ACS Sensors最新文献

{"title":"Completely Fused Non‐Fullerene Acceptor Enables Efficient Postprocessing‐Free Organic Photovoltaics Cells","authors":"Wenxuan Wang, Shaoqing Zhang, Tao Zhang, Chaoyi Wang, Zhihao Chen, Shuohan Cheng, Yang Xiao, Jianqiu Wang, Yong Cui, Jianhui Hou","doi":"10.1002/aenm.202404482","DOIUrl":"https://doi.org/10.1002/aenm.202404482","url":null,"abstract":"The photovoltaic performance of organic photovoltaic (OPV) cells can be significantly improved by regulating the aggregation structure and film formation kinetics of the constituent materials. However, many regulation strategies, including the use of additives and annealing, require complex fabrication processes and additional investments, which poses challenges for the industrialization of OPV cells. In this work, a completely fused non‐fullerene acceptor, GS‐20 is designed and synthesized, with strong aggregation properties. The incorporation of GS‐20 as a third component into the PBQx‐TF:eC9‐2Cl‐based cell accelerates aggregation of eC9‐2Cl and improves molecular stacking by promoting film deposition. The as‐cast ternary OPV cells fabricated without any post‐treatments exhibited a high <jats:italic>V</jats:italic><jats:sub>OC</jats:sub> of 0.890 V and a maximum PCE of 19.0%. Moreover, a postprocessing‐free OPV module is fabricated using the blade coating method and obtains a satisfactory PCE of 13.5%, indicating excellent feasibility for large‐scale preparation. This work realizes an efficient postprocessing‐free OPV cell through molecular design and ternary strategy, facilitating the industrialization of OPV technology.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"95 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142599068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"CeO2‐Accelerated Surface Reconstruction of CoSe2 Nanoneedle Forms Active CeO2@CoOOH Interface to Boost Oxygen Evolution Reaction for Water Splitting","authors":"Quanxin Guo, Yu Li, Zhengrong Xu, Rui Liu","doi":"10.1002/aenm.202403744","DOIUrl":"https://doi.org/10.1002/aenm.202403744","url":null,"abstract":"Interface engineering is an efficient strategy to create high‐performance electrocatalysts for water splitting. In the present work, CeO<jats:sub>2</jats:sub>@CoSe<jats:sub>2</jats:sub> nanoneedle on carbon cloth (CeO<jats:sub>2</jats:sub>@CoSe<jats:sub>2</jats:sub>/CC) demonstrates high efficiency for oxygen evolution reaction (OER) and water splitting. CeO<jats:sub>2</jats:sub> with abundant O vacancies facilitates the adsorption of OH<jats:sup>−</jats:sup> and boosts the reconstruction of CoSe<jats:sub>2</jats:sub> into CoOOH at lower potentials. The in situ generated active CeO<jats:sub>2</jats:sub>@CoOOH heterointerface upshifts the d‐band center of Co site, thereby decreasing the free energy of rate‐determining step (RDS) (<jats:sup>*</jats:sup>O to <jats:sup>*</jats:sup>OOH) during the OER process. It delivers a low OER overpotential of 245 mV at 10 mA cm<jats:sup>−2</jats:sup>. CeO<jats:sub>2</jats:sub>@CoSe<jats:sub>2</jats:sub>/CC is also found to be active for hydrogen evolution reaction (HER, 138 mV overpotential at 10 mA cm<jats:sup>−2</jats:sup>), profiting from CeO<jats:sub>2</jats:sub>‐facilitated <jats:sup>*</jats:sup>H<jats:sub>2</jats:sub>O dissociation and <jats:sup>*</jats:sup>H adsorption on CoSe<jats:sub>2</jats:sub>. The overall water splitting is achieved over the CeO<jats:sub>2</jats:sub>@CoSe<jats:sub>2</jats:sub>/CC bifunctional electrode with a low electrolysis voltage of 1.54 V at 10 mA cm<jats:sup>−2</jats:sup>. This work offers valuable insights into CeO<jats:sub>2</jats:sub>‐assisted surface reconstruction as well as provides water electrolysis catalysts through interface engineering.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"19 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Prevalence of Adverse Childhood Experiences in Child Population Samples","authors":"Sheri Madigan, Raela Thiemann, Audrey-Ann Deneault, R. M. Pasco Fearon, Nicole Racine, Julianna Park, Carole A. Lunney, Gina Dimitropoulos, Serena Jenkins, Tyler Williamson, Ross D. Neville","doi":"10.1001/jamapediatrics.2024.4385","DOIUrl":"https://doi.org/10.1001/jamapediatrics.2024.4385","url":null,"abstract":"ImportanceExposure to adverse childhood experiences (ACEs) before the age of 18 years is a major contributor to the global burden of disease and disability.ObjectiveTo meta-analyze data from samples with children 18 years or younger to estimate the average prevalence of ACEs, identify characteristics and contexts associated with higher or lower ACE exposure, and explore methodological factors that might influence these prevalence estimates.Design, Setting, and ParticipantsStudies that were published between January 1, 1998 and February 19, 2024, were sourced from MEDLINE, PsycINFO, CINHAL, and Embase. Inclusion criteria required studies to report the prevalence of 0, 1, 2, 3, or 4 or more ACEs using an 8- or 10-item ACEs questionnaire (plus or minus 2 items), include population samples of children 18 years or younger, and be published in English. Data from 65 studies, representing 490 423 children from 18 countries, were extracted and synthesized using a multicategory prevalence meta-analysis. These data were analyzed from February 20, 2024, through May 17, 2024.Main Outcomes and MeasuresACEs.ResultsThe mean age of children across studies was 11.9 (SD, 4.3) years, the age range across samples was 0 to 18 years, and 50.5% were female. The estimated mean prevalences were 42.3% for 0 ACEs (95% CI, 25.3%-52.7%), 22.0% for 1 ACE (95% CI, 9.9%-32.7%), 12.7% for 2 ACEs (95% CI, 3.8%-22.3%), 8.1% for 3 ACEs (95% CI, 1.4%-16.8%), and 14.8% for 4 or more ACEs (95% CI, 5.1%-24.8%). The prevalence of 4 or more ACEs was higher among adolescents vs children (prevalence ratio, 1.16; 95% CI, 1.04-1.30), children in residential care (1.26; 95% CI, 1.10-1.43), with a history of juvenile offending (95% CI, 1.29; 1.24-1.34), and in Indigenous peoples (1.63; 95% CI, 1.28-2.08), as well as in studies where file review was the primary assessment method (1.29; 95% CI, 1.23-1.34). The prevalence of 0 ACEs was lower in questionnaire-based studies where children vs parents were informants (0.85; 95% CI, 0.80-0.90).ConclusionsIn this study, ACEs were prevalent among children with notable disparities across participant demographic characteristics and contexts. As principal antecedent threats to child and adolescent well-being that can affect later life prospects, ACEs represent a pressing global social issue. Effective early identification and prevention strategies, including targeted codesigned community interventions, can reduce the prevalence of ACEs and mitigate their severe effects, thereby minimizing the harmful health consequences of childhood adversity in future generations.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"71 1","pages":""},"PeriodicalIF":26.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Toward Flexible and Stretchable Organic Solar Cells: A Comprehensive Review of Transparent Conductive Electrodes, Photoactive Materials, and Device Performance","authors":"Yongdie Yan, Bowen Duan, Min Ru, Qinyin Gu, Sunsun Li, Wenchao Zhao","doi":"10.1002/aenm.202404233","DOIUrl":"https://doi.org/10.1002/aenm.202404233","url":null,"abstract":"Flexible and stretchable organic solar cells (FOSCs and SOSCs) hold immense potential due to their versatility and applicability in emerging areas such as wearable electronics, foldable devices, and biointegrated systems. Despite these promising applications, several challenges remain, primarily related to the mechanical durability, material performance, and scalability required for commercialization. This review comprehensively highlights recent advancements in the design and fabrication of FOSCs and SOSCs, with a particular emphasis on key functional layers, including transparent conductive electrodes, interfacial layers, photoactive materials, and top electrodes. Innovations in material design, such as active layers and transparent conductive electrodes with improved flexibility, are discussed alongside developments in device processes to achieve power conversion efficiencies exceeding 19%. Furthermore, the review addresses remaining challenges, including the need for scalable manufacturing techniques and enhanced mechanical robustness under strain. Finally, the prospects of FOSCs and SOSCs are analyzed, providing insights into how these technologies can contribute to the development of sustainable, high‐performance power sources for wearable electronic devices and other flexible electronics. This review offers valuable insights, bringing the commercialization of wearable, high‐performance FOSCs and SOSCs closer to reality.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"37 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crystallographic Texturing of Electrodeposits for Sustainable Zn Anodes","authors":"Xiaomeng Tian, Ying Sun, Hui Li, Xiaoguang Duan, Qin Zhao, Tianyi Ma","doi":"10.1002/aenm.202403995","DOIUrl":"https://doi.org/10.1002/aenm.202403995","url":null,"abstract":"Aqueous Zn metal batteries (AZMBs) offer a promising solution for grid‐scale energy storage. Nonetheless, their commercial deployment is hindered by pivotal challenges related to the Zn metal anode, particularly the morphological heterogeneity of electrodeposits and interfacial chemical instability arising from irreversible and uneven electrodeposition. Crystallographic texturing during Zn electrodeposition emerges as a robust approach to achieve grain‐refinement and chemically stable electrodeposits, thereby promoting the sustainable cycling of the Zn anode. Despite substantial progress in Zn texturing, a comprehensive review that systematically elucidates the principles and mechanisms underlying irregular morphological evolution and crystallographic texturing is still lacking. Therefore, this review addresses this gap by first examining the formation of these issues from a crystallographic perspective. The review then categorizes and details five distinct induction mechanisms for crystallographic texturing in Zn electrodeposits. Eventually, the review offers future perspectives on crystallographic texturing, aiming to advance the transition from academic research to industrial application of AZMBs.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"37 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microsporidia and invertebrate hosts: genome-informed taxonomy surrounding a new lineage of crayfish-infecting Nosema spp. (Nosematida)","authors":"Cheyenne E. Stratton, Sara A. Bolds, Lindsey S. Reisinger, Donald C. Behringer, Amjad Khalaf, Jamie Bojko","doi":"10.1007/s13225-024-00543-w","DOIUrl":"https://doi.org/10.1007/s13225-024-00543-w","url":null,"abstract":"<p>The Microsporidia, an often overlooked fungal lineage, exhibit increasing diversity and taxonomic understanding with the use of genomic techniques. They are obligate parasites infecting a diversity of hosts, including crustaceans. Crustacea are, in essence, ancient insects and their relationship with the Microsporidia is both diverse and convoluted. Relationships between crayfish and their microsporidian parasites display geospatial and taxonomic diversity. Through classical (histological, ultrastructural, developmental) and genomic (phylogenetic, phylogenomic) approaches, we expand the known diversity of crayfish-infecting microsporidia into the genus <i>Nosema</i> by describing three novel species from North America: <i>Nosema astafloridana</i> n. sp. infecting <i>Procambarus pictus</i> and <i>Procambarus spiculifer</i>, <i>Nosema rusticus</i> n. sp. infecting <i>Faxonius rusticus</i>, and <i>Nosema wisconsinii</i> n. sp. infecting <i>Faxonius propinquus</i> and <i>Faxonius virilis</i>. Additionally, we provide SSU sequence data for further <i>Nosema</i> diversity from <i>Procambarus clarkii</i> and <i>Pacifasticus gambelii</i>. The taxonomy of aquatic crustacean-infecting <i>Nosema</i> have been under scrutiny among microsporidiologists—using genomic data we solidify this systematic relationship. Our genomic data reveal phylogenomic divergence between terrestrial insect-infecting <i>Nosema</i> and aquatic crustacean-infecting <i>Nosema</i> but place our novel species within the <i>Nosema</i>. Comparative genomic analysis reveal that <i>Nosema rusticus</i> n. sp. is a tetraploid organism, making this the first known polyploid from the genus <i>Nosema</i>. Annotation of the genomic data highlight that crayfish-infecting <i>Nosema</i> have distinct proteomic differences when compared to amphipod and insect-infecting microsporidians. Alongside the new diversity uncovered and genome-supported systematics, we consider the role of these new ‘invasive’ parasites in biological invasion systems, exploring their relationship with their invasive hosts.</p>","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"19 1","pages":""},"PeriodicalIF":20.3,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142599658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Location of Pediatric Deaths in the US","authors":"Sarah H. Cross, Khaliah A. Johnson, Maura A. Savage, Dio Kavalieratos","doi":"10.1001/jamapediatrics.2024.4443","DOIUrl":"https://doi.org/10.1001/jamapediatrics.2024.4443","url":null,"abstract":"This cross-sectional study assesses the associations of decedent demographic characteristics and cause of death with place of death among children, adolescents, and young adults.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"4 1","pages":""},"PeriodicalIF":26.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Degradation Mechanism of Phosphate‐Based Li‐NASICON Conductors in Alkaline Environment","authors":"Benjamin X. Lam, Zhuohan Li, Tara P. Mishra, Gerbrand Ceder","doi":"10.1002/aenm.202403596","DOIUrl":"https://doi.org/10.1002/aenm.202403596","url":null,"abstract":"NASICON‐type Li conductors (Li‐NASICON) have traditionally been regarded as promising candidates for solid‐state Li‐air battery applications because of their stability in water and ambient air. However, the presence of water in the cathode of a Li‐air battery can induce a highly alkaline environment by modifying the discharge product from Li<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub> to LiOH which can potentially degrade cathode and separator materials. This study investigates the alkaline stability of common Li‐NASICON chemistries through a systematic experimental study of LiTi<jats:sub>x</jats:sub>Ge<jats:sub>2‐x</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub> (LTGP) with varying x = 0–2.0. Density functional theory calculations are combined to gain a mechanistic understanding of the alkaline instability. It is demonstrated that the instability of LTGP in an alkaline environment is mainly driven by the dissolution of PO<jats:sub>4</jats:sub><jats:sup>3–</jats:sup> groups, which subsequently precipitate as Li<jats:sub>3</jats:sub>PO<jats:sub>4</jats:sub>. The introduction of Ti facilitates the formation of a Ti‐rich compound on the surface that eventually passivates the material, but only after significant bulk degradation. Consequently, phosphate‐based Li‐NASICON materials exhibit limited alkaline stability, raising concerns about their viability in humid Li‐air batteries.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"36 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142599070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"School Readiness and Early Childhood Education and Care Services Among Dual Language Learners","authors":"Ophélie A. Collet, Pascale M. Domond, Cédric Galéra, Thuy Mai Luu, Tianna Loose, Alejandro Vásquez-Echeverría, Massimiliano Orri, Sylvana M. Côté","doi":"10.1001/jamapediatrics.2024.4489","DOIUrl":"https://doi.org/10.1001/jamapediatrics.2024.4489","url":null,"abstract":"ImportanceDual language learners (DLL) (ie, children learning 2 or more languages) present lower school readiness than non-DLL children, putting DLL children at risk of later school difficulties and adverse outcomes. However, it is unclear whether participation in early childhood education and care (ECEC) services may reduce this gap.ObjectiveTo assess whether ECEC exposure may reduce the school readiness gap between DLL and non-DLL children in a population-based sample.Design, Setting, and ParticipantsThis census survey study was performed from February to May 2022 in the Canadian province of Quebec using data from the Quebec Survey of Child Development in Kindergarten, which includes all children who attended kindergarten in the 2021 to 2022 school year in public and private schools in Quebec (n = 80 587), except for Cree and Inuit territories.ExposureChildren’s ECEC arrangement before kindergarten was retrieved from register-based data and teachers and arrangements were categorized as exclusive parental care, childcare, pre-kindergarten only, or childcare and pre-kindergarten. Based on their mother tongue and language of instruction, children were classified as French speaking, English speaking, bilingual French-English speaking, or neither French nor English speaking (allophone) children, the last 2 groups of which represented the DLL category.Main Outcomes and MeasuresVulnerability in school readiness was defined as a score below the 10th percentile in any of the 5 domains of the validated Early Development Instrument (EDI): (1) physical health and well-being; (2) social competence; (3) emotional maturity; (4) language and cognitive development; and (5) communication skills and general knowledge.ResultsIn total, 80 587 children were surveyed, and 71 585 children were included in analyses. Mean (SD) child age was 6.0 (0.3) years, 34 911 children (48.8%) were female, and 18 341 children (25.6%) were DLL. English-speaking, bilingual French-English–speaking, and allophone children were more likely to be vulnerable in the EDI (769 of 2355 children [32.7%], 4814 of 13 981 children [34.4%], and 1622 of 4360 children [37.2%], respectively) than French-speaking children (13 664 of 50 890 children [26.9%]). In logistic regression analyses adjusted for social selection bias in ECEC arrangement, attending ECEC services was associated with a lower risk of being vulnerable among all language groups compared to parental care, with odds ratios ranging from 0.26 (95% CI, 0.25-0.27) to 0.96 (95% CI, 0.80-1.14), except in the emotional maturity domain. ECEC exposure was associated with reduction in vulnerabilities disparities between DLL and non-DLL children after adjusting for confounding factors, including socioeconomic status.Conclusions and RelevanceECEC services may foster school readiness for all children, especially DLL, and should be considered to reduce school inequalities.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"215 1","pages":""},"PeriodicalIF":26.1,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modulating Local Oxygen Coordination to Achieve Highly Reversible Anionic Redox and Negligible Voltage Decay in O2‐Type Layered Cathodes for Li‐Ion Batteries","authors":"Xiaoxia Yang, Kai Wang, Jilu Zhang, Hang Li, Hao Liu, Tian Zhao, Xinyue Zhai, Qin Wang, Chengjun Fan, Martin Etter, Sylvio Indris, Weibo Hua, Xiaoping Ouyang","doi":"10.1002/aenm.202404276","DOIUrl":"https://doi.org/10.1002/aenm.202404276","url":null,"abstract":"O2‐type layered oxides have emerged as promising cathode materials for high‐energy lithium‐ion batteries, offering a solution to mitigate voltage decay through reversible transition metal (TM) migration between TM and Li layers during cycling. However, achieving a fully reversible oxygen redox remains a significant challenge. Here, this is addressed by introducing Li─O─Li configurations in the layered structure of Li<jats:sub>0.85□0.15</jats:sub>[Li<jats:sub>0.08□0.04</jats:sub>Ni<jats:sub>0.22</jats:sub>Mn<jats:sub>0.66</jats:sub>]O<jats:sub>2</jats:sub> (O2‐LLNMO), where <jats:sub>□</jats:sub> represents vacancies. This adjustment alters the redox‐active oxygen environment and increases the energy gap between the O 2p nonbonding and TM─O antibonding bands. As a result, the contribution of lattice oxygen to capacity is significantly enhanced, improving the reversibility of oxygen redox processes. The O2‐LLNMO cathode demonstrates minimal voltage decay (0.13 mV per cycle) and excellent cycling stability, retaining 95.8% of its capacity after 100 cycles. A novel strategy is presented to design high‐performance layered oxides with stable anionic redox activity, advancing the development of next‐generation lithium‐ion batteries.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"35 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142597948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}