Chemical Reviews最新文献

{"title":"Correction to “Theory and Simulations of Ionic Liquids in Nanoconfinement”","authors":"Svyatoslav Kondrat*, Guang Feng*, Fernando Bresme*, Michael Urbakh* and Alexei A. Kornyshev*, ","doi":"10.1021/acs.chemrev.4c0088510.1021/acs.chemrev.4c00885","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00885https://doi.org/10.1021/acs.chemrev.4c00885","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"521 521"},"PeriodicalIF":51.4,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00885","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143085257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nondestructive Analysis of Commercial Batteries","authors":"Wenhua Zuo, Rui Liu, Jiyu Cai, Yonggang Hu, Manar Almazrouei, Xiangsi Liu, Tony Cui, Xin Jia, Emory Apodaca, Jakob Alami, Zonghai Chen, Tianyi Li, Wenqian Xu, Xianghui Xiao, Dilworth Parkinson, Yong Yang, Gui-Liang Xu, Khalil Amine","doi":"10.1021/acs.chemrev.4c00566","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00566","url":null,"abstract":"Electrochemical batteries play a crucial role for powering portable electronics, electric vehicles, large-scale electric grids, and future electric aircraft. However, key performance metrics such as energy density, charging speed, lifespan, and safety raise significant consumer concerns. Enhancing battery performance hinges on a deep understanding of their operational and degradation mechanisms, from material composition and electrode structure to large-scale pack integration, necessitating advanced characterization methods. These methods not only enable improved battery performance but also facilitate early detection of substandard or potentially hazardous batteries before they cause serious incidents. This review comprehensively examines the operational principles, applications, challenges, and prospects of cutting-edge characterization techniques for commercial batteries, with a specific focus on in situ and operando methodologies. Furthermore, it explores how these powerful tools have elucidated the operational and degradation mechanisms of commercial batteries. By bridging the gap between advanced characterization techniques and commercial battery technologies, this review aims to guide the design of more sophisticated experiments and models for studying battery degradation and enhancement.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"60 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Nondestructive Analysis of Commercial Batteries","authors":"Wenhua Zuo,&nbsp;Rui Liu,&nbsp;Jiyu Cai,&nbsp;Yonggang Hu,&nbsp;Manar Almazrouei,&nbsp;Xiangsi Liu,&nbsp;Tony Cui,&nbsp;Xin Jia,&nbsp;Emory Apodaca,&nbsp;Jakob Alami,&nbsp;Zonghai Chen,&nbsp;Tianyi Li,&nbsp;Wenqian Xu,&nbsp;Xianghui Xiao,&nbsp;Dilworth Parkinson,&nbsp;Yong Yang*,&nbsp;Gui-Liang Xu* and Khalil Amine*,&nbsp;","doi":"10.1021/acs.chemrev.4c0056610.1021/acs.chemrev.4c00566","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00566https://doi.org/10.1021/acs.chemrev.4c00566","url":null,"abstract":"<p >Electrochemical batteries play a crucial role for powering portable electronics, electric vehicles, large-scale electric grids, and future electric aircraft. However, key performance metrics such as energy density, charging speed, lifespan, and safety raise significant consumer concerns. Enhancing battery performance hinges on a deep understanding of their operational and degradation mechanisms, from material composition and electrode structure to large-scale pack integration, necessitating advanced characterization methods. These methods not only enable improved battery performance but also facilitate early detection of substandard or potentially hazardous batteries before they cause serious incidents. This review comprehensively examines the operational principles, applications, challenges, and prospects of cutting-edge characterization techniques for commercial batteries, with a specific focus on in situ and operando methodologies. Furthermore, it explores how these powerful tools have elucidated the operational and degradation mechanisms of commercial batteries. By bridging the gap between advanced characterization techniques and commercial battery technologies, this review aims to guide the design of more sophisticated experiments and models for studying battery degradation and enhancement.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"369–444 369–444"},"PeriodicalIF":51.4,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143085154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Octadecanoids: Synthesis and Bioactivity of 18-Carbon Oxygenated Fatty Acids in Mammals, Bacteria, and Fungi","authors":"Johanna Revol-Cavalier,&nbsp;Alessandro Quaranta,&nbsp;John W. Newman,&nbsp;Alan R. Brash,&nbsp;Mats Hamberg and Craig E. Wheelock*,&nbsp;","doi":"10.1021/acs.chemrev.3c0052010.1021/acs.chemrev.3c00520","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00520https://doi.org/10.1021/acs.chemrev.3c00520","url":null,"abstract":"<p >The octadecanoids are a broad class of lipids consisting of the oxygenated products of 18-carbon fatty acids. Originally referring to production of the phytohormone jasmonic acid, the octadecanoid pathway has been expanded to include products of all 18-carbon fatty acids. Octadecanoids are formed biosynthetically in mammals via cyclooxygenase (COX), lipoxygenase (LOX), and cytochrome P450 (CYP) activity, as well as nonenzymatically by photo- and autoxidation mechanisms. While octadecanoids are well-known mediators in plants, their role in the regulation of mammalian biological processes has been generally neglected. However, there have been significant advancements in recognizing the importance of these compounds in mammals and their involvement in the mediation of inflammation, nociception, and cell proliferation, as well as in immuno- and tissue modulation, coagulation processes, hormone regulation, and skin barrier formation. More recently, the gut microbiome has been shown to be a significant source of octadecanoid biosynthesis, providing additional biosynthetic routes including hydratase activity (e.g., CLA-HY, FA-HY1, FA-HY2). In this review, we summarize the current field of octadecanoids, propose standardized nomenclature, provide details of octadecanoid preparation and measurement, summarize the phase-I metabolic pathway of octadecanoid formation in mammals, bacteria, and fungi, and describe their biological activity in relation to mammalian pathophysiology as well as their potential use as biomarkers of health and disease.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 1","pages":"1–90 1–90"},"PeriodicalIF":51.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.3c00520","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Phages to Fight Multidrug-Resistant Bacteria","authors":"Huan Peng, Irene A. Chen, Udi Qimron","doi":"10.1021/acs.chemrev.4c00681","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00681","url":null,"abstract":"Facing the global “superbug” crisis due to the emergence and selection for antibiotic resistance, phages are among the most promising solutions. Fighting multidrug-resistant bacteria requires precise diagnosis of bacterial pathogens and specific cell-killing. Phages have several potential advantages over conventional antibacterial agents such as host specificity, self-amplification, easy production, low toxicity as well as biofilm degradation. However, the narrow host range, uncharacterized properties, as well as potential risks from exponential replication and evolution of natural phages, currently limit their applications. Engineering phages can not only enhance the host bacteria range and improve phage efficacy, but also confer new functions. This review first summarizes major phage engineering techniques including both chemical modification and genetic engineering. Subsequent sections discuss the applications of engineered phages for bacterial pathogen detection and ablation through interdisciplinary approaches of synthetic biology and nanotechnology. We discuss future directions and persistent challenges in the ongoing exploration of phage engineering for pathogen control.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"25 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Octadecanoids: Synthesis and Bioactivity of 18-Carbon Oxygenated Fatty Acids in Mammals, Bacteria, and Fungi","authors":"Johanna Revol-Cavalier, Alessandro Quaranta, John W. Newman, Alan R. Brash, Mats Hamberg, Craig E. Wheelock","doi":"10.1021/acs.chemrev.3c00520","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00520","url":null,"abstract":"The octadecanoids are a broad class of lipids consisting of the oxygenated products of 18-carbon fatty acids. Originally referring to production of the phytohormone jasmonic acid, the octadecanoid pathway has been expanded to include products of all 18-carbon fatty acids. Octadecanoids are formed biosynthetically in mammals via cyclooxygenase (COX), lipoxygenase (LOX), and cytochrome P450 (CYP) activity, as well as nonenzymatically by photo- and autoxidation mechanisms. While octadecanoids are well-known mediators in plants, their role in the regulation of mammalian biological processes has been generally neglected. However, there have been significant advancements in recognizing the importance of these compounds in mammals and their involvement in the mediation of inflammation, nociception, and cell proliferation, as well as in immuno- and tissue modulation, coagulation processes, hormone regulation, and skin barrier formation. More recently, the gut microbiome has been shown to be a significant source of octadecanoid biosynthesis, providing additional biosynthetic routes including hydratase activity (e.g., CLA-HY, FA-HY1, FA-HY2). In this review, we summarize the current field of octadecanoids, propose standardized nomenclature, provide details of octadecanoid preparation and measurement, summarize the phase-I metabolic pathway of octadecanoid formation in mammals, bacteria, and fungi, and describe their biological activity in relation to mammalian pathophysiology as well as their potential use as biomarkers of health and disease.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"87 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering Phages to Fight Multidrug-Resistant Bacteria","authors":"Huan Peng*,&nbsp;Irene A. Chen* and Udi Qimron*,&nbsp;","doi":"10.1021/acs.chemrev.4c0068110.1021/acs.chemrev.4c00681","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00681https://doi.org/10.1021/acs.chemrev.4c00681","url":null,"abstract":"<p >Facing the global “superbug” crisis due to the emergence and selection for antibiotic resistance, phages are among the most promising solutions. Fighting multidrug-resistant bacteria requires precise diagnosis of bacterial pathogens and specific cell-killing. Phages have several potential advantages over conventional antibacterial agents such as host specificity, self-amplification, easy production, low toxicity as well as biofilm degradation. However, the narrow host range, uncharacterized properties, as well as potential risks from exponential replication and evolution of natural phages, currently limit their applications. Engineering phages can not only enhance the host bacteria range and improve phage efficacy, but also confer new functions. This review first summarizes major phage engineering techniques including both chemical modification and genetic engineering. Subsequent sections discuss the applications of engineered phages for bacterial pathogen detection and ablation through interdisciplinary approaches of synthetic biology and nanotechnology. We discuss future directions and persistent challenges in the ongoing exploration of phage engineering for pathogen control.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 2","pages":"933–971 933–971"},"PeriodicalIF":51.4,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00681","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation","authors":"John Marques Dos Santos, David Hall, Biju Basumatary, Megan Bryden, Dongyang Chen, Praveen Choudhary, Thomas Comerford, Ettore Crovini, Andrew Danos, Joydip De, Stefan Diesing, Mahni Fatahi, Máire Griffin, Abhishek Kumar Gupta, Hassan Hafeez, Lea Hämmerling, Emily Hanover, Janine Haug, Tabea Heil, Durai Karthik, Shiv Kumar, Oliver Lee, Haoyang Li, Fabien Lucas, Campbell Frank Ross Mackenzie, Aminata Mariko, Tomas Matulaitis, Francis Millward, Yoann Olivier, Quan Qi, Ifor D. W. Samuel, Nidhi Sharma, Changfeng Si, Leander Spierling, Pagidi Sudhakar, Dianming Sun, Eglė Tankelevičiu̅tė, Michele Duarte Tonet, Jingxiang Wang, Tao Wang, Sen Wu, Yan Xu, Le Zhang, Eli Zysman-Colman","doi":"10.1021/acs.chemrev.3c00755","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00755","url":null,"abstract":"Since the seminal report by Adachi and co-workers in 2012, there has been a veritable explosion of interest in the design of thermally activated delayed fluorescence (TADF) compounds, particularly as emitters for organic light-emitting diodes (OLEDs). With rapid advancements and innovation in materials design, the efficiencies of TADF OLEDs for each of the primary color points as well as for white devices now rival those of state-of-the-art phosphorescent emitters. Beyond electroluminescent devices, TADF compounds have also found increasing utility and applications in numerous related fields, from photocatalysis, to sensing, to imaging and beyond. Following from our previous review in 2017 ( <cite><i>Adv. Mater.</i></cite> <span>2017</span>, 1605444), we here comprehensively document subsequent advances made in TADF materials design and their uses from 2017–2022. Correlations highlighted between structure and properties as well as detailed comparisons and analyses should assist future TADF materials development. The necessarily broadened breadth and scope of this review attests to the bustling activity in this field. We note that the rapidly expanding and accelerating research activity in TADF material development is indicative of a field that has reached adolescence, with an exciting maturity still yet to come.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"9 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142816432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation","authors":"John Marques Dos Santos,&nbsp;David Hall,&nbsp;Biju Basumatary,&nbsp;Megan Bryden,&nbsp;Dongyang Chen,&nbsp;Praveen Choudhary,&nbsp;Thomas Comerford,&nbsp;Ettore Crovini,&nbsp;Andrew Danos,&nbsp;Joydip De,&nbsp;Stefan Diesing,&nbsp;Mahni Fatahi,&nbsp;Máire Griffin,&nbsp;Abhishek Kumar Gupta,&nbsp;Hassan Hafeez,&nbsp;Lea Hämmerling,&nbsp;Emily Hanover,&nbsp;Janine Haug,&nbsp;Tabea Heil,&nbsp;Durai Karthik,&nbsp;Shiv Kumar,&nbsp;Oliver Lee,&nbsp;Haoyang Li,&nbsp;Fabien Lucas,&nbsp;Campbell Frank Ross Mackenzie,&nbsp;Aminata Mariko,&nbsp;Tomas Matulaitis,&nbsp;Francis Millward,&nbsp;Yoann Olivier,&nbsp;Quan Qi,&nbsp;Ifor D. W. Samuel,&nbsp;Nidhi Sharma,&nbsp;Changfeng Si,&nbsp;Leander Spierling,&nbsp;Pagidi Sudhakar,&nbsp;Dianming Sun,&nbsp;Eglė Tankelevičiu̅tė,&nbsp;Michele Duarte Tonet,&nbsp;Jingxiang Wang,&nbsp;Tao Wang,&nbsp;Sen Wu,&nbsp;Yan Xu,&nbsp;Le Zhang and Eli Zysman-Colman*,&nbsp;","doi":"10.1021/acs.chemrev.3c0075510.1021/acs.chemrev.3c00755","DOIUrl":"https://doi.org/10.1021/acs.chemrev.3c00755https://doi.org/10.1021/acs.chemrev.3c00755","url":null,"abstract":"<p >Since the seminal report by Adachi and co-workers in 2012, there has been a veritable explosion of interest in the design of thermally activated delayed fluorescence (TADF) compounds, particularly as emitters for organic light-emitting diodes (OLEDs). With rapid advancements and innovation in materials design, the efficiencies of TADF OLEDs for each of the primary color points as well as for white devices now rival those of state-of-the-art phosphorescent emitters. Beyond electroluminescent devices, TADF compounds have also found increasing utility and applications in numerous related fields, from photocatalysis, to sensing, to imaging and beyond. Following from our previous review in 2017 ( <cite><i>Adv. Mater.</i></cite> <span>2017</span>, 1605444), we here comprehensively document subsequent advances made in TADF materials design and their uses from 2017–2022. Correlations highlighted between structure and properties as well as detailed comparisons and analyses should assist future TADF materials development. The necessarily broadened breadth and scope of this review attests to the bustling activity in this field. We note that the rapidly expanding and accelerating research activity in TADF material development is indicative of a field that has reached adolescence, with an exciting maturity still yet to come.</p>","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"124 24","pages":"13736–14110 13736–14110"},"PeriodicalIF":51.4,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.3c00755","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143125707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Introduction to Green Hydrogen","authors":"Shannon W. Boettcher*,&nbsp;","doi":"10.1021/acs.chemrev.4c0078710.1021/acs.chemrev.4c00787","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00787https://doi.org/10.1021/acs.chemrev.4c00787","url":null,"abstract":"","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"124 23","pages":"13095–13098 13095–13098"},"PeriodicalIF":51.4,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142842031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}