Water Resources and Industry最新文献_第4页

Tailoring photocatalytic performance through Fe-doped TiO2/ZnO for effective remediation of organic contaminants 通过掺杂铁的 TiO2/ZnO 调整光催化性能，有效修复有机污染物

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2024-01-04 DOI: 10.1016/j.wri.2024.100239

Yalda Davoodi, Mohammad Saleh Shafeeyan

{"title":"Tailoring photocatalytic performance through Fe-doped TiO2/ZnO for effective remediation of organic contaminants","authors":"Yalda Davoodi, Mohammad Saleh Shafeeyan","doi":"10.1016/j.wri.2024.100239","DOIUrl":"10.1016/j.wri.2024.100239","url":null,"abstract":"<div><p>The development of highly efficient photocatalysts holds significant promise for addressing contemporary environmental challenges. This study focuses on the synthesis and characterization of a novel photocatalyst, iron-doped TiO<sub>2</sub>/ZnO particles, created through the sol-gel technique. The incorporation of iron ions into the crystalline structure of TiO<sub>2</sub>/ZnO aims to enhance the photocatalytic efficiency of TiO<sub>2</sub>. The findings revealed that Fe–ZnO/TiO<sub>2</sub> exhibits a more thermally stable lattice compared to TiO<sub>2</sub>/ZnO, thereby retarding the phase transformation from anatase to rutile under higher calcination temperature. The photocatalytic performance of the synthesized photocatalyst was evaluated through the degradation of methyl orange under visible light irradiation. A statistical response surface methodology based on a central composite design was employed to develop a predictive model for color removal (as the dependent variable) considering variations in irradiation intensity, initial color concentration, catalyst concentration, reaction time, and pH (as independent variables). The analysis of variance identified the initial color concentration as the most influential factor, negatively affecting the predicted response. The experimental values of color removal exhibited good agreement with the predicted values from the regression model with a coefficient of determination of 0.949, indicating the accuracy of this model in predicting the mentioned outcomes. The presented model indicated that, for a sample of methyl orange with an initial concentration of 21.97 ppm, a reaction time of 117.69 min under direct irradiation of 21.63 W, a catalyst concentration of 0.61 g/L, and a pH of 4.74, the optimal color removal efficiency of 78.99 % was achieved.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371724000015/pdfft?md5=f812791dac071f513fc687f9ac04efec&pid=1-s2.0-S2212371724000015-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139392958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Modeling and optimization of efficient removal of diclofenac and naproxen based on chemometric approaches 基于化学计量学方法的双氯芬酸和萘普生高效去除模型的建立和优化

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2024-01-01 DOI: 10.1016/j.wri.2023.100238

Seyyed Amirreza Abdollahi , Amirasad Pourabadeh , Mahsa Alishiri , Abolfazl Sodagartojgi , Seyyed Faramarz Ranjbar , Mir Biuok Ehghaghi , Faramarz Talati

{"title":"Modeling and optimization of efficient removal of diclofenac and naproxen based on chemometric approaches","authors":"Seyyed Amirreza Abdollahi , Amirasad Pourabadeh , Mahsa Alishiri , Abolfazl Sodagartojgi , Seyyed Faramarz Ranjbar , Mir Biuok Ehghaghi , Faramarz Talati","doi":"10.1016/j.wri.2023.100238","DOIUrl":"10.1016/j.wri.2023.100238","url":null,"abstract":"<div><p>This work investigated the efficiency of CoFe<sub>2</sub>O<sub>4</sub> nanoparticles in removing diclofenac and naproxen drugs from aqueous solutions. At first, the Taguchi method was performed to choose the most important factors among the investigated factors affecting the removal efficacy of these drugs. Afterward, the optimal conditions of the effective factors were investigated and modeled by the central composite design-based response surface method. The results revealed that the maximum drug removal was obtained at pH = 7, temperature of 25 °C, adsorbent dosage of 215 mg, sonication time of 21 min, and diclofenac and naproxen concentrations of 15 mg L<sup>−1</sup>. The removal efficacy of diclofenac and naproxen under these optimal conditions was 99.42 % and 95.11 %, respectively. Based on the results, it is concluded that CoFe<sub>2</sub>O<sub>4</sub> nanoparticles can be applied as an easy-available and effective adsorbent for removing diclofenac and naproxen from water samples.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000380/pdfft?md5=8475ccb6868277f9cd99b11111b9beaf&pid=1-s2.0-S2212371723000380-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139129382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating the biomass-specific inhibitory effect of benzalkonium chloride on anaerobic granules: A kinetic approach 研究苯扎氯铵对厌氧颗粒的生物质特异性抑制作用：动力学方法

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-12-12 DOI: 10.1016/j.wri.2023.100237

Sinem Fundneider-Kale , Vanessa Acevedo Alonso , Markus Engelhart

{"title":"Investigating the biomass-specific inhibitory effect of benzalkonium chloride on anaerobic granules: A kinetic approach","authors":"Sinem Fundneider-Kale , Vanessa Acevedo Alonso , Markus Engelhart","doi":"10.1016/j.wri.2023.100237","DOIUrl":"https://doi.org/10.1016/j.wri.2023.100237","url":null,"abstract":"<div><p>Benzalkonium Chloride (BAC), a quaternary ammonium compound commonly used in industrial disinfection processes, was studied for its biomass-specific inhibitory effect on the specific methanogenic activity (SMA) of anaerobic granules. Inhibition batch assays were conducted with varying BAC concentrations (5–40 mg/L), resulting in biomass-dependent inhibition. Considering its surface-active nature, a biomass-specific BAC load was a suitable parameter to determine IC<sub>50</sub> values, ranging from 4.3 to 6.1 mg BAC/g VS. For predicting the corresponding biomass-specific inhibition constant in ADM1, the inclusion of an additional adsorption-inhibition term was required for a better validation of results. The model yielded a biomass-specific IC<sub>50</sub> of 5.3 mg BAC/g VS. The results encourage a change in perspective on IC<sub>50</sub> for surfactants by determining a biomass-specific IC<sub>50</sub>, particularly in scenarios when surfactants accumulate within anaerobic reactors. Hereby, the reliability and practical relevance of IC<sub>50</sub> is increased, driving the development of mitigation strategies.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000379/pdfft?md5=de3b36c21751f1de7fcf0a170205cbf7&pid=1-s2.0-S2212371723000379-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138633722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Examination of interactions between heavy metals and benzotriazoles in rainwater runoff and snowmelt in an urban catchment in Poland 波兰城市集水区雨水径流和融雪中重金属与苯并三唑之间相互作用的研究

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-12-07 DOI: 10.1016/j.wri.2023.100236

Maciej Bełcik , Martyna Grzegorzek , Fausto A. Canales , Joanna Struk-Sokołowska , Bartosz Kaźmierczak

{"title":"Examination of interactions between heavy metals and benzotriazoles in rainwater runoff and snowmelt in an urban catchment in Poland","authors":"Maciej Bełcik , Martyna Grzegorzek , Fausto A. Canales , Joanna Struk-Sokołowska , Bartosz Kaźmierczak","doi":"10.1016/j.wri.2023.100236","DOIUrl":"https://doi.org/10.1016/j.wri.2023.100236","url":null,"abstract":"<div><p>Heavy metals (HMs) are toxic pollutants that can accumulate and harm human health and the environment. Monitoring their concentration in water is an essential tool for evaluating the quality and safety of this vital resource. The aims of this study were (i) to characterize HMs contamination in rainwater runoff and snowmelt, identify likely sources and compliance with regulations and guidelines, and (ii) to conduct a preliminary assessment regarding the potential link between the occurrence of HMs and benzotriazoles based on a previous experiment. This study investigates the concentration of six HMs (cadmium, lead, nickel, chromium, copper, and zinc) in rainwater runoff and snowmelt samples collected in twelve Białystok locations in northeastern Poland. The highest concentration of Cu (517.5 μg/L) was identified in snowmelt from the city's ring road, with heavy vehicle traffic, and near an industrial area. A 4-lane asphalt street near the city center exhibited the highest concentrations of Pb (91.1 μg/L) and Ni (64.6 μg/L) for snowmelt and also for Cd (1.37 μg/L) and Ni (27.3 μg/L) in rainwater runoff. A snowmelt sample from a pedestrian-only area in the city center presented the highest Zn concentration (3672.2 μg/L). Considerable contents of Cr (353.2 μg/L) were found in snowmelt near an industrial and warehousing area. Snowmelt presented higher HMs concentrations than rainwater runoff. Our results indicate that most benzotriazoles and heavy metals occur independently. The analysis of the winds and the tendency of HMs to travel with dust particles suggest that specific contaminants might have originated in Belarus, a neighboring territory of Białystok.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000367/pdfft?md5=51b2898a084e1e9d758292b0b0bdc3c1&pid=1-s2.0-S2212371723000367-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138582080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical treatment of antibiotic wastewater containing ceftriaxone sodium by porous Ti/Magnéli Ti4O7 nanotube arrays 利用多孔钛/马涅利 Ti4O7 纳米管阵列对含有头孢曲松钠的抗生素废水进行电化学处理

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-12-02 DOI: 10.1016/j.wri.2023.100235

Yonghao Zhang, Yating Song, Liu Liu, Jie Zhang, Zhaoyi Zhang, Qian Li, Jing Yang, Wen Li, Lulu Huang, Xue Li, Yulei Zhang, Qiangshun Wu, Xuejie Guo

{"title":"Electrochemical treatment of antibiotic wastewater containing ceftriaxone sodium by porous Ti/Magnéli Ti4O7 nanotube arrays","authors":"Yonghao Zhang, Yating Song, Liu Liu, Jie Zhang, Zhaoyi Zhang, Qian Li, Jing Yang, Wen Li, Lulu Huang, Xue Li, Yulei Zhang, Qiangshun Wu, Xuejie Guo","doi":"10.1016/j.wri.2023.100235","DOIUrl":"https://doi.org/10.1016/j.wri.2023.100235","url":null,"abstract":"<div><p>In this study, porous Ti/Magnéli Ti<sub>4</sub>O<sub>7</sub> nanotube arrays (NTA) was fabricated to pretreat antibiotic wastewater. Characterization of the Ti<sub>4</sub>O<sub>7</sub>-NTA illustrated that highly ordered NTA was successfully generated on the porous Ti substrate, which enlarged the specific surface area by 1.67 times. The Ti<sub>4</sub>O<sub>7</sub>-NTA has a high oxygen evolution potential (2.60 V) as well as low interfacial charge transfer resistance (4.479 Ω cm<sup>−2</sup>). Ceftriaxone sodium (CRO) was completely removed from raw antibiotic wastewater after 3 h of treatment by the Ti<sub>4</sub>O<sub>7</sub>-NTA, under optimal operation conditions. The biodegradability and toxicity of the wastewater were also significantly enhanced and reduced, as the BOD/COD and EC<sub>50,48h</sub> values were increased to 0.48 and 57.62 % ± 2.16 %, respectively. The possible degradation pathway of CRO was proposed by LC‒MS. Cathodic polarization was proven to be an effective way to ensure the long-term durability of the Ti<sub>4</sub>O<sub>7</sub>-NTA.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000355/pdfft?md5=76d8a16c8ba55e790c19e9701ad881c0&pid=1-s2.0-S2212371723000355-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138549203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing sonocatalytic dye pollutant degradation using MoS2/RGO nanocomposites: An optimization study 二硫化钼/还原氧化石墨烯纳米复合材料增强声催化降解染料污染物的优化研究

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-12-01 DOI: 10.1016/j.wri.2023.100223

Farid Ahani , Maisam Jalaly , Javad Moghaddam , Mohammad Hossein Rasoulifard

{"title":"Enhancing sonocatalytic dye pollutant degradation using MoS2/RGO nanocomposites: An optimization study","authors":"Farid Ahani , Maisam Jalaly , Javad Moghaddam , Mohammad Hossein Rasoulifard","doi":"10.1016/j.wri.2023.100223","DOIUrl":"10.1016/j.wri.2023.100223","url":null,"abstract":"<div><p>This research focuses on the synthesis of MoS<sub>2</sub>/RGO nanocomposite, which serves as an efficient sonocatalyst, using a simple one-step hydrothermal method. The MoS<sub>2</sub>/RGO was characterized through various techniques including X-ray diffraction (XRD), field-emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), Raman spectrometry, diffuse reflectance spectroscopy (DRS), and Fourier transform infrared (FTIR) spectroscopy. A comprehensive investigation into the sonocatalytic degradation efficiency of methylene blue (MB) dye was conducted under different conditions using design of experiment (DOE) approach. Response surface methodology (RSM) based on central composite design (CCD) was employed to optimize the key operational parameters, namely initial dye concentration, catalyst dosage, ultrasonic power, sonication time, and pH. The reliability of the model was assessed using analysis of variance. Under the optimal conditions of 20 mg/L initial MB concentration, catalyst dosage of 0.5 g/L, 67 W ultrasonic power, sonication time of 28 min, and pH of 7, a remarkable MB degradation efficiency of 99% was achieved. Hydroxyl radical (<sup>●</sup>OH) were identified as the main radical species in the sonoluminescence reaction. Additionally, the sonocatalyst demonstrated an excellent reusability, with approximately 95% retention of the degradation efficiency observed over five sonocatalysis cycles.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000239/pdfft?md5=fba9b7eb4373cbea7d1712cb1180bc33&pid=1-s2.0-S2212371723000239-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47059034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Stability of geothermal waters parameters as a major factor guaranteeing the possibility of its use and discharge into the environment 地热水参数的稳定性是保证地热水利用和向环境排放可能性的主要因素

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-11-23 DOI: 10.1016/j.wri.2023.100233

Agnieszka Operacz , Agnieszka Zachora-Buławska , Zuzanna Gonek , Barbara Tomaszewska , Bogusław Bielec , Tomasz Operacz , Jochen Bundschuh

{"title":"Stability of geothermal waters parameters as a major factor guaranteeing the possibility of its use and discharge into the environment","authors":"Agnieszka Operacz , Agnieszka Zachora-Buławska , Zuzanna Gonek , Barbara Tomaszewska , Bogusław Bielec , Tomasz Operacz , Jochen Bundschuh","doi":"10.1016/j.wri.2023.100233","DOIUrl":"https://doi.org/10.1016/j.wri.2023.100233","url":null,"abstract":"<div><p>Geothermal waters are considered a type of renewable energy source. Waters with elevated temperatures are also used in balneotherapy. In each type of use, the stability of the basic parameters guarantees the reliable operation of the plant. On the other hand, useable geothermal waters, which in legal terms are usually wastewater, are discharged into a surface water reservoir or injected into the rock. The diversity of geothermal waters use options creates the need to assess stability. Low and known variability of the basic parameters is extremely important for the protection of the receiving environment or the reliability of the injection process. This paper identifies the basic parameters, the relationships between them and a methodology for assessing their stability, which has not been widely used to date. The approach presented is universal and can be successfully applied to other geothermal installations anywhere in the world.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000331/pdfft?md5=e604667b8d7b1dae9c55b7526962fc11&pid=1-s2.0-S2212371723000331-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138436961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

MXene-based composites for capacitive deionization – The advantages, progress, and their role in desalination - A review mxene基电容去离子复合材料的优点、进展及其在海水淡化中的应用综述

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-11-02 DOI: 10.1016/j.wri.2023.100230

Bakhtiar Ali Samejo , Kainat Naseer , Suraya Samejo , Farooque Ahmed Janjhi , Najma Memon , Roberto Castro-Muñoz , Grzegorz Boczkaj

{"title":"MXene-based composites for capacitive deionization – The advantages, progress, and their role in desalination - A review","authors":"Bakhtiar Ali Samejo , Kainat Naseer , Suraya Samejo , Farooque Ahmed Janjhi , Najma Memon , Roberto Castro-Muñoz , Grzegorz Boczkaj","doi":"10.1016/j.wri.2023.100230","DOIUrl":"10.1016/j.wri.2023.100230","url":null,"abstract":"<div><p>MXenes, a novel large family of 2D transition metal carbides, carbonitrides and nitrides are currently a “hot topic” in science due to their several fascinating physical and chemical properties. It follows from a rich diversity of their elemental compositions and chemical functionalities. MXenes can form composites with many substances, including polymers or metal oxides, which allows to effective “tune” MXene characteristics to a fit-to-the-purpose applications. Capacitive deionization (CDI) is currently widely studied as advanced desalination technique due to the advantages of cost-effectiveness, eco-friendly, and high salt removal capacity. One of key fields for CDI development relates to the ion's intercalation materials as concept taken from the sodium ion batteries, which is used in CDI because of their excellent desalination capacity<strong>.</strong> These materials provide effective sodium ions removal from the brine based on intercalation mechanism as well as redox reactions. In this review, we timely review an up-to-date accomplishment in the advancement of distinct MXene-based composite materials used as CDI electrodes, along with discussion of fundamental electrochemical energy storage mechanisms. The most relevant outcomes are highlighted together with the phenomena observed when applied in desalination applications. Finally, potential solutions as well as challenges in this field are summarized.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371723000306/pdfft?md5=be53178db0c9a43c14432bdfefc29bda&pid=1-s2.0-S2212371723000306-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135371739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating COVID-19 active pharmaceutical ingredients (APIs) degradation using Peroxydisulfate/FeMnOx binary metal oxide/Ultrasound System 使用过硫酸氢盐/FeMnOx二元金属氧化物/超声系统研究COVID-19活性药物成分(api)的降解

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-11-02 DOI: 10.1016/j.wri.2023.100232

Amin Bagheri , Akram Fallah , Jakub Karczewski , Akbar Eslami , Amir Mohammad Sheikh Asadi , Grzegorz Boczkaj

{"title":"Investigating COVID-19 active pharmaceutical ingredients (APIs) degradation using Peroxydisulfate/FeMnOx binary metal oxide/Ultrasound System","authors":"Amin Bagheri , Akram Fallah , Jakub Karczewski , Akbar Eslami , Amir Mohammad Sheikh Asadi , Grzegorz Boczkaj","doi":"10.1016/j.wri.2023.100232","DOIUrl":"10.1016/j.wri.2023.100232","url":null,"abstract":"<div><p>Degradation of Favipiravir using a hybrid system of peroxydisulfate, FeMnOx binary metal oxide, and ultrasound irradiation was studied. A novel catalyst was synthesized with deep eutectic solvent (DES). The effects of DES type on catalytic performance was evaluated and the catalysts were characterized using XRD, SEM, BET, XPS, and EDS. DES-based catalysts exhibited higher efficiency due to structure change, surface area enhancement and significantly improved Favipiravir adsorption. The DES-based catalyst exhibited a 30 % increase in surface area and a 20-fold increase in Mn content. Additionally, XRD and XPS analyses suggested the reduction of Fe<sup>3</sup><sup>+</sup> ions, possibly to Fe<sub>3</sub>O<sub>4</sub>. Optimal operational parameters (pH = 10, catalyst dose = 500 mg/L, and rox = 20) provide removal efficiency of 70.1 % after 3 h. The catalyst showed stable activity after three cycles, indicating reusability. This study presents a promising approach for the sustainable degradation of COVID-19 APIs, with implications for the pharmaceutical industry.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":null,"pages":null},"PeriodicalIF":5.1,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S221237172300032X/pdfft?md5=ffc7517e3aec599cb164edb66c3bb45d&pid=1-s2.0-S221237172300032X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135410832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Treatment of radium-bearing brine using various zeolites: NaP1, NaX, clinoptilolite, 3A, 5A, 13X, ZSM-5, SAPO-11, SAPO-34 使用各种沸石处理含镭盐水：NaP1、NaX、斜发沸石、3A、5A、13X、ZSM-5、SAPO-11、SAPO-34

IF 5.1 3区工程技术

Water Resources and Industry Pub Date : 2023-10-24 DOI: 10.1016/j.wri.2023.100231

K. Samolej , S. Chalupnik , M. Franus

引用次数: 0