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Thermal degradation of peeled cotton stalk with thermogravimetry/fourier transform infrared analysis and shuffled complex evolution algorithm 利用热重/傅立叶变换红外分析和洗牌复合进化算法分析去皮棉秆的热降解过程
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-06 DOI: 10.1016/j.biombioe.2025.107853
Qian Xie , Fahang Liu , Yu Zhong , Changhai Li , Yanming Ding
{"title":"Thermal degradation of peeled cotton stalk with thermogravimetry/fourier transform infrared analysis and shuffled complex evolution algorithm","authors":"Qian Xie ,&nbsp;Fahang Liu ,&nbsp;Yu Zhong ,&nbsp;Changhai Li ,&nbsp;Yanming Ding","doi":"10.1016/j.biombioe.2025.107853","DOIUrl":"10.1016/j.biombioe.2025.107853","url":null,"abstract":"<div><div>Cotton is one of the most important crops globally and is widely planted. This study systematically investigated the pyrolysis characteristics and product distribution of peeled cotton stalks using thermogravimetry/Fourier transform infrared analysis (TG-FTIR) at heating rates ranging from 5 to 60 K/min. Kinetic parameters were estimated using the two model-free methods, and the results revealed that the activation energy for pyrolysis varied between 182.97 and 213.11 kJ/mol. The three-component parallel reaction model, combined with the Shuffled Complex Evolution algorithm, was applied to perform inverse modeling of the experimental data. The corresponding exact kinetic parameters for independent hemicellulose, cellulose and lignin were obtained. The results revealed that the predicted values based on the optimized kinetic parameters were in good agreement with the experimental data. Ultimately, the blind prediction of the experimental curves at extra heating rates further confirmed the precision and suitability of the optimized kinetic parameters. The FTIR analysis indicated that the absorption spectra related to the peaks remained largely consistent at various heating rates. The evolution patterns of the gas components aligned with the trends observed in the derivative thermogravimetric curves, with the produced gases in the following order: CO<sub>2</sub>, formaldehyde, methanol, CO, and finally methane.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable biodiesel synthesis using bamboo leaves ash doped with Anser cygnoides eggshell derived CaO (BLA@SiO2-CaO) green catalyst: Characterization and optimization study
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-05 DOI: 10.1016/j.biombioe.2025.107815
Mohd. Rakimuddin Khan, Huirem Neeranjan Singh, Wangkhem Robinson Singh
{"title":"Sustainable biodiesel synthesis using bamboo leaves ash doped with Anser cygnoides eggshell derived CaO (BLA@SiO2-CaO) green catalyst: Characterization and optimization study","authors":"Mohd. Rakimuddin Khan,&nbsp;Huirem Neeranjan Singh,&nbsp;Wangkhem Robinson Singh","doi":"10.1016/j.biombioe.2025.107815","DOIUrl":"10.1016/j.biombioe.2025.107815","url":null,"abstract":"<div><div>The increasing demand for sustainable and renewable energy sources has led to significant research in biodiesel production. This study explores the synthesis of castor biodiesel using a novel bamboo leaves ash (BLA@SiO<sub>2</sub>) doped with swan goose (<em>Anser cygnoides</em>) eggshell derived CaO (BLA@SiO<sub>2</sub>-CaO) as green catalyst. <em>Anser cygnoides</em> eggshells were calcinated at 900°C for 3 h, and doped with (BLA@SiO<sub>2</sub>) via wet impregnation method at a mixing ratio of BLA@SiO<sub>2</sub>:CaO – 1:2, 1:3, and 1:4 wt%. The catalysts were characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and energy dispersive X-ray to determine their structural and morphological properties. Box-Behnken design-response surface methodology was employed for optimizing biodiesel production process with four input factors viz. methanol: oil molar ratio, catalyst concentration, reaction temperature and reaction time. Results indicated that BLA@SiO<sub>2</sub>-CaO catalyst exhibited excellent catalytic activity producing maximum biodiesel yield of 96.59 <span><math><mrow><mo>±</mo><mn>0</mn><mo>.</mo><mn>95</mn></mrow></math></span>% under the optimal conditions of 11.49:1 methanol to oil ratio, 5.27 wt% catalyst concentration, 60.24°C reaction temperature, and 1.54 h reaction time. The properties of biodiesel, including acid value (0.48 mg KOH/g), density (0.87 g/cm<sup>3</sup>), calorific value (40.5 MJ/kg), flash point (166°C), ester content (96.9 wt%), and kinematic viscosity (4.7 mm<sup>2</sup>/s) are found to be within the ASTM-D6751 and EN 14214 standard limits. The synthesized BLA@SiO<sub>2</sub>-CaO catalyst could be reused for up to seven cycles with yield above 84.2 <span><math><mrow><mo>±</mo><mn>1</mn><mo>.</mo><mn>1</mn></mrow></math></span>%. This study highlights the potential of utilizing waste materials like bamboo leaves ash and swan goose eggshells as a cost-effective and eco-friendly catalyst in biodiesel production.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":"Article 107815"},"PeriodicalIF":5.8,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143777658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the efficacy of TiO2-mediated calcareous nanocatalyst towards cost-effective biodiesel synthesis
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-05 DOI: 10.1016/j.biombioe.2025.107852
Rashid Imran Ahmad Khan , Rhithuparna D. , Abdul Razzaq Khan , Sadaf Ahmad , Samuel Lalthazuala Rokhum , Gopinath Halder
{"title":"Unveiling the efficacy of TiO2-mediated calcareous nanocatalyst towards cost-effective biodiesel synthesis","authors":"Rashid Imran Ahmad Khan ,&nbsp;Rhithuparna D. ,&nbsp;Abdul Razzaq Khan ,&nbsp;Sadaf Ahmad ,&nbsp;Samuel Lalthazuala Rokhum ,&nbsp;Gopinath Halder","doi":"10.1016/j.biombioe.2025.107852","DOIUrl":"10.1016/j.biombioe.2025.107852","url":null,"abstract":"<div><div>The global energy matrix, predominantly fuelled by fossil sources constituting 85 % of consumption, confronts critical ecological ramifications, including prodigious greenhouse gas emissions precipitating climate change and pervasive pollution. This probe elucidates the mechanistic proficiency and economic viability of TiO<sub>2</sub>-augmented CaO-derived nano-catalysts for biodiesel production from <em>Brassica napus</em> oil. Synthesized via sol-gel techniques with variable precursor concentrations and calcination temperatures, these nano-catalysts were rigorously characterized using UV spectroscopy, FTIR, SEM, XRD, zeta potential, EDAX, and particle size analysis. The utmost biodiesel yield of 95.87 % was attained utilizing response surface methodology under a 2.25-h reaction interval with a 5 % catalyst weight, a 1:12 oil-to-methanol ratio, and a temperature of 60 °C. Thermodynamic and kinetic examinations revealed the transesterification reaction to be endothermic following pseudo-first-order kinetics. The catalyst exhibited notable reusability, maintaining a conversion efficiency of 76.86 % after five consecutive cycles. The characteristics of the produced biodiesel met the required standards, with production costs calculated at $0.78 per litre and $7.0 per kilogram of TiO<sub>2</sub>-CaO catalyst, underscoring its economic feasibility. This research accentuates the TiO<sub>2</sub>-CaO nanocatalyst's potential in mitigating the environmental and economic detriments associated with fossil fuel dependency. Finally, the study provided future perspectives by identifying gaps highlighted in recent bibliometric analyses of the reported research.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":"Article 107852"},"PeriodicalIF":5.8,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143777657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Five-year impacts of biomass crop monoculture on soil enzyme activity, nitrogen pools, and other soil health indicators
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-05 DOI: 10.1016/j.biombioe.2025.107856
Nevien Elhawat , Éva Domokos-Szabolcsy , Szilvia Veres , Miklós G. Fári , Tarek Alshaal
{"title":"Five-year impacts of biomass crop monoculture on soil enzyme activity, nitrogen pools, and other soil health indicators","authors":"Nevien Elhawat ,&nbsp;Éva Domokos-Szabolcsy ,&nbsp;Szilvia Veres ,&nbsp;Miklós G. Fári ,&nbsp;Tarek Alshaal","doi":"10.1016/j.biombioe.2025.107856","DOIUrl":"10.1016/j.biombioe.2025.107856","url":null,"abstract":"<div><div>Soil health and nitrogen cycling are critical for sustainable biomass production, yet the long-term effects of monoculture biomass cropping on these factors remain underexplored. This study examines the five-year monoculture cultivation effects of giant reed (<em>Arundo donax</em> L.), miscanthus (<em>Miscanthus</em> x <em>giganteus</em>), and sida (<em>Sida hermaphrodita</em>) on soil biochemical properties, nitrogen species, and biomass yield stability under field conditions. Soil samples collected in autumn 2014 and spring 2015 revealed significant seasonal and crop-specific impacts on soil health indicators. Giant reed cultivation resulted in the highest urease activity in autumn (346 μg NH<sub>4</sub><sup>+</sup> g<sup>−1</sup> soil h<sup>−1</sup>), supporting enhanced nitrogen cycling, while miscanthus increased soil organic matter (SOM) to 4.77 % in spring, aiding carbon sequestration. Sida contributed to the highest dehydrogenase activity, indicating robust microbial activity, alongside increased organic nitrogen (4.92 mg kg<sup>−1</sup>) and total nitrogen levels (17.0 mg kg<sup>−1</sup>) in spring. Soil respiration and electrical conductivity varied by season, with pH values slightly higher in spring. Across all crops, nitrogen forms (nitrate, ammonium, and organic nitrogen) were generally higher in spring than autumn, highlighting seasonal dynamics. Yield stability was greatest in giant reed (2.01 kg m<sup>−2</sup> on average), while miscanthus and sida averaged 1.62 and 0.86 kg m<sup>−2</sup>, respectively. The findings underscore these crops' potential for sustainable biomass production and improved soil health in low-input systems.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":"Article 107856"},"PeriodicalIF":5.8,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143777655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal carbonization of swine manure in a continuous flow reactor pilot plant with process water recycling
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-05 DOI: 10.1016/j.biombioe.2025.107854
R.P. Ipiales , E. Diaz , M.A. de la Rubia , J.J. Rodriguez , A.F. Mohedano
{"title":"Hydrothermal carbonization of swine manure in a continuous flow reactor pilot plant with process water recycling","authors":"R.P. Ipiales ,&nbsp;E. Diaz ,&nbsp;M.A. de la Rubia ,&nbsp;J.J. Rodriguez ,&nbsp;A.F. Mohedano","doi":"10.1016/j.biombioe.2025.107854","DOIUrl":"10.1016/j.biombioe.2025.107854","url":null,"abstract":"<div><div>This paper deals with hydrothermal carbonization (HTC) of swine manure in a pilot plant setup operating in continuous mode. Two temperatures (210 °C and 250 °C) were tested and recycling of the liquid fraction was studied to improve the quality of the resulting hydrochar. The hydrochars obtained at 210 °C fulfill the criteria to be used as solid biofuels (ISO 17225–8:2023). Increasing the reaction temperature led to a dramatic reduction of hydrochar yield (from 50 to 20 %) in conventional HTC (with tap water), accompanied by a moderate improvement of higher heating value (HHV, 18.2–20.4 MJ/kg), which decreased the energy yield (from 52.2 % to 23.8 %). Process water recycling significantly improved the hydrochar yield, reaching more than 80 % and 55 % at 210 °C and 250 °C, respectively, because of the formation of secondary hydrochar. C content and HHV also increased, giving rise to substantially higher energy recovery, which surpassed 93 % after four recycling tests at 210 °C. Fouling and alkali indexes of hydrochars showed much lower values than those of the feedstock mainly attributed to the solubilization of Na and K. At 210 °C, process water recycling favored a further reduction of those indexes. N and P were largely transferred to the liquid fraction, particularly the latter. Zn and Cu were, by far, the most abundant heavy metals in hydrochars, with a Zn content being slightly above the value established in Decision (EU) 2022/1244 for their application as a soil amendment.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":"Article 107854"},"PeriodicalIF":5.8,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143777656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bio-jet fuels from photosynthetic microorganisms: A focus on downstream processes
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-04 DOI: 10.1016/j.biombioe.2025.107833
Giovanni Antonio Lutzu , Luca Usai , Adriana Ciurli , Carolina Chiellini , Fabrizio Di Caprio , Francesca Pagnanelli , Ali Parsaeimehr , Ilze Malina , Kristaps Malins , Bartolomeo Cosenza , Massimiliano Fabbricino , Alessandra Cesaro , Grazia Policastro , Giacomo Cao , Alessandro Concas
{"title":"Bio-jet fuels from photosynthetic microorganisms: A focus on downstream processes","authors":"Giovanni Antonio Lutzu ,&nbsp;Luca Usai ,&nbsp;Adriana Ciurli ,&nbsp;Carolina Chiellini ,&nbsp;Fabrizio Di Caprio ,&nbsp;Francesca Pagnanelli ,&nbsp;Ali Parsaeimehr ,&nbsp;Ilze Malina ,&nbsp;Kristaps Malins ,&nbsp;Bartolomeo Cosenza ,&nbsp;Massimiliano Fabbricino ,&nbsp;Alessandra Cesaro ,&nbsp;Grazia Policastro ,&nbsp;Giacomo Cao ,&nbsp;Alessandro Concas","doi":"10.1016/j.biombioe.2025.107833","DOIUrl":"10.1016/j.biombioe.2025.107833","url":null,"abstract":"<div><div>The aviation industry is a \"hard to electrify\" sector with limited possibilities for alternative fuels such as green hydrogen. Therefore, there is a call for sustainable fuel alternatives which is driving intensive research into bio-jet fuels (BJF) that could be used in aviation, without revamping the aircraft fleets and the aviation infrastructures. This review evaluates the potential of photosynthetic microorganisms, focusing on the most challenging downstream processes, i.e. bio-oil production and its catalytic upgrade. The main bottlenecks of such processes are identified, and the most recent solutions, offered to overcome them, are critically reviewed. Finally, a statistical analysis of the key characteristics of current BJF derived from microalgae and cyanobacteria is presented, along with a discussion on their suitability for the aviation industry and the primary areas for improvement.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"198 ","pages":"Article 107833"},"PeriodicalIF":5.8,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermochemical conversion of bioplastics: Evolved gas analysis and kinetics factors for polylactic acid (PLA) - waste biomass mixture
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-03 DOI: 10.1016/j.biombioe.2025.107848
Muhammad Rabah, Labeeb Ali, Mohamed Shafi Kuttiyathil, Mohammednoor Altarawneh
{"title":"Thermochemical conversion of bioplastics: Evolved gas analysis and kinetics factors for polylactic acid (PLA) - waste biomass mixture","authors":"Muhammad Rabah,&nbsp;Labeeb Ali,&nbsp;Mohamed Shafi Kuttiyathil,&nbsp;Mohammednoor Altarawneh","doi":"10.1016/j.biombioe.2025.107848","DOIUrl":"10.1016/j.biombioe.2025.107848","url":null,"abstract":"<div><div>Polylactic acid (PLA) is the highest produced bioplastic globally but facing end-life disposal challenges. Pyrolysis proves to be a viable option, but the recovered product profile is not desirable in terms of quality and value. Date Pits (DP), a waste byproduct chemically rich with lignocellulosic fragments, can provide unique carbon-rich precursors which are highly desirable in the pyrolysis process. This study aims to investigate the synergistic effect of DP addition on PLA pyrolysis products. Thermogravimetric data demonstrates that PLA mixing with DP promotes char formation, initiates degradation at lower temperatures, and decreases the peak decomposition temperature (T<sub>p</sub>) from 362 °C to 343 °C. Primary pyrolysis occurs in the range of (200–400 °C) with 75.5 % weight loss and low heating rate shifts T<sub>p</sub> toward lower temperatures by averting the development of the thermal lag effect. Chemical structure analysis through FTIR shows that DP addition promotes controlled volatile release through PLA depolymerization hence yielding more uniformed and distinguished peaks for hydroxyl, phenols, and ester-containing groups. Moreover, it promoted free radical reactions that enhanced lactide recovery by restricting aldehyde formation. GCMS profiling indicates that pure PLA pyrolysis majorly yieldes lactide (3,6-Dimethyl-1,4-dioxane-2,5-dione). While the copyrolysis with date pits diversifies this product profile with the production of hydrocarbons (heptane and decane), aromatics (xylene, toluene and styrene), and furans which are highly valued in biorefineries, as drop-in fuels and in petrochemical industries. Kinetic analysis shows that the PLA/DP co-pyrolysis mixture reduces activation energies (E<sub>a</sub>) by 18 % and also reduces the thermodynamic parameters.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107848"},"PeriodicalIF":5.8,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143759749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing marine cellulose-based packaging: A review on sustainable biorefinery perspectives
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-03 DOI: 10.1016/j.biombioe.2025.107849
Senthilkumar Palanisamy , Barani Kumar Saravana Kumar , Gayathri Sivakumar , Sakshadhan Selvan , Jintae Lee , Devaraj Bharathi
{"title":"Advancing marine cellulose-based packaging: A review on sustainable biorefinery perspectives","authors":"Senthilkumar Palanisamy ,&nbsp;Barani Kumar Saravana Kumar ,&nbsp;Gayathri Sivakumar ,&nbsp;Sakshadhan Selvan ,&nbsp;Jintae Lee ,&nbsp;Devaraj Bharathi","doi":"10.1016/j.biombioe.2025.107849","DOIUrl":"10.1016/j.biombioe.2025.107849","url":null,"abstract":"<div><div>The growing environmental effect of traditional plastic packaging has caused a growing search for sustainable alternatives, and cellulose has emerged as an attractive option due to its mechanical strength, biodegradability, and renewable nature. Marine-derived cellulose from algae, mangroves, and marine sediments remains poorly understood despite its unique structural and functional advantages, whereas a significant amount of research has been conducted on terrestrial cellulose sources including plants and agricultural waste. This review emphasizes marine cellulose's potential for biodegradable and functional food packaging applications through examining its biological origins, isolation techniques, and physicochemical characteristics. The increased moisture resistance, biodegradability, and flexibility of marine-derived cellulose are highlighted in compared to terrestrial cellulose, making it an excellent option for sustainable packaging. It remains a number of challenges to be resolved, such as low extraction efficiency, expensive processing, and inconsistent physicochemical characteristics. Unlocking the full potential of marine cellulose requires addressing these technical and financial obstacles through scalability studies, material functionalization, and green extraction techniques. This review provides a comprehensive evaluation of marine cellulose as an alternative packaging material and identifies key research gaps and future directions. By bridging the knowledge gap in marine cellulose research and its industrial applications, this study contributes to the ongoing efforts to reduce plastic pollution, promote a circular bioeconomy, and enhance environmental sustainability.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107849"},"PeriodicalIF":5.8,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the potential of novel feedstock (Caesalpinia bonduc seeds) for circular biodiesel production using seed shell-derived green nanocatalysts
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-02 DOI: 10.1016/j.biombioe.2025.107847
Roshan Amjad , Mushtaq Ahmad , Shazia Sultana , Mamoona Munir , Muhammad Ishtiaq Ali , Mohamed M. El-Toony , Nizomova Maksuda Usmankulovna , Burkhan Avutkhanov , Ahmad Mustafa
{"title":"Exploring the potential of novel feedstock (Caesalpinia bonduc seeds) for circular biodiesel production using seed shell-derived green nanocatalysts","authors":"Roshan Amjad ,&nbsp;Mushtaq Ahmad ,&nbsp;Shazia Sultana ,&nbsp;Mamoona Munir ,&nbsp;Muhammad Ishtiaq Ali ,&nbsp;Mohamed M. El-Toony ,&nbsp;Nizomova Maksuda Usmankulovna ,&nbsp;Burkhan Avutkhanov ,&nbsp;Ahmad Mustafa","doi":"10.1016/j.biombioe.2025.107847","DOIUrl":"10.1016/j.biombioe.2025.107847","url":null,"abstract":"<div><div>Current work focuses on the investigation of newly explored <em>Caesalpinia bonduc</em> (L.) seed oil as an efficient and oil rich (45 % w/w) source for producing user friendly biodiesel during transesterification reaction. The whole process was facilitated using green nanocatalyst (K<sub>2</sub>O) synthesized from discarded <em>Caesalpinia bonduc</em> seed coat as reducing agent. About 98.27 % <em>Caesalpinia</em> biodiesel yield was attained with 1:6 oil to methanol, 0.15 (wt. %) K<sub>2</sub>O nanocatalyst at 120 °C temperature and 120 min interval. GCMS studies of <em>Caesalpinia</em> biodiesel depicts the presence of seven major peaks with retention time (12.640, 17.072, 18.722, 18.816, 18.981 and 23.921 min) confirms the successful conversion of <em>Caesalpinia</em> oil to corresponding biodiesel. The fuel properties of <em>Caesalpinia</em> biodiesel were 70 °C Flash point, 0.36 mgKOH/g Acid number, 0.89 kg/L Density, 3.52 Kinematic viscosity, 0.0063 % Sulphur, −12 °C Pour point, −8 °C Cloud Point are in excellent hormony with global bifuel standards. The green K<sub>2</sub>O nanocatalyst exhibits excellent reusability for up to 9th runs exhibiting its maximum reactivity up to three cycles. The outcomes of this investigation led to the conclusion that the non-conventional and non edible oil seeds of <em>Caesalpinia bonduc</em> (L.) Roxb and green K<sub>2</sub>O nanocatalyst is a viable, low-cost and sustainable and highly reactive contenders for future biodiesel industry with the potential to mitigate energy glitches along with positive and healther socio economic wellbeing of community at global level.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107847"},"PeriodicalIF":5.8,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Maximizing energy recovery from food waste through integrated microalgae harvest using lipid-rich particles followed by anaerobic digestion of biomass residues
IF 5.8 2区 生物学
Biomass & Bioenergy Pub Date : 2025-04-02 DOI: 10.1016/j.biombioe.2025.107850
Adel W. Almutairi
{"title":"Maximizing energy recovery from food waste through integrated microalgae harvest using lipid-rich particles followed by anaerobic digestion of biomass residues","authors":"Adel W. Almutairi","doi":"10.1016/j.biombioe.2025.107850","DOIUrl":"10.1016/j.biombioe.2025.107850","url":null,"abstract":"<div><div>The present study evaluated the potential of algae-based integrated food waste biorefinery to produce valuable bio-based compounds. Lipid-rich particles (FW-LRP) were applied for microalgae harvest, followed by using the solid fraction of food waste (FW-S) for biogas production. The FW-LRP showed 57.2 % higher lipid content with 73.3 % higher polyunsaturated fatty acid compared to food waste mixture. When used for microalgae harvest, FW-LRP demonstrated 92.7 % harvest efficiency with improved biodiesel quality. The highest biodiesel yield of microalgae harvested by FW-LRP was 21.28 g L<sup>−1</sup>, showing higher cetane number of 57.49 and lower iodine value of 72.8 g I<sub>2</sub> per 100 g oil. Furthermore, co-digestion of microalgal lipid-free residues with FW-S yielded biogas of 407.3 L kg<sup>−1</sup> VS (with 70.9 % biomethane proportion). These findings confirm the high potential of food waste valorization in microalgae industry to improve biodiesel characteristics and boost anaerobic digestion processes, presenting a promising outlook for sustainable food waste management strategies.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"197 ","pages":"Article 107850"},"PeriodicalIF":5.8,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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