wall propagation in Fe-based magnetic microwires","authors":"Valerii Savin ,&nbsp;Valeria Kolesnikova ,&nbsp;Artem Ignatov ,&nbsp;Valentina Zhukova ,&nbsp;Valeria Rodionova ,&nbsp;Arcady Zhukov","doi":"10.1016/j.intermet.2025.108726","DOIUrl":"10.1016/j.intermet.2025.108726","url":null,"abstract":"<div><div>Nowadays the novel ambitious studies dedicated to magnetic materials for sensing technologies highlights the importance of understanding the ways of control the magnetization process. Among variety of soft magnetic materials with fast magnetization process the cheap in production and ultra magnetically soft Fe-based ferromagnetic glass-coated microwires stands out.</div><div>In this paper, we experimentally studied the domain wall (DW) motion in amorphous Fe<sub>77.5</sub>Si<sub>7.5</sub>B<sub>15</sub> and Fe<sub>77</sub>Si<sub>10</sub>B<sub>10</sub>C<sub>3</sub> ferromagnetic glass-coated microwires. Using the modified Sixtus-Tonks method the influence of the inhomogeneities distribution and the effect of stray fields on the parameters of DW motion (velocity, local nucleation fields) have been evaluated. Three types of DW motion mechanism were firstly identified. And the model of DW velocity tuning with the mechanical defects influence is presented. This study could lead to decrease the response time of sensitive devices which are based on magnetic domain wall motion mechanism.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"181 ","pages":"Article 108726"},"PeriodicalIF":4.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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