（P^N^C）金（III）配合物的串联氧化加成/碳氢化反应合成。

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY

ACS Organic & Inorganic Au Pub Date : 2025-08-23 eCollection Date: 2025-10-01 DOI:10.1021/acsorginorgau.5c00057

Michał Biedrzycki, Jaime Martín, Alexandre Genoux, Elia Boschi, Cristina Nevado

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引用次数: 0

摘要

报道了一种合成以（P^N^C）为配体的环金属化金（III）配合物的新方法。该方案采用串联氧化加成/环化过程，通过在一个锅中从结构多样的C-(sp2)-和C-(sp)-碘化物底物中产生两个Au-C键，从而形成(P^N^C)-金-(III)-芳基，-烯基和-炔基衍生物。此外，我们还开发了一种互补的两步法来获得(P^N^C)-金-(III)-炔基配合物，该配合物在蓝光和绿光区都有发射。

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Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C-H Auration.

A new method for the synthesis of cyclometalated gold-(III) complexes featuring (P^N^C) ligands is reported. This protocol employs a tandem oxidative addition/cycloauration process, enabling the formation of (P^N^C)-gold-(III)-aryl, -alkenyl and -alkynyl derivatives by creating two Au-C bonds in one pot from a structurally diverse range of C-(sp²)- and C-(sp)-iodide substrates. Additionally, a complementary two-step method was developed to access (P^N^C)-gold-(III)-alkynyl complexes, which exhibit emission in the blue and green light regions.

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来源期刊

ACS Organic & Inorganic Au 有机化学、无机化学-

CiteScore

4.10

自引率

0.00%

发文量

期刊介绍： ACS Organic & Inorganic Au is an open access journal that publishes original experimental and theoretical/computational studies on organic organometallic inorganic crystal growth and engineering and organic process chemistry. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Organic chemistry Organometallic chemistry Inorganic Chemistry and Organic Process Chemistry.