{"title":"Optimization of Toluenediamine degradation in synthetic wastewater by a UV/H2O2 process using full factorial design","authors":"Mahdi Sanavi Fard , Ali Ehsani , Fariba Soleimani","doi":"10.1016/j.wri.2023.100218","DOIUrl":"https://doi.org/10.1016/j.wri.2023.100218","url":null,"abstract":"","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"30 ","pages":""},"PeriodicalIF":5.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49714811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Steve Harris , Linda Kanders , Fabrizio Vassallo , Andrea Cipollina , Sirous Ebrahimi , Dimitrios Xevgenos
{"title":"Challenges in preparing for Environmental Technology Verification in a demonstration project: A case study of three innovative water treatment technologies","authors":"Steve Harris , Linda Kanders , Fabrizio Vassallo , Andrea Cipollina , Sirous Ebrahimi , Dimitrios Xevgenos","doi":"10.1016/j.wri.2022.100176","DOIUrl":"10.1016/j.wri.2022.100176","url":null,"abstract":"<div><p>The European Union's Environmental Technology Verification (ETV) program aims to foster innovative environmental technologies to reach the market and reassure potential users. This paper presents an investigation of using ETV for three technologies, being developed within the EU Zero Brine research and innovation project. The technologies were designed to recover high quality water, salts and minerals from brine solutions. The technologies in focus are the forward feed MED evaporator, the Multi Feed – Plug Flow Reactor Crystalliser and Eutectic Freeze Crystallization. The study sought to understand the challenges of the ETV process, the readiness and eligibility of technologies, and possible preparations within the project lifetime. Challenges identified included: understanding what sufficient market readiness is, and achieving this within the duration of a project (also linked to funding allocation for the ETV process); and developing suitable performance claims, supported with sufficient levels of test data. A simple framework is presented to aid the integration of ETV into the development process. It promotes the use of life cycle assessment to understand the environmental added value of the technology and aid the development of performance claims.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100176"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000063/pdfft?md5=501365bbd657fa640d180c001dc006fa&pid=1-s2.0-S2212371722000063-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44213115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Joanna Bok-Badura, Alicja Kazek-Kęsik, Krzysztof Karoń, Agata Jakóbik-Kolon
{"title":"Highly efficient copper hexacyanoferrate-embedded pectin sorbent for radioactive cesium ions removal","authors":"Joanna Bok-Badura, Alicja Kazek-Kęsik, Krzysztof Karoń, Agata Jakóbik-Kolon","doi":"10.1016/j.wri.2022.100190","DOIUrl":"10.1016/j.wri.2022.100190","url":null,"abstract":"<div><p>Released cesium-137 poses a serious threat to living organisms and the environment. As a radioactive substance, it can only be disposed by the greatest possible concentration and safe storage. In our work, a highly efficient sorbent @CuHCF/P (q<sub>max</sub> = 143.6 ± 3.2 mg/g) composed of pectin (P) and modified copper hexacyanoferrate (@CuHCF) was prepared for the removal of cesium from aqueous solutions. Suitable modification of CuHCF generated a homogeneous and highly packed sorbent with active substances (up to 50%). The as-prepared sorbent exhibited a suitable bead shape (round, 2–4 mm diameter, wet form) for application in dynamic systems and allowed easy separation from the purified solution. @CuHCF/P sorbent showed high sorption capacity in seawater (q = 104.6 ± 3.5 mg/g) and stability over a wide range of pH (4-10) and temperatures (12 °C, 22 °C and 32 °C). In addition, @CuHCF was dust-free, and occupied little volume when dry. Therefore proposed sorbent can be successfully used to trap cesium ions.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100190"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000233/pdfft?md5=729c5c81367c24437b779e9d149a4dd7&pid=1-s2.0-S2212371722000233-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48912370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nikhil Dilip Pawar , Steve Harris , Krzysztof Mitko , Gijsbert Korevaar
{"title":"Valorization of coal mine effluents — Challenges and economic opportunities","authors":"Nikhil Dilip Pawar , Steve Harris , Krzysztof Mitko , Gijsbert Korevaar","doi":"10.1016/j.wri.2022.100179","DOIUrl":"10.1016/j.wri.2022.100179","url":null,"abstract":"<div><p>Coal-mine effluent treatment has the potential to both reduce the environmental impact of the effluent and provide economic opportunities by recovering valuable minerals and clean water. In this study, we modeled a novel treatment process, which includes nanofiltration (NF), two-step crystallization, reverse osmosis (RO), electrodialysis (ED), multi-effect distillation (MED), and a NaCl crystallizer, and performed a techno-economic analysis of its full-scale implementation, using a circular economy approach. We estimated the thermal and electrical energy consumption to be 745.5 kWh<sub>th</sub>/ton<sub>NaCl</sub> and 565.1 kWh<sub>el</sub>/ton<sub>NaCl</sub> (or 13.6 kWh<sub>th</sub> and 10.3 kWh<sub>el</sub> per m<sup>3</sup> of feed effluent), respectively. The levelized cost of the NaCl salt that accounts for the revenue from the plant's co-products (Mg(OH)<sub>2</sub>, CaSO<sub>4</sub> and, pure water) was estimated to be 203 USD/ton<sub>NaCl</sub>. The economic viability of the treatment chain can be improved by using renewable electricity sources, reducing the total expenditure on NF and RO, and integrating alternate technologies into the treatment plant.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100179"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000099/pdfft?md5=4ed7bbda0310030a290a577f1e37cf35&pid=1-s2.0-S2212371722000099-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45587808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marc Arpad Boncz , Niels van Linden , Amir Haidari , Yundan Wang , Henri Spanjers
{"title":"Physicochemical model for simulating the chemical processes during the crystallization of minerals from spent ion exchange regenerant","authors":"Marc Arpad Boncz , Niels van Linden , Amir Haidari , Yundan Wang , Henri Spanjers","doi":"10.1016/j.wri.2022.100185","DOIUrl":"10.1016/j.wri.2022.100185","url":null,"abstract":"<div><p>Traditionally, industrial processes produce wastes that, even though often containing useful materials, are discarded, contributing to environmental pollution and depletion of natural resources. An example of such wastes are brines, flows of concentrated salts, produced in water treatment processes, which are now routinely discharged into receiving water bodies. Brines however can also be considered as flows of reusable materials which should be recovered, and the Zero Brine cooperation project aims to develop processes for that purpose. For a demineralized water production plant in the port of Rotterdam (the Netherlands), a closed water processing cycle was proposed to treat the large volume of spent Ion Exchange (IEX) regenerant brine which, apart from recovering demineralized water, is also intended to produce magnesium (Mg<sup>2+</sup>) and calcium (Ca<sup>2+</sup>) salts, with the highest purity possible, from the otherwise discharged brine. The process scheme includes nanofiltration (NF) for separating mono- and multivalent ions, followed by sequential chemical precipitation of Mg<sup>2+</sup> and Ca<sup>2+</sup> ions from the NF concentrate, and production of demineralized water by evaporation of the NF permeate. The concentrate of monovalent ions produced in the evaporator, essentially a concentrated sodium chloride solution, in its turn might be reused for IEX regeneration. Part of the supernatant of the sequential precipitation may be fed to the evaporator as well, but bleeding the other part of this supernatant is essential in order to maintain process stability, avoid accumulation of minor pollutants, and reduce scaling. In this study, various scenarios to operate the process were modeled, using PHREEQC and Excel. According to the simulation results, recovery of ≈97% of Mg<sup>2+</sup> and Ca<sup>2+</sup> is possible, the latter with a higher purity than the former. The main factors affecting the results are the concentration of carbonate present in the spent IEX regenerant, as well as characteristics of the NF membrane and the dosing of sodium hydroxide in the sequential precipitation steps. The results of the simulations were used for the design and operation of a pilot plant, comprising all mentioned process steps.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100185"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S221237172200018X/pdfft?md5=74fa6a975a392d200d34a21d84cd369e&pid=1-s2.0-S221237172200018X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45273697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nilay Elginoz , Christina Papadaskalopoulou , Steve Harris
{"title":"Using life cycle assessment at an early stage of design and development of zero discharge brine treatment and recovery","authors":"Nilay Elginoz , Christina Papadaskalopoulou , Steve Harris","doi":"10.1016/j.wri.2022.100184","DOIUrl":"10.1016/j.wri.2022.100184","url":null,"abstract":"<div><p>It is critical that the development of new technologies to solve environmental problems do not shift the burdens (impacts) to other mediums. Therefore, to ensure the optimum environmental design of water treatment and recovery systems, it is pertinent to apply life cycle assessment (LCA) at an early stage of development. Using LCA at an early developmental stage is known as prospective LCA and is particularly challenging due to the low data availability or quality. The aim of this study is to highlight the opportunities and challenges of using prospective LCA in the development of water treatment and recovery technologies. To do this we utilise two case studies from the EU Zero Brine project and apply LCA at two developmental stages. The treatment systems are specifically tailored for each case to treat the individual brine compositions and selectively recover its constituents. The first stage LCAs are based on laboratory experiments and engineering-based calculations, whilst the second stage assessments use improved input data from pilot plants and simulation. The paper compares the analyses of both stages, identifies key differences and discusses these disparities. In addition, it provides insights on the challenges of applying LCA for the design and development of wastewater treatment and recovery systems.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100184"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000178/pdfft?md5=5046991eb9518add0c2ef3251133d347&pid=1-s2.0-S2212371722000178-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49532429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pegah Fatehbasharzad , Samira Aliasghari , Ipak Shaterzadeh Tabrizi , Javed Ali Khan , Grzegorz Boczkaj
{"title":"Microbial fuel cell applications for removal of petroleum hydrocarbon pollutants: A review","authors":"Pegah Fatehbasharzad , Samira Aliasghari , Ipak Shaterzadeh Tabrizi , Javed Ali Khan , Grzegorz Boczkaj","doi":"10.1016/j.wri.2022.100178","DOIUrl":"10.1016/j.wri.2022.100178","url":null,"abstract":"<div><p>Bioelectrochemical systems (BESs) are considered as the potential approaches to remediate the environments contaminated by hydrocarbons. This review addresses the application of BESs particularly microbial fuel cells (MFCs) in degradation of petroleum hydrocarbons, including BTEXs, from soil, water, wastewater and sediments. Details on reactor design and critical issues are discussed. Aspects on electrodes, redox mediators and membranes are evaluated, including economic feasibility. The microbial community is considered in detail. It can be concluded, that comparing to classic configurations, single-chamber air-cathode reactors are more cost-effective. Secondly, systems based on small-scale units are recommended for future developments.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100178"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000087/pdfft?md5=53dd12e49c1a0f82142a4a11bc6a3513&pid=1-s2.0-S2212371722000087-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48865198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Corrigendum to “Remediation of chromium and copper on water hyacinth (E. crassipes) shoot powder” [Water Resour. Ind. 17 (2017) 1-6]","authors":"A.M. Sarkar , A.K.M.L. Rahman , N.C. Bhoumik","doi":"10.1016/j.wri.2022.100180","DOIUrl":"10.1016/j.wri.2022.100180","url":null,"abstract":"","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100180"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000130/pdfft?md5=c719c9d0f2b0d9a1275bf14c3ae759dc&pid=1-s2.0-S2212371722000130-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42444997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Truong M. Le , K. Kujawa-Roeleveld , Dieu T.M. Tran , Huub H.M. Rijnaarts
{"title":"Data envelopment analysis as a tool to assess the water demand minimization potential in industrial zones in the Vietnamese Delta","authors":"Truong M. Le , K. Kujawa-Roeleveld , Dieu T.M. Tran , Huub H.M. Rijnaarts","doi":"10.1016/j.wri.2022.100181","DOIUrl":"10.1016/j.wri.2022.100181","url":null,"abstract":"<div><p>This work employs the data envelopment analysis technique to assess the water use efficiency of companies and the water reduction potential of industrial categories in industrial zones. Fifty-eight companies were selected from four industrial categories: wearing apparel (<em>WA</em>,18), fabricated metal (<em>FM</em>,12), rubber and plastic (<em>RP</em>,12), and other manufacturing (<em>OM</em>,12) based on six variables: monthly water usage, two types of effluent contaminant loadings, monthly production capacity, number of employees, and surface occupied by a company. The results indicate that significant numbers of companies are inefficient in water use, namely <em>WA</em>(28%), <em>OM</em>(42%), <em>FM</em>(43%), and <em>RP</em>(46%). Implementing technical measures to improve water use efficiency at these companies offers a varying water reduction potential per industrial category, namely in the order <em>RP</em>(25%) > <em>FM</em>(17%) ≫ <em>WA</em>(7%) > <em>OM</em>(4%). These results show that improving water efficiency by water use minimization is not the only ptential measure for improving the industrial zone's water metabolism towards self-sufficiency.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100181"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000142/pdfft?md5=0b67ff18e7c63b60e02f0622cfc364ce&pid=1-s2.0-S2212371722000142-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45369579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Adrian Garrido Sanchis , Zachary J.H. Berra , Lamia Sultana , Hongxu Wang , Paul J. Hazell
{"title":"Establishing the lower thresholds for water sterilisation with shock waves and hot gas bubbles from the detonation of explosives in water","authors":"Adrian Garrido Sanchis , Zachary J.H. Berra , Lamia Sultana , Hongxu Wang , Paul J. Hazell","doi":"10.1016/j.wri.2022.100187","DOIUrl":"10.1016/j.wri.2022.100187","url":null,"abstract":"<div><p>Water sterilisation requires the inactivation of waterborne pathogens, like <em>E.coli</em>, to such low levels that its use will not cause illness. Here, we examine a potential methodology for disinfecting water through the combined effect of hot expanding gases and shock waves from underwater explosions. Water pathogens located within the proximity of the explosive charge will be exposed to two different sterilisation conditions: firstly, the high-pressure shock wave moving within the fluid, and secondly, the expanding hot N<sub>2</sub>, O<sub>2,</sub> and CO<sub>2</sub> bubbles that are products of the explosion. To simulate the first case, we used a flyer-plate technique to understand the lower threshold for inactivation. We did this with a novel capsule design in a single-stage light gas-gun and observed 0.813 Logs of <em>E.coli</em> inactivation after subjecting an entire bacterial broth to a minimum pressure of 3.53 GPa thereby indicating a lower threshold for shock pressure-induced inactivation. For the second case, we show that hot gas bubbles from different explosive gaseous products at 150°C in a bubble column established the minimum gas temperature thresholds required to successfully inactivate <em>E.coli</em>. This work shows that any benefit of using explosives to sterilise water will principally come from the release of hot gaseous bubbles rather than the effect of the shock. This new approach could be used in conflict areas or remote locations with no access to standard sterilisation technologies or power.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"28 ","pages":"Article 100187"},"PeriodicalIF":5.1,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371722000208/pdfft?md5=425b3065b6a47bfbf6ab5fce54349817&pid=1-s2.0-S2212371722000208-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44500756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}