Chemical Reviews最新文献_第9页

A Comprehensive Review of Modeling of Solid Oxide Fuel Cells: From Large Systems to Fine Electrodes 固体氧化物燃料电池建模综述：从大系统到精细电极

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-07 DOI: 10.1021/acs.chemrev.4c0061410.1021/acs.chemrev.4c00614

Zhen Wu, Pengfei Zhu, Yakun Huang, Jing Yao, Fusheng Yang, Zaoxiao Zhang and Meng Ni*,

{"title":"A Comprehensive Review of Modeling of Solid Oxide Fuel Cells: From Large Systems to Fine Electrodes","authors":"Zhen Wu, Pengfei Zhu, Yakun Huang, Jing Yao, Fusheng Yang, Zaoxiao Zhang and Meng Ni*, ","doi":"10.1021/acs.chemrev.4c0061410.1021/acs.chemrev.4c00614","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00614https://doi.org/10.1021/acs.chemrev.4c00614","url":null,"abstract":"Commercialization of solid oxide fuel cell (SOFC) systems requires improved SOFC performance and durability, which is highly dependent on the coupling of the SOFC stack with other auxiliary components, SOFC stack configuration, and electrode microstructure. Optimization of SOFC systems at the system/stack/cell/electrode scale via experimentation is expensive and challenging, whereas numerical modeling can be fast and cost-effective. Although many excellent reviews on SOFCs have been published, the previous articles lack practical problem-oriented literature classification and do not cover new emerging models, such as artificial intelligence (AI) assisted models, heterogeneous models, and so on. These models are important for accelerating the solution of large-scale multiphysics models and describing mesoscopic electrode behaviors. In this review, a top-down approach is adopted that can truly guide SOFC system/stack/cell/electrode design to meet targeted applications. Another distinct feature of this review is the inclusion of the latest developments in SOFC modeling. This review offers a thorough summary and in-depth analysis of an extensive collection of research on SOFC simulations, classifying the models into distinct categories based on their varying scales, and serves as a valuable tool to assist researchers in selecting the most suitable models for diverse research objects.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 4","pages":"2184–2268 2184–2268"},"PeriodicalIF":51.4,"publicationDate":"2025-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00614","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermoelectricity in Molecular Tunnel Junctions

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-02-05 DOI: 10.1021/acs.chemrev.4c00886

Peng He, Jiung Jang, Hungu Kang, Hyo Jae Yoon

{"title":"Thermoelectricity in Molecular Tunnel Junctions","authors":"Peng He, Jiung Jang, Hungu Kang, Hyo Jae Yoon","doi":"10.1021/acs.chemrev.4c00886","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00886","url":null,"abstract":"The growing interest in thermoelectric energy conversion technologies has recently extended to the molecular scale, with molecular tunnel junctions emerging as promising platforms for energy harvesting from heat in a quantum-tunneling regime. This Review explores the advances in thermoelectricity within molecular junctions, highlighting the unique ability of these junctions to exploit charge tunneling and controlled molecular structure to enhance thermoelectric performance. Molecular thermoelectrics, which bridge nanoscale material design and thermoelectric applications, utilize tunneling mechanisms, such as coherent tunneling and hopping processes, including coherent and incoherent pathways, to facilitate energy conversion. Complementing these mechanisms is an array of high-precision fabrication techniques for molecular junctions, from single-molecule break junctions to large-area liquid metal-based systems, each tailored to optimize heat and charge transfer properties. With novel design strategies such as the incorporation of electron-dense ligands, customizable anchor groups, and advanced junction architectures, molecular tunnel junctions hold promise for addressing challenging targets in thermoelectricity. This Review focuses on theoretical models, experimental methodologies, and design principles aimed at understanding the thermoelectric function in molecular junctions and enhancing the performance.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"138 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143192482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermoelectricity in Molecular Tunnel Junctions 分子隧道结中的热电

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-05 DOI: 10.1021/acs.chemrev.4c0088610.1021/acs.chemrev.4c00886

Peng He, Jiung Jang, Hungu Kang and Hyo Jae Yoon*,

{"title":"Thermoelectricity in Molecular Tunnel Junctions","authors":"Peng He, Jiung Jang, Hungu Kang and Hyo Jae Yoon*, ","doi":"10.1021/acs.chemrev.4c0088610.1021/acs.chemrev.4c00886","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00886https://doi.org/10.1021/acs.chemrev.4c00886","url":null,"abstract":"The growing interest in thermoelectric energy conversion technologies has recently extended to the molecular scale, with molecular tunnel junctions emerging as promising platforms for energy harvesting from heat in a quantum-tunneling regime. This Review explores the advances in thermoelectricity within molecular junctions, highlighting the unique ability of these junctions to exploit charge tunneling and controlled molecular structure to enhance thermoelectric performance. Molecular thermoelectrics, which bridge nanoscale material design and thermoelectric applications, utilize tunneling mechanisms, such as coherent tunneling and hopping processes, including coherent and incoherent pathways, to facilitate energy conversion. Complementing these mechanisms is an array of high-precision fabrication techniques for molecular junctions, from single-molecule break junctions to large-area liquid metal-based systems, each tailored to optimize heat and charge transfer properties. With novel design strategies such as the incorporation of electron-dense ligands, customizable anchor groups, and advanced junction architectures, molecular tunnel junctions hold promise for addressing challenging targets in thermoelectricity. This Review focuses on theoretical models, experimental methodologies, and design principles aimed at understanding the thermoelectric function in molecular junctions and enhancing the performance.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 5","pages":"2953–3004 2953–3004"},"PeriodicalIF":51.4,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143591094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Therapeutic Reprogramming toward Regenerative Medicine 面向再生医学的治疗性重编程

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-05 DOI: 10.1021/acs.chemrev.4c0033210.1021/acs.chemrev.4c00332

Sheng Ding*,

{"title":"Therapeutic Reprogramming toward Regenerative Medicine","authors":"Sheng Ding*, ","doi":"10.1021/acs.chemrev.4c0033210.1021/acs.chemrev.4c00332","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00332https://doi.org/10.1021/acs.chemrev.4c00332","url":null,"abstract":"Therapeutic reprogramming represents a transformative paradigm in regenerative medicine, developing new approaches in cell therapy, small molecule drugs, biologics, and gene therapy to address unmet medical challenges. This paradigm encompasses the precise modulation of cellular fate and function to either generate safe and functional cells ex vivo for cell-based therapies or to directly reprogram endogenous cells in vivo or in situ for tissue repair and regeneration. Building on the discovery of induced pluripotent stem cells (iPSCs), advancements in chemical modulation and CRISPR-based gene editing have propelled a new iterative medicine paradigm, focusing on developing scalable, standardized cell therapy products from universal starting materials and enabling iterative improvements for more effective therapeutic profiles. Beyond cell-based therapies, non-cell-based therapeutic strategies targeting endogenous cells may offer a less invasive, more convenient, accessible, and cost-effective alternative for treating a broad range of diseases, potentially rejuvenating tissues and extending healthspan.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 4","pages":"1805–1822 1805–1822"},"PeriodicalIF":51.4,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Therapeutic Reprogramming toward Regenerative Medicine

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-02-05 DOI: 10.1021/acs.chemrev.4c00332

Sheng Ding

引用次数: 0

Confined Water for Catalysis: Thermodynamic Properties and Reaction Kinetics 用于催化的封闭水：热力学性质和反应动力学

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-02-04 DOI: 10.1021/acs.chemrev.4c00274

Tao Wang, Haldrian Iriawan, Jiayu Peng, Reshma R. Rao, Botao Huang, Daniel Zheng, Davide Menga, Abhishek Aggarwal, Shuai Yuan, John Eom, Yirui Zhang, Kaylee McCormack, Yuriy Román-Leshkov, Jeffrey Grossman, Yang Shao-Horn

{"title":"Confined Water for Catalysis: Thermodynamic Properties and Reaction Kinetics","authors":"Tao Wang, Haldrian Iriawan, Jiayu Peng, Reshma R. Rao, Botao Huang, Daniel Zheng, Davide Menga, Abhishek Aggarwal, Shuai Yuan, John Eom, Yirui Zhang, Kaylee McCormack, Yuriy Román-Leshkov, Jeffrey Grossman, Yang Shao-Horn","doi":"10.1021/acs.chemrev.4c00274","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00274","url":null,"abstract":"Water is a salient component in catalytic systems and acts as a reactant, product and/or spectator species in the reaction. Confined water in distinct local environments can display significantly different behaviors from that of bulk water. Therefore, the wide-ranging chemistry of confined water can provide tremendous opportunities to tune the reaction kinetics. In this review, we focus on drawing the connection between confined water properties and reaction kinetics for heterogeneous (electro)catalysis. First, the properties of confined water are presented, where the enthalpy, entropy, and dielectric properties of water can be regulated by tuning the geometry and hydrophobicity of the cavities. Second, experimental and computational studies that investigate the interactions between water and inorganic materials, such as carbon nanotubes (1D confinement), charged metal or metal oxide surfaces (2D), zeolites and metal–organic frameworks (3D) and ions/solvent molecules (0D), are reviewed to demonstrate the opportunity to create confined water structures with unique H-bonding network properties. Third, the role of H-bonding structure and dynamics in governing the activation free energy, reorganization energy and pre-exponential factor for (electro)catalysis are discussed. We highlight emerging opportunities to enhance proton-coupled electron transfer by optimizing interfacial H-bond networks to regulate reaction kinetics for the decarbonization of chemicals and fuels.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"76 2 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143083434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Quantum Algorithms and Applications for Open Quantum Systems 开放量子系统的量子算法和应用

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-04 DOI: 10.1021/acs.chemrev.4c0042810.1021/acs.chemrev.4c00428

Luis H. Delgado-Granados, Timothy J. Krogmeier, LeeAnn M. Sager-Smith, Irma Avdic, Zixuan Hu, Manas Sajjan, Maryam Abbasi, Scott E. Smart, Prineha Narang, Sabre Kais, Anthony W. Schlimgen, Kade Head-Marsden* and David A. Mazziotti*,

{"title":"Quantum Algorithms and Applications for Open Quantum Systems","authors":"Luis H. Delgado-Granados, Timothy J. Krogmeier, LeeAnn M. Sager-Smith, Irma Avdic, Zixuan Hu, Manas Sajjan, Maryam Abbasi, Scott E. Smart, Prineha Narang, Sabre Kais, Anthony W. Schlimgen, Kade Head-Marsden* and David A. Mazziotti*, ","doi":"10.1021/acs.chemrev.4c0042810.1021/acs.chemrev.4c00428","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00428https://doi.org/10.1021/acs.chemrev.4c00428","url":null,"abstract":"Accurate models for open quantum systems─quantum states that have nontrivial interactions with their environment─may aid in the advancement of a diverse array of fields, including quantum computation, informatics, and the prediction of static and dynamic molecular properties. In recent years, quantum algorithms have been leveraged for the computation of open quantum systems as the predicted quantum advantage of quantum devices over classical ones may allow previously inaccessible applications. Accomplishing this goal will require input and expertise from different research perspectives, as well as the training of a diverse quantum workforce, making a compilation of current quantum methods for treating open quantum systems both useful and timely. In this Review, we first provide a succinct summary of the fundamental theory of open quantum systems and then delve into a discussion on recent quantum algorithms. We conclude with a discussion of pertinent applications, demonstrating the applicability of this field to realistic chemical, biological, and material systems.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 4","pages":"1823–1839 1823–1839"},"PeriodicalIF":51.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Confined Water for Catalysis: Thermodynamic Properties and Reaction Kinetics

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-04 DOI: 10.1021/acs.chemrev.4c0027410.1021/acs.chemrev.4c00274

Tao Wang, Haldrian Iriawan, Jiayu Peng*, Reshma R. Rao*, Botao Huang, Daniel Zheng, Davide Menga, Abhishek Aggarwal, Shuai Yuan, John Eom, Yirui Zhang, Kaylee McCormack, Yuriy Román-Leshkov, Jeffrey Grossman and Yang Shao-Horn*,

{"title":"Confined Water for Catalysis: Thermodynamic Properties and Reaction Kinetics","authors":"Tao Wang, Haldrian Iriawan, Jiayu Peng*, Reshma R. Rao*, Botao Huang, Daniel Zheng, Davide Menga, Abhishek Aggarwal, Shuai Yuan, John Eom, Yirui Zhang, Kaylee McCormack, Yuriy Román-Leshkov, Jeffrey Grossman and Yang Shao-Horn*, ","doi":"10.1021/acs.chemrev.4c0027410.1021/acs.chemrev.4c00274","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00274https://doi.org/10.1021/acs.chemrev.4c00274","url":null,"abstract":"Water is a salient component in catalytic systems and acts as a reactant, product and/or spectator species in the reaction. Confined water in distinct local environments can display significantly different behaviors from that of bulk water. Therefore, the wide-ranging chemistry of confined water can provide tremendous opportunities to tune the reaction kinetics. In this review, we focus on drawing the connection between confined water properties and reaction kinetics for heterogeneous (electro)catalysis. First, the properties of confined water are presented, where the enthalpy, entropy, and dielectric properties of water can be regulated by tuning the geometry and hydrophobicity of the cavities. Second, experimental and computational studies that investigate the interactions between water and inorganic materials, such as carbon nanotubes (1D confinement), charged metal or metal oxide surfaces (2D), zeolites and metal–organic frameworks (3D) and ions/solvent molecules (0D), are reviewed to demonstrate the opportunity to create confined water structures with unique H-bonding network properties. Third, the role of H-bonding structure and dynamics in governing the activation free energy, reorganization energy and pre-exponential factor for (electro)catalysis are discussed. We highlight emerging opportunities to enhance proton-coupled electron transfer by optimizing interfacial H-bond networks to regulate reaction kinetics for the decarbonization of chemicals and fuels.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 3","pages":"1420–1467 1420–1467"},"PeriodicalIF":51.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143386049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Characterizing Electrode Materials and Interfaces in Solid-State Batteries 固态电池中电极材料和界面的表征

IF 51.4 1区化学

Chemical Reviews Pub Date : 2025-02-04 DOI: 10.1021/acs.chemrev.4c0058410.1021/acs.chemrev.4c00584

Elif Pınar Alsaç, Douglas Lars Nelson, Sun Geun Yoon, Kelsey Anne Cavallaro, Congcheng Wang, Stephanie Elizabeth Sandoval, Udochukwu D. Eze, Won Joon Jeong and Matthew T. McDowell*,

{"title":"Characterizing Electrode Materials and Interfaces in Solid-State Batteries","authors":"Elif Pınar Alsaç, Douglas Lars Nelson, Sun Geun Yoon, Kelsey Anne Cavallaro, Congcheng Wang, Stephanie Elizabeth Sandoval, Udochukwu D. Eze, Won Joon Jeong and Matthew T. McDowell*, ","doi":"10.1021/acs.chemrev.4c0058410.1021/acs.chemrev.4c00584","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00584https://doi.org/10.1021/acs.chemrev.4c00584","url":null,"abstract":"Solid-state batteries (SSBs) could offer improved energy density and safety, but the evolution and degradation of electrode materials and interfaces within SSBs are distinct from conventional batteries with liquid electrolytes and represent a barrier to performance improvement. Over the past decade, a variety of imaging, scattering, and spectroscopic characterization methods has been developed or used for characterizing the unique aspects of materials in SSBs. These characterization efforts have yielded new understanding of the behavior of lithium metal anodes, alloy anodes, composite cathodes, and the interfaces of these various electrode materials with solid-state electrolytes (SSEs). This review provides a comprehensive overview of the characterization methods and strategies applied to SSBs, and it presents the mechanistic understanding of SSB materials and interfaces that has been derived from these methods. This knowledge has been critical for advancing SSB technology and will continue to guide the engineering of materials and interfaces toward practical performance.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"125 4","pages":"2009–2119 2009–2119"},"PeriodicalIF":51.4,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.chemrev.4c00584","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In Situ TEM Characterization of Battery Materials 电池材料的原位 TEM 表征

IF 62.1 1区化学

Chemical Reviews Pub Date : 2025-02-04 DOI: 10.1021/acs.chemrev.4c00507

Diyi Cheng, Jinseok Hong, Daewon Lee, Seung-Yong Lee, Haimei Zheng

{"title":"In Situ TEM Characterization of Battery Materials","authors":"Diyi Cheng, Jinseok Hong, Daewon Lee, Seung-Yong Lee, Haimei Zheng","doi":"10.1021/acs.chemrev.4c00507","DOIUrl":"https://doi.org/10.1021/acs.chemrev.4c00507","url":null,"abstract":"Transmission electron microscopy (TEM) is an indispensable analytical technique in materials research as it probes material information down to the atomic level and can be utilized to examine dynamic phenomena during material transformations. In situ TEM resolves transient metastable states via direct observation of material dynamics under external stimuli. With innovative sample designs developed over the past decades, advanced in situ TEM has enabled emulation of battery operation conditions to unveil nanoscale changes within electrodes, at interfaces, and in electrolytes, rendering it a unique tool to offer unequivocal insights of battery materials that are beam-sensitive, air-sensitive, or that contain light elements, etc. In this review, we first briefly outline the history of advanced electron microscopy along with battery research, followed by an introduction to various in situ TEM sample cell configurations. We provide a comprehensive review on in situ TEM studies of battery materials for lithium batteries and beyond (e.g., sodium batteries and other battery chemistries) via open-cell and closed-cell in situ TEM approaches. At the end, we raise several unresolved points regarding sample preparation protocol, imaging conditions, etc., for in situ TEM experiments. We also provide an outlook on the next-stage development of in situ TEM for battery material study, aiming to foster closer collaboration between in situ TEM and battery research communities for mutual progress.","PeriodicalId":32,"journal":{"name":"Chemical Reviews","volume":"1 1","pages":""},"PeriodicalIF":62.1,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143083473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0