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Ion exchange membranes in environmental applications: Comprehensive review
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-21 DOI: 10.1016/j.chemosphere.2025.144327
Yokubjon Bozorov , Khait Turaev , Rustam Alikulov , Masud Karimov , Bakhriddin Muminov , Elyor Berdimurodov , Ilyos Eliboev , Muslum Demir , Adeyinka Sikiru Yusuff , Natarajan Elangovan
{"title":"Ion exchange membranes in environmental applications: Comprehensive review","authors":"Yokubjon Bozorov ,&nbsp;Khait Turaev ,&nbsp;Rustam Alikulov ,&nbsp;Masud Karimov ,&nbsp;Bakhriddin Muminov ,&nbsp;Elyor Berdimurodov ,&nbsp;Ilyos Eliboev ,&nbsp;Muslum Demir ,&nbsp;Adeyinka Sikiru Yusuff ,&nbsp;Natarajan Elangovan","doi":"10.1016/j.chemosphere.2025.144327","DOIUrl":"10.1016/j.chemosphere.2025.144327","url":null,"abstract":"<div><div>Ion exchange membranes (IEMs) are transformative materials in environmental and industrial applications, offering selective ion transport capabilities crucial for water desalination, wastewater treatment, energy generation, and resource recovery. Recent advancements have focused on developing nanocomposite and organic-inorganic hybrid membranes, integrating materials like graphene oxide, silica, and carbon nanotubes to enhance mechanical strength, thermal stability, and chemical resistance. These innovations have yielded remarkable results, such as achieving 77.9 % energy conversion efficiency and current densities of 1000 mA/cm<sup>2</sup> in seawater electrolysis systems. Additionally, advanced IEMs demonstrate significant improvements in selective ion removal, with lithium recovery efficiencies reaching 93 % and fluoride reduction below WHO guidelines. Despite these successes, challenges like fouling, chemical degradation, high costs, and scalability barriers remain. Future research directions emphasize sustainability, with a focus on biopolymer-based membranes, renewable energy integration, and computational modeling. By addressing these challenges, IEMs can significantly contribute to global environmental sustainability and resource efficiency. IEMs are vital in energy generation, enabling ion transport in fuel cells (PEMFCs, AEMFCs) for clean energy, redox flow batteries (VRFBs) for efficient energy storage, and electrolyzers (PEMELs, AEMELs) for hydrogen production. They also support salinity gradient power in reverse electrodialysis (RED) and pressure-retarded osmosis (PRO) and facilitate CO<sub>2</sub> electroreduction (CO<sub>2</sub>RR) for carbon-neutral fuel production. This review (covering 2020–2024 publication years) explores recent developments in IEM technology, highlighting their applications, challenges, and future prospects in addressing global environmental and industrial challenges.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144327"},"PeriodicalIF":8.1,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interactions of erythromycin and an antibiotic mixture with the gut microbiome of juvenile rainbow trout
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-21 DOI: 10.1016/j.chemosphere.2025.144263
Phillip J. Ankley , Jonathan Challis , Pu Xia , Yufeng Gong , Yutong Zhou , Markus Hecker , John P. Giesy , Markus Brinkmann
{"title":"Interactions of erythromycin and an antibiotic mixture with the gut microbiome of juvenile rainbow trout","authors":"Phillip J. Ankley ,&nbsp;Jonathan Challis ,&nbsp;Pu Xia ,&nbsp;Yufeng Gong ,&nbsp;Yutong Zhou ,&nbsp;Markus Hecker ,&nbsp;John P. Giesy ,&nbsp;Markus Brinkmann","doi":"10.1016/j.chemosphere.2025.144263","DOIUrl":"10.1016/j.chemosphere.2025.144263","url":null,"abstract":"<div><div>Erythromycin (ERY) is a commonly used antibiotic found in wastewater effluents and the environment globally. Due to the bioactivity by which they kill and prevent bacterial growth, ERY and other antibiotics may have significant unwanted impacts on the gut microbiome of fishes. The overall objective of this project was to assess effects on the gut microbiome in response to exposure to ERY alone or in a mixture with other common antibiotics, which was accomplished in two experiments. The objectives of experiment 1 as a pilot study were to understand uptake and depuration of ERY in juvenile rainbow trout (RBT) over a 7-d exposure to three concentrations of ERY followed by a 7-d depuration period. Furthermore, throughout the study changes in gut microbiome were assessed. In experiment 2, an identical experimental design was used to assess the effects of a mixture of antibiotics containing, in addition to ERY, 100 μg/g each of ampicillin, metronidazole, and ciprofloxacin. In that study, three matrices were analyzed, with gut collected for 16S rRNA metabarcoding, blood plasma for non-targeted metabolomics, and brain tissue for mRNA-seq analysis. ERY was relatively quickly depurated from fish and gut microbiome dysbiosis was observed at 7 d after exposure, with a slight recovery after the 7-d depuration period. A greater number of plasma metabolites was dysregulated at 14 d compared to 7 d revealing distinct temporal dynamics compared to gut microbiome dysbiosis. Furthermore, several transformation products of antibiotics and biomarker metabolites were observed in plasma due to antibiotic exposure. The transcriptome of the brain was only slightly altered due to antibiotic exposure. Results of these studies will help inform aquaculture practitioners and risk assessors when assessing the potential impacts of antibiotics present in fish feed and the environment, with implications for host health.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144263"},"PeriodicalIF":8.1,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical background of some trace elements in Atlantic Forest soils in a cocoa-producing region and its implications for human health and food safety
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-21 DOI: 10.1016/j.chemosphere.2025.144341
Tatiana Reis dos Santos Bastos , João Carlos Medeiros , Clistenes Williams Araújo do Nascimento , Kaique Mesquita Cardoso , Paula Nascimento Alves , Pâmalla Graziely Carvalho Morais , Geison dos Santos Pereira , Ana Luísa Leite Pereira , Maria Eugênia Ortiz Escobar , Cácio Luiz Boechat
{"title":"Geochemical background of some trace elements in Atlantic Forest soils in a cocoa-producing region and its implications for human health and food safety","authors":"Tatiana Reis dos Santos Bastos ,&nbsp;João Carlos Medeiros ,&nbsp;Clistenes Williams Araújo do Nascimento ,&nbsp;Kaique Mesquita Cardoso ,&nbsp;Paula Nascimento Alves ,&nbsp;Pâmalla Graziely Carvalho Morais ,&nbsp;Geison dos Santos Pereira ,&nbsp;Ana Luísa Leite Pereira ,&nbsp;Maria Eugênia Ortiz Escobar ,&nbsp;Cácio Luiz Boechat","doi":"10.1016/j.chemosphere.2025.144341","DOIUrl":"10.1016/j.chemosphere.2025.144341","url":null,"abstract":"<div><div>The background values for trace elements (TEs) in soils are crucial for environmental monitoring and food safety, as establishing quality reference values (QRVs) and help distinguish natural from anthropogenic sources. Brazil is the sixth-largest cocoa producer globally, with plantations concentrated in northeast and north regions. However, data on natural TEs concentrations in soils remain scarce, posing a significant challenge for food safety, human health, and environmental regulations. This study aims to determine natural TEs concentrations and establish QRVs for selected elements. Surface soil samples were collected from 38 native forest units and analyzed using exploratory, univariate, and multivariate statistical methods. Compared to soils around the world and from northern and northeastern Brazil, Ba and Cd (66.8 and 2.7 mg kg<sup>−1</sup>, respectively) exhibited the highest mean concentrations, except when compared to European soils. The results highlight that TEs concentrations in Atlantic Forest soils of southern Bahia differ due to geological diversity. Pedogenetic processes influenced TEs distribution, following the order: Fe &gt; Ti &gt; Ba &gt; V &gt; Cr &gt; Zn &gt; Cu &gt; Co &gt; Ni &gt; Pb &gt; Cd &gt; Sb &gt; Mo. QRVs were established using the 75th and 90th percentiles. Future research could integrate ecological and human health risk indices in cocoa-cultivated areas, considering soil, litter, plant tissues, and almonds. This approach would enhance understanding of TEs behavior under varying edaphic conditions, ultimately strengthening environmental monitoring strategies and food safety regulations.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144341"},"PeriodicalIF":8.1,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineral content in clam species from Sicily and Sardinia: A geographical, temporal and species-specific statistical comparison
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-21 DOI: 10.1016/j.chemosphere.2025.144328
Salvatore Giacobbe , Vincenzo Nava , Benedetta Sgrò , Fabio Scarpa , Daria Sanna , Marco Casu , Ilenia Azzena , Angela Giorgia Potortì , Giuseppa Di Bella
{"title":"Mineral content in clam species from Sicily and Sardinia: A geographical, temporal and species-specific statistical comparison","authors":"Salvatore Giacobbe ,&nbsp;Vincenzo Nava ,&nbsp;Benedetta Sgrò ,&nbsp;Fabio Scarpa ,&nbsp;Daria Sanna ,&nbsp;Marco Casu ,&nbsp;Ilenia Azzena ,&nbsp;Angela Giorgia Potortì ,&nbsp;Giuseppa Di Bella","doi":"10.1016/j.chemosphere.2025.144328","DOIUrl":"10.1016/j.chemosphere.2025.144328","url":null,"abstract":"<div><div>Clams are bivalves molluscs that have been exploited as food since ancient times. They contain high-quality nutrients, including essential minerals that have a great influence on human health. However, clams absorb and bioaccumulate potentially toxic elements, characterized by persistence in the environment, toxicity, and ability to accumulate and magnify within biological systems. For the first time, three co-occurring clam species (<em>Ruditapes decussatus</em>, <em>Cerastoderma glaucum</em> and <em>Polititapes aureus</em>) were investigated in their concentration of 20 mineral elements by inductively coupled plasma mass spectrometry (ICP-MS). The samples were collected in 2023 and 2024 from transitional water environments in Sicily, characterized by different levels of anthropogenic pressure. Additionally, <em>R. decussatus</em> samples from commercially exploited beds in two Sardinian lagoons were compared with samples of the locally consumed Sicilian stocks. Aim of the study was to carry out a geographical, temporal and species-specific statistical comparison of a wide range of elements, providing a novel contribution to the field. The clams showed an important level of essential elements, including Fe and Zn. The concentration of potentially toxic elements, being very low (Hg, Pd and Cd below the legal limits), does not cause health problems, according to risk assessment. The main potentially toxic element found in all samples is Al. The results showed a high variability in mineral concentrations among the different samples, in terms of time, species and, mostly, location, as proved by the PCA statistical model which discriminated Sicilian clams from Sardinian clams, due to the higher concentration of potentially toxic elements in the latter.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144328"},"PeriodicalIF":8.1,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143684081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hotspots and dynamics of dissolved thallium species at oxic-anoxic interfaces in flooded soils
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-20 DOI: 10.1016/j.chemosphere.2025.144331
Sha Zhang , Qianrui Huangfu , John Boyle , Longhua Wu , Jing Song , Zheng Chen
{"title":"Hotspots and dynamics of dissolved thallium species at oxic-anoxic interfaces in flooded soils","authors":"Sha Zhang ,&nbsp;Qianrui Huangfu ,&nbsp;John Boyle ,&nbsp;Longhua Wu ,&nbsp;Jing Song ,&nbsp;Zheng Chen","doi":"10.1016/j.chemosphere.2025.144331","DOIUrl":"10.1016/j.chemosphere.2025.144331","url":null,"abstract":"<div><div>Thallium (Tl) is highly toxic, predominantly existing in its monovalent Tl(I) state in the environment. However, the redox “niche” of both dissolved trivalent and monovalent Tl(III/I) remain under-studied in typical oxic-anoxic interfaces. Here, we hypothesize that the behavior of dissolved Tl is constrained by manganese (Mn), iron (Fe), and sulfur (S) species. Dissolved Tl(III/I) profiles and associated redox species Fe(III/II), Mn(II), and S(VI/II) were quantified spatially (a resolution of 1.8 mm) and temporally (diurnal and seasonal) at the rice rhizosphere and the soil-water interface (SWI). The results showed that hotspots of both dissolved Tl(III) and Tl(I) were identified at the rhizosphere and SWI, with redox niche closely following Mn-reducing conditions and also supporting an oxidation mechanism from Tl(I) to Tl(III). Supporting evidence were that newly formed ferromanganese plaque strongly retained the dissolved Tl, while dissolved Tl(III/I) hotspots coincided with moderate Mn-reducing conditions in both SWI and rhizosphere. Dissolved Tl(III) prevailed at higher ratios of dissolved Fe(III)-to-Fe(II). Additionally, porewater Tl(III/I) and copper (Cu(II)) showed similar behaviors at different temporospatial scales, likely due to shared redox constraints. Collectively, the evidence suggests that Mn oxides serve as both sources and sinks of dissolved Tl(III/I) at redox fluctuated areas. Tl mobility was greatly constrained in both more reduced (Fe and S) and more oxidized conditions, highlighting implications for developing effective remediation strategies.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144331"},"PeriodicalIF":8.1,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143674981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ecological risk assessment and ingestion of microplastics in edible finfish and shellfish species collected from tropical mangrove forest, Southeastern India
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-20 DOI: 10.1016/j.chemosphere.2025.144308
Sourav Bhattacharya , Prabhu Kolandhasamy , Abhishek Mandal , Rajendran Rajaram , Gopala Krishna Darbha
{"title":"Ecological risk assessment and ingestion of microplastics in edible finfish and shellfish species collected from tropical mangrove forest, Southeastern India","authors":"Sourav Bhattacharya ,&nbsp;Prabhu Kolandhasamy ,&nbsp;Abhishek Mandal ,&nbsp;Rajendran Rajaram ,&nbsp;Gopala Krishna Darbha","doi":"10.1016/j.chemosphere.2025.144308","DOIUrl":"10.1016/j.chemosphere.2025.144308","url":null,"abstract":"<div><div>In the Pichavaram mangroves in Southeast India, this study examines the seasonal trends and consumption of microplastic (MPs) by several fish and shellfish species. Four different seasons viz. summer, pre-monsoon, monsoon, and post-monsoon were used to gather the fish and shellfish samples from Pichavaram Mangrove Forest. The results of the present investigation revealed that MP abundance was higher during the monsoon (45 %), suggesting seasonal runoff and increased plastic pollution during heavy rains as key contributors. We observed microplastics in <em>Liza tade</em> (mullet), with 13.33 MPs/individuals in the summer, 0.77 MPs/individuals in the pre-monsoon, 6.3 MPs/individuals in the monsoon, and 2.67 MPs/individuals in the post-monsoon. A significant proportion (32 %) of MPs were smaller than 1 mm. The fibres were predominated with blue (40 %) and red (13 %). The polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET) were the primary polymers, according to μ-Raman spectroscopy. The fish species <em>Liza tade</em> and <em>Etroplus suratensis</em> showed the highest levels of contamination, while the shellfish species <em>Portunus sanguinolentus</em> and <em>Scylla serrata</em> did the same. Comparative global analyses reveal that mangrove ecosystems across different regions exhibit the presence of similar polymer types, but microplastic sources vary greatly from place to place. This work highlights the pervasive nature of MPs, their complex seasonal behavior, and their ecological implications, advocating for targeted mitigation strategies to address MP pollution and its potential risks to marine life and ecosystems.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144308"},"PeriodicalIF":8.1,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143674976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Removal of Ni2+ and Cd2+ from aqueous solutions by bionanosorbents: Isotherm, thermodynamic and mechanistic studies
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-20 DOI: 10.1016/j.chemosphere.2025.144311
Christophe Waterlot , Daniela Duarte-Serrano , Caroline Hadad , Arash Jamali , Albert Nguyen Van Nhien
{"title":"Removal of Ni2+ and Cd2+ from aqueous solutions by bionanosorbents: Isotherm, thermodynamic and mechanistic studies","authors":"Christophe Waterlot ,&nbsp;Daniela Duarte-Serrano ,&nbsp;Caroline Hadad ,&nbsp;Arash Jamali ,&nbsp;Albert Nguyen Van Nhien","doi":"10.1016/j.chemosphere.2025.144311","DOIUrl":"10.1016/j.chemosphere.2025.144311","url":null,"abstract":"<div><div>The present work presents the efficiency and the limit in using bionanosorbents (cellulose, chitin and modified chitin nanocrystals) for the sorption of metal ions M<sup>2+</sup> (M = Ni and Cd) in batch systems. Bionanosorbents were extracted from plants and shrimp shells, two available and low-cost materials. If cellulose and chitin nanocrystals did not efficiently remove metals in the experimental conditions of this work, the surface-modified chitin exhibited enhancement for the Ni<sup>2+</sup> and Cd<sup>2+</sup> adsorption capacity than original chitin nanocrystals. The Langmuir and Freundlich models fitted well to the experimental data from which the maximum adsorption capacity was 139.2 mg Ni g<sup>−1</sup> and 38.4 mg Cd g<sup>−1</sup>. Regarding the Gibbs free energy and the Hall parameter, the sorption of Ni<sup>2+</sup> and Cd<sup>2+</sup> were spontaneous and favourable for pH around the neutrality. This corroborates the examination of IR spectra of oxidized chitin nanocrystals before and after the sorption process from which the metal removal mechanism was mainly attributed to the formation of complexes and ion exchanges of the bionanosorbent and metal ions. Element mappings of the bionanosorbents after sorption revealed a homogeneous distribution of Cd(II).</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144311"},"PeriodicalIF":8.1,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143674989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boosting biodegradation and mineralization efficiencies of chlorinated VOCs: The synergy of H2O2 and biotrickling filtration
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-19 DOI: 10.1016/j.chemosphere.2025.144309
Shiva Ghiasvand , Gholamreza Moussavi , Madjid Mohseni
{"title":"Boosting biodegradation and mineralization efficiencies of chlorinated VOCs: The synergy of H2O2 and biotrickling filtration","authors":"Shiva Ghiasvand ,&nbsp;Gholamreza Moussavi ,&nbsp;Madjid Mohseni","doi":"10.1016/j.chemosphere.2025.144309","DOIUrl":"10.1016/j.chemosphere.2025.144309","url":null,"abstract":"<div><div>This study explores a new biodegradation process of H<sub>2</sub>O<sub>2</sub>-stimulated BTFs to remove perchloroethylene (PCE) from the contaminated air stream. BTF stimulated with H<sub>2</sub>O<sub>2</sub> significantly boosted PCE biodegradation compared to conventional methods. Optimal parameters for H<sub>2</sub>O<sub>2</sub>-assisted PCE biodegradation were also identified (nominal inlet concentration = 150 ppm, EBCT = 30 s, H<sub>2</sub>O<sub>2</sub>/PCE molar ratio = 0.2). Under these optimum conditions, the BTF achieved a maximum PCE removal efficiency of around 95 %, a mineralization rate of 65 %, and an elimination capacity of 117 g/m<sup>3</sup>.h, demonstrating its effectiveness. The BTF maintained stable performance under various PCE loads, suggesting its applicability for industrial cases. Moreover, the study revealed a positive correlation between increasing H<sub>2</sub>O<sub>2</sub>/PCE ratios and the activities of key enzymes responsible for biodegradation including dehydrogenase)increased from 1.3 to 26.1 mg-TF/g<sub>biomass</sub>), peroxidase (increased from 0 to 251 U/g<sub>biomass</sub>), and catalase (increased from 0 to 7.8 U/g<sub>biomass</sub>) when the ratio was increased from 0 to 0.2. The H<sub>2</sub>O<sub>2</sub>-stimulated BTF performed efficiently for biodegradation (&gt;90 %) and mineralization (&gt;60 %) of PCE at empty bed contact times between 20 and 60 s. Finally, the absence of PCE and toxic intermediates in the recycled liquid supports the efficient biodegradation of PCE in the developed system. In conclusion, H<sub>2</sub>O<sub>2</sub>-stimulated BTF shows promise as a sustainable and cost-effective approach for biodegradation of chlorinated organic compounds in contaminated air streams.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144309"},"PeriodicalIF":8.1,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Postprocessing methods based on minimum detectable amount and method blank for data reporting of particle count and refining estimation of matrix spike recovery in environmental microplastics analysis
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-18 DOI: 10.1016/j.chemosphere.2025.144325
Wenjian Lao
{"title":"Postprocessing methods based on minimum detectable amount and method blank for data reporting of particle count and refining estimation of matrix spike recovery in environmental microplastics analysis","authors":"Wenjian Lao","doi":"10.1016/j.chemosphere.2025.144325","DOIUrl":"10.1016/j.chemosphere.2025.144325","url":null,"abstract":"<div><div>Data handling that converts the raw data into a deliverable dataset is a necessary step in any analytical work. This procedure involves applying detection limits to shaping the raw data to form a deliverable dataset. The detection limit for microplastics analysis is the minimum detectable amount (MDA) that can be calculated from the particle counts of procedural blank samples following the rules of the Poisson distribution. Currently, there is a lack of adequate data reporting guidance encompassing the MDA for microplastics analysis. The goal of this study was to establish a robust protocol for processing count-based raw data using the particle counts of the MDA and the procedural blank. Utilizing the dataset of an interlaboratory comparison exercise, effectiveness of the protocol was elaborated to generate a deliverable dataset and to accurately define the matrix spiking recoveries. The guidance was applied to the raw data of all size fractions (1 - &gt;500 μm), four individual size fractions (&gt;500, 212–500, 20–212, 1–20 μm), and two morphologies (fiber and non-fiber). Six possible data reporting scenarios were identified, with the raw data ranging well above the MDA to below the critical value. One-third (12 of 34) of the raw data for all size fractions needed blank-MDA corrections. The mean values of the spiking recoveries decreased by up to 10 % after performing the data reporting guidance. Application of this suggested data reporting guidance may be beneficial for high quality data for microplastics analysis.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144325"},"PeriodicalIF":8.1,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessment of PFAS levels in drinking water: A case study from Poznań County (Poland)
IF 8.1 2区 环境科学与生态学
Chemosphere Pub Date : 2025-03-18 DOI: 10.1016/j.chemosphere.2025.144326
Dominika Sikora , Barbara Poniedziałek , Piotr Rzymski
{"title":"Assessment of PFAS levels in drinking water: A case study from Poznań County (Poland)","authors":"Dominika Sikora ,&nbsp;Barbara Poniedziałek ,&nbsp;Piotr Rzymski","doi":"10.1016/j.chemosphere.2025.144326","DOIUrl":"10.1016/j.chemosphere.2025.144326","url":null,"abstract":"<div><div>Exposure to per- and polyfluoroalkyl substances (PFAS) through drinking water has emerged as a significant public health concern due to their persistent, bioaccumulative nature and adverse health effects. Drinking water is the primary non-occupational source of PFAS exposure. Recently, investigative journalism has alerted about the presumptive contamination of drinking water at various European sites, including Poland. However, direct data on PFAS concentrations in raw and treated drinking water in Poland remain scarce. Therefore, this study analyzed the concentrations of 20 PFAS in 18 drinking water samples from Poznań County in Greater Poland, where the contamination of drinking water with PFAS was also presumed. In most samples (14/18; 77.7 %), PFAS concentrations were below the method detection limit (&lt;0.001 μg/L). Positive samples revealed total PFAS levels in the 0.0014–0.0041 μg/L range, decisively below the safety threshold established by the European Drinking Water Directive (&lt;0.1 μg/L). Daily consumption of 1.5 or 2.0 L of water containing PFAS by a 70-kg adult would constitute 4.8–9.3 % or 6.4–18.6 % of tolerable intake set by the European Food Safety Authority. These findings suggest that drinking water in the studied area is not a significant source of PFAS exposure. Further research is recommended to assess PFAS contamination in drinking water across a broader geographic scope in Poland to better understand the national contamination status.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"377 ","pages":"Article 144326"},"PeriodicalIF":8.1,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143654527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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