ACS Organic & Inorganic Au最新文献_第8页

When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors 当孔遇见半孔：描绘多孔金属卤化物半导体的兴起

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-28 DOI: 10.1021/acsorginorgau.4c0009310.1021/acsorginorgau.4c00093

Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E. S. Nassar and Ioannis Spanopoulos*,

{"title":"When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors","authors":"Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E. S. Nassar and Ioannis Spanopoulos*, ","doi":"10.1021/acsorginorgau.4c0009310.1021/acsorginorgau.4c00093","DOIUrl":"https://doi.org/10.1021/acsorginorgau.4c00093https://doi.org/10.1021/acsorginorgau.4c00093","url":null,"abstract":"<p >Metal halide semiconductors (MHS) are a versatile class of materials with fully customizable mechanical and optoelectronic properties that have proven to be prominent candidates in numerous impactful applications. Finding a way to generate porosity in MHS would bestow upon them an additional node in property engineering, thus allowing them to be utilized in uncharted technologies. Motivated by this promise, we developed a general strategy to render the MHS porous. We employed molecular cages as structure-directing agents and countercations, which fostered a new family of materials: porous metal halide semiconductors (PMHS). The presence of molecular cages gave rise to ultramicroporous structures imposed by the organic part cavities and a record water stability performance of 27 months so far. In this Perspective, we discuss the principles and promises of PMHS, which combine the merits of porous and electronic compounds.</p>","PeriodicalId":29797,"journal":{"name":"ACS Organic & Inorganic Au","volume":"5 2","pages":"87–96 87–96"},"PeriodicalIF":3.3,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsorginorgau.4c00093","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}