Haodong Duan , Geng Li , Xiaoyu Chen , Cheng Ai , Jie Kang , Yi Ru , Heng Zhang , Yanling Pei , Shusuo Li , Shengkai Gong , Huibin Xu
{"title":"Ru添加对ni基单晶高温合金γ/γ′配分行为、γ/γ′晶格失配和1200℃蠕变性能的影响","authors":"Haodong Duan , Geng Li , Xiaoyu Chen , Cheng Ai , Jie Kang , Yi Ru , Heng Zhang , Yanling Pei , Shusuo Li , Shengkai Gong , Huibin Xu","doi":"10.1016/j.intermet.2025.108987","DOIUrl":null,"url":null,"abstract":"<div><div>The influence of Ru addition on γ/γ′ partitioning behavior of alloying elements, solid solution strengthening degree of γ and γ′ phases, γ/γ′ lattice misfit and 1200 °C/80 MPa creep properties of Ni-based single-crystal superalloys was detailed investigated. Ru addition increased 1200 °C/80 MPa rupture life of Ni-based single-crystal superalloy from 125.93 ± 5.61 h to 179.87 ± 4.43 h. The experimental single-crystal superalloys exhibited a high γ′ phase volume fraction at 1200 °C, which contributed to the superior 1200 °C/80 MPa creep properties of both Ru-free and Ru-containing single-crystal superalloys. In this study, Ru addition increased Mo, Cr, and Re contents in γ phase, and thus increased both solid solution strengthening degree and lattice constant of γ phase. These effects collectively decreased γ/γ′ lattice misfit and γ/γ′ interfacial dislocation network spacing, which increased γ/γ′ interfacial strengthening effect, and ultimately increased 1200 °C/80 MPa creep life. Furthermore, it was revealed that the 1200 °C/80 MPa creep/stress rupture lives of single-crystal superalloys with low thermal stability of γ′ phase, creep/stress rupture lives are dominated by volume fraction of γ′ phase. In contrast, for single-crystal superalloys with high thermal stability of γ′ phase (such as the two single crystal superalloys in this study), the 1200 °C/80 MPa creep/stress rupture lives were primarily governed by γ/γ′ lattice misfit. Therefore, in order to design single-crystal superalloys with excellent 1200 °C/80 MPa creep performance, it is essential to simultaneously improve thermal stability of γ′ phase and decrease γ/γ′ lattice misfit of single crystal superalloys.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"187 ","pages":"Article 108987"},"PeriodicalIF":4.8000,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Ru addition on γ/γ′ partitioning behavior of alloying elements, γ/γ′ lattice misfit and 1200 °C creep properties of Ni-based single-crystal superalloy\",\"authors\":\"Haodong Duan , Geng Li , Xiaoyu Chen , Cheng Ai , Jie Kang , Yi Ru , Heng Zhang , Yanling Pei , Shusuo Li , Shengkai Gong , Huibin Xu\",\"doi\":\"10.1016/j.intermet.2025.108987\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The influence of Ru addition on γ/γ′ partitioning behavior of alloying elements, solid solution strengthening degree of γ and γ′ phases, γ/γ′ lattice misfit and 1200 °C/80 MPa creep properties of Ni-based single-crystal superalloys was detailed investigated. Ru addition increased 1200 °C/80 MPa rupture life of Ni-based single-crystal superalloy from 125.93 ± 5.61 h to 179.87 ± 4.43 h. The experimental single-crystal superalloys exhibited a high γ′ phase volume fraction at 1200 °C, which contributed to the superior 1200 °C/80 MPa creep properties of both Ru-free and Ru-containing single-crystal superalloys. In this study, Ru addition increased Mo, Cr, and Re contents in γ phase, and thus increased both solid solution strengthening degree and lattice constant of γ phase. These effects collectively decreased γ/γ′ lattice misfit and γ/γ′ interfacial dislocation network spacing, which increased γ/γ′ interfacial strengthening effect, and ultimately increased 1200 °C/80 MPa creep life. Furthermore, it was revealed that the 1200 °C/80 MPa creep/stress rupture lives of single-crystal superalloys with low thermal stability of γ′ phase, creep/stress rupture lives are dominated by volume fraction of γ′ phase. In contrast, for single-crystal superalloys with high thermal stability of γ′ phase (such as the two single crystal superalloys in this study), the 1200 °C/80 MPa creep/stress rupture lives were primarily governed by γ/γ′ lattice misfit. Therefore, in order to design single-crystal superalloys with excellent 1200 °C/80 MPa creep performance, it is essential to simultaneously improve thermal stability of γ′ phase and decrease γ/γ′ lattice misfit of single crystal superalloys.</div></div>\",\"PeriodicalId\":331,\"journal\":{\"name\":\"Intermetallics\",\"volume\":\"187 \",\"pages\":\"Article 108987\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Intermetallics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0966979525003528\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Intermetallics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0966979525003528","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Effect of Ru addition on γ/γ′ partitioning behavior of alloying elements, γ/γ′ lattice misfit and 1200 °C creep properties of Ni-based single-crystal superalloy
The influence of Ru addition on γ/γ′ partitioning behavior of alloying elements, solid solution strengthening degree of γ and γ′ phases, γ/γ′ lattice misfit and 1200 °C/80 MPa creep properties of Ni-based single-crystal superalloys was detailed investigated. Ru addition increased 1200 °C/80 MPa rupture life of Ni-based single-crystal superalloy from 125.93 ± 5.61 h to 179.87 ± 4.43 h. The experimental single-crystal superalloys exhibited a high γ′ phase volume fraction at 1200 °C, which contributed to the superior 1200 °C/80 MPa creep properties of both Ru-free and Ru-containing single-crystal superalloys. In this study, Ru addition increased Mo, Cr, and Re contents in γ phase, and thus increased both solid solution strengthening degree and lattice constant of γ phase. These effects collectively decreased γ/γ′ lattice misfit and γ/γ′ interfacial dislocation network spacing, which increased γ/γ′ interfacial strengthening effect, and ultimately increased 1200 °C/80 MPa creep life. Furthermore, it was revealed that the 1200 °C/80 MPa creep/stress rupture lives of single-crystal superalloys with low thermal stability of γ′ phase, creep/stress rupture lives are dominated by volume fraction of γ′ phase. In contrast, for single-crystal superalloys with high thermal stability of γ′ phase (such as the two single crystal superalloys in this study), the 1200 °C/80 MPa creep/stress rupture lives were primarily governed by γ/γ′ lattice misfit. Therefore, in order to design single-crystal superalloys with excellent 1200 °C/80 MPa creep performance, it is essential to simultaneously improve thermal stability of γ′ phase and decrease γ/γ′ lattice misfit of single crystal superalloys.
期刊介绍:
This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys.
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