ACS Organic & Inorganic Au最新文献

The Acidity of Weak NH Acids: Expanding the pK _a Scale in Acetonitrile. 弱 NH 酸的酸度：扩大乙腈中的 pK a 范围。

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-03-13 eCollection Date: 2025-04-02 DOI: 10.1021/acsorginorgau.4c00095

Märt Lõkov, Carmen Kesküla, Sofja Tshepelevitsh, Marta-Lisette Pikma, Jaan Saame, Dmitri Trubitsõn, Tõnis Kanger, Ivo Leito

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引用次数: 0

The Acidity of Weak NH Acids: Expanding the pKa Scale in Acetonitrile 弱NH酸的酸性：扩大乙腈中的pKa垢

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-03-13 DOI: 10.1021/acsorginorgau.4c0009510.1021/acsorginorgau.4c00095

Märt Lõkov*, Carmen Kesküla, Sofja Tshepelevitsh, Marta-Lisette Pikma, Jaan Saame, Dmitri Trubitsõn, Tõnis Kanger and Ivo Leito,

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引用次数: 0

When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors. 当孔隙遇到半导体：描绘多孔金属卤化物半导体的崛起。

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-28 eCollection Date: 2025-04-02 DOI: 10.1021/acsorginorgau.4c00093

Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E S Nassar, Ioannis Spanopoulos

引用次数: 0

When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors 当孔遇见半孔：描绘多孔金属卤化物半导体的兴起

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-28 DOI: 10.1021/acsorginorgau.4c0009310.1021/acsorginorgau.4c00093

Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E. S. Nassar and Ioannis Spanopoulos*,

{"title":"When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors","authors":"Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E. S. Nassar and Ioannis Spanopoulos*, ","doi":"10.1021/acsorginorgau.4c0009310.1021/acsorginorgau.4c00093","DOIUrl":"https://doi.org/10.1021/acsorginorgau.4c00093https://doi.org/10.1021/acsorginorgau.4c00093","url":null,"abstract":"Metal halide semiconductors (MHS) are a versatile class of materials with fully customizable mechanical and optoelectronic properties that have proven to be prominent candidates in numerous impactful applications. Finding a way to generate porosity in MHS would bestow upon them an additional node in property engineering, thus allowing them to be utilized in uncharted technologies. Motivated by this promise, we developed a general strategy to render the MHS porous. We employed molecular cages as structure-directing agents and countercations, which fostered a new family of materials: porous metal halide semiconductors (PMHS). The presence of molecular cages gave rise to ultramicroporous structures imposed by the organic part cavities and a record water stability performance of 27 months so far. In this Perspective, we discuss the principles and promises of PMHS, which combine the merits of porous and electronic compounds.","PeriodicalId":29797,"journal":{"name":"ACS Organic & Inorganic Au","volume":"5 2","pages":"87–96 87–96"},"PeriodicalIF":3.3,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsorginorgau.4c00093","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Celebrating 5 Years of the ACS Au Journal Family 庆祝ACS Au期刊家族成立五周年

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-25 DOI: 10.1021/acsorginorgau.5c0001510.1021/acsorginorgau.5c00015

Paul D. Goring, Amelia Newman, Christopher W. Jones* and Shelley D. Minteer*,

引用次数: 0

Celebrating 5 Years of the ACS Au Journal Family. 庆祝ACS Au期刊家族成立五周年。

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-25 eCollection Date: 2025-04-02 DOI: 10.1021/acsorginorgau.5c00015

Paul D Goring, Amelia Newman, Christopher W Jones, Shelley D Minteer

引用次数: 0

One-Pot NIS-Promoted Cyclization/Palladium-Catalyzed Carbonylation for the Selective Synthesis of HFIP Ester-Containing Indenes and Thiochromenes 一锅nis促进环化/钯催化羰基化选择性合成含HFIP酯的茚和硫代铬烯

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-21 DOI: 10.1021/acsorginorgau.5c0000510.1021/acsorginorgau.5c00005

Pengfei Ji, Xing-Feng Pan, Xinxin Qi* and Xiao-Feng Wu*,

引用次数: 0

One-Pot NIS-Promoted Cyclization/Palladium-Catalyzed Carbonylation for the Selective Synthesis of HFIP Ester-Containing Indenes and Thiochromenes. 一锅nis促进环化/钯催化羰基化选择性合成含HFIP酯的茚和硫代铬烯。

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-02-21 eCollection Date: 2025-04-02 DOI: 10.1021/acsorginorgau.5c00005

Pengfei Ji, Xing-Feng Pan, Xinxin Qi, Xiao-Feng Wu

引用次数: 0

Rearrangement Cascade Initiated by Nucleophilic Benzyne Attack on 3,6-Di(2-pyridyl)-1,2-diazines. 亲核苯基攻击3,6-二（2-吡啶基）-1,2-嘧啶引发的重排级联。

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-01-28 eCollection Date: 2025-04-02 DOI: 10.1021/acsorginorgau.4c00070

Johannes Schöntag, Theresa Hettiger, William Roberts, Marcus Scheele, Markus Ströbele, Holger F Bettinger

引用次数: 0

Rearrangement Cascade Initiated by Nucleophilic Benzyne Attack on 3,6-Di(2-pyridyl)-1,2-diazines 亲核苯基攻击3,6-二（2-吡啶基）-1,2-嘧啶引发的重排级联

IF 3.3

ACS Organic & Inorganic Au Pub Date : 2025-01-27 DOI: 10.1021/acsorginorgau.4c0007010.1021/acsorginorgau.4c00070

Johannes Schöntag, Theresa Hettiger, William Roberts, Marcus Scheele, Markus Ströbele and Holger F. Bettinger*,

{"title":"Rearrangement Cascade Initiated by Nucleophilic Benzyne Attack on 3,6-Di(2-pyridyl)-1,2-diazines","authors":"Johannes Schöntag, Theresa Hettiger, William Roberts, Marcus Scheele, Markus Ströbele and Holger F. Bettinger*, ","doi":"10.1021/acsorginorgau.4c0007010.1021/acsorginorgau.4c00070","DOIUrl":"https://doi.org/10.1021/acsorginorgau.4c00070https://doi.org/10.1021/acsorginorgau.4c00070","url":null,"abstract":"Aryne intermediates in synthetic organic chemistry offer versatile routes to complex heterocyclic structures that are valuable in pharmaceuticals and materials science. We present a one-step aryne-mediated reaction to synthesize pyrido[1,2-a]indoles interconnected through vinylene or 1,2-phenylene linkers to pyridotriazoles using 2-pyridyl-substituted pyridazines and phthalazines as confirmed via single-crystal X-ray crystallography and NMR spectroscopy. This unexpected rearrangement proceeds under mild conditions. Considering that five bonds are broken and three new bonds are formed in the reaction between 3,6-di-2-pyridyl-1,2,4,5-tetrazine and benzyne, the yield of 16% is fair. Electron-rich substituents on aryne precursors destabilized the products, while electron-deficient substituents offered some stability improvements. DFT studies could reveal the mechanism of this rearrangement.","PeriodicalId":29797,"journal":{"name":"ACS Organic & Inorganic Au","volume":"5 2","pages":"97–104 97–104"},"PeriodicalIF":3.3,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsorginorgau.4c00070","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143745973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0