Chemical Reviews最新文献

{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 9","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":51.4,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/crv125i009_1934704","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144446307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Semiconducting Covalent Organic Frameworks","authors":"Donglin Jiang, Vincent Guan Wu Tan, Yifan Gong, Haipei Shao, Xinyu Mu, Zhangliang Luo, Shuyue He","doi":"10.1021/acs.chemrev.4c00950","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00950","url":null,"abstract":"Semiconductors form the foundational bedrock of modern electronics and numerous cutting-edge technologies. Particularly, semiconductors crafted from organic building blocks hold immense promise as next-generation pioneers, thanks to their vast array of chemical structures, customizable frontier orbital energy levels and bandgap structures, and easily adjustable π electronic properties. Over the past 50 years, advancements in chemistry and materials science have facilitated extensive investigations into small organic π compounds, oligomers, and polymers, resulting in a rich library of organic semiconductors. However, a longstanding challenge persists: how to organize π building units or chains into well-defined π structures, which are crucial for the performance of organic semiconductors. Consequently, the pursuit of methodologies capable of synthesizing and/or fabricating organic semiconductors with ordered structures has emerged as a frontier in organic and polymeric semiconductor research. In this context, covalent organic frameworks (COFs) stand out as unique platforms allowing for the covalent integration of organic π units into periodically ordered π structures, thus facilitating the development of semiconductors with extended yet precisely defined π architectures. Since their initial report in 2008, significant strides have been made in exploring various chemistries to develop semiconducting COFs, resulting in a rich library of structures, properties, functions, and applications. This review provides a comprehensive yet focused exploration of the general structural features of semiconducting COFs, outlining the basic principles of structural design, illustrating the linkage chemistry and synthetic strategies based on typical one-pot polymerization reactions to demonstrate the growth of bulk materials, nanosheets, films, and membranes. By elucidating the interactions between COFs and various entities such as photons, phonons, electrons, holes, ions, molecules, and spins, this review categorizes semiconducting COFs into nine distinct sections: semiconductors, photoconductors, light emitters, sensors, photocatalysts, photothermal conversion materials, electrocatalysts, energy storage electrodes, and radical spin materials, focusing on disclosing structure-originated properties and functions. Furthermore, this review scrutinizes structure–function correlations and highlights the unique features, breakthroughs, and challenges associated with semiconducting COFs. Furnished with foundational knowledges and state-of-the-art insights, this review predicts the fundamental issues to be addressed and outlines future directions for semiconducting COFs, offering a comprehensive overview of this rapidly evolving and remarkable field.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"12 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143946211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"","authors":"Rafał Kusy*,  and , Karol Grela, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 9","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":51.4,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.4c00001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144342028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"","authors":"Zifei Chen, Anjay Manian, Asaph Widmer-Cooper, Salvy P. Russo and Paul Mulvaney*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 9","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":51.4,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.chemrev.4c00967","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144446306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid–Liquid Interfacial Free Energy from Computer Simulations: Challenges and Recent Advances","authors":"Nicodemo Di Pasquale*,&nbsp;Jesús Algaba,&nbsp;Pablo Montero de Hijes,&nbsp;Ignacio Sanchez-Burgos,&nbsp;Andres R. Tejedor,&nbsp;Stephen R. Yeandel,&nbsp;Felipe J. Blas,&nbsp;Ruslan L. Davidchack,&nbsp;Jorge R. Espinosa,&nbsp;Colin L. Freeman,&nbsp;John H. Harding,&nbsp;Brian B. Laird,&nbsp;Eduardo Sanz,&nbsp;Carlos Vega and Lorenzo Rovigatti,&nbsp;","doi":"10.1021/acs.chemrev.4c0083310.1021/acs.chemrev.4c00833","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00833https://doi.org/10.1021/acs.chemrev.4c00833","url":null,"abstract":"<p >The study of interfacial properties in liquid–liquid and liquid–vapor systems has a history of nearly 200 years, with significant contributions from scientific luminaries such as Thomas Young and Willard Gibbs. However, a similar level of understanding of solid–liquid interfaces has emerged only more recently, largely because of the numerous complications associated with the thermodynamics needed to describe them. The accurate calculation of the interfacial free energy of solid–liquid systems is central to determining which interfaces will be observed and their properties. However, designing and analyzing the molecular dynamics simulations required to do this remains challenging, unlike the liquid–liquid or liquid–vapor cases, because of the unique complications associated with solid–liquid systems. Specifically, the lattice structure of solids introduces spatial directionality, and atomic configurations in solids can be altered by stretching. The primary aim of this review is to provide an overview of the numerical approaches developed to address the challenge of calculating the interfacial free energy in solid–liquid systems. These approaches are classified as (i) direct methods, which compute interfacial free energies explicitly, albeit often through convoluted procedures, and (ii) indirect methods, which derive these free energies as secondary results obtained from the analysis of simulations of an idealized experimental configuration. We also discuss two key topics related to the calculation of the interfacial free energy of solid–liquid systems: nucleation theory and curved interfaces, which represent important problems where research remains highly active.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 10","pages":"5003–5053 5003–5053"},"PeriodicalIF":51.4,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00833","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144146489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid–Liquid Interfacial Free Energy from Computer Simulations: Challenges and Recent Advances","authors":"Nicodemo Di Pasquale, Jesús Algaba, Pablo Montero de Hijes, Ignacio Sanchez-Burgos, Andres R. Tejedor, Stephen R. Yeandel, Felipe J. Blas, Ruslan L. Davidchack, Jorge R. Espinosa, Colin L. Freeman, John H. Harding, Brian B. Laird, Eduardo Sanz, Carlos Vega, Lorenzo Rovigatti","doi":"10.1021/acs.chemrev.4c00833","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00833","url":null,"abstract":"The study of interfacial properties in liquid–liquid and liquid–vapor systems has a history of nearly 200 years, with significant contributions from scientific luminaries such as Thomas Young and Willard Gibbs. However, a similar level of understanding of solid–liquid interfaces has emerged only more recently, largely because of the numerous complications associated with the thermodynamics needed to describe them. The accurate calculation of the interfacial free energy of solid–liquid systems is central to determining which interfaces will be observed and their properties. However, designing and analyzing the molecular dynamics simulations required to do this remains challenging, unlike the liquid–liquid or liquid–vapor cases, because of the unique complications associated with solid–liquid systems. Specifically, the lattice structure of solids introduces spatial directionality, and atomic configurations in solids can be altered by stretching. The primary aim of this review is to provide an overview of the numerical approaches developed to address the challenge of calculating the interfacial free energy in solid–liquid systems. These approaches are classified as (i) direct methods, which compute interfacial free energies explicitly, albeit often through convoluted procedures, and (ii) indirect methods, which derive these free energies as secondary results obtained from the analysis of simulations of an idealized experimental configuration. We also discuss two key topics related to the calculation of the interfacial free energy of solid–liquid systems: nucleation theory and curved interfaces, which represent important problems where research remains highly active.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"13 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comprehensive Review on the Structural Diversity and Versatility of Multi-Resonance Fluorescence Emitters: Advance, Challenges, and Prospects toward OLEDs","authors":"Xiugang Wu, Songqian Ni, Chih-Hsing Wang, Weiguo Zhu, Pi-Tai Chou","doi":"10.1021/acs.chemrev.5c00021","DOIUrl":"https://doi.org/10.1021/acs.chemrev.5c00021","url":null,"abstract":"Fluorescence emitters with a multiple-resonant (MR) effect have become a research hotspot. These MR emitters mainly consist of polycyclic aromatic hydrocarbons with boron/nitrogen, nitrogen/carbonyl, and indolocarbazole frameworks. The staggered arrangement of the highest occupied molecular orbital and the lowest unoccupied molecular orbital facilitates MR, resulting in smaller internal reorganization energy and a narrower emission bandwidth. Optimal charge separation suppresses the energy gap between singlet and triplet excited states, favoring thermally activated delayed fluorescence (TADF). These MR-TADF materials, due to color purity and high emission efficiency, are excellent candidates for organic light-emitting diodes. Nevertheless, significant challenges remain; in particular, the limitation imposed by the alternated core configuration hinders their diversity and versatility. Most existing MR-TADF materials are concentrated in the blue-green range, with only a few in red and near-infrared spectra. This review provides a timely and comprehensive screening of MR emitters from their pioneering work to the present. Our goal is to gain understandings of the MR-TADF structure–performance relationship from both basic and advanced perspectives. Special emphasis is placed on exploring the correlations between chemical structure, photophysical properties and electroluminescent performance in both depth and breadth with an aim to promote the future development of MR emitters.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"145 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143931111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Understanding the Electrochemical Window of Solid-State Electrolyte in Full Battery Application","authors":"Chen Bai, Yuhang Li, Guanyou Xiao, Jiajing Chen, Shendong Tan, Peiran Shi, Tingzheng Hou, Ming Liu, Yan-Bing He, Feiyu Kang","doi":"10.1021/acs.chemrev.4c01012","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c01012","url":null,"abstract":"In recent years, solid-state Li batteries (SSLBs) have emerged as a promising solution to address the safety concerns associated. However, the limited electrochemical window (ECW) of solid-state electrolytes (SEs) remains a critical constraint full battery application. Understanding the factors that influence the ECW is an essential step toward designing more robust and high-performance electrochemical systems. This review provides a detailed classification of the various “windows” of SEs and a comprehensive understanding of the associated interfacial stability of SEs in full battery application. The paper begins with a historical overview of SE development, followed by a detailed discussion of their structural characteristics. Next, examination of various methodologies used to calculate and measure the ECW is presented, culminating in the proposal of standardized testing procedures. Furthermore, a comprehensive analysis of the numerous parameters that influence the thermodynamic ECW of SEs is provided, along with a synthesis of strategies to address these challenges. At last, this review concludes with an in-depth exploration of the interfacial issues associated with SEs exhibiting narrow ECWs in full SSLBs.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"49 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143927054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomolecular Actuators for Soft Robots","authors":"Michelle C. Quan, Danielle J. Mai","doi":"10.1021/acs.chemrev.4c00811","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00811","url":null,"abstract":"Biomolecules present promising stimuli-responsive mechanisms to revolutionize soft actuators. Proteins, peptides, and nucleic acids foster specific intermolecular interactions, and their boundless sequence design spaces encode precise actuation capabilities. Drawing inspiration from nature, biomolecular actuators harness existing stimuli-responsive properties to meet the needs of diverse applications. This review features biomolecular actuators that respond to a wide variety of stimuli to drive both user-directed and autonomous actuation. We discuss how advances in biomaterial fabrication accelerate prototyping of precise, custom actuators, and we identify biomolecules with untapped actuation potential. Finally, we highlight opportunities for multifunctional and reconfigurable biomolecules to improve the versatility and sustainability of next-generation soft actuators.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"22 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomolecular Actuators for Soft Robots","authors":"Michelle C. Quan,&nbsp; and ,&nbsp;Danielle J. Mai*,&nbsp;","doi":"10.1021/acs.chemrev.4c0081110.1021/acs.chemrev.4c00811","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00811https://doi.org/10.1021/acs.chemrev.4c00811","url":null,"abstract":"<p >Biomolecules present promising stimuli-responsive mechanisms to revolutionize soft actuators. Proteins, peptides, and nucleic acids foster specific intermolecular interactions, and their boundless sequence design spaces encode precise actuation capabilities. Drawing inspiration from nature, biomolecular actuators harness existing stimuli-responsive properties to meet the needs of diverse applications. This review features biomolecular actuators that respond to a wide variety of stimuli to drive both user-directed and autonomous actuation. We discuss how advances in biomaterial fabrication accelerate prototyping of precise, custom actuators, and we identify biomolecules with untapped actuation potential. Finally, we highlight opportunities for multifunctional and reconfigurable biomolecules to improve the versatility and sustainability of next-generation soft actuators.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 10","pages":"4974–5002 4974–5002"},"PeriodicalIF":51.4,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144146597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}