Chemosphere最新文献_第7页

Retraction notice to “Recent advancement challenges with synthesis of biocompatible hemodialysis membranes” [Chemosphere 307, November 2022, 135626] 关于“生物相容性血液透析膜合成的最新进展”的撤回通知[j]。

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-23 DOI: 10.1016/j.chemosphere.2025.144621

Shafiq Uz Zaman , Sikander Rafiq , Abulhassan Ali , Muhammad Shozab Mehdi , Amber Arshad , Saif-ur Rehman , Nawshad Muhammad , Muhammad Irfan , Muhammad Shahzad Khurram , Muhammad Khaliq U. Zaman , Abdulkader S. Hanbazazah , Hooi Ren Lim , Pau Loke Show

引用次数: 0

Retraction notice to “Efficient cesium encapsulation from contaminated water by cellulosic biomass based activated wood charcoal” [Chemosphere 262, January 2021, 127801] 引用本文：“纤维素生物质活性炭对污水中铯的高效封装”[j].环境科学学报，2001,26(1):1271 - 1271。

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-23 DOI: 10.1016/j.chemosphere.2025.144639

Shahjalal Khandaker , Mir Ferdous Chowdhury , Md Rabiul Awual , Aminul Islam , Takahiro Kuba

引用次数: 0

Retraction notice to “Strigolactone decreases cadmium concentrations by regulating cadmium localization and glyoxalase defense system: Effects on nodules organic acids and soybean yield” [Chemosphere 335, September 2023, 139028] “单角曲内酯通过调节镉定位和glyoxalase防御系统降低镉浓度：对根瘤有机酸和大豆产量的影响”的撤回通知[j].中国农业科学，2023(9),139028。

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-22 DOI: 10.1016/j.chemosphere.2025.144633

Tariq Shah , Muhammad Asad , Zeeshan Khan , Khadija Amjad , Abdulaziz Abdullah Alsahli , Roberto D'amato

引用次数: 0

Corrigendum to ‘Metal ferrites-based nanocomposites and nanohybrids for photocatalytic water treatment and electrocatalytic water splitting’ [Chemosphere 310 (2023) 136835] 金属铁氧体基纳米复合材料和纳米杂化物用于光催化水处理和电催化水分解[Chemosphere 310(2023) 136835]的勘误。

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-22 DOI: 10.1016/j.chemosphere.2025.144652

Ahmad Farhan , Javeria Arshad , Ehsan Ullah Rashid , Haroon Ahmad , Shahid Nawaz , Junaid Munawar , Jakub Zdarta , Teofil Jesionowski , Muhammad Bilal

引用次数: 0

Pelagia noctiluca as a new model organism in marine ecotoxicology: effects of common surfactants 作为海洋生态毒理学新模式生物的夜藻：常见表面活性剂的影响

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-21 DOI: 10.1016/j.chemosphere.2025.144657

V. Ferrari , D. Prevedelli , E. Bergami

{"title":"Pelagia noctiluca as a new model organism in marine ecotoxicology: effects of common surfactants","authors":"V. Ferrari , D. Prevedelli , E. Bergami","doi":"10.1016/j.chemosphere.2025.144657","DOIUrl":"10.1016/j.chemosphere.2025.144657","url":null,"abstract":"<div><div>Marine ecotoxicology typically relies on a limited number of invertebrate models used to assess the effects of anthropogenic stressors, including pollutants. Nevertheless, selected model species may not fully represent marine communities and Including sensitive and ecologically relevant organisms is thus crucial. Despite jellyfish are exposed to pollutants via multiple pathways, few species have been investigated for ecotoxicity purposes focusing on the ephyra stage as suitable due to its susceptibility to toxic compounds. Here we explore the use of the mauve stinger <em>P. noctiluca</em> (ephyra stage) as a new model organism in ecotoxicology, by evaluating its responses to two common surfactants. Following optimization of test conditions, <em>P. noctiluca</em> ephyrae were exposed to reference toxicants (SDS and Tween 20). After 24 h and 48 h, both lethal (mortality) and sub-lethal endpoints (behaviour) were evaluated. Both surfactants caused a concentration-dependent increase in mortality, with a milder acute toxicity of Tween 20 (LC<sub>50(24 h,48 h)</sub> = 0.045 ± 0.00 %) compared to SDS (LC<sub>50(24 h)</sub> = 7.5 ± 0.6 mg L<sup>−1</sup>, LC<sub>50(48 h)</sub> = 6.1 ± 0.8 mg L<sup>−1</sup>) on <em>P. noctiluca</em> ephyrae. The exposure resulted in evident alterations on ephyrae morphology, with tissue decomposition and lappet damage. The frequency of pulsations was affected at both time-points by surfactants and alterations in the swimming quality were recorded, along with altered lappet contractions or immobility. Our findings show acute toxicity of SDS and Tween 20 to <em>P. noctiluca</em> ephyrae. Their high sensitivity underscores their potential use in ecotoxicological research, improving the impact assessment of pollutants on marine life.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"387 ","pages":"Article 144657"},"PeriodicalIF":8.1,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144887159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Retraction notice to “Synergistic effect of silicon and arbuscular mycorrhizal fungi reduces cadmium accumulation by regulating hormonal transduction and lignin accumulation in maize” [Chemosphere 346, January 2024, 140507] 引用本文：“硅和丛枝菌根真菌通过调节激素转导和木素积累的协同效应降低玉米镉的积累”[j].环境科学学报，2004,24(1):557 - 557。

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-21 DOI: 10.1016/j.chemosphere.2025.144634

ShahRukh Khan , Zubair Ahmad , Zeeshan Khan , Umair Khan , Muhammad Asad , Tariq Shah

引用次数: 0

Biomonitoring of atmospheric depositions of rare earth elements and other elements in Quebec, Canada 加拿大魁北克地区大气中稀土元素和其他元素沉积的生物监测

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-21 DOI: 10.1016/j.chemosphere.2025.144649

Laurie Michel , Shaghayegh Ramezany , Daniel Houle , Jean-Philippe Bellenger

{"title":"Biomonitoring of atmospheric depositions of rare earth elements and other elements in Quebec, Canada","authors":"Laurie Michel , Shaghayegh Ramezany , Daniel Houle , Jean-Philippe Bellenger","doi":"10.1016/j.chemosphere.2025.144649","DOIUrl":"10.1016/j.chemosphere.2025.144649","url":null,"abstract":"<div><div>Despite the growing demand for rare earth elements (REE) in technological applications and the potential risks associated with their environmental release, few studies have focused on atmospheric levels of REE. Nowadays, in Canada, only one active mine is exploiting REE ores. In Quebec (eastern Canada), several exploration projects are underway; however, no mine is currently active, and few human activities are likely to represent a source of atmospheric REE. Thus, we established the first estimates of atmospheric depositions of REE and other elements (e.g., transition metals) in Quebec and identified the current emission sources by comparing these depositions across different land uses (forest, rural, and anthropogenic). We also report on some elements of interest for moss physiology and biogeochemistry (e.g., K, Na, Mg, and Ca). We employed a biomonitoring approach, utilizing <em>Pleurozium schreberi</em> as an indicator of elemental composition in atmospheric deposition. 210 sites were sampled across southern Quebec, in the most densely populated areas of Quebec. Elements were analyzed by ICP-MS and ICP-OES. Atmospheric depositions of REE (and other elements) are low in Quebec compared to other biomonitoring studies worldwide, with ∑REE average values of 2.63 ppm in the mosses. Hotspots were detected in urban, tourist, or industrial areas, with concentrations reaching up to ∑REE = 32.14 ppm. Overall, the origin was mainly terrigenous, as shown by the enrichment factor (EF ≈ 1 for all REE). However, a few elements (Cd, Zn, Ag, B, Mn, Sb, K, Ca, and Cu) exhibited EF > 10, indicating contamination at nearly all locations.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"387 ","pages":"Article 144649"},"PeriodicalIF":8.1,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144887089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An enhanced degradation of polyhydroxyalkanoates (PHAs) using adaptive laboratory methods: A sustainable approach alternates to genetic engineering 使用适应性实验室方法增强聚羟基烷酸酯（pha）的降解：一种替代基因工程的可持续方法

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-21 DOI: 10.1016/j.chemosphere.2025.144654

Young-Cheol Chang , Masamitsu Shimadzu , DuBok Choi , Omprakash Sarkar , M. Venkateswar Reddy

{"title":"An enhanced degradation of polyhydroxyalkanoates (PHAs) using adaptive laboratory methods: A sustainable approach alternates to genetic engineering","authors":"Young-Cheol Chang , Masamitsu Shimadzu , DuBok Choi , Omprakash Sarkar , M. Venkateswar Reddy","doi":"10.1016/j.chemosphere.2025.144654","DOIUrl":"10.1016/j.chemosphere.2025.144654","url":null,"abstract":"<div><div>Polyhydroxybutyrate (PHB) is a biodegradable plastic synthesized by several bacterial species, regarded as a sustainable alternative to petroleum-derived plastics owing to its biodegradability, biocompatibility, and renewable production processes. Although PHB exhibits inherent biodegradability, its natural degradation can be slow and inefficient in real-world conditions. This study employed the Adaptive Laboratory Evolution (ALE) method to enhance the degradation of PHB in natural environments. This study started with an examination of the degradation processes of PHB and poly (butylene adipate-co-terephthalate) (PBAT) mulch films in soil using two bacterial strains, <em>Ralstonia insidiosa</em> C1 and <em>Comamonas</em> sp. K5. A two stage ALE methodology achieved 70–80 % degradation of PHB, while a four-stage approach resulted 100 % degradation. <em>R. insidiosa</em> C1 degraded 100 % PHB within 144 h at 1.5 % (w/v), whereas <em>Comamonas</em> sp. K5 within 120 h at 1.0 % (w/v). Further, the gene expression during ALE showed that a 1 % (w/v) PHB significantly increased the gene expression levels at 1.7 times than the baseline. Conversely, the 2 % (w/v) PHB resulted in lower gene expressions indicating a correlation between ALE's degradation activity enhancement and <em>phaZ</em> gene expression levels. The identification of 3-hydroxybutyrate (3-HB) and acetoacetate via NMR analysis substantiates that <em>Ralstonia</em> sp. C1 effectively degrades PHB into 3-HB as a principal metabolite resulting from the hydrolysis of PHB's ester bonds. Finally, strain C1's PHB production was examined in the context of ALE; a reduction in PHB production compared to non-ALE, suggesting that ALE may compromise PHB production. The study advocates further research into ALE's effectiveness for synthetic and bioplastic degradation in real-world scenarios, particularly under varying environmental conditions.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"387 ","pages":"Article 144654"},"PeriodicalIF":8.1,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144887090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Early ageing in Caenorhabditis elegans caused by exposure to airborne benzene, toluene, ethylbenzene and xylenes (BTEX) 接触空气中苯、甲苯、乙苯和二甲苯（BTEX）引起的秀丽隐杆线虫过早衰老

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-20 DOI: 10.1016/j.chemosphere.2025.144624

Marcell Valandro Soares , Larissa Marafiga Cordeiro , Aline Franzen da Silva , Gustavo Ugalde , Luiza Venturini , Félix Alexandre Antunes Soares , Daiana Silva Ávila

{"title":"Early ageing in Caenorhabditis elegans caused by exposure to airborne benzene, toluene, ethylbenzene and xylenes (BTEX)","authors":"Marcell Valandro Soares , Larissa Marafiga Cordeiro , Aline Franzen da Silva , Gustavo Ugalde , Luiza Venturini , Félix Alexandre Antunes Soares , Daiana Silva Ávila","doi":"10.1016/j.chemosphere.2025.144624","DOIUrl":"10.1016/j.chemosphere.2025.144624","url":null,"abstract":"<div><div>Air pollution is a major environmental and health concern. It has been linked to diseases and contributes to aging. However, there is a lack of studies on the effects of realistic mixtures of air pollutants, notably solvents. Therefore, we investigated the aging effects of benzene, toluene, ethylbenzene, and xylenes (BTEX) airborne exposure using the <em>Caenorhabditis elegans (C. elegans)</em> model, simulating a real scenario. Nematodes at larval stage four (L4) were exposed to benzene (0.9 ppm), toluene (40 ppm), ethylbenzene (25 ppm), and xylenes (17 ppm), either individually or in combination, for seven days in a chamber designed to contain volatile compounds. The results showed that the mixture caused early aging in nematodes, with decreased mobility and mitochondrial function on days 4 (15 % and 40 %), 7 (27 % and 10 %), and 10 (30 % and 5 %). The mixture also increased the damage to physiological and neuronal parameters on days 4 (26 % and 5 %), 7 (70 % and 43 %), and 10 (95 % and 25 %). The Frailty Index analysis revealed elevated values (index above 0.5) on all days in the mixture group compared to the control and isolated groups. The combination index demonstrated that synergism was predominant among the majority of the endpoints assayed. Our findings showed that low-level exposure to BTEX compounds could reduce the healthspan of <em>C. elegans</em>, reinforcing the utility of this model for aging and ecotoxicological studies, and underscoring the risks associated with prolonged exposure to BTEX pollutants in association.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"387 ","pages":"Article 144624"},"PeriodicalIF":8.1,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144887160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymorphisms in Hg-related genes and their impact on mercury burden and oxidative stress biomarkers among riverside Amazonian populations 亚马逊河流域汞相关基因多态性及其对汞负荷和氧化应激生物标志物的影响

IF 8.1 2区环境科学与生态学

Chemosphere Pub Date : 2025-08-20 DOI: 10.1016/j.chemosphere.2025.144646

Flora Troina Maraslis , Nathália de Assis Aguilar Duarte , Emilene Arusievicz Nunes , Lindiane Eloisa de Lima , Juliana Mara Serpeloni , Milena Horvat , José L. Domingo , Fernando Barbosa Jr. , Gustavo Rafael Mazzaron Barcelos

{"title":"Polymorphisms in Hg-related genes and their impact on mercury burden and oxidative stress biomarkers among riverside Amazonian populations","authors":"Flora Troina Maraslis , Nathália de Assis Aguilar Duarte , Emilene Arusievicz Nunes , Lindiane Eloisa de Lima , Juliana Mara Serpeloni , Milena Horvat , José L. Domingo , Fernando Barbosa Jr. , Gustavo Rafael Mazzaron Barcelos","doi":"10.1016/j.chemosphere.2025.144646","DOIUrl":"10.1016/j.chemosphere.2025.144646","url":null,"abstract":"<div><div>Mercury (Hg) is a widespread environmental contaminant, with methylmercury (MeHg) being its most toxic and bioavailable form. MeHg accumulates in aquatic food chains, leading to significant human exposure, particularly in Amazonian riverine populations where fish is a dietary staple. This study examined the impact of genetic polymorphisms on Hg exposure levels and oxidative stress biomarkers in 329 individuals from riverside communities in the Brazilian Amazon.</div><div>Hg concentrations in blood, plasma, and hair were measured using inductively coupled plasma mass spectrophotometer, while TaqMan genotyping assays were used to analyze polymorphisms in genes involved in Hg toxicokinetics and toxicodynamics (<em>GSS</em>, <em>GLRX</em>, <em>TXNRD</em>, <em>SELENOP</em>, <em>MT</em>, <em>SLC6</em>, and <em>SLC11</em>). Oxidative stress biomarkers were assessed through spectrophotometric analysis.</div><div>Statistical analyses revealed significant genetic associations with Hg levels and oxidative stress markers. Individuals with the <em>TXNRD2</em> rs5748469 AA genotype had higher blood and plasma Hg concentrations, while <em>SLC6A15</em> rs11116642 CT carriers had lower Hg levels and increased glutathione peroxidase (GPX) activity. <em>GLRX2</em> rs912071 CC carriers exhibited reduced GPX activity, particularly among males and non-smokers.</div><div>These findings contribute to a better understanding of individual susceptibility to Hg toxicity, particularly in populations chronically exposed to MeHg.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"387 ","pages":"Article 144646"},"PeriodicalIF":8.1,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144887161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0