Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-02-24DOI: 10.1016/j.biombioe.2026.109170
Mosaed S. Alhumaimess, Shahad K.M. Alsirhani, Modather F. Hussein, Ibrahim Hotan Alsohaimi, Huda I. Aljaddua, Amr A. Essawy, M.R. El-Aassar, Hassan M.A. Hassan
{"title":"Biogenic synthesis of Fe2O3-MgO nanocomposites for biodiesel production from waste cooking oil: Optimization via response surface methodology","authors":"Mosaed S. Alhumaimess, Shahad K.M. Alsirhani, Modather F. Hussein, Ibrahim Hotan Alsohaimi, Huda I. Aljaddua, Amr A. Essawy, M.R. El-Aassar, Hassan M.A. Hassan","doi":"10.1016/j.biombioe.2026.109170","DOIUrl":"10.1016/j.biombioe.2026.109170","url":null,"abstract":"<div><div>Fe<sub>2</sub>O<sub>3</sub>-MgO nanocomposites containing 5 and 10 mol% Fe<sub>2</sub>O<sub>3</sub> were synthesized via a biogenic solution combustion method using pomegranate seed extract as a bio-fuel and stabilizing agent. The combustion process promoted rapid gas evolution, resulting in mesoporous structures with reduced crystallite sizes. XRD confirmed the formation of cubic MgO with no secondary MgFe<sub>2</sub>O<sub>4</sub> phase, while Scherrer analysis showed a decrease in crystallite size from 15.4 nm (MgO) to 10.6 nm (10 mol% Fe<sub>2</sub>O<sub>3</sub>-MgO). BET analysis revealed an increase in surface area from 73.3 m<sup>2</sup>/g (MgO) to 87.4 m<sup>2</sup>/g (10 mol% Fe<sub>2</sub>O<sub>3</sub>-MgO) with mesoporous characteristics. XPS results confirmed Fe–O–Mg interactions and the presence of Fe<sup>3+</sup>/Fe<sup>2+</sup> species, generating bifunctional acidic–basic active sites. TGA demonstrated that the composite exhibited enhanced thermal stability compared to pristine MgO. The catalytic activity was evaluated for the transesterification of waste cooking oil. A central composite design (CCD) under Response Surface Methodology (RSM) was employed to optimize methanol-to-oil molar ratio (3–18), catalyst loading (1–5%), reaction time (1–6 h), and temperature (40–70 °C). ANOVA analysis showed a significant quadratic model (R<sup>2</sup> = 0.9668, F-value = 31.19). The optimal conditions (15:1 M ratio, 2% catalyst, 5 h, 60 °C) yielded 91.8% biodiesel conversion. The catalyst maintained high activity over multiple cycles with minimal performance loss. These results demonstrate that controlled Fe incorporation enhances surface properties and catalytic efficiency in biodiesel production.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109170"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147279194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-02-27DOI: 10.1016/j.biombioe.2026.109186
Yanjun Hu , Chong Yang , Fan Yu , Qianqian Guo , Xingxuan Zhang , Wei Bao , Kitae Baek , Rufei Lu , Frederik Ronsse
{"title":"Molten salt-assisted Co-pyrolysis of biomass and waste plastics: Analysis of product characteristics","authors":"Yanjun Hu , Chong Yang , Fan Yu , Qianqian Guo , Xingxuan Zhang , Wei Bao , Kitae Baek , Rufei Lu , Frederik Ronsse","doi":"10.1016/j.biombioe.2026.109186","DOIUrl":"10.1016/j.biombioe.2026.109186","url":null,"abstract":"<div><div>Co-pyrolysis is an effective way to achieve high-value utilization of biomass and waste plastics. To overcome the limitations of asynchronous heat transfer in traditional co-pyrolysis processes, a ternary molten carbonate system (Li<sub>2</sub>CO<sub>3</sub>–Na<sub>2</sub>CO<sub>3</sub>–K<sub>2</sub>CO<sub>3</sub>) was used as the reaction medium to study the effects of temperature (450–550 °C) and feedstock ratio (CS:PE = 3:1–1:3) on the co-pyrolysis products of corn stover (CS) and polyethylene (PE) plastic. The molten-salt environment facilitated synchronized decomposition of CS and PE plastic, effectively suppressing polycondensation and coking reactions while promoting hydrodeoxygenation of functional groups and C–O bond cleavage. Moreover, alkaline sites provided by alkali-metal cations catalyzed more complete secondary cracking and reforming of volatiles, resulting in an increase in gas production and a decrease in bio-oil and biochar production. Meanwhile, the fractions of H<sub>2</sub> and CO in the syngas were enriched, the hydrocarbon content in the pyrolysis bio-oil increased, and oxygenated compounds such as alcohols, aldehydes, and ketones were markedly reduced. Additionally, the templating and etching effects of the molten salt improved the structural ordering of the biochar, lowered its O/C ratio, and promoted a transition from microporous to mesoporous architecture. Notably, the synergistic effect between CS and PE was most pronounced at 550 °C with a 1:1 blending ratio, where the H<sub>2</sub> content reached 29.26 vol% (108.11 mL g<sup>−1</sup>) and the hydrocarbon fraction in the bio-oil increased to 62.52%. Overall, molten salt-assisted co-pyrolysis provides a promising strategy for the targeted production of H<sub>2</sub>/CO-rich syngas, low-oxygen bio-oil, and structurally optimized biochar from biomass and waste plastics.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109186"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147329986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-02-26DOI: 10.1016/j.biombioe.2026.109171
Yang Wang , Dong Guo , Junlin Ji , Zhihan Luo , Zhicheng Zhu , Ruirui Hou , Kai Wu , Hong Yang , Jinhe Jiang , Fang Yin
{"title":"Anaerobic digestion of acidic waste mash via light-assisted & hemin-acclimated inoculum: A case study of cassava alcohol stillage","authors":"Yang Wang , Dong Guo , Junlin Ji , Zhihan Luo , Zhicheng Zhu , Ruirui Hou , Kai Wu , Hong Yang , Jinhe Jiang , Fang Yin","doi":"10.1016/j.biombioe.2026.109171","DOIUrl":"10.1016/j.biombioe.2026.109171","url":null,"abstract":"<div><div>Cassava alcohol stillage is high-strength organic wastewater generated during bioethanol production. Its high organic load and propensity for volatile fatty acid accumulation during anaerobic digestion (AD) can inhibit its degradation efficiency significantly. This study introduced porphyrin-mediated inoculum acclimation under light to investigate the synergy between photosynthetic and methanogenic communities in AD. In the present study, preliminary experiments were conducted by supplementing the AD system with varying concentrations of hemin (2.5–7.5 g/L), using cassava alcohol stillage as the substrate. Methane (CH<sub>4</sub>) production enhancement was limited, ranging from 4.66% to 17.49%. Under 5 g/L hemin combined with acclimated inoculum, methane production increased by > 120%, total organic carbon degradation rate improved by 20.94%, acidification lag phase was shortened by 80%, and the digestion cycle was reduced from 28 d to 14–16 d. Following introduction of the inoculum acclimated under light in the presence of hemin over a four-month period, the methanogenic community was enriched substantially at the end of fermentation. The relative abundances of <em>Methanobacteriota</em>—the core methanogenic archaeal phylum—reached 5.92%, 10.12%, and 4.11% in the 2.5 g/L, 5 g/L, and 7.5 g/L treatment groups, respectively, exceeding the control group value of 2.69%. Furthermore, the proportion of persistent microbial taxa increased from 69.57% to approximately 82%, indicating selective enrichment and stabilization of the core microbiome responsible for AD through the combined effects of light and hemin. The results confirm that pretreatment with light and hemin effectively enhances the AD of cassava alcohol stillage.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109171"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-02DOI: 10.1016/j.biombioe.2026.109213
Muhammad Waqas , Abdul-Sattar Nizami , Mohammad Rehan , Hesam Kamyab , Osman Atilla Arikan , Cosimo Magazzino
{"title":"The implication of continuous thermophilic composting for the resource recovery from slaughterhouse waste","authors":"Muhammad Waqas , Abdul-Sattar Nizami , Mohammad Rehan , Hesam Kamyab , Osman Atilla Arikan , Cosimo Magazzino","doi":"10.1016/j.biombioe.2026.109213","DOIUrl":"10.1016/j.biombioe.2026.109213","url":null,"abstract":"<div><div>This study implies the continuous thermophilic composting (CTC) in the context of sustainable management and resource recovery from slaughterhouse waste (SHW). Various temperature trials, including 35 °C, 45 °C, 55 °C, and 65 °C, were applied using a batch mode in-vessel composting system to determine its impact on the composting of SHW. It was observed that thermophilic temperature trials (55 °C and 65 °C) significantly enhanced the pH of the compost matrix, promoting both degradation and mineralization processes. The highest degree of OM degradation (56.59%) was recorded at 65 °C, followed by 55 °C (53.52%). Similarly, in comparison to the initial ash content (13.76%), the maximum ash content (54.19%) was observed at 65 °C after 40 days of incubation. Substantial variations were also observed for NH<sub>4</sub><sup>+</sup>-N and NO<sub>3</sub><sup>−</sup>-N concentration, where the highest NH<sub>4</sub><sup>+</sup>-N (334.55 mg kg<sup>−1</sup>) and NO<sub>3</sub><sup>−</sup>-N (157.63 mg kg<sup>−1</sup>) concentrations were observed at 65 °C, followed by 55 °C. Compost stability was achieved within 40 to 45 days in the trial incubated at 65 °C, and remained unchanged when the temperature was maintained at 25 °C for the last 10 days of experimentation. Therefore, compared to 55 °C, composting at 65 °C with uniform turning to ensure proper air supply can achieve compost stability in 40 to 45 days, with compost quality according to international compost quality guidelines. However, future research is required to explore the enlargement of the scale of CTC, microbial analysis in the final compost, nitrogen losses in the form of ammonia emissions and novel additives to reduce nitrogen losses and enhance the quality of SHW composting.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109213"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-05DOI: 10.1016/j.biombioe.2026.109227
Tereza Zlevorová , Jakub Lachman , Antonín Kintl , Julie Sobotková , Martin Lisý , Marek Baláš
{"title":"Interchangeability of various agricultural residues in small-scale boilers based on their inorganic composition: combustion similarities, environmental impact and ash properties","authors":"Tereza Zlevorová , Jakub Lachman , Antonín Kintl , Julie Sobotková , Martin Lisý , Marek Baláš","doi":"10.1016/j.biombioe.2026.109227","DOIUrl":"10.1016/j.biombioe.2026.109227","url":null,"abstract":"<div><div>Agricultural processing leaves behind many residues that could be further utilized, for example for heating. Among currently unused crop residues are those of <em>Melilotus albus</em>, <em>Medicago sativa</em>, <em>Medicago lupulina</em>, <em>Sinapis alba</em>, <em>Hordeum vulgare</em> and <em>Trifolium incarnatum</em>. Various samples of these plants were pelletized for the purposes of this study. All pellets were subsequently thoroughly analyzed and then combusted in a 25 kW boiler. Several similarities in their combustion behavior were observed: no slagging, high PM emissions (due to high K and Cl content), high NO<sub>x</sub> emissions and the production of soft, powdery ash rich in nutrients. The ash elemental composition of the raw fuels plotted in an SCK ternary diagram indicated such behavior was likely to occur. This method could thus be utilized by boiler operators when looking for possible fuel replacement or supplementation. A widely used biofuel of similar inorganic composition, in this case sunflower husks, was used to successfully confirm this hypothesis. The use of fertilizers on fodder crops increases the environmental impact of their subsequent combustion, however, the high retention rates of essential plant nutrients in the produced ash make it a valuable commodity in circular economy.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109227"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-05DOI: 10.1016/j.biombioe.2026.109210
Linh Doan , Anh Q.V. Tran , Quynh K.L. Ong , Khanh G. Huynh , Khoa Tran , Thanh Khoa Phung
{"title":"Enhancing lipid accumulation in marine microalgae for sustainable biofuel applications: A review of Nannochloropsis and Tetraselmis","authors":"Linh Doan , Anh Q.V. Tran , Quynh K.L. Ong , Khanh G. Huynh , Khoa Tran , Thanh Khoa Phung","doi":"10.1016/j.biombioe.2026.109210","DOIUrl":"10.1016/j.biombioe.2026.109210","url":null,"abstract":"<div><div>Marine microalgae are increasingly recognized as promising feedstocks for sustainable biofuel production due to their rapid growth rates, high lipid productivity, and ability to utilize saline water resources. Among them, <em>Nannochloropsis</em> and <em>Tetraselmis</em> have attracted particular attention because of their robust cultivation characteristics, favorable fatty acid profiles, and adaptability to large-scale systems. This review critically examines lipid biosynthesis pathways in these two genera and systematically analyzes environmental, metabolic, and cultivation strategies employed to enhance lipid accumulation. Key approaches, including nutrient limitation, carbon supplementation, light and salinity modulation, and metabolic engineering, are evaluated in terms of lipid yield, fatty acid composition, and process feasibility. A focused comparison between <em>Nannochloropsis</em> and <em>Tetraselmis</em> is provided to highlight their respective advantages, limitations, and application scenarios in biofuel production. In addition, integration with wastewater treatment, co-cultivation systems, and techno-economic considerations are discussed to assess industrial viability. Unlike previous generalized reviews, this work emphasizes the linkage between biochemical mechanisms, enhancement strategies, and scalable biofuel applications. Finally, current technological bottlenecks and future research directions are outlined to support the transition of marine microalgal lipid production from laboratory studies to sustainable industrial deployment.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109210"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147359681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-03DOI: 10.1016/j.biombioe.2026.109196
Antonia Mabrysa T. Gadelha , Maria Alexsandra de S. Rios , Glauber Cruz , Samuel L.S. Medeiros , Graziela C.A. Zaninetti , Juliana T.de C. Leite
{"title":"Systematic analysis of babassu coconut shell combustion using TG, FTIR, activation energy, and prediction of gas emissions","authors":"Antonia Mabrysa T. Gadelha , Maria Alexsandra de S. Rios , Glauber Cruz , Samuel L.S. Medeiros , Graziela C.A. Zaninetti , Juliana T.de C. Leite","doi":"10.1016/j.biombioe.2026.109196","DOIUrl":"10.1016/j.biombioe.2026.109196","url":null,"abstract":"<div><div>In this study, the thermal behavior of babassu coconut shell (BCS) combustion was analyzed through a systematic approach. The analysis was based on data from thermogravimetric analysis, Fourier-transform infrared spectroscopy, molar ratios (H/C and O/C), and prediction of the combustion gases. The isoconversional methods of Friedman, Ozawa–Flynn–Wall (OFW), and Kissinger–Akahira–Sunose (KAS) were utilized to evaluate the kinetics in the conversion range of 0.1 to 0.9. The molar ratio of hydrogen to carbon was found to range from approximately 1.3 to 1.8, with the ratio of oxygen to carbon ranging from 0.45 to 0.9. The FTIR spectra revealed functional groups consistent with lignocellulosic biomass. The mean activation energies were determined to be 133 kJ mol<sup>−1</sup> (Friedman), 180 kJ mol<sup>−1</sup> (KAS), and 190 kJ mol<sup>−1</sup> (OFW). The percentage of combustion gases was 21.05% for CO<sub>2</sub>, 0.012% for NO, and 0% for SO<sub>2</sub>. The results of E and the prediction of emitted gases are consistent with those observed for other lignocellulosic biomasses. The findings indicate the viability of BCS for utilization in combustion processes.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109196"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147360749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Energy efficiency in chemo-mechanical pretreatment of oil palm biomass: Sequence analysis and process optimization for enhanced bioethanol production","authors":"Yitong Niu , Kamoldeen Abiodun Ajijolakewu , Chee Keong Lee , Cheu Peng Leh","doi":"10.1016/j.biombioe.2026.109203","DOIUrl":"10.1016/j.biombioe.2026.109203","url":null,"abstract":"<div><div>Pretreatment of biomass to enhance enzymatic hydrolysis typically incurs additional energy inputs and associated costs in bioethanol production. This study evaluated the energy consumption and performance of two chemo-mechanical sequences—refining before chemical treatment (RBCT) and refining after chemical treatment (RACT)—for improving enzymatic saccharification of oil palm empty fruit bunches (OPEFB). On the basis of initial untreated OPEFB dry mass, RACT reduced the specific pretreatment energy requirement to 30.92 kWh·kg<sup>−1</sup> compared with 43.65 kWh·kg<sup>−1</sup> for RBCT, while achieving a higher glucose yield (41.4%) and sugar recovery (79.7%). Although RBCT and RACT showed only minor differences in fibre morphology and bulk composition, RACT delivered superior energy-normalized saccharification performance and is therefore more cost-effective within the defined laboratory energy boundary. In addition, the effects of NaOH concentration, temperature, and reaction time on energy consumption and fermentation efficiency were evaluated. Excessive pretreatment severity did not improve fermentation performance, whereas the mildest alkaline conditions achieved the most favourable balance between energy input and bioconversion outcome.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109203"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147360752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-02DOI: 10.1016/j.biombioe.2026.109145
Rene Lesme Jaén , Olasunkanmi Opeoluwa Adeoye , Electo Eduardo Silva Lora , Albert Ratner , Rubenildo Vieira Andrade , Luis Roberto de Mello e Pinto , Diego Mauricio Yepes Maya , Leonardo Peña Pupo
{"title":"Hydrogen production through biomass gasification in bubbling fluidized bed: A meta-review of key parameters and performance data","authors":"Rene Lesme Jaén , Olasunkanmi Opeoluwa Adeoye , Electo Eduardo Silva Lora , Albert Ratner , Rubenildo Vieira Andrade , Luis Roberto de Mello e Pinto , Diego Mauricio Yepes Maya , Leonardo Peña Pupo","doi":"10.1016/j.biombioe.2026.109145","DOIUrl":"10.1016/j.biombioe.2026.109145","url":null,"abstract":"<div><div>Biomass gasification is a promising pathway for sustainable hydrogen production, but the vast and varied results in the report on hydrogen content in syngas from the literature hinder process optimization. This study addresses this through a rigorous meta-review, applying a PRISMA methodology and statistical framework to a dataset of 257 unique points from selected studies on bubbling fluidized bed gasifiers between 1996 and 2025. The study quantitatively synthesizes the complex, multi-dimensional parameter space, moving beyond qualitative summaries. Using k-means clustering, heterogeneous feedstocks were classified into distinct biomass categories based on their elemental ratios. Analysis of Covariance (ANCOVA), Response Surface Methodology (RSM), and Random Forest algorithms were employed to model variable effects, identify optimal conditions, and rank their relative importance. Results show steam is the superior gasifying agent. Sensitivity analysis revealed that catalyst category is the most influential variable (importance score = 0.58), followed by temperature and steam-to-biomass ratio. The models identified optimal conditions, predicting an average hydrogen content of 71% for a biomass category with H/C and O/C range of 1.23-1.52 and 0.52-0.75, respectively, using a metal catalyst with CaO. These findings showed that catalyst selection, particularly in sorption-enhanced reforming systems, for maximizing hydrogen yield and advancing efficient biomass-to-hydrogen conversion.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109145"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147360755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biomass & BioenergyPub Date : 2026-08-01Epub Date: 2026-03-07DOI: 10.1016/j.biombioe.2026.109223
J. Venkatesan , J. Preethi Rency Fathima , J. Bosco Franklin , A. Padmanaban , A. Kumaresan , S. John Sundaram , P. Maadeswaran , Kasinathan Kaviyarasu
{"title":"Interface-engineered CuBi2O4/biomass-derived activated carbon composites for supercapacitors","authors":"J. Venkatesan , J. Preethi Rency Fathima , J. Bosco Franklin , A. Padmanaban , A. Kumaresan , S. John Sundaram , P. Maadeswaran , Kasinathan Kaviyarasu","doi":"10.1016/j.biombioe.2026.109223","DOIUrl":"10.1016/j.biombioe.2026.109223","url":null,"abstract":"<div><div>In the present study, a co-precipitation method was used to synthesize CuBi<sub>2</sub>O<sub>4</sub> nanoflakes (NFs), and a CuBi<sub>2</sub>O<sub>4</sub>/biomass-derived activated carbon (AC) composite was prepared via sonication and investigated as a promising supercapacitor electrode material. Despite the intrinsic redox activity of CuBi<sub>2</sub>O<sub>4</sub>, its practical application is limited by low electrical conductivity and restricted surface area. To address these challenges, a porous AC matrix was introduced to enhance the electrochemical performance. Electrochemical measurements, including cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD), revealed that the CuBi<sub>2</sub>O<sub>4</sub>/AC composite exhibited a significantly enhanced specific capacitance of 228 F gg<sup>−1</sup> at 5 mV s<sup>−1</sup> and 170 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, compared to 131 F g<sup>−1</sup> and 105 F g<sup>−1</sup> for pristine CuBi<sub>2</sub>O<sub>4</sub>. Electrochemical impedance spectroscopy (EIS) analysis indicated a lower charge-transfer resistance. These findings suggest that the CuBi<sub>2</sub>O<sub>4</sub>/AC composite is a promising candidate for sustainable supercapacitor electrode applications with improved electrochemical performance.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"211 ","pages":"Article 109223"},"PeriodicalIF":5.8,"publicationDate":"2026-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147387620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}