Rejuvenation of a Zr-based metallic glass originates from strong icosahedral short-range order

IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Yunwei Cao, Yifan Yang, Jing Geng, Li Fan, Bo Shi
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引用次数: 0

Abstract

When a Zr-based metallic glass (MG) is stimulated by cryogenic thermal cycling (CTC), its atomic icosahedral short-range order (ISRO) has a crucial impact on the evolution of its energy state, determining whether the system undergoes relaxation or rejuvenation. Through experiments and molecular dynamic simulations, it was found that CTC increases the degree of structural heterogeneity in the MG with strong ISRO, thereby introducing more free volume, inducing its rejuvenation, and enhancing its plasticity. However, for the MG with weak ISRO, its response to CTC is completely opposite, that is, relaxation and densification occur. The response of CTC is highly sensitive to the initial atomic short-range order of MG. This finding provides some insights into achieving high rejuvenation of MGs from the perspective of atomic cluster structure.
锆基金属玻璃的回春源于强二十面体近程有序
低温热循环(CTC)刺激锆基金属玻璃(MG)时,其原子二十面体近程序(ISRO)对其能态演化具有至关重要的影响,决定了体系是发生松弛还是恢复。通过实验和分子动力学模拟发现,CTC增加了强ISRO MG的结构非均质性,从而引入更多的自由体积,诱导其回春,增强其塑性。而对于弱ISRO的MG,其对CTC的响应则完全相反,即发生弛豫和致密化。CTC的响应对MG的初始原子近程阶数高度敏感。这一发现为从原子团簇结构的角度实现mg的高再生提供了一些见解。
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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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